JPS5953603A - Active sintering method of metallic chromium - Google Patents
Active sintering method of metallic chromiumInfo
- Publication number
- JPS5953603A JPS5953603A JP57162122A JP16212282A JPS5953603A JP S5953603 A JPS5953603 A JP S5953603A JP 57162122 A JP57162122 A JP 57162122A JP 16212282 A JP16212282 A JP 16212282A JP S5953603 A JPS5953603 A JP S5953603A
- Authority
- JP
- Japan
- Prior art keywords
- metallic
- salt
- sintering
- powder
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/045—Alloys based on refractory metals
Abstract
Description
【発明の詳細な説明】
本発明&J金属クロノ・の活性9y“1r、粘状に関・
すZ)ものである。更に詳t、 < )Jl、金属クロ
ノ・微粉に水溶性パラジウJ、塙水溶液を含浸させニ一
段焼結を行い、相対密度の高い金属り「1ノ、炉、粘体
を(l 2)だめの活性焼結法に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention & J Metal Chrono's activity 9y"1r, viscous...
Z). For further details, metal fine powder is impregnated with water-soluble Palladium J and Hanawa aqueous solution and sintered in two stages to form a metal with a high relative density. It concerns an activated sintering method.
金属クロJ、鋳塊シ」、非當に脆いだめ、従来、板状や
棒状に成形加ニーj/)ことは全く行わJしCいなかっ
/r−0捷た、金属クロムし11、本来高湿強度、i1
酸性。Metal chrome ingots are extremely brittle, and conventionally, they have not been formed into plate or rod shapes at all. High humidity strength, i1
Acidic.
耐食性などに優れたty゛¥性を有しており、寸だ、ニ
ッケル、コバルトなどのiI熱金合金元素比べて安価で
あることから、而1i+、3 、耐食合金の元素と17
で、あるいケ」それらの基地成分と]−21広い用途が
Fr、]’\まれている。かかる状況から金属クロI、
粉末から強度の大きい板状、棒状などの成形体を?!?
2)ため+7)焼結Yムの出現が強< ’i7旨*l
じ\れ”UいA・小発明者らV、[、叙−1−の状況に
無力、柔軟骨に富む金属クロノ、加−1′品” il
2)i−と4[1的)L −rJ 972.7’1(1
1[究した結果、金※liりtl 、lz微粉に少fi
1σ)パラソウ−2−塩を混イ)さぜ二段焼結すること
(・′(−11)、相対密lrFの高い金Jiriり1
7ノ、焼結体がイF)らノ1ノ)という知見をイ(tて
$発明所、完成17六−ものでt)/)。4−hわ1′
ン、4・発明Ii金にり11人微粉に1)溶+’lパラ
ジウム1スΔ水6行u含(’1%さ11乾燥し7た後、
1011〜4 (l nHp+(10〜40吋/−2)
で圧粉L2、とれ’ニアn [+へ・900°(ユで一
次焼結し、更に1 rl [10〜14 n IIo(
″、で二次焼結−することを’l”l徴と′才゛Z)金
属クロノ・の活性焼結法を電供するものであ/)。It has excellent corrosion resistance, etc., and is cheaper than II hot metal alloy elements such as nickel and cobalt.
So, their base components and ]-21 have a wide range of uses. Due to this situation, metal black I,
From powder to molded objects such as strong plates and rods? ! ?
2) Because +7) The appearance of sintered Y is strong<'i7effect*l
The small inventors V, helpless in the situation described above, are metal chronographs rich in flexible bones, addition 1' products.
2) i- and 4 [1] L -rJ 972.7'1 (1
1 [As a result of research, there is a small amount of gold*light, lz fine powder,
1σ) Parasol-2-salt mixture) sintering in two stages (・'(-11), gold with high relative density lrF1)
7, the knowledge that the sintered body is 1) was completed by the Inventory Institute. 4-h1'
4. Invention Ii Gold paste 11 people 1) Dissolve + 'l palladium 1 s Δ water 6 rows u ('1%) 11 After drying 7,
1011~4 (l nHp+ (10~40 inches/-2)
Press powder L2, remove the powder at +900° (primary sintering at
It is intended to provide an active sintering method for metal chlorine, which is characterized by secondary sintering.
本発明に於−で−1金属クロムJ・1.て(+1、通常
47.)金(惧り「1)、粉末が使用できるが、ilY
、解金匡り「1ノ、粉末又&1脱ガス金屈クロノ、粉末
がU「ま1.〈用いr〕れろ。c−J’1r))’、1
、+l’f+ 紳1(「f 仙(7) 4. #’l!
+141 jHl 素(71含4417J カ/[・
ないからである。この粉末t\“i ll’F 11.
1. ’$’J、小な11ど活性に畠カθrまl−、い
が、子の活t”CIl’l’ /6びにト済性等の1”
’1点上す111’l常(L 2 n? / 9 j’
l、 l、 h(41,(lJ 〔1,4□1・5 r
r? / 9の11′、表面積を有−す/、ものが用い
C1わム、この全h@クロノ、微粉に含江込)J、 Z
>水溶1’l=パラジウノ、用ノ」L、てシ(、硝酸パ
ランT゛7)1. (l’f、 (V?パラジウノ・工
水堪、用化パラジウム若り、 < &Jこの工水均など
が挙げられる。これらのパラジウムmのノド溶液添加+
?t &J、金ル[カフr’J /、微粉に添加し、両
者に汎神[7た1県に泥状となる程す(に;*17a
qi甘−4〕)。バラシラノ、塩のl1li nJ +
110、金属クロノ、に苅し7で、金に1(バラシラノ
、4イI(算05〜・2.5 [11“)チがhf庄]
2い1、こねより少iH,(7戸JJ、イ)V、1イ1
)C)れz)焼結体の相7J ’+’!’? In’
;+5叫l; IQ 的小さく充分な効果を期待し1!
トぜ、これ」、り多i)に【−1ても−そわ1゛J、1
−の動片を期待1.、イ! !ないからである。In the present invention, -1 metal chromium J.1. (+1, usually 47.) Gold (+1), powder can be used, but ilY
, Kaikin Matari ``1, Powder Mata & 1 Degassing Kinku Kurono, Powder is U ``Ma1.
, +l'f+ sen 1 (``f sen (7) 4. #'l!
+141 jHl element (71 included 4417J Ka/[・
That's because there isn't. This powdert\"i ll'F 11.
1. '$'J, small 11 etc. activation, Hatake Ka θrmal-, Iga, child's activation t"CIl'l' /6 and to finished sex etc. 1"
'1 point up 111'l always (L 2 n? / 9 j'
l, l, h(41, (lJ [1,4□1・5 r
r? / 11' of 9, has a surface area /, the thing is used C1, this whole h@chrono, fine powder contains) J, Z
>Water soluble 1'l=Paranium nitric acid T'7) 1. (l'f, (V? Palladium, Kosui-tan, practical palladium young, <&J this Kosui-Hyun, etc.). Addition of these palladium m throat solutions +
? t & J, gold [cuff r'J /, added to the fine powder, both panshin [7 and 1 prefectures become muddy (ni; *17a
qi sweet-4]). Balashirano, salt l1li nJ +
110, metal chrono, Nikarushi 7, gold 1 (Bara Shirano, 4 I (calculation 05~・2.5 [11") Chiga hf sho]
2-1, less than kone iH, (7 doors JJ, i) V, 1-1
) C) Rez) Phase 7J of sintered body '+'! '? In'
; +5 shout l; IQ 1, hoping for a small and sufficient effect!
Toze, this”, Rita i) to [-1 mo-sowa 1゛J, 1
- Expecting moving pieces 1. ,stomach! ! That's because there isn't.
金11ベク11ノ、微粉に水溶性パラジウムjバ水溶液
4含浸させるにシ」、悄J’[lのブレンダー&で、L
り混紳゛J))と−に、Lり行わわるブレンター−容器
内+ll、111シの異わ11金属の混入を避し)ノ)
た、めシラスブーツクなどによリコーデングしたもの存
用い7)ξ−ノーがrrrj+、い。Impregnate the fine powder with 4 ml of water-soluble palladium aqueous solution in a blender with
The mixture is mixed with J)) and - in the blender container +ll, 111 to avoid contamination of metals).
7) ξ-no is rrrj+, yes.
次いで、金属り「l J’% n:’l粉/7)水1キ
i件パンジソノ、]甚。Next, add 1 kg of metal powder/7) water.
水溶液の含浸物を8 f、l〜9 fl ’(:て゛加
−゛″(り1ハ・Y町【5、圧粉す1′、−結エイ゛?
に供さ71/、。Add the impregnated material with the aqueous solution to 8 f, l~9 fl'
Offered to 71/.
−l ’、 jjl、:乾t・V’ 1’、k & 1
.、圧fつ)成形用1 <、:j5’i%、!Ill
l 、 ’7’ し、、x −tl)か、才・/)いヲ
1■t−ルなど匠、L b 41J、状依′1[、延)
\わ/、0成型11力111n n−411II川)n
(I旧−4nnlr4+ /門2)で行わわイ、。-l', jjl,: dry t・V'1', k & 1
.. , pressure f) for molding 1 <,:j5'i%,! Ill
l , '7' し、、x -tl)か、さ、/)Iwo1■t-る等工、L b 41J、 Status い'1[、弄)
\wa/, 0 molding 11 force 111n n-411II river)n
(I old-4nnlr4+/gate 2).
−−一次幻゛1.結U lr【二)J、7 rl
11 〜9 11 11 ”に、 6r、l−7〈t、
175【1−・85〔1℃である、この焼結時間か、1
的1時間で左1分°Cメ・)る。→、た1、−’J!、
17iK1’iB 1 n n n 。--Primary illusion 1. Yui U lr [2) J, 7 rl
11 to 9 11 11'', 6r, l-7〈t,
175[1-85[1℃, this sintering time, 1
1 minute to the left in 1 hour. →, Ta1, -'J! ,
17iK1'iB 1 n n n .
1400°(:、好オ12<シJ、 1 [150へ
−1、’+ [1no(′、で約1時間行う。これCつ
の両’)”l、I+結]、稈t[、アルゴン。1400° (:, good o12<shiJ, 1 [to 150-1,'+ [1no(', do this for about 1 hour. This is both C')"l, I + connection], culm t[, argon .
・\ソウノ、などの不活付雰囲気中、又11−水素W囲
気中て′、型切、炉など存用い1行わJ+p)。こねに
より酸化物の生成が抑制される。・In an inert atmosphere such as \Souno, or in a 11-hydrogen W atmosphere, mold cutting, furnace, etc. are used (J+p). Kneading suppresses the formation of oxides.
か<L−r、本発明により+1’相ン1密11’l’
9 n嘴1jlの金属り「1ム焼結f+が1!IらJす
る。or<L-r, according to the present invention +1'phase-1density11'l'
9 n beak 1jl metal ``1mu sintered f+ is 1!I et al J.
4; TM Ql l tハ焼粘状を採用Jノ1げ4)
1伏、 4’S11:なノ゛σ〉強値Jな成)1そ加工
品がイl C)h、金に1眞り11ノ・(7)本来の’
Vj (’lである高?席強度、耐酸+’1.1li1
食t1に優れブンー加土品がイ(すられるものてあメ、
。4; TM Ql t has a hardened viscous form J No. 1 ge 4)
1 fall, 4'S11: な゛σ〉strong value J な生) 1 The processed product is Il C) h, 1 true to gold 11 no. (7) Original'
Vj ('l high seat strength, acid resistance +'1.1li1
Excellent food T1, Boon Kado products are good (Susuremono Teame,
.
以下、本発明を′=P:施例により更にJ(体重にH9
,明するが、俸発明CIこれに」、り何ら限定式れZう
もので11ゾrい。Hereinafter, the present invention will be described as ′=P: J (body weight and H9
However, I would like to clarify that there is no such thing as a limited expression for the invention CI.
1]ζJ〆IIイに・1
Jb表面tl’t1. n 、(7g y、有−12、
’fli、I’l’r金[・+iミクロ、粉10 (1
重附部に対[ノテ、(if’l ri”:lパ’ニア
ン’) J、217重b1部(金P’iパラジウム1ぐ
Li111重1・1部)る水2r1部に4)角了1、こ
わ、A混合[2、画?、を、1.〈渭、糸1j L、9
0℃で乾燥した。次いでξれを圧粉用金パリに入れ油圧
式シラスによ的2[] If N4■)pの圧力でIF
第5)シだ。このI[、粉IiV形(+: ’に′Il
’i’、気炉イ【用いて紳水素π囲気下で800℃に1
時加−:〜1−2、−次焼結を行い、更に1150℃で
1時間二゛次i”’1結に行つカニ11、Ill/、蔚
寺諷紳収縮率ケI、 11.3チ、イ;Iられ7′7−
焼1結併の相対密m′は90チて、柔軟性に爪むもので
才・Z)ことが明らかとなっプロ
比申立例1
硝酸バラシラノ、用水溶液を含浸Δ、)」−ず、5に4
1イU例1と同様に実施1−2だ結果、線収縮率は5.
5係、書Cっれた焼結体の相幻密庶は76メでオ)す、
実施例1rノ)す’:’、結体と粘体つし2−テ6、柔
軟(’目t ’!5 /1 ? 、 ) 、/、i 1
lll (、か)な−)/こ。1]ζJ〆IIii・1 Jb surface tl't1. n, (7g y, y-12,
'fli, I'l'r gold [・+i micro, powder 10 (1
For the heavy division [note, (if'l ri":l pa'nia
N') J, 1 part of 217 weight b (gold P'i 1 palladium, 1.1 part of Li 111 weight) to 2r 1 part of water 4) Corner 1, stiff, A mixture [2, picture? , 1. <渭、Ito 1j L、9
It was dried at 0°C. Next, put the ξ into a powder compaction plate and press it with a hydraulic shirasu at a pressure of 2[] If N4■) p.
5th) It's shi. This I[, powder IiV form (+: 'to'Il
'i', air furnace I
Temperature: ~1-2, -Next sintering, and then second I'''1 sintering at 1150°C for 1 hour. 3chi, i;Ire7'7-
It is clear that the relative density m' of sintering is 90 cm, which is difficult for flexibility. 4
1-U Example 1-2 was carried out in the same manner as in Example 1. As a result, the linear shrinkage rate was 5.
Section 5, the sintered body with the letter C written on it is 76 meters.
Example 1r)su':', Concretion and viscous body 2-te6, Softness ('me t'!5/1?, ), /, i 1
lll (,ka)na-)/ko.
” /7iii 1列2〜・ 12
実ji’ifl 1 pt i′1/(じテ、 Fp、
1 (y、+に承・4条イ′Iσ)Iに、金1・j(
りn jb WW粉(?水n1件バラジウI、」;1S
水溶静、4含浸さ−1、−q旧1“11、結及び工法焼
結を行−)t(。ifi+i ’lηj1;率及び得ら
)B’i−焼結体の相”tl ’flT li−’at
i’% 1壱に7i−J、。/7iii 1 row 2~・12 ji'ifl 1 pt i'1/(jite, Fp,
1 (y, + to jo・4 article a′Iσ) I, gold 1・j (
Rin jb WW powder (?Water n1 item barajiu I,'';1S
water solution, 4 impregnated -1, -q old 1 "11, perform sintering and method sintering -)t(.ifi+i'lηj1; rate and obtained)B'i-phase of sintered body"tl 'flT li-'at
i'% 1 to 7i-J.
第 19゛1
比較例2〜・4
第2表に示す条件の下に、金lIsり1−t 、/、微
粉末W1水浴P1バラジウノ、水溶液を・含7..%
7N +4 ・J’、−’′/jfi 例2゜7及び1
1に準じて、−(p:焼結及び二次包「、結に1l−)
fr。、v’+’ 収縮率及r)’ (!t I’)
I+ /: ・h7、結体ノ相’?l Vi′!度1<
9112衣に示−す。No. 19゛1 Comparative Examples 2 to 4 Under the conditions shown in Table 2, gold lIs 1-t, fine powder W1, water bath P1, and aqueous solution were added.7. .. %
7N +4 ・J', -''/jfi Example 2゜7 and 1
According to 1, - (p: sintered and secondary packaging ", 1l -)
fr. , v'+' shrinkage rate and r)' (!t I')
I+ /: ・h7, cohesion phase'? l Vi′! degree 1<
Shown on 9112 clothes.
gF、 2 %’4 特許出願人 東洋曹達1’青−株式会社ほか1名 19gF, 2%’4 Patent applicant: Toyo Soda 1'Ao - Co., Ltd. and 1 other person 19
Claims (2)
ノ、塩水溶液を含浸さヒ、乾t′1・し7/・・後、j
II E+−4El’ tl氷416(10〜40に
9/宵−)で月15N、、こJ)イ1−700〜901
1℃で一次$、l’Mシ目7、史(クニ10 n +1
〜1400°(じで二次焼結′1′Z・ξとを′ll:
?’、1ノーする金属クロムの活性焼結法。(1) Kanai + 7, fine powder impregnated with water-soluble para,; Uno, salt aqueous solution, dried t'1, 7/..., then j
II E+-4El' tl ice 416 (10-40 9/evening-) a month 15N,, Ko J) I1-700-901
At 1℃, primary $, l'M seam 7, history (kuni 10 n +1
~1400° (secondary sintering '1'Z and ξ'll:
? 1. Active sintering method for metal chromium.
ジウム、硫酸パラジウノ、工水基又シロ名に化バノ。!
ラム若し1、Lコc7)工水L’s、 fあル4”F
it’ Ri’l求c/+ (Fat 囲r■s at
JFiに記載の金属り[1)、活性焼に1’r ?、
+80(1)金属り「1ムに月1.で、金用パラジウノ
、換9IT、 5〜25重r74チの水溶1′1パラジ
ウム川水溶液を含浸さ4J−る特許請求の範囲第(1)
項又v1第(9川百G・(−記4.砲の全F11り[1
)・の活性)直結法2、(4) fl、 2 nl/
り」+1、上の比!、′−,面積を有する金属りt1ノ
・微粉をIllいZ)’I−′rn’f’ Ii7求の
範囲f(’、 fll珀からfP、(3) にqのい1
れかの項姓−泥載の全1iヘク!1人の活性焼結法。、(2) Is jsH nitrate 11' in water-soluble barajiuno? Pandium, palladium sulfate, chemical water base, also known as kabano. !
Ram 1, Lko c7) Industrial water L's, 4"F
it'Ri'l search c/+ (Fat enclosure r■s at
The metal paste described in JFi [1], 1'r for activated firing? ,
+80 (1) Metallic material impregnated with 4J of aqueous 1'1 palladium solution containing 5 to 25 weight r74 of palladium for gold at 1 month per month.Claim No. (1)
Item v1 No. 9 River 100G (-4. All F11 guns [1
)・Activity) Direct connection method 2, (4) fl, 2 nl/
ri”+1, the above ratio! , '-, the area of metal t1 is IlliZ)'I-'rn'f'
Reka's surname - All 1i heku of mud! Activated sintering method for one person. ,
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57162122A JPS5953603A (en) | 1982-09-20 | 1982-09-20 | Active sintering method of metallic chromium |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57162122A JPS5953603A (en) | 1982-09-20 | 1982-09-20 | Active sintering method of metallic chromium |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5953603A true JPS5953603A (en) | 1984-03-28 |
JPS6330978B2 JPS6330978B2 (en) | 1988-06-21 |
Family
ID=15748452
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP57162122A Granted JPS5953603A (en) | 1982-09-20 | 1982-09-20 | Active sintering method of metallic chromium |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5953603A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63164683A (en) * | 1986-12-26 | 1988-07-08 | Hitachi Ltd | Long time operation magnetic recording and reproducing device |
JPS63280583A (en) * | 1987-05-13 | 1988-11-17 | Hitachi Ltd | Intermittent magnetic recording and reproducing device |
JPS63280584A (en) * | 1987-05-13 | 1988-11-17 | Hitachi Ltd | Time lapse system magnetic recorder |
JPS63283286A (en) * | 1987-05-15 | 1988-11-21 | Hitachi Ltd | Time lapse type magnetic recording device |
JPS63283285A (en) * | 1987-05-15 | 1988-11-21 | Hitachi Ltd | Intermittent magnetic sound and picture recording device |
JPS6477285A (en) * | 1987-09-18 | 1989-03-23 | Hitachi Ltd | Time lapse system magnetic playback device |
-
1982
- 1982-09-20 JP JP57162122A patent/JPS5953603A/en active Granted
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63164683A (en) * | 1986-12-26 | 1988-07-08 | Hitachi Ltd | Long time operation magnetic recording and reproducing device |
JPS63280583A (en) * | 1987-05-13 | 1988-11-17 | Hitachi Ltd | Intermittent magnetic recording and reproducing device |
JPS63280584A (en) * | 1987-05-13 | 1988-11-17 | Hitachi Ltd | Time lapse system magnetic recorder |
JPS63283286A (en) * | 1987-05-15 | 1988-11-21 | Hitachi Ltd | Time lapse type magnetic recording device |
JPS63283285A (en) * | 1987-05-15 | 1988-11-21 | Hitachi Ltd | Intermittent magnetic sound and picture recording device |
JPS6477285A (en) * | 1987-09-18 | 1989-03-23 | Hitachi Ltd | Time lapse system magnetic playback device |
Also Published As
Publication number | Publication date |
---|---|
JPS6330978B2 (en) | 1988-06-21 |
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