JPS59202240A - 難燃性熱可塑性樹脂組成物 - Google Patents
難燃性熱可塑性樹脂組成物Info
- Publication number
- JPS59202240A JPS59202240A JP7809283A JP7809283A JPS59202240A JP S59202240 A JPS59202240 A JP S59202240A JP 7809283 A JP7809283 A JP 7809283A JP 7809283 A JP7809283 A JP 7809283A JP S59202240 A JPS59202240 A JP S59202240A
- Authority
- JP
- Japan
- Prior art keywords
- acid ester
- polyphosphoric acid
- flame
- resin
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 29
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 229920005992 thermoplastic resin Polymers 0.000 title claims abstract description 13
- 239000011342 resin composition Substances 0.000 title claims description 5
- 150000002148 esters Chemical class 0.000 claims abstract description 73
- 239000002253 acid Substances 0.000 claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 229920001955 polyphenylene ether Polymers 0.000 claims abstract description 8
- 229920000728 polyester Polymers 0.000 claims abstract description 5
- 229920000098 polyolefin Polymers 0.000 claims abstract description 4
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 40
- 229920005989 resin Polymers 0.000 claims description 22
- 239000011347 resin Substances 0.000 claims description 22
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 150000002989 phenols Chemical class 0.000 claims description 8
- 229930185605 Bisphenol Natural products 0.000 claims description 6
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 5
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 claims description 4
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 claims description 4
- 229930003836 cresol Natural products 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- 239000000088 plastic resin Substances 0.000 claims description 3
- 229920006122 polyamide resin Polymers 0.000 claims description 3
- 229920005668 polycarbonate resin Polymers 0.000 claims description 2
- 239000004431 polycarbonate resin Substances 0.000 claims description 2
- 150000003739 xylenols Chemical class 0.000 claims description 2
- HIZCTWCPHWUPFU-UHFFFAOYSA-N Glycerol tribenzoate Chemical compound C=1C=CC=CC=1C(=O)OCC(OC(=O)C=1C=CC=CC=1)COC(=O)C1=CC=CC=C1 HIZCTWCPHWUPFU-UHFFFAOYSA-N 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 229920000388 Polyphosphate Polymers 0.000 abstract description 17
- 239000001205 polyphosphate Substances 0.000 abstract description 17
- 235000011176 polyphosphates Nutrition 0.000 abstract description 17
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract description 10
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 abstract description 6
- MIHINWMALJZIBX-UHFFFAOYSA-N cyclohexa-2,4-dien-1-ol Chemical compound OC1CC=CC=C1 MIHINWMALJZIBX-UHFFFAOYSA-N 0.000 abstract description 4
- 239000004417 polycarbonate Substances 0.000 abstract description 3
- 229920000515 polycarbonate Polymers 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 2
- 239000004952 Polyamide Substances 0.000 abstract 1
- 125000004437 phosphorous atom Chemical group 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 18
- -1 arylene diol Chemical class 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 8
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 8
- 239000004793 Polystyrene Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 229910052698 phosphorus Inorganic materials 0.000 description 7
- 229920002223 polystyrene Polymers 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 239000010452 phosphate Substances 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 150000002903 organophosphorus compounds Chemical class 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 238000004383 yellowing Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Substances CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910052717 sulfur Chemical group 0.000 description 2
- 239000011593 sulfur Chemical group 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- LIAWCKFOFPPVGF-UHFFFAOYSA-N 2-ethyladamantane Chemical compound C1C(C2)CC3CC1C(CC)C2C3 LIAWCKFOFPPVGF-UHFFFAOYSA-N 0.000 description 1
- CRBJBYGJVIBWIY-UHFFFAOYSA-N 2-isopropylphenol Chemical compound CC(C)C1=CC=CC=C1O CRBJBYGJVIBWIY-UHFFFAOYSA-N 0.000 description 1
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- CONKBQPVFMXDOV-QHCPKHFHSA-N 6-[(5S)-5-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-2-oxo-1,3-oxazolidin-3-yl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C[C@H]1CN(C(O1)=O)C1=CC2=C(NC(O2)=O)C=C1 CONKBQPVFMXDOV-QHCPKHFHSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 241000277331 Salmonidae Species 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000004380 ashing Methods 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 125000004438 haloalkoxy group Chemical group 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Fireproofing Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7809283A JPS59202240A (ja) | 1983-05-02 | 1983-05-02 | 難燃性熱可塑性樹脂組成物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7809283A JPS59202240A (ja) | 1983-05-02 | 1983-05-02 | 難燃性熱可塑性樹脂組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59202240A true JPS59202240A (ja) | 1984-11-16 |
JPS6225706B2 JPS6225706B2 (enrdf_load_stackoverflow) | 1987-06-04 |
Family
ID=13652211
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7809283A Granted JPS59202240A (ja) | 1983-05-02 | 1983-05-02 | 難燃性熱可塑性樹脂組成物 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59202240A (enrdf_load_stackoverflow) |
Cited By (55)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01203468A (ja) * | 1988-02-10 | 1989-08-16 | Marubishi Yuka Kogyo Kk | 難燃性合成樹脂組成物 |
JPH02115262A (ja) * | 1988-09-22 | 1990-04-27 | General Electric Co <Ge> | 芳香族ポリカーボネート、スチレン含有共重合体及び/又はグラフトポリマー、及び難燃剤を含むポリマー混合物、及び該ポリマー混合物から成形された物品 |
US5122556A (en) * | 1990-04-23 | 1992-06-16 | General Electric Company | Tetra (lower alkaryl) p-phenylene diphosphate-polycarbonate blends |
US5194581A (en) * | 1989-03-09 | 1993-03-16 | Leong Kam W | Biodegradable poly(phosphoesters) |
US5204394A (en) * | 1988-09-22 | 1993-04-20 | General Electric Company | Polymer mixture having aromatic polycarbonate, styrene I containing copolymer and/or graft polymer and a flame-retardant, articles formed therefrom |
JPH05186681A (ja) * | 1992-01-16 | 1993-07-27 | Asahi Chem Ind Co Ltd | ポリフェニレンエーテル系難燃樹脂組成物 |
US5309261A (en) * | 1991-07-03 | 1994-05-03 | Goldstar Co., Ltd. | Optical system for laser beam scanner |
JPH0753876A (ja) * | 1992-08-06 | 1995-02-28 | Asahi Chem Ind Co Ltd | 樹脂組成物 |
EP0640655A3 (de) * | 1993-08-26 | 1995-05-24 | Bayer Ag | Flammwidrige, spannungsrissbeständige Polycarbonat-ABS-Formmassen. |
WO1996011977A1 (en) * | 1994-10-13 | 1996-04-25 | Akzo Nobel N.V. | Polycarbonate-containing polymers flame retarded with oligomeric phosphate esters |
EP0761746A1 (de) | 1995-08-17 | 1997-03-12 | Bayer Ag | Feinsteilige anorganische Pulver als Flammschutzmittel in thermoplastischen Formmassen |
US5627228A (en) * | 1994-05-10 | 1997-05-06 | Daicel Chemical Industries, Ltd. | Flame-retardant resin composition |
US5663280A (en) * | 1995-10-23 | 1997-09-02 | The Dow Chemical Company | Carbonate polymer resins containing low volatility aromatic phosphate ester compounds |
USRE36188E (en) * | 1989-09-20 | 1999-04-06 | General Electric Company | Polymer mixture having aromatic polycarbonate styrene I containing copolymer and/or graft polymer and a flame-retardant, articles formed therefrom |
US6096821A (en) * | 1999-04-02 | 2000-08-01 | General Electric Company | Polyphenylene ether resin concentrates |
US6258881B1 (en) | 1998-10-07 | 2001-07-10 | Sumitomo Chemical Company, Limited | Polyphenylene ether resin composition |
US6319432B1 (en) | 1999-06-11 | 2001-11-20 | Albemarle Corporation | Bisphenol-A bis(diphenyl phosphate)-based flame retardant |
US6322882B1 (en) | 1998-10-14 | 2001-11-27 | Sumitomo Chemical Company, Limited | Polyphenylene ether resin composition |
US6359043B1 (en) | 1998-09-24 | 2002-03-19 | General Electric Company | Mica as flame retardant in glass filled noryl |
US6399685B1 (en) | 2000-12-11 | 2002-06-04 | Albemarle Corporation | Purification of arylene polyphosphate esters |
JP2002161211A (ja) * | 2000-11-24 | 2002-06-04 | Daicel Chem Ind Ltd | 難燃性樹脂組成物 |
US6437029B1 (en) | 2000-10-31 | 2002-08-20 | Cheil Industries Inc. | Flame retardant polycarbonate resin composition |
US6469077B1 (en) | 1998-10-13 | 2002-10-22 | Sumitomo Chemical Company Limited | Polyphenylene ether resin composition |
US6569930B1 (en) | 1997-08-11 | 2003-05-27 | Bayer Aktiengesellschaft | Flame and stress crack resistant polycarbonate molding compositions |
US6590015B1 (en) * | 1992-10-22 | 2003-07-08 | Bayer Aktiengesellschaft | Flame-resistant molding compounds |
US6706788B2 (en) | 1997-05-23 | 2004-03-16 | Bayer Aktiengesellschaft | Flame-resistant polycarbonate moulding materials which are dimensionally stable at high temperatures and have high flow line strength |
US6727301B1 (en) | 1999-03-27 | 2004-04-27 | Bayer Aktiengesellschaft | Flame-resistant, impact-resistant modified polycarbonate molding and extrusion masses |
US6767943B1 (en) | 1999-03-27 | 2004-07-27 | Bayer Aktiengesellschaft | Flame-resistant polycarbonate moulding materials modified with graft polymers |
US6797784B1 (en) | 1998-11-10 | 2004-09-28 | Bayer Aktiengesellschaft | Thermoplastic resins with a low proportion of coarse particles |
US6815476B1 (en) | 1995-06-07 | 2004-11-09 | General Electric Company | Phosphate flame retardant polymers |
US7094818B2 (en) | 2001-09-03 | 2006-08-22 | Cheil Industries, Inc. | Thermoplastic resin compositions containing mixtures of cyclic phosphazenes and phosphoric acid esters |
JP2006328175A (ja) * | 2005-05-25 | 2006-12-07 | Jsr Corp | 環状オレフィン系樹脂組成物およびその成形体 |
JP2006328174A (ja) * | 2005-05-25 | 2006-12-07 | Jsr Corp | 環状オレフィン系樹脂組成物およびその成形体 |
US7196130B2 (en) | 2002-06-14 | 2007-03-27 | Mitsui Chemicals, Inc. | Thermoplastic resin composition, polymer composition, and molded product comprising the composition |
US7235598B1 (en) | 1999-02-04 | 2007-06-26 | Bayer Materialscience Ag | Polycarbonate moulding materials with anti-static properties |
US7319116B2 (en) | 2002-08-05 | 2008-01-15 | Bayer Materialscience Ag | Flame-resistant polycarbonate molding composition modified with a graft polymer |
US7498370B2 (en) | 2002-07-08 | 2009-03-03 | Cheil Industries Inc. | Flame retardant thermoplastic resin composition |
US7511088B2 (en) | 2002-07-11 | 2009-03-31 | Cheil Industries Inc. | Flame retardant thermoplastic resin composition |
US7569629B2 (en) | 2004-12-30 | 2009-08-04 | Cheil Industries Inc. | Flame retardant polycarbonate resin composition |
WO2010010669A1 (ja) | 2008-07-21 | 2010-01-28 | 三菱エンジニアリングプラスチックス株式会社 | 難燃性ポリブチレンテレフタレート系樹脂組成物 |
US7659332B2 (en) | 2005-12-30 | 2010-02-09 | Cheil Industries Inc. | Flame retardant polycarbonate thermoplastic resin composition having good extrusion moldability and impact resistance |
US8119726B2 (en) | 2004-10-13 | 2012-02-21 | Cheil Industries Inc. | Flame retardant thermoplastic resin composition |
WO2013157345A1 (ja) | 2012-04-20 | 2013-10-24 | 三菱エンジニアリングプラスチックス株式会社 | ポリカーボネート樹脂組成物 |
KR20140050149A (ko) | 2012-10-17 | 2014-04-29 | 에스케이씨 주식회사 | 그물형 난연제 및 이의 제조방법 |
US8901218B2 (en) | 2007-12-18 | 2014-12-02 | Cheil Industries Inc. | Branched (meth)acrylate copolymer with high refractive index and method for preparing the same |
US8940836B2 (en) | 2008-12-17 | 2015-01-27 | Cheil Industries Inc. | Polycarbonate resin composition with improved transparency and scratch-resistance |
US9353260B2 (en) | 2013-04-19 | 2016-05-31 | Mitsubishi Engineering-Plastics Corporation | Polycarbonate resin composition and molded article |
US9365671B2 (en) | 2013-12-04 | 2016-06-14 | Samsung Sdi Co., Ltd. | Styrene-based copolymer and thermoplastic resin composition including the same |
WO2016197915A1 (zh) * | 2015-06-08 | 2016-12-15 | 金发科技股份有限公司 | 一种聚碳酸酯组合物及其制备方法 |
US9790362B2 (en) | 2014-06-27 | 2017-10-17 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and molded article made using the same |
US9850333B2 (en) | 2014-06-27 | 2017-12-26 | Lotte Advanced Materials Co., Ltd. | Copolymers and thermoplastic resin composition including the same |
US9856371B2 (en) | 2014-06-27 | 2018-01-02 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and low-gloss molded article made therefrom |
US9862822B2 (en) | 2014-11-18 | 2018-01-09 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and molded article made using the same |
US9902850B2 (en) | 2014-06-26 | 2018-02-27 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition |
US10640624B2 (en) | 2016-12-22 | 2020-05-05 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and article using the same |
Families Citing this family (1)
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---|---|---|---|---|
JP5214099B2 (ja) | 2005-09-28 | 2013-06-19 | ウィンテックポリマー株式会社 | 難燃性ポリブチレンテレフタレート樹脂組成物 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB787356A (en) * | 1955-03-29 | 1957-12-04 | British Cellophane Ltd | Improvements in or relating to the manufacture of articles comprising ethylene polymer |
JPS5432818A (en) * | 1977-08-19 | 1979-03-10 | Nippon Kokan Kk <Nkk> | Anti-corrosion coating process for pipe joint part |
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1983
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JPS5432818A (en) * | 1977-08-19 | 1979-03-10 | Nippon Kokan Kk <Nkk> | Anti-corrosion coating process for pipe joint part |
JPS55118957A (en) * | 1979-03-02 | 1980-09-12 | Gen Electric | Flameeproof composition |
JPS5667253A (en) * | 1979-10-19 | 1981-06-06 | Ici Ltd | Manufacture of thermoplastic film molecularroriented |
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JPS6225706B2 (enrdf_load_stackoverflow) | 1987-06-04 |
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