JPS59181504A - Constant permeability core - Google Patents

Constant permeability core

Info

Publication number
JPS59181504A
JPS59181504A JP58053767A JP5376783A JPS59181504A JP S59181504 A JPS59181504 A JP S59181504A JP 58053767 A JP58053767 A JP 58053767A JP 5376783 A JP5376783 A JP 5376783A JP S59181504 A JPS59181504 A JP S59181504A
Authority
JP
Japan
Prior art keywords
alloy
magnetic
kinds
amorphous
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP58053767A
Other languages
Japanese (ja)
Other versions
JPH0544165B2 (en
Inventor
Tadahiko Kobayashi
忠彦 小林
Michio Hasegawa
長谷川 迪雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP58053767A priority Critical patent/JPS59181504A/en
Publication of JPS59181504A publication Critical patent/JPS59181504A/en
Publication of JPH0544165B2 publication Critical patent/JPH0544165B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/12Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
    • H01F1/14Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
    • H01F1/147Alloys characterised by their composition
    • H01F1/153Amorphous metallic alloys, e.g. glassy metals
    • H01F1/15308Amorphous metallic alloys, e.g. glassy metals based on Fe/Ni

Abstract

PURPOSE:To obtain a constant permeability within a wide operation range without providing a gap by using at least partly resin molded amorphous magnetic alloy which includes one or two kinds of iron, cobalt and nickel and one or more kinds of half-metal elements and shows the positive property of magnetic distortion. CONSTITUTION:Used here is an alloy including one or more kinds of iron, cobalt, nickel and one kind or more of half-metal elements such as boron, carbon, silicon and phosphorus, or an alloy further including oen or more kinds of transition elements of the III-VII groups in the periodic table such as yttrium, titanium, vanadium, chromium and manganese, etc., particularly at least a partly resin molded amorphous alloy which has a positive property of magnetic distortion and includes crystal nature phase of 1-50%. For example, an amorphous magnetic alloy thin belt 1 which is composed of Fe83Si3B12C2 in terms of atom% and has positive magnetic distortion is manufactured. It is then wound like a ring and it is then annealed for an hour at a temperature of 470 deg.C. Thereafter, it is impregnated with electrically insulating resin such as epoxy resin, etc. for hardening.

Description

【発明の詳細な説明】 C発明の技術分野〕 本発明i−1:恒蒸UB率性の優れた非晶質磁性合金磁
芯に関するものである。
DETAILED DESCRIPTION OF THE INVENTION Technical Field of the Invention The present invention i-1 relates to an amorphous magnetic alloy core with excellent constant vapor UB rate.

〔発明の技術的背景とその問題点J 一般に溶融金属を高速急冷すると非晶質合金が得られる
ことが知られている。この非晶質合金は同じ組成の結晶
費合金に比べて著しくnなる磁気的性質と機械的付質と
を有し、特に磁気品方性が小さいことに層目して軟俤磁
性利料としての用途が研死きれている。
[Technical background of the invention and its problems J It is generally known that an amorphous alloy can be obtained by rapidly cooling a molten metal. This amorphous alloy has significantly higher magnetic properties and mechanical properties than crystallized alloys of the same composition, and is particularly useful as a soft magnetic material due to its low magnetic properties. Its use has been exhausted.

しかしながら、この非晶質合金は優れた軟磁気特性ケ有
するものの、広いpd+作卸四に於てほぼ一定の透磁率
が必要とされている恒速磁率磁芯への用途を考えた場合
、磁芯の一部にギャップを設ける必要があった。
However, although this amorphous alloy has excellent soft magnetic properties, it cannot be used as a constant-velocity magnetic core, which requires almost constant magnetic permeability over a wide range of pd+. It was necessary to create a gap in a part of the core.

従来、この恒速磁率性の特徴を生がして、チコクトラン
ス、′へ力変換リアクトル(アノードリアクトル)など
種々の用途がち4)、、これらに要求される特性として
は、高磁界までR−H曲線の直線性が良く、まだ3巻線
に直流電流が重畳(チョウジヨウ)される事から、磁芯
の磁束密度が飽和しにくい恒速磁率性が必要である。
Conventionally, this characteristic of constant velocity magnetic property has been used in various applications such as Chikoku transformers and force conversion reactors (anode reactors)4), and the characteristics required for these are R- to high magnetic fields. Since the H curve has good linearity and DC current is still superimposed on the three windings, it is necessary to have constant velocity magnetic properties that prevent the magnetic flux density of the magnetic core from becoming saturated.

この様な用途に用いられる利料としては、一般に方向性
珪素KI:・・4板、フェライト等が知られているが以
下の問題点が・16つた。
Generally, oriented silicon KI:4 plates, ferrite, etc. are known as materials used for such purposes, but they have the following problems.

方[1・+ l′−I F)弓素確i板の場合、鉄芯を
所定のカットコア形状にし、コア間のギャップ^1月整
を17なければならず、カッF t’*lLの磁歪揚動
による騒音が発生する。壕だフェライトでは1.)→束
′1竹度が低く、リンク状に形成された磁芯においては
Ail記の様なギャップを設ける小ができず、磁芯の1
,1[面積を大きくしたり、巻線量を制作1したりしな
くてはならないという欠点があった。
[1・+l'-I F) In the case of a bow-cut i-plate, the iron core must be cut into a predetermined core shape, and the gap between the cores must be adjusted to 17. Noise is generated due to magnetostrictive lifting. In the case of ferrite, 1. )→Bundle '1 In a magnetic core formed in a link shape with low bamboo density, it is not possible to create a small gap as shown in Ail, and one part of the magnetic core is
, 1 [The disadvantages were that the area had to be increased and the amount of winding had to be increased by 1.

1発明の目的〕 本発明は、この様な従来の問題点を@C笑した恒速磁率
磁芯でありギヤソゲを設ける事なく、広い動作範囲に於
いて一定の透磁率が得られる・i亘透磁率(1丑芯をt
Xl供するものCある。
1. Purpose of the Invention The present invention is a constant-velocity magnetic core that overcomes these conventional problems, and can obtain constant magnetic permeability over a wide operating range without providing a gear saw. Magnetic permeability (1 core is t
Xl There is something C to offer.

〔発明の標1要〕 本発明(f」、鉄、コバルト、ニッケルの1種または2
種以上とホウ素、カーボン、シリコン、リンなどの半金
属元素の1種または2種以上を含む合金およU nit
記麩、コバルト9.=・ノケルなとの◆移元素の1 、
rJR’t /ζは2棟以−Fの−部をイツトリウム。
[Required Mark 1 of the Invention] The present invention (f), one or two of iron, cobalt, and nickel
Alloys and units containing one or more metalloid elements such as boron, carbon, silicon, phosphorus, etc.
Kifu, cobalt 9. =・Nokelnato's ◆transfer element 1,
rJR't /ζ is yttrium for the second part of F.

チタン、バナジウム、クロノ4.マンガンなど周期律表
′r743,4,5,6.71rMi七g元素で1^換
した合金で磁歪が正の1質を41シ、かつ1〜り0%の
評f晶賀相を3む非晶質合金’i、’ +(7J ll
jイでモールドしたものである。
Titanium, vanadium, chrono 4. Manganese and other alloys with 743, 4, 5, 6.71rMi 7g elements of the periodic table, with 41 elements having a positive magnetostriction, and 3 elements with a rating of 1 to 0%. Amorphous alloy 'i,' + (7J ll
It was molded with J-I.

なお本発明(で用いる組成と17では (Fed−)(−yCoy N1x)ton−BXaで
示される組成範囲(j京fチによる)の合金、さらに上
式においてP’eの一部をY 、 ’L”i +V、(
、’r、Mn  など周期律表第3〜7族遭移元素で向
換した合金(ただし、IK換量は0〜015J駅子チと
する)等を誉げる事ができる。
In addition, in the composition used in the present invention (17), an alloy with a composition range (according to jkyofchi) shown by (Fed-)(-yCoyN1x)ton-BXa, and furthermore, in the above formula, a part of P'e is replaced by Y, 'L”i +V, (
, 'r, Mn, etc., which are converted by transition elements from groups 3 to 7 of the periodic table (however, the IK conversion amount is 0 to 015J), etc. can be praised.

なお本発明に係る非晶質合金は例えは以下の通り製造さ
れる。この合金を溶融状態でロール間に吹付けて急冷圧
延するローラ・フランチ法、或は回転トラム中(・こ浴
融金属を注入1〜で急冷“掲造する遠心急冷法などの方
法((より非晶質合金とする。
Note that the amorphous alloy according to the present invention is manufactured, for example, as follows. The roller flanch method involves spraying this alloy in a molten state between rolls and rapidly rolling it, or the centrifugal quenching method in which the molten metal is quenched in a rotating tram (injection 1). It is an amorphous alloy.

この場合冷却速度を10 ”(3/秒以トとすることに
より完全な非晶゛h状態がイ!+ !っれる。
In this case, by setting the cooling rate to 10'' (3/sec) or more, a completely amorphous state can be achieved.

次にこの非晶質合金中その結晶化転移?、爆度より低い
温度で熱処理l−ることにより結晶質が一部形成される
。こO)場合結晶化転移温度より高い温度で加熱1−5
でも、結晶質が一部形成されるが、数秒のオーダーで完
全な結晶質となってしまうため温度コントロールに熟練
を要する。捷だ急冷Q″こより完全な非晶質状態とぜず
に、冷却i・ti既を1〇−1o”(+/秒稈度に調整
fることにより、一部週14品質を形成することもでき
るが、この場合も同様シこ温厚jントロールが引]シク
、熟練を要する問題がある。
Then that crystallization transition in this amorphous alloy? A part of crystalline material is formed by heat treatment at a temperature lower than the explosive temperature. In this case, heating at a temperature higher than the crystallization transition temperature 1-5
However, although some crystals are formed, it becomes completely crystalline within a few seconds, so it requires skill to control the temperature. By adjusting the cooling rate to 10-1o'' (+/sec) without changing to a completely amorphous state, a part of the quality can be formed. It is also possible to do this, but in this case as well, there is a problem in that it requires skill and skill.

この非晶質合金中に占める結晶質相の割合は1〜50%
が望呼し2い。結晶質相の割合を一ヒGシ:範囲に限定
した珪由け、完全な非晶質状態の場合、ギャップを設け
ろことなく、広い動作範囲で恒辺綴率性を得ることは非
常に靴かしい。
The proportion of crystalline phase in this amorphous alloy is 1 to 50%
The hope is 2. If the ratio of crystalline phase is limited to a certain range, it is extremely difficult to obtain a constant rate in a wide range of motion without creating gaps in the case of a completely amorphous state. That's funny.

斗だれイ晶質相が50係を超えた(!ミ合、声研率が泡
、檄に低丁し、1lfll磁力も急激(l(」1q太し
、同速磁率1]、を太幅(・ξ(こなう。
The crystalline phase exceeded 50. (・ξ(Konau.

本究明に4・・いて、ト記した結晶質相を11シ、かつ
イ1dφが(トの1゛ト質全もつ争件をlPo・□dだ
したリング状の非晶質La性合会尚芯に少なくとも−H
ats分を樹脂、1−−ルトしたことで4j、 j;q
 llへ嘉<+十の作れた(1弓芯が得らJLることを
特徴と一1′るものである〔本発明の効果〕 本)へ明G′こより得られる1亘・を磁率イ゛1ナシ芯
は、リング状の磁芯でありながらギャップを一般けるこ
となく広い動作範囲に於て1、り′1、一定のぜ1磁率
がイQられ、烙らに1は結晶質相のtiを、1^当に久
える事でその1時性を任意にR1″1整できるといっだ
効果をイイしてい7)。
In the present study, there are 11 crystalline phases mentioned above, and a ring-shaped amorphous La polymerization in which 1dφ is (1Po・□d). At least -H in the core
By converting ats into resin, 4j, j; q
It is characterized by the fact that 1 bow core is obtained. [Effects of the present invention] 1. Although the core is a ring-shaped core, it has a constant magnetic flux of 1, 1 and 1 over a wide operating range without leaving any gaps, and 1 has a crystalline phase. It would be even more effective if the temporality could be arbitrarily adjusted to R1'' by adjusting the ti of 1^ for a long time7).

i/ζ、非晶質磁性合金を用いた+Hcで、その’t!
J’ lit上フエフエライトもf8束密度を高く出来
、さらには結晶質相がある事から磁歪が減少しギャップ
を設け〃い/ζめ、磁歪抛動による、1音をも低減でき
る利点があゐ。
i/ζ, +Hc using an amorphous magnetic alloy, that't!
J'lit upper Huehuerite can also have a high f8 flux density, and since it has a crystalline phase, magnetostriction is reduced, creating a gap, which has the advantage of reducing even one sound due to magnetostrictive vibration. Wow.

まだ1.+;tJ指モールドにより恒速7iB性を得る
効果の他に、結晶質相を含む事で非晶R磁性合金がもろ
くなりJIv扱上問題が生じろ事Vこも十分対応できる
利点を有している。
Still 1. +; In addition to the effect of obtaining constant velocity 7iB properties by using the tJ finger mold, it also has the advantage of being able to fully cope with the problems that arise when an amorphous R magnetic alloy becomes brittle due to the inclusion of a crystalline phase, which may cause problems in JIv handling. There is.

〔発明の実施例〕[Embodiments of the invention]

以上に本発明を図面に則して説明する。 The present invention will be described above with reference to the drawings.

〔尭l・i+1例1〕 原子チでFe53Si3B+2C2からなり、+、B歪
が正である。中10市の非晶質磁性合金薄帯を製造した
[尭l・i+1例1] The atom is composed of Fe53Si3B+2C2, and the + and B strains are positive. Amorphous magnetic alloy ribbons of 10 sizes were manufactured.

次に、第1図の如く、内径40m1’lのリング状に巻
回し、470”(”3の温度で1時間焼鈍し7y0 こ
の時、結晶η相の割合を得るためX線回折像によるピー
クから求めた結果8チ程度の結晶質相がざ1れていた。
Next, as shown in Figure 1, it was wound into a ring shape with an inner diameter of 40ml, and annealed for 1 hour at a temperature of 470" (7y0). At this time, in order to obtain the proportion of the crystalline η phase, the As a result, about 8 crystalline phases were found.

次に、リング状に回巻されだ薄帯を例えばエポキシ樹脂
の様な電気絶縁性樹脂を含侵L %常法により該樹脂を
硬化する。エポキシi4を脂はリーク状に回巻されだ薄
帯を全体として一体化して固定した。この時の直流磁化
曲線を第2図曲柳a VC示す。
Next, the thin ribbon wound into a ring shape is impregnated with an electrically insulating resin such as epoxy resin, and the resin is cured by a conventional method. Epoxy I4 was rolled around in a leaky manner, and the thin ribbon was fixed as a whole. The DC magnetization curve at this time is shown in Figure 2.

比較のだめ圏脂モールド前の直流磁化曲線を2ル2図曲
線すに、および完針な非晶質状態の直流磁化曲線も第2
図曲線Cに示しだ。第2図より、完全な非晶質状態の直
流磁化曲線(c)では恒速磁率性は1とんど見られない
。寸だ、樹脂モールド前の直流(1d化曲線(b)では
恒速(み重性は見られるが広卸1囲な動作には不十分で
あり、樹脂モールド後の直流磁化曲線(a)でもわかる
ようにqi vi6a率性が飛躍的eこ改善されたこと
が明らかである。
For comparison, the DC magnetization curve before the sphere resin mold is shown in Figure 2, and the DC magnetization curve in the completely amorphous state is also shown in the second diagram.
This is shown in curve C in the figure. From FIG. 2, in the DC magnetization curve (c) in a completely amorphous state, no constant velocity magnetic property is observed at all. The direct current (1d curve (b) before resin molding shows constant velocity (heaviness), but it is insufficient for widespread operation, and the direct current magnetization curve (a) after resin molding also shows As can be seen, it is clear that the qi vi6a efficiency has been dramatically improved.

〔実施例2J 原子チで(Fe、g2co、03Nb、05 )86s
i 2B】2からなり磁歪が正である中lOx7mの非
晶質イ1任性合金薄帯を製造し、内径4Q:rrniの
リング状に巻回し7.430 ’Oの温度で1時間焼鈍
し、結晶質相を10−程度にした。
[Example 2J Atom (Fe, g2co, 03Nb, 05) 86s
i2B] 2 with positive magnetostriction and a medium lOx7m amorphous permanent alloy ribbon, wound into a ring shape with an inner diameter of 4Q:rrni and annealed at a temperature of 7.430'O for 1 hour, The crystalline phase was made to be about 10-.

以下、実施例1と同様の方法により恒速磁率磁芯ケ作製
した。この時の直流磁化曲線を第3図aに示す。比較の
だめ樹脂モールド前の直流磁化曲線も第3図すに、およ
び完全な非晶質状態の直流磁化曲線も第3図Cに示した
。第3図より、実施例1とはは同様の結果が得られる事
がわかる。
Thereafter, a constant velocity magnetic core was produced in the same manner as in Example 1. The DC magnetization curve at this time is shown in FIG. 3a. For comparison, the DC magnetization curve before resin molding is also shown in Figure 3, and the DC magnetization curve in a completely amorphous state is also shown in Figure 3C. From FIG. 3, it can be seen that the same results as in Example 1 are obtained.

【図面の簡単な説明】 第1図は本発明方法に係る磁芯の斜視図。第2図は実施
例1より倚られた直流1市化曲線図。第3図は実施例2
より得ら;h、 fLifI流磁化曲形β図。 1・・・非晶質磁性合金薄帯 第  1  図 第  2 図
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a perspective view of a magnetic core according to the method of the present invention. FIG. 2 is a DC single city curve diagram based on Example 1. Figure 3 shows Example 2
h, fLifI flow magnetization curve β diagram. 1...Amorphous magnetic alloy ribbon Figure 1 Figure 2

Claims (1)

【特許請求の範囲】 (11鉄、コバルト、ニッケルの1秒または2秤を含み
、半金属元素の1種または2秤以上とを含み、磁歪が正
の性質を示めす非晶質磁性合金で、1〜50%の結晶質
相を治し、かつ少なくとも一部分を樹脂モールドしたこ
とを特徴とする恒速&J率磁芯。 (2)ζツク、コバルト、ニッケルのlf!または2種
以上と、周期律表第3乃至第7族遷移金朽元素の1種ブ
たは28f以上と、半金ハ元素の12I!または2種以
上とを含み、磁歪が正の性質を示す非晶η磁。 性合金で、1〜50チの結晶質を有し、かつ少なくとも
一部分を樹脂モールドした事を特徴とする恒速磁率磁芯
[Claims] (11) An amorphous magnetic alloy containing one or two quantities of iron, cobalt, and nickel, and one or more semimetallic elements, and exhibiting a positive magnetostriction property. , 1 to 50% of the crystalline phase has been cured, and at least a portion of the constant velocity & J ratio magnetic core is molded with resin. A non-crystalline η magnet containing one or more of the transition metal elements of Groups 3 to 7 of the Table of Laws and 12I! or two or more of the semimetal elements, and exhibiting a positive magnetostriction property. A constant-velocity magnetic core made of an alloy, having a crystallinity of 1 to 50 degrees, and having at least a portion molded with a resin.
JP58053767A 1983-03-31 1983-03-31 Constant permeability core Granted JPS59181504A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58053767A JPS59181504A (en) 1983-03-31 1983-03-31 Constant permeability core

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58053767A JPS59181504A (en) 1983-03-31 1983-03-31 Constant permeability core

Publications (2)

Publication Number Publication Date
JPS59181504A true JPS59181504A (en) 1984-10-16
JPH0544165B2 JPH0544165B2 (en) 1993-07-05

Family

ID=12951955

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58053767A Granted JPS59181504A (en) 1983-03-31 1983-03-31 Constant permeability core

Country Status (1)

Country Link
JP (1) JPS59181504A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2606873A1 (en) * 1986-11-13 1988-05-20 Ckd Corp PISTON POSITION DETECTOR FOR A PRESSURIZED FLUID CYLINDER
WO1997013259A1 (en) * 1995-10-05 1997-04-10 Alliedsignal Inc. Magnetic core-coil assembly for spark ignition systems
WO2000028556A1 (en) * 1998-11-06 2000-05-18 Honeywell International Inc. Bulk amorphous metal magnetic components
WO2001050483A1 (en) * 2000-01-05 2001-07-12 Honeywell International Inc. Bulk amorphous metal magnetic component
WO2001078088A1 (en) * 2000-04-06 2001-10-18 Honeywell International Inc. Bulk amorphous metal magnetic component
US6552639B2 (en) 2000-04-28 2003-04-22 Honeywell International Inc. Bulk stamped amorphous metal magnetic component
WO2003067615A1 (en) 2002-02-08 2003-08-14 Honeywell International Inc. Current transformer having an amorphous fe-based core
US6737951B1 (en) 2002-11-01 2004-05-18 Metglas, Inc. Bulk amorphous metal inductive device
US6873239B2 (en) 2002-11-01 2005-03-29 Metglas Inc. Bulk laminated amorphous metal inductive device
US7235910B2 (en) 2003-04-25 2007-06-26 Metglas, Inc. Selective etching process for cutting amorphous metal shapes and components made thereof
JP2011155278A (en) * 2003-01-30 2011-08-11 Metglas Inc Magnetic implement using magnetic metal ribbon coated with insulator

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