JPS59197492A - Combustion promoter for gasoline and diesel engines - Google Patents

Combustion promoter for gasoline and diesel engines

Info

Publication number
JPS59197492A
JPS59197492A JP7215783A JP7215783A JPS59197492A JP S59197492 A JPS59197492 A JP S59197492A JP 7215783 A JP7215783 A JP 7215783A JP 7215783 A JP7215783 A JP 7215783A JP S59197492 A JPS59197492 A JP S59197492A
Authority
JP
Japan
Prior art keywords
gasoline
combustion
diesel engines
castor oil
lithium borohydride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7215783A
Other languages
Japanese (ja)
Inventor
Iwao Takeda
巌 竹田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SEIKI KAGAKU KK
Original Assignee
SEIKI KAGAKU KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SEIKI KAGAKU KK filed Critical SEIKI KAGAKU KK
Priority to JP7215783A priority Critical patent/JPS59197492A/en
Publication of JPS59197492A publication Critical patent/JPS59197492A/en
Pending legal-status Critical Current

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  • Liquid Carbonaceous Fuels (AREA)

Abstract

PURPOSE:To provide a combustion promoter for gasoline and diesel engines which forms no harmful gas nor products in combustion and has an improved cetane number, prepared by adding olive oil, castor oil and lithium borohydride to an aromatic solvent solution of a specified chemical substance. CONSTITUTION:The combustion promotor is prepared by adding olive oil, castor oil and lithium borohydride to an aromatic hydrocarbon solvent solution of a chemical substance such as bicyclopentadienyliron, methylcyclopentadienylmagnesium tricarbonyl, iron naphthenate, barium naphthenate, PP or PE. EFFECT:Generation of incombustible gas causative of formation of graphite is reduced by 10-20%, leading to a decrease in amounts of exhausted black smoke and CO to a marked extent.

Description

【発明の詳細な説明】 近年の自動車工業の発展に伴い、燃料消費効率の問題、
公害問題、エンジンの耐久性などが大きくクローズアッ
プされています。それは、燃料の性状が自動車エンジン
の急激′な改良進展と不可分な関係にあるだめであると
考えられます。燃料節約と同時にエンジン作動状況を良
くするだめに、数多くの燃料への化学物質の添加が行わ
れています。公知の、ものとしては、アンチノック剤、
たい状物改質剤、金属活性低下剤、清浄剤、腐食防止剤
、氷結防止剤、上部シリンダ潤滑剤、静電気防止剤、セ
タン価向上剤。
[Detailed Description of the Invention] With the recent development of the automobile industry, the problem of fuel consumption efficiency,
Pollution issues, engine durability, and other issues are receiving a lot of attention. This is thought to be due to the fact that the properties of fuel are inseparable from the rapid improvement of automobile engines. Numerous chemicals are added to fuels to save fuel and improve engine performance at the same time. Known examples include anti-knock agents,
Plate modifier, metal activity reducer, detergent, corrosion inhibitor, anti-icing agent, upper cylinder lubricant, antistatic agent, cetane number improver.

流動点降下剤、煤煙防止剤、燃焼媒剤、スラツヂ分散剤
、水分散剤、灰分改質剤等数多くの物質があげられます
。しかし、一般的に市販されている燃料等には上記の項
目のほんの一部が添加されているにすぎません。特にガ
ソリン用としてオクタン価を向上させる目的で有鉛ガソ
リンが多くのガソリンスタンドでまだ市販されています
。これは非常に公害の問題点が大きく、有鉛ガソリンを
使用しない方向に進められてはいますが自動車のエンジ
ンによってはまだ数年間は必要とされています。この他
公害問題としては、未燃焼の排気ガスからのアルデヒド
9.ベンツアルデヒド、ペンツピレン、−酸化炭素、黒
煙等の排出があげられ、これらの物質は我々人類の生活
に大変な悪影響を及ぼし、近年各国で肺ガン、気管支ガ
ン等が急増していることの原因の一つとみられています
There are many substances such as pour point depressants, soot inhibitors, combustion media, sludge dispersants, water dispersants, ash modifiers, etc. However, only a small portion of the above items are added to commonly commercially available fuels. Leaded gasoline is still sold at many gas stations, especially to improve the octane rating of gasoline. This poses a huge pollution problem, and although progress is being made to eliminate the use of leaded gasoline, some car engines will still require leaded gasoline for several years. Other pollution problems include aldehydes from unburned exhaust gas9. Emissions include benzaldehyde, pentsupyrene, carbon oxide, and black smoke.These substances have a very negative impact on human life, and are the cause of the rapid increase in lung cancer, bronchial cancer, etc. in various countries in recent years. It is considered to be one of the.

本発明は上記の諸々の問題点を改善すべく考案された多
目的添加剤です。〜アンチノッキング剤兼オクタン価向
上剤としてり一りロベンタデエニル基に毒性のない二価
の鉄、マグネシウム等を付加させ、かつエンジン内部の
高温時での金属腐食防止のためにヒマシ油、ツバキ油、
オリーブ油等を使用しましたので耐摩耗性が向上し、か
つ燃焼時に有毒なるガス及び生成物が排出されません。
The present invention is a multi-purpose additive designed to improve the various problems mentioned above. - Castor oil, camellia oil,
The use of olive oil, etc. improves wear resistance, and no toxic gases or products are emitted during combustion.

又、ガソリン等の燃料中にはオレフィン炭化水素が多い
ために酸化によってガス状の重合物を析出し、燃料系統
や吸入弁などの障害を起こすことがあり捷す。これは過
酸化物の生成進行に伴って起因するものですが、これ等
の生成物を生じさせないようにするため水素化ホウソリ
チウム、水素化ホウツナトリウム、水素化ホウソアルミ
ニウムを添加し、酸化性の物質を還元してしまいます。
Furthermore, since fuel such as gasoline contains a large amount of olefin hydrocarbons, gaseous polymers are precipitated by oxidation, which can cause trouble in the fuel system, intake valves, etc. This is caused by the progress of the formation of peroxides, but in order to prevent the formation of these products, lithium borohydride, sodium borohydride, and aluminum borohydride are added to oxidize. will reduce the substance.

エンジン内の腐食及び公害の原因となるアルデヒド、ベ
ンツアルデヒド、ベンツピレンなどを還元してアルコー
ル類にし、燃焼させてしまいます。
It reduces aldehydes, benzaldehyde, benzpyrene, etc. that cause corrosion and pollution inside the engine, converts them into alcohols, and burns them.

更にポリエチレンイシン、ポリプロピレンなどの添加に
よって、燃料の燃焼で生成されたスラッチ、その他の付
着物の清浄並びにセタン側内上等にも効果を示していま
す。本発明において使用されているナブタン系金属塩は
、スラツヂ分散、黒煙防止等に大きな効果をもたらして
います。これ等は化学結合において二重、三重結合され
てい゛ますがπ電子の働きによりなされるものと考えら
れます。黒煙の原因としては、未燃性ガスの発生が考え
られますが、鉄塩等の添加によシ未燃性ガス量が5分の
1になり、黒煙及び−酸化炭素の排気が大巾に少なくな
シました。
Furthermore, the addition of polyethylene ysine, polypropylene, etc. has been shown to be effective in cleaning slatch and other deposits generated during fuel combustion, as well as on the inside of the cetane side. The nabutane metal salt used in this invention has great effects in dispersing sludge and preventing black smoke. These are double and triple chemical bonds, but it is thought that they are created by the action of π electrons. The cause of black smoke is thought to be the generation of unburned gas, but by adding iron salts, etc., the amount of unburned gas is reduced to one-fifth, and the exhaust of black smoke and carbon oxide becomes large. There was not much space in the width.

本発明の燃料添加剤は、少量を添加することによって多
目的の効果を発揮し、自動車公害を少なくし省エネルギ
ーへの貢献と工業社会に対する貢献を期するものです。
The fuel additive of the present invention exhibits multipurpose effects when added in small amounts, and is expected to contribute to reducing automobile pollution, saving energy, and contributing to industrial society.

本発明の例を2,3示すと次のようです。A few examples of the invention are as follows.

例1  ビシクロベンタデエニルマグネシウム    
  3%ポリプロピレン(液状)     7係ポリエ
チレンイミン       2チナフテン酸鉄    
       8係ヒマシ油            
10チ水酸化ホウ素リチウム      2チエタノー
ル           10チ無煙灯油(引火点72
℃以上) 57チ鉄染料              
1%例2  ビシクロペンタデエニルアイゼン  2〜
3%ポリプロピレン(液状)   7〜10チポリエチ
レンイミン     1〜2%ナフテン酸バリウム  
   5〜8チオリーブ油         10〜1
5チ水素化ホウツナトリウム   1〜2チエタノール
        10〜15%無煙灯油       
 63.5〜44係着色剤          0.5
〜1.0%例3  ビシクロペンタデエニルマンガン 
    5係−トリカルボニル ポリプロピレン(液状)     7%ポリエチレンイ
ミン       2優ナンテン酸マンガン     
 10%ナフテン酸鉄          2乃ヒマシ
油            10チ水素化ホウソアルミ
ニウム    2チエタノール           
10チ無煙灯油           51.5%着色
剤            0.5係以上の例の如きも
のをガソリン又はディーゼル油に。
Example 1 Bicyclobentadeenylmagnesium
3% polypropylene (liquid) 7-functional polyethyleneimine 2 iron thinaphthenate
Section 8 castor oil
10% lithium boron hydroxide 2% ethanol 10% smokeless kerosene (flash point 72
℃ or higher) 57th iron dye
1% Example 2 Bicyclopentadeenylisen 2~
3% polypropylene (liquid) 7-10 polyethyleneimine 1-2% barium naphthenate
5-8 chili olive oil 10-1
5% sodium borohydride 1-2% ethanol 10-15% smokeless kerosene
63.5-44 colorant 0.5
~1.0% Example 3 Bicyclopentadeenylmanganese
Section 5 - Tricarbonyl polypropylene (liquid) 7% polyethyleneimine 2 manganese nanthenate
10% iron naphthenate, 2, castor oil, 10, borous aluminum hydride, 2, ethanol
10% smokeless kerosene, 51.5% colorant, 0.5% or more, and add it to gasoline or diesel oil.

その量の1ooo分の1に当たる量を添加し、自動車で
実験しだ結果、すべての自動車がノッキングすることな
く走行障害はありませんでした0又、CO。
We added an amount equivalent to 100% of that amount and conducted experiments on cars, and as a result, all cars did not knock and did not have any driving problems.

HCは3分の1になり、黒煙も10〜20パーセント減
少しました。その上オイルも2倍の耐久性を示しました
HC was reduced to one-third, and black smoke was reduced by 10 to 20 percent. Moreover, the oil also showed twice the durability.

Claims (1)

【特許請求の範囲】 ビシクロペンタデエニル鉄、メチルシクロペンタアエニ
ルマンガンートリカルボニル、ナフf:/ 酸鉄。 ナフテン酸バリウム、ポリプロピレン、ポリエチレン等
の化学物質を芳香族炭化水素溶剤中に溶解させたものに
オリーブ油、ヒマシ油、水素化ホウ素リチウムを加えて
なるガソリン、ディーゼル燃料用助燃剤。
[Claims] Bicyclopentadeenyl iron, methylcyclopentadeenyl manganese-tricarbonyl, napf f:/ iron acid. A combustion improver for gasoline and diesel fuel, which is made by adding olive oil, castor oil, and lithium borohydride to a solution of chemical substances such as barium naphthenate, polypropylene, and polyethylene in an aromatic hydrocarbon solvent.
JP7215783A 1983-04-26 1983-04-26 Combustion promoter for gasoline and diesel engines Pending JPS59197492A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7215783A JPS59197492A (en) 1983-04-26 1983-04-26 Combustion promoter for gasoline and diesel engines

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7215783A JPS59197492A (en) 1983-04-26 1983-04-26 Combustion promoter for gasoline and diesel engines

Publications (1)

Publication Number Publication Date
JPS59197492A true JPS59197492A (en) 1984-11-09

Family

ID=13481135

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7215783A Pending JPS59197492A (en) 1983-04-26 1983-04-26 Combustion promoter for gasoline and diesel engines

Country Status (1)

Country Link
JP (1) JPS59197492A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6245691A (en) * 1985-08-22 1987-02-27 Toa Netsuken Kk Method of modifying combustion dust of low quality fuel derived from petroleum
JPH03244692A (en) * 1990-02-23 1991-10-31 Taiho Ind Co Ltd Fuel additive
WO2001096502A1 (en) * 2000-06-14 2001-12-20 I.B.E. Co., Ltd. Fuel modifier
US8771385B2 (en) 2008-12-29 2014-07-08 Shell Oil Company Fuel compositions

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6245691A (en) * 1985-08-22 1987-02-27 Toa Netsuken Kk Method of modifying combustion dust of low quality fuel derived from petroleum
JPH0362754B2 (en) * 1985-08-22 1991-09-26 Toa Netsuken Kk
JPH03244692A (en) * 1990-02-23 1991-10-31 Taiho Ind Co Ltd Fuel additive
WO2001096502A1 (en) * 2000-06-14 2001-12-20 I.B.E. Co., Ltd. Fuel modifier
JP2001354979A (en) * 2000-06-14 2001-12-25 Ibe:Kk Fuel modifier
US8771385B2 (en) 2008-12-29 2014-07-08 Shell Oil Company Fuel compositions

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