JPS59182206A - 硫酸再生のための改良された方法 - Google Patents
硫酸再生のための改良された方法Info
- Publication number
- JPS59182206A JPS59182206A JP59018505A JP1850584A JPS59182206A JP S59182206 A JPS59182206 A JP S59182206A JP 59018505 A JP59018505 A JP 59018505A JP 1850584 A JP1850584 A JP 1850584A JP S59182206 A JPS59182206 A JP S59182206A
- Authority
- JP
- Japan
- Prior art keywords
- sulfuric acid
- oxygen
- furnace
- acid
- air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title claims description 41
- 230000008929 regeneration Effects 0.000 title description 8
- 238000011069 regeneration method Methods 0.000 title description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 37
- 239000001301 oxygen Substances 0.000 claims description 37
- 229910052760 oxygen Inorganic materials 0.000 claims description 37
- 239000003570 air Substances 0.000 claims description 33
- 239000002253 acid Substances 0.000 claims description 26
- 239000002699 waste material Substances 0.000 claims description 22
- HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 claims description 21
- 239000007789 gas Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- BIGPRXCJEDHCLP-UHFFFAOYSA-N ammonium bisulfate Chemical compound [NH4+].OS([O-])(=O)=O BIGPRXCJEDHCLP-UHFFFAOYSA-N 0.000 claims description 9
- 239000000446 fuel Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000010521 absorption reaction Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 18
- 239000003546 flue gas Substances 0.000 description 17
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 16
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 14
- 230000001590 oxidative effect Effects 0.000 description 8
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000006096 absorbing agent Substances 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 6
- 239000011261 inert gas Substances 0.000 description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000029936 alkylation Effects 0.000 description 3
- 238000005804 alkylation reaction Methods 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 238000006396 nitration reaction Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 239000002918 waste heat Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- MWFMGBPGAXYFAR-UHFFFAOYSA-N 2-hydroxy-2-methylpropanenitrile Chemical compound CC(C)(O)C#N MWFMGBPGAXYFAR-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- -1 oleum Chemical compound 0.000 description 2
- 230000001172 regenerating effect Effects 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/90—Separation; Purification
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/48—Sulfur dioxide; Sulfurous acid
- C01B17/50—Preparation of sulfur dioxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US464429 | 1983-02-07 | ||
| US06/464,429 US4490347A (en) | 1983-02-07 | 1983-02-07 | Process for sulfuric acid regeneration |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59182206A true JPS59182206A (ja) | 1984-10-17 |
| JPH059366B2 JPH059366B2 (OSRAM) | 1993-02-04 |
Family
ID=23843920
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59018505A Granted JPS59182206A (ja) | 1983-02-07 | 1984-02-06 | 硫酸再生のための改良された方法 |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US4490347A (OSRAM) |
| JP (1) | JPS59182206A (OSRAM) |
| CA (1) | CA1206324A (OSRAM) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1198261A (en) * | 1983-04-29 | 1985-12-24 | Gordon M. Cameron | Liquid sulphur dioxide manufacture |
| ES2066432T3 (es) * | 1990-03-23 | 1995-03-01 | Monsanto Co | Procedimiento para recuperar energia de procesamiento de alta calidad de un procedimiento de obtencion de acido sulfurico por contacto. |
| US5022332A (en) * | 1990-08-15 | 1991-06-11 | Union Carbide Industrial Gases Technology Corporation | Combustion method for improved endothermic dissociation |
| GB9127096D0 (en) * | 1991-12-20 | 1992-02-19 | Ici Plc | Treatment of liquid waste material |
| US5498790A (en) * | 1993-06-09 | 1996-03-12 | Novus International, Inc. | Regeneration of sulfuric acid from sulfate by-products of 2-hydroxy-4-(methylthio)butyric acid manufacture |
| CA2147195C (en) * | 1994-04-15 | 2005-04-05 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Proced Es Georges Claude | Processing sulfur-containing streams |
| US5628976A (en) * | 1995-10-17 | 1997-05-13 | Air Products And Chemicals | Cofiring biosolids in a spent sulfuric acid regeneration facility |
| ATE368002T1 (de) * | 1999-06-03 | 2007-08-15 | Rohm & Haas | Verfahren zur erzeugung von wiedergewinnbaren schwefelenthaltenden verbindungen aus einem abfallsäurestrom |
| WO2001010776A1 (en) | 1999-08-05 | 2001-02-15 | Novus International, Inc. | Reductive combustion of ammonium salts of sulfuric acid |
| US20080033227A1 (en) * | 2006-08-03 | 2008-02-07 | David Campbell Graves | Recovery of sulfur value in an alkylation process |
| US7632479B2 (en) * | 2006-08-31 | 2009-12-15 | Iogen Energy Corporation | Process for producing ammonia and sulfuric acid from a stream comprising ammonium sulfate |
| US20090317321A1 (en) * | 2008-06-18 | 2009-12-24 | James Patrick Meagher | Decomposition of spent sulfuric acid using oxygen |
| US8227366B2 (en) | 2009-06-01 | 2012-07-24 | Uop Llc | Alkylation system including a catalyst regeneration zone, and a process relating thereto |
| WO2013044937A1 (en) * | 2011-09-29 | 2013-04-04 | Haldor Topsøe A/S | Sulphuric acid production with recycle of desulphurized gas |
| WO2013150081A2 (en) * | 2012-04-04 | 2013-10-10 | Shell Internationale Research Maatschappij B.V. | Process for producing power from a sour gas |
| RU2641121C1 (ru) * | 2016-12-28 | 2018-01-16 | Публичное Акционерное Общество "Корпорация Всмпо-Ависма" | Способ регенерации отработанного раствора серной кислоты |
| KR102326500B1 (ko) * | 2017-03-10 | 2021-11-16 | 에스케이케미칼 주식회사 | 바이사이클로글리옥살 설페이트의 제조방법 |
| CN109052332B (zh) * | 2018-10-24 | 2022-02-22 | 泰兴锦汇化工有限公司 | 一种高cod含盐稀酸再生制备氯磺酸的方法 |
| US12264066B2 (en) | 2022-04-25 | 2025-04-01 | Messer Industries Usa, Inc. | Process and apparatus for acid regeneration |
| CN115259104B (zh) * | 2022-07-07 | 2024-04-26 | 江苏索普新材料科技有限公司 | 硫酸生产系统以及控制吹扫装置出酸浓度的方法 |
| US12303832B2 (en) * | 2022-12-07 | 2025-05-20 | Sar Technology Inc. | Method for recycling electronic-grade and industrial-grade sulfuric acid |
| US12577103B2 (en) | 2023-04-20 | 2026-03-17 | Messer Industries Usa, Inc. | Process and redox furnace for acid regeneration |
| US12600627B2 (en) | 2023-04-20 | 2026-04-14 | Messer Industries Usa, Inc. | Process and apparatus for oxygen injection in a sulfur furnace |
| US12607352B2 (en) | 2023-04-20 | 2026-04-21 | Messer Industries Usa, Inc. | Process and burner apparatus for acid regeneration |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1467005A1 (de) * | 1964-06-16 | 1969-03-13 | Chemiebau Dr Alfons Zieren Gmb | Verfahren zur Aufarbeitung von ammoniumsulfithaltiger Loesung aus der Endgaswaesche von Schwefelsaeurekontaktanlagen |
| JPS4879791A (OSRAM) * | 1972-01-14 | 1973-10-25 | ||
| JPS4962394A (OSRAM) * | 1972-06-08 | 1974-06-17 | ||
| JPS51149195A (en) * | 1975-02-15 | 1976-12-21 | Davy Powergas Gmbh | Process for thermal decomposion of sulfuric acid and apparatus for producing mist of waste sulfuric acid |
| JPS5618526A (en) * | 1979-07-25 | 1981-02-21 | Kunihiro Houjiyou | Atracting bait cage |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1447645A (en) * | 1919-05-01 | 1923-03-06 | Cos Process Company Inc | Roasting sulphur-bearing materials, etc. |
| US1344905A (en) * | 1919-06-09 | 1920-06-29 | Laist Frederick | Method of producing sulfur dioxid |
| US1520093A (en) * | 1923-10-13 | 1924-12-23 | Hercules Powder Co Ltd | Process of making sulphuric acid |
| US1995360A (en) * | 1930-04-29 | 1935-03-26 | Gen Chemical Corp | Manufacture of sulphuric acid |
| BE406758A (OSRAM) * | 1933-12-13 | 1900-01-01 | ||
| US2394426A (en) * | 1942-01-26 | 1946-02-05 | Gen Chemical Corp | Manufacture of oleum |
| US2406930A (en) * | 1942-06-12 | 1946-09-03 | Chemical Construction Corp | Sulphuric acid regeneration |
| DE1199243B (de) * | 1963-07-10 | 1965-08-26 | Huels Chemische Werke Ag | Verfahren zur Herstellung schwefeldioxydhaltiger Gase aus ammoniumsalzhaltigen Abfallschwefelsaeuren |
| US3419601A (en) * | 1964-03-03 | 1968-12-31 | Du Pont | Cyclic process for the production of methyl methacrylate |
| US3645683A (en) * | 1970-03-10 | 1972-02-29 | Du Pont | Regeneration of acid |
| DE2037619B2 (de) * | 1970-07-29 | 1972-07-13 | Chemiebau Dr. A. Zieren GmbH & Co KG, 5000 Köln | Verfahren zur spaltung von schwefelsaeure |
| DE2223131C3 (de) * | 1972-05-12 | 1979-10-11 | Davy Powergas Gmbh, 5000 Koeln | Verfahren zur Herstellung von Schwefelsäure aus Schwefel und Sauerstoff |
| GB1603093A (en) * | 1977-05-09 | 1981-11-18 | Boc Ltd | Catalytic process for the prodcution of sulphuric acid |
| DE2725432C3 (de) * | 1977-06-04 | 1980-02-21 | Davy International Ag, 6000 Frankfurt | Verfahren zur Herstellung von konzentrierter Schwefelsäure |
| GB1602621A (en) * | 1978-05-31 | 1981-11-11 | Boc Ltd | Thermal cracking of sulphuric acid |
| US4256721A (en) * | 1979-02-23 | 1981-03-17 | Boc Limited | Combustion method and apparatus |
-
1983
- 1983-02-07 US US06/464,429 patent/US4490347A/en not_active Expired - Lifetime
-
1984
- 1984-02-02 CA CA000446652A patent/CA1206324A/en not_active Expired
- 1984-02-06 JP JP59018505A patent/JPS59182206A/ja active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1467005A1 (de) * | 1964-06-16 | 1969-03-13 | Chemiebau Dr Alfons Zieren Gmb | Verfahren zur Aufarbeitung von ammoniumsulfithaltiger Loesung aus der Endgaswaesche von Schwefelsaeurekontaktanlagen |
| JPS4879791A (OSRAM) * | 1972-01-14 | 1973-10-25 | ||
| JPS4962394A (OSRAM) * | 1972-06-08 | 1974-06-17 | ||
| JPS51149195A (en) * | 1975-02-15 | 1976-12-21 | Davy Powergas Gmbh | Process for thermal decomposion of sulfuric acid and apparatus for producing mist of waste sulfuric acid |
| JPS5618526A (en) * | 1979-07-25 | 1981-02-21 | Kunihiro Houjiyou | Atracting bait cage |
Also Published As
| Publication number | Publication date |
|---|---|
| US4490347A (en) | 1984-12-25 |
| CA1206324A (en) | 1986-06-24 |
| JPH059366B2 (OSRAM) | 1993-02-04 |
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