JPS5939182B2 - 触媒活性化の方法 - Google Patents
触媒活性化の方法Info
- Publication number
- JPS5939182B2 JPS5939182B2 JP52008596A JP859677A JPS5939182B2 JP S5939182 B2 JPS5939182 B2 JP S5939182B2 JP 52008596 A JP52008596 A JP 52008596A JP 859677 A JP859677 A JP 859677A JP S5939182 B2 JPS5939182 B2 JP S5939182B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- temperature
- nickel
- copper
- silica
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims description 71
- 238000000034 method Methods 0.000 title claims description 33
- 230000004913 activation Effects 0.000 title description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 40
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
- 229910052759 nickel Inorganic materials 0.000 claims description 17
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 239000010949 copper Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000002243 precursor Substances 0.000 claims description 5
- 230000003213 activating effect Effects 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 4
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
- -1 silicic acid ions Chemical class 0.000 claims 2
- 150000002500 ions Chemical class 0.000 claims 1
- 229910000652 nickel hydride Inorganic materials 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 238000005984 hydrogenation reaction Methods 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000007789 gas Substances 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000005909 Kieselgur Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
- C10G49/04—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/392—Metal surface area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US65469376A | 1976-02-02 | 1976-02-02 | |
| US000000654693 | 1976-02-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5294890A JPS5294890A (en) | 1977-08-09 |
| JPS5939182B2 true JPS5939182B2 (ja) | 1984-09-21 |
Family
ID=24625877
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP52008596A Expired JPS5939182B2 (ja) | 1976-02-02 | 1977-01-28 | 触媒活性化の方法 |
Country Status (10)
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU774584A1 (ru) * | 1978-01-05 | 1980-10-30 | Предприятие П/Я А-7531 | Способ активации катализатора |
| DK144996C (da) * | 1980-05-19 | 1982-12-20 | Haldor Topsoe As | Fremgangsmaade ved udfoerelse af katalytiske eksoterme gasfaseprocesser og fremgangsmaade til fremstilling af en katalysator dertil |
| GB2280618A (en) * | 1993-07-28 | 1995-02-08 | Exxon Chemical Patents Inc | Activating catalysts |
| EP2380953A1 (en) * | 2010-04-22 | 2011-10-26 | BASF Corporation | Hydrogenation of fatty acids using a promoted supported nickel catalyst |
| KR20210001784A (ko) | 2019-06-28 | 2021-01-06 | 한화솔루션 주식회사 | 수소화반응용 촉매 및 그 제조방법 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3868332A (en) * | 1970-10-26 | 1975-02-25 | Exxon Research Engineering Co | Massive nickel catalysts |
| AU511696B2 (en) * | 1975-05-14 | 1980-09-04 | Exxon Research And Engineering Company | Supported Cuni-Sio2 catalyst for hydrogenation |
-
1977
- 1977-01-18 CA CA269,936A patent/CA1080685A/en not_active Expired
- 1977-01-20 AU AU21494/77A patent/AU514928B2/en not_active Expired
- 1977-01-21 DE DE19772702327 patent/DE2702327A1/de active Granted
- 1977-01-25 GB GB2974/77A patent/GB1574389A/en not_active Expired
- 1977-01-28 JP JP52008596A patent/JPS5939182B2/ja not_active Expired
- 1977-02-01 BE BE174555A patent/BE850966A/xx not_active IP Right Cessation
- 1977-02-01 BR BR7700626A patent/BR7700626A/pt unknown
- 1977-02-01 IT IT19855/77A patent/IT1080316B/it active
- 1977-02-01 FR FR7702761A patent/FR2339432A1/fr active Granted
- 1977-02-02 NL NL7701077A patent/NL7701077A/xx not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| FR2339432A1 (fr) | 1977-08-26 |
| IT1080316B (it) | 1985-05-16 |
| JPS5294890A (en) | 1977-08-09 |
| NL7701077A (nl) | 1977-08-04 |
| BE850966A (fr) | 1977-08-01 |
| DE2702327A1 (de) | 1977-08-04 |
| FR2339432B1 (US20100154137A1-20100624-C00004.png) | 1983-10-07 |
| AU2149477A (en) | 1978-07-27 |
| AU514928B2 (en) | 1981-03-05 |
| DE2702327C2 (US20100154137A1-20100624-C00004.png) | 1987-07-30 |
| BR7700626A (pt) | 1977-10-04 |
| GB1574389A (en) | 1980-09-03 |
| CA1080685A (en) | 1980-07-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5198592A (en) | Hydrogenolysis reaction and catalyst suitable therefor | |
| US4088603A (en) | Catalyst activation process | |
| EP0123517B1 (en) | Vapour phase hydrogenation of esters | |
| JP4345038B2 (ja) | 不飽和化合物の選択的水素化方法 | |
| CA2470945A1 (en) | Regeneration of catalysts for carbon monoxide hydrogenation | |
| JPS58216131A (ja) | カルボン酸エステルの水素化分解によるアルコ−ルの接触製造方法 | |
| JPS6156139A (ja) | ニツケルと錫、ゲルマニウムまたは鉛とを含有する触媒の存在下におけるカルボン酸エステルの水素化分解によるアルコールの製造方法 | |
| CN1244446A (zh) | 有机化合物转化反应中可使用的载体上的催化剂 | |
| EP0120122A2 (en) | Hydrogenation of long chain olefinic oils with Raney catalyst | |
| JPH07112545B2 (ja) | 触媒の製造方法 | |
| US4855267A (en) | Regeneration of methanol dissociation catalysts | |
| CA2472607A1 (en) | Catalyst enhancement | |
| US3668148A (en) | Catalyst prepared by homogeneous precipitation under high temperature and pressure | |
| JPH0376789A (ja) | 液状炭化水素中の砒素および燐除去用の捕集物質、その製造方法およびその使用法 | |
| Choi et al. | XAFS study of tin modification of supported palladium catalyst for 1, 3-butadiene hydrogenation in the presence of 1-butene | |
| CN102091629A (zh) | 二氧化碳甲烷化催化剂 | |
| US4052333A (en) | Catalyst treatment | |
| JPS5939182B2 (ja) | 触媒活性化の方法 | |
| EP0072612B1 (en) | Amorphous silica based catalyst and process for its production | |
| CA1132966A (en) | Supported nickel catalysts and process for their preparation | |
| JPH0639293A (ja) | 担持された金属触媒を製造する方法 | |
| EP0320074B1 (en) | Chemical reaction in the presence of a supported copper catalyst | |
| JP2004261771A (ja) | 無担持炭化水素直接分解触媒およびその製造方法ならびに炭化水素直接分解による水素と炭素の製造方法 | |
| CN113292395B (zh) | 一种碳负载Ni基催化剂及其制备和在固定床催化对苯二酚加氢制1,4-环己二醇 | |
| JP2652668B2 (ja) | 液状炭化水素からヒ素および／またはリンの化合物を除去する方法 |