JPS5953603A - Active sintering method of metallic chromium - Google Patents

Active sintering method of metallic chromium

Info

Publication number
JPS5953603A
JPS5953603A JP57162122A JP16212282A JPS5953603A JP S5953603 A JPS5953603 A JP S5953603A JP 57162122 A JP57162122 A JP 57162122A JP 16212282 A JP16212282 A JP 16212282A JP S5953603 A JPS5953603 A JP S5953603A
Authority
JP
Japan
Prior art keywords
metallic
salt
sintering
powder
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP57162122A
Other languages
Japanese (ja)
Other versions
JPS6330978B2 (en
Inventor
Yoshimichi Masuda
増田 良道
Ryuzo Watanabe
渡辺 龍三
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tosoh Corp
Original Assignee
Toyo Soda Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Soda Manufacturing Co Ltd filed Critical Toyo Soda Manufacturing Co Ltd
Priority to JP57162122A priority Critical patent/JPS5953603A/en
Publication of JPS5953603A publication Critical patent/JPS5953603A/en
Publication of JPS6330978B2 publication Critical patent/JPS6330978B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/045Alloys based on refractory metals

Abstract

PURPOSE:To obtain a sintered body of active metallic Cr having high relative density by impregnating an aq. soln. of water soluble Pd salt to the pulverized powder of metallic Cr and compacting the powder under prescribed pressure after drying then raising temp. in two stages and sintering the green compact. CONSTITUTION:Water soluble Pd salt [e.g.; Pd(NO3)2] is impregnated in the pulverized powder of metallic Cr which is preferably the powder of electrolytic metallic Cr or degassed metallic Cr and has usually >=0.2m<2>/g, more specifically, 0.4-1.5m<2>/g specific surface area. The Pd salt in this case is used in the form of an aq. soln., and the amt. of the Pd salt to be added is adjusted to the extent at which the pulverized powder of the metallic Cr becomes muddy when said salt is added and both are kneaded. The amt. of the Pd salt to be used with respect to the metallic Cr is preferably 0.5-2.5wt% in terms of the metallic Cr. The pulverized powder of the metallic Cr impregnated with the Pd salt is dried by heating at 80-90 deg.C and is compacted under 100-400kg/mm.<2> molding pressure. The green compact is subjected to a primary sintering at 700-900 deg.C followed by a secondary sintering at 1,000-1,400 deg.C, whereby the intended activated metallic Cr is obtd. The sintering is accomplished in an inert atmosphere of Ar, He, etc. or in an H2 atmosphere.

Description

【発明の詳細な説明】 本発明&J金属クロノ・の活性9y“1r、粘状に関・
すZ)ものである。更に詳t、 < )Jl、金属クロ
ノ・微粉に水溶性パラジウJ、塙水溶液を含浸させニ一
段焼結を行い、相対密度の高い金属り「1ノ、炉、粘体
を(l 2)だめの活性焼結法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention & J Metal Chrono's activity 9y"1r, viscous...
Z). For further details, metal fine powder is impregnated with water-soluble Palladium J and Hanawa aqueous solution and sintered in two stages to form a metal with a high relative density. It concerns an activated sintering method.

金属クロJ、鋳塊シ」、非當に脆いだめ、従来、板状や
棒状に成形加ニーj/)ことは全く行わJしCいなかっ
/r−0捷た、金属クロムし11、本来高湿強度、i1
酸性。
Metal chrome ingots are extremely brittle, and conventionally, they have not been formed into plate or rod shapes at all. High humidity strength, i1
Acidic.

耐食性などに優れたty゛¥性を有しており、寸だ、ニ
ッケル、コバルトなどのiI熱金合金元素比べて安価で
あることから、而1i+、3 、耐食合金の元素と17
で、あるいケ」それらの基地成分と]−21広い用途が
Fr、]’\まれている。かかる状況から金属クロI、
粉末から強度の大きい板状、棒状などの成形体を?!?
 2)ため+7)焼結Yムの出現が強< ’i7旨*l
じ\れ”UいA・小発明者らV、[、叙−1−の状況に
無力、柔軟骨に富む金属クロノ、加−1′品” il 
2)i−と4[1的)L −rJ 972.7’1(1
1[究した結果、金※liりtl 、lz微粉に少fi
1σ)パラソウ−2−塩を混イ)さぜ二段焼結すること
(・′(−11)、相対密lrFの高い金Jiriり1
7ノ、焼結体がイF)らノ1ノ)という知見をイ(tて
$発明所、完成17六−ものでt)/)。4−hわ1′
ン、4・発明Ii金にり11人微粉に1)溶+’lパラ
ジウム1スΔ水6行u含(’1%さ11乾燥し7た後、
1011〜4 (l nHp+(10〜40吋/−2)
で圧粉L2、とれ’ニアn [+へ・900°(ユで一
次焼結し、更に1 rl [10〜14 n IIo(
″、で二次焼結−することを’l”l徴と′才゛Z)金
属クロノ・の活性焼結法を電供するものであ/)。
It has excellent corrosion resistance, etc., and is cheaper than II hot metal alloy elements such as nickel and cobalt.
So, their base components and ]-21 have a wide range of uses. Due to this situation, metal black I,
From powder to molded objects such as strong plates and rods? ! ?
2) Because +7) The appearance of sintered Y is strong<'i7effect*l
The small inventors V, helpless in the situation described above, are metal chronographs rich in flexible bones, addition 1' products.
2) i- and 4 [1] L -rJ 972.7'1 (1
1 [As a result of research, there is a small amount of gold*light, lz fine powder,
1σ) Parasol-2-salt mixture) sintering in two stages (・'(-11), gold with high relative density lrF1)
7, the knowledge that the sintered body is 1) was completed by the Inventory Institute. 4-h1'
4. Invention Ii Gold paste 11 people 1) Dissolve + 'l palladium 1 s Δ water 6 rows u ('1%) 11 After drying 7,
1011~4 (l nHp+ (10~40 inches/-2)
Press powder L2, remove the powder at +900° (primary sintering at
It is intended to provide an active sintering method for metal chlorine, which is characterized by secondary sintering.

本発明に於−で−1金属クロムJ・1.て(+1、通常
47.)金(惧り「1)、粉末が使用できるが、ilY
、解金匡り「1ノ、粉末又&1脱ガス金屈クロノ、粉末
がU「ま1.〈用いr〕れろ。c−J’1r))’、1
、+l’f+ 紳1(「f 仙(7) 4. #’l!
 +141 jHl 素(71含4417J カ/[・
ないからである。この粉末t\“i ll’F 11.
1. ’$’J、小な11ど活性に畠カθrまl−、い
が、子の活t”CIl’l’ /6びにト済性等の1”
’1点上す111’l常(L 2 n? / 9 j’
l、 l、 h(41,(lJ 〔1,4□1・5 r
r? / 9の11′、表面積を有−す/、ものが用い
C1わム、この全h@クロノ、微粉に含江込)J、 Z
>水溶1’l=パラジウノ、用ノ」L、てシ(、硝酸パ
ランT゛7)1. (l’f、 (V?パラジウノ・工
水堪、用化パラジウム若り、 < &Jこの工水均など
が挙げられる。これらのパラジウムmのノド溶液添加+
?t &J、金ル[カフr’J /、微粉に添加し、両
者に汎神[7た1県に泥状となる程す(に;*17a 
qi甘−4〕)。バラシラノ、塩のl1li nJ +
110、金属クロノ、に苅し7で、金に1(バラシラノ
、4イI(算05〜・2.5 [11“)チがhf庄]
2い1、こねより少iH,(7戸JJ、イ)V、1イ1
)C)れz)焼結体の相7J ’+’!’? In’ 
;+5叫l; IQ 的小さく充分な効果を期待し1!
トぜ、これ」、り多i)に【−1ても−そわ1゛J、1
−の動片を期待1.、イ! !ないからである。
In the present invention, -1 metal chromium J.1. (+1, usually 47.) Gold (+1), powder can be used, but ilY
, Kaikin Matari ``1, Powder Mata & 1 Degassing Kinku Kurono, Powder is U ``Ma1.
, +l'f+ sen 1 (``f sen (7) 4. #'l!
+141 jHl element (71 included 4417J Ka/[・
That's because there isn't. This powdert\"i ll'F 11.
1. '$'J, small 11 etc. activation, Hatake Ka θrmal-, Iga, child's activation t"CIl'l' /6 and to finished sex etc. 1"
'1 point up 111'l always (L 2 n? / 9 j'
l, l, h(41, (lJ [1,4□1・5 r
r? / 11' of 9, has a surface area /, the thing is used C1, this whole h@chrono, fine powder contains) J, Z
>Water soluble 1'l=Paranium nitric acid T'7) 1. (l'f, (V? Palladium, Kosui-tan, practical palladium young, <&J this Kosui-Hyun, etc.). Addition of these palladium m throat solutions +
? t & J, gold [cuff r'J /, added to the fine powder, both panshin [7 and 1 prefectures become muddy (ni; *17a
qi sweet-4]). Balashirano, salt l1li nJ +
110, metal chrono, Nikarushi 7, gold 1 (Bara Shirano, 4 I (calculation 05~・2.5 [11") Chiga hf sho]
2-1, less than kone iH, (7 doors JJ, i) V, 1-1
) C) Rez) Phase 7J of sintered body '+'! '? In'
; +5 shout l; IQ 1, hoping for a small and sufficient effect!
Toze, this”, Rita i) to [-1 mo-sowa 1゛J, 1
- Expecting moving pieces 1. ,stomach! ! That's because there isn't.

金11ベク11ノ、微粉に水溶性パラジウムjバ水溶液
4含浸させるにシ」、悄J’[lのブレンダー&で、L
り混紳゛J))と−に、Lり行わわるブレンター−容器
内+ll、111シの異わ11金属の混入を避し)ノ)
た、めシラスブーツクなどによリコーデングしたもの存
用い7)ξ−ノーがrrrj+、い。
Impregnate the fine powder with 4 ml of water-soluble palladium aqueous solution in a blender with
The mixture is mixed with J)) and - in the blender container +ll, 111 to avoid contamination of metals).
7) ξ-no is rrrj+, yes.

次いで、金属り「l J’% n:’l粉/7)水1キ
i件パンジソノ、]甚。
Next, add 1 kg of metal powder/7) water.

水溶液の含浸物を8 f、l〜9 fl ’(:て゛加
−゛″(り1ハ・Y町【5、圧粉す1′、−結エイ゛?
に供さ71/、。
Add the impregnated material with the aqueous solution to 8 f, l~9 fl'
Offered to 71/.

−l ’、 jjl、:乾t・V’ 1’、k & 1
.、圧fつ)成形用1 <、:j5’i%、!Ill 
l 、 ’7’ し、、x −tl)か、才・/)いヲ
1■t−ルなど匠、L b 41J、状依′1[、延)
\わ/、0成型11力111n n−411II川)n
 (I旧−4nnlr4+ /門2)で行わわイ、。
-l', jjl,: dry t・V'1', k & 1
.. , pressure f) for molding 1 <,:j5'i%,! Ill
l , '7' し、、x -tl)か、さ、/)Iwo1■t-る等工、L b 41J、 Status い'1[、弄)
\wa/, 0 molding 11 force 111n n-411II river)n
(I old-4nnlr4+/gate 2).

−−一次幻゛1.結U lr【二)J、7  rl  
11 〜9 11 11 ”に、 6r、l−7〈t、
175【1−・85〔1℃である、この焼結時間か、1
的1時間で左1分°Cメ・)る。→、た1、−’J!、
17iK1’iB 1 n n n 。
--Primary illusion 1. Yui U lr [2) J, 7 rl
11 to 9 11 11'', 6r, l-7〈t,
175[1-85[1℃, this sintering time, 1
1 minute to the left in 1 hour. →, Ta1, -'J! ,
17iK1'iB 1 n n n .

1400°(:、好オ12<シJ、 1  [150へ
−1、’+ [1no(′、で約1時間行う。これCつ
の両’)”l、I+結]、稈t[、アルゴン。
1400° (:, good o12<shiJ, 1 [to 150-1,'+ [1no(', do this for about 1 hour. This is both C')"l, I + connection], culm t[, argon .

・\ソウノ、などの不活付雰囲気中、又11−水素W囲
気中て′、型切、炉など存用い1行わJ+p)。こねに
より酸化物の生成が抑制される。
・In an inert atmosphere such as \Souno, or in a 11-hydrogen W atmosphere, mold cutting, furnace, etc. are used (J+p). Kneading suppresses the formation of oxides.

か<L−r、本発明により+1’相ン1密11’l’ 
9 n嘴1jlの金属り「1ム焼結f+が1!IらJす
る。
or<L-r, according to the present invention +1'phase-1density11'l'
9 n beak 1jl metal ``1mu sintered f+ is 1!I et al J.

4; TM Ql l tハ焼粘状を採用Jノ1げ4)
1伏、 4’S11:なノ゛σ〉強値Jな成)1そ加工
品がイl C)h、金に1眞り11ノ・(7)本来の’
Vj (’lである高?席強度、耐酸+’1.1li1
食t1に優れブンー加土品がイ(すられるものてあメ、
4; TM Ql t has a hardened viscous form J No. 1 ge 4)
1 fall, 4'S11: な゛σ〉strong value J な生) 1 The processed product is Il C) h, 1 true to gold 11 no. (7) Original'
Vj ('l high seat strength, acid resistance +'1.1li1
Excellent food T1, Boon Kado products are good (Susuremono Teame,
.

以下、本発明を′=P:施例により更にJ(体重にH9
,明するが、俸発明CIこれに」、り何ら限定式れZう
もので11ゾrい。
Hereinafter, the present invention will be described as ′=P: J (body weight and H9
However, I would like to clarify that there is no such thing as a limited expression for the invention CI.

1]ζJ〆IIイに・1 Jb表面tl’t1. n 、(7g y、有−12、
’fli、I’l’r金[・+iミクロ、粉10 (1
重附部に対[ノテ、(if’l ri”:lパ’ニア 
ン’) J、217重b1部(金P’iパラジウム1ぐ
Li111重1・1部)る水2r1部に4)角了1、こ
わ、A混合[2、画?、を、1.〈渭、糸1j L、9
0℃で乾燥した。次いでξれを圧粉用金パリに入れ油圧
式シラスによ的2[] If N4■)pの圧力でIF
第5)シだ。このI[、粉IiV形(+: ’に′Il
’i’、気炉イ【用いて紳水素π囲気下で800℃に1
時加−:〜1−2、−次焼結を行い、更に1150℃で
1時間二゛次i”’1結に行つカニ11、Ill/、蔚
寺諷紳収縮率ケI、 11.3チ、イ;Iられ7′7−
焼1結併の相対密m′は90チて、柔軟性に爪むもので
才・Z)ことが明らかとなっプロ 比申立例1 硝酸バラシラノ、用水溶液を含浸Δ、)」−ず、5に4
1イU例1と同様に実施1−2だ結果、線収縮率は5.
5係、書Cっれた焼結体の相幻密庶は76メでオ)す、
実施例1rノ)す’:’、結体と粘体つし2−テ6、柔
軟(’目t ’!5 /1 ? 、 ) 、/、i 1
lll (、か)な−)/こ。
1]ζJ〆IIii・1 Jb surface tl't1. n, (7g y, y-12,
'fli, I'l'r gold [・+i micro, powder 10 (1
For the heavy division [note, (if'l ri":l pa'nia
N') J, 1 part of 217 weight b (gold P'i 1 palladium, 1.1 part of Li 111 weight) to 2r 1 part of water 4) Corner 1, stiff, A mixture [2, picture? , 1. <渭、Ito 1j L、9
It was dried at 0°C. Next, put the ξ into a powder compaction plate and press it with a hydraulic shirasu at a pressure of 2[] If N4■) p.
5th) It's shi. This I[, powder IiV form (+: 'to'Il
'i', air furnace I
Temperature: ~1-2, -Next sintering, and then second I'''1 sintering at 1150°C for 1 hour. 3chi, i;Ire7'7-
It is clear that the relative density m' of sintering is 90 cm, which is difficult for flexibility. 4
1-U Example 1-2 was carried out in the same manner as in Example 1. As a result, the linear shrinkage rate was 5.
Section 5, the sintered body with the letter C written on it is 76 meters.
Example 1r)su':', Concretion and viscous body 2-te6, Softness ('me t'!5/1?, ), /, i 1
lll (,ka)na-)/ko.

” /7iii 1列2〜・ 12 実ji’ifl 1 pt i′1/(じテ、 Fp、
 1 (y、+に承・4条イ′Iσ)Iに、金1・j(
りn jb WW粉(?水n1件バラジウI、」;1S
水溶静、4含浸さ−1、−q旧1“11、結及び工法焼
結を行−)t(。ifi+i ’lηj1;率及び得ら
)B’i−焼結体の相”tl ’flT li−’at
i’% 1壱に7i−J、。
/7iii 1 row 2~・12 ji'ifl 1 pt i'1/(jite, Fp,
1 (y, + to jo・4 article a′Iσ) I, gold 1・j (
Rin jb WW powder (?Water n1 item barajiu I,'';1S
water solution, 4 impregnated -1, -q old 1 "11, perform sintering and method sintering -)t(.ifi+i'lηj1; rate and obtained)B'i-phase of sintered body"tl 'flT li-'at
i'% 1 to 7i-J.

第  19゛1 比較例2〜・4 第2表に示す条件の下に、金lIsり1−t 、/、微
粉末W1水浴P1バラジウノ、水溶液を・含7..% 
7N +4 ・J’、−’′/jfi 例2゜7及び1
1に準じて、−(p:焼結及び二次包「、結に1l−)
fr。、v’+’ 収縮率及r)’ (!t I’) 
I+ /: ・h7、結体ノ相’?l Vi′!度1<
9112衣に示−す。
No. 19゛1 Comparative Examples 2 to 4 Under the conditions shown in Table 2, gold lIs 1-t, fine powder W1, water bath P1, and aqueous solution were added.7. .. %
7N +4 ・J', -''/jfi Example 2゜7 and 1
According to 1, - (p: sintered and secondary packaging ", 1l -)
fr. , v'+' shrinkage rate and r)' (!t I')
I+ /: ・h7, cohesion phase'? l Vi′! degree 1<
Shown on 9112 clothes.

gF、  2  %’4 特許出願人 東洋曹達1’青−株式会社ほか1名 19gF, 2%’4 Patent applicant: Toyo Soda 1'Ao - Co., Ltd. and 1 other person 19

Claims (2)

【特許請求の範囲】[Claims] (1)  金居りj+ 7、微粉に水溶性パラ・、;ウ
ノ、塩水溶液を含浸さヒ、乾t′1・し7/・・後、j
 II E+−4El’ tl氷416(10〜40に
9/宵−)で月15N、、こJ)イ1−700〜901
1℃で一次$、l’Mシ目7、史(クニ10 n +1
〜1400°(じで二次焼結′1′Z・ξとを′ll:
 ?’、1ノーする金属クロムの活性焼結法。
(1) Kanai + 7, fine powder impregnated with water-soluble para,; Uno, salt aqueous solution, dried t'1, 7/..., then j
II E+-4El' tl ice 416 (10-40 9/evening-) a month 15N,, Ko J) I1-700-901
At 1℃, primary $, l'M seam 7, history (kuni 10 n +1
~1400° (secondary sintering '1'Z and ξ'll:
? 1. Active sintering method for metal chromium.
(2)  水溶性バラジウノ、jsHが硝11′?パン
ジウム、硫酸パラジウノ、工水基又シロ名に化バノ。!
ラム若し1、Lコc7)工水L’s、 fあル4”F 
it’ Ri’l求c/+ (Fat 囲r■s at
 JFiに記載の金属り[1)、活性焼に1’r ?、
+80(1)金属り「1ムに月1.で、金用パラジウノ
、換9IT、 5〜25重r74チの水溶1′1パラジ
ウム川水溶液を含浸さ4J−る特許請求の範囲第(1)
項又v1第(9川百G・(−記4.砲の全F11り[1
)・の活性)直結法2、(4)  fl、 2 nl/
り」+1、上の比!、′−,面積を有する金属りt1ノ
・微粉をIllいZ)’I−′rn’f’ Ii7求の
範囲f(’、 fll珀からfP、(3) にqのい1
れかの項姓−泥載の全1iヘク!1人の活性焼結法。、
(2) Is jsH nitrate 11' in water-soluble barajiuno? Pandium, palladium sulfate, chemical water base, also known as kabano. !
Ram 1, Lko c7) Industrial water L's, 4"F
it'Ri'l search c/+ (Fat enclosure r■s at
The metal paste described in JFi [1], 1'r for activated firing? ,
+80 (1) Metallic material impregnated with 4J of aqueous 1'1 palladium solution containing 5 to 25 weight r74 of palladium for gold at 1 month per month.Claim No. (1)
Item v1 No. 9 River 100G (-4. All F11 guns [1
)・Activity) Direct connection method 2, (4) fl, 2 nl/
ri”+1, the above ratio! , '-, the area of metal t1 is IlliZ)'I-'rn'f'
Reka's surname - All 1i heku of mud! Activated sintering method for one person. ,
JP57162122A 1982-09-20 1982-09-20 Active sintering method of metallic chromium Granted JPS5953603A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57162122A JPS5953603A (en) 1982-09-20 1982-09-20 Active sintering method of metallic chromium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57162122A JPS5953603A (en) 1982-09-20 1982-09-20 Active sintering method of metallic chromium

Publications (2)

Publication Number Publication Date
JPS5953603A true JPS5953603A (en) 1984-03-28
JPS6330978B2 JPS6330978B2 (en) 1988-06-21

Family

ID=15748452

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57162122A Granted JPS5953603A (en) 1982-09-20 1982-09-20 Active sintering method of metallic chromium

Country Status (1)

Country Link
JP (1) JPS5953603A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63164683A (en) * 1986-12-26 1988-07-08 Hitachi Ltd Long time operation magnetic recording and reproducing device
JPS63280583A (en) * 1987-05-13 1988-11-17 Hitachi Ltd Intermittent magnetic recording and reproducing device
JPS63280584A (en) * 1987-05-13 1988-11-17 Hitachi Ltd Time lapse system magnetic recorder
JPS63283286A (en) * 1987-05-15 1988-11-21 Hitachi Ltd Time lapse type magnetic recording device
JPS63283285A (en) * 1987-05-15 1988-11-21 Hitachi Ltd Intermittent magnetic sound and picture recording device
JPS6477285A (en) * 1987-09-18 1989-03-23 Hitachi Ltd Time lapse system magnetic playback device

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63164683A (en) * 1986-12-26 1988-07-08 Hitachi Ltd Long time operation magnetic recording and reproducing device
JPS63280583A (en) * 1987-05-13 1988-11-17 Hitachi Ltd Intermittent magnetic recording and reproducing device
JPS63280584A (en) * 1987-05-13 1988-11-17 Hitachi Ltd Time lapse system magnetic recorder
JPS63283286A (en) * 1987-05-15 1988-11-21 Hitachi Ltd Time lapse type magnetic recording device
JPS63283285A (en) * 1987-05-15 1988-11-21 Hitachi Ltd Intermittent magnetic sound and picture recording device
JPS6477285A (en) * 1987-09-18 1989-03-23 Hitachi Ltd Time lapse system magnetic playback device

Also Published As

Publication number Publication date
JPS6330978B2 (en) 1988-06-21

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