JPS59179155A - 流動床におけるエチレンのオキシクロリネ−シヨンによる1,2−ジクロルエタンの合成用の担持触媒 - Google Patents
流動床におけるエチレンのオキシクロリネ−シヨンによる1,2−ジクロルエタンの合成用の担持触媒Info
- Publication number
- JPS59179155A JPS59179155A JP59052446A JP5244684A JPS59179155A JP S59179155 A JPS59179155 A JP S59179155A JP 59052446 A JP59052446 A JP 59052446A JP 5244684 A JP5244684 A JP 5244684A JP S59179155 A JPS59179155 A JP S59179155A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- compound
- carrier
- mol
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims description 91
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 title claims description 21
- 230000015572 biosynthetic process Effects 0.000 title claims description 4
- 238000003786 synthesis reaction Methods 0.000 title claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title description 6
- 239000005977 Ethylene Substances 0.000 title description 6
- 239000010949 copper Substances 0.000 claims description 52
- 150000001875 compounds Chemical class 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 229910021592 Copper(II) chloride Inorganic materials 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 239000011148 porous material Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 238000004458 analytical method Methods 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- 239000002344 surface layer Substances 0.000 claims description 3
- 239000010410 layer Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 229910001629 magnesium chloride Inorganic materials 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 15
- 238000005243 fluidization Methods 0.000 description 12
- 239000000203 mixture Substances 0.000 description 10
- 239000011777 magnesium Substances 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 150000001805 chlorine compounds Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 230000004913 activation Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- BYFGZMCJNACEKR-UHFFFAOYSA-N aluminium(i) oxide Chemical compound [Al]O[Al] BYFGZMCJNACEKR-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 1
- 238000000295 emission spectrum Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000035987 intoxication Effects 0.000 description 1
- 231100000566 intoxication Toxicity 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- -1 rare earth chlorides Chemical class 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT20198/83A IT1163160B (it) | 1983-03-22 | 1983-03-22 | Catalizzatori supportati per la sintesi di 1-2 dicloroetano per ossiclorurazione di etilene in letto fluidizzato |
| IT20198A/83 | 1983-03-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59179155A true JPS59179155A (ja) | 1984-10-11 |
| JPH0361499B2 JPH0361499B2 (https=) | 1991-09-20 |
Family
ID=11164650
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59052446A Granted JPS59179155A (ja) | 1983-03-22 | 1984-03-21 | 流動床におけるエチレンのオキシクロリネ−シヨンによる1,2−ジクロルエタンの合成用の担持触媒 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4587230A (https=) |
| EP (1) | EP0119933B1 (https=) |
| JP (1) | JPS59179155A (https=) |
| DE (1) | DE3462434D1 (https=) |
| IT (1) | IT1163160B (https=) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4747552A (en) * | 1984-07-31 | 1988-05-31 | Takao Takasaki | Roll grinding blade |
| JPS63294949A (ja) * | 1987-02-13 | 1988-12-01 | エニチェム スインセシス エス・ピー・エー | オキシ塩素化触媒、その製造方法、及びそれを使用するエチレンのオキシ塩素化 |
| JP2002503536A (ja) * | 1998-01-08 | 2002-02-05 | イーヴィーシー・テクノロジー・アクチエン・ゲゼルシャフト | 触媒、その製造方法、および1,2−ジクロロエタンの合成におけるその使用 |
| JP2011083751A (ja) * | 2009-10-19 | 2011-04-28 | Jgc Catalysts & Chemicals Ltd | オキシクロリネーション用触媒の製造方法 |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1176719B (it) * | 1984-09-19 | 1987-08-18 | Ausind | Metodo per la preparazione di un catalizzatore per la sintesi di 1,2-dicloroetano |
| FR2641779B1 (fr) * | 1988-12-26 | 1991-04-19 | Atochem | Procede et catalyseur d'oxychloration, leur application a la production du 1-2 dichloroethane |
| US5192733A (en) * | 1989-12-15 | 1993-03-09 | Vulcan Materials Company | Oxychlorination catalysts comprising copper chloride supported on rare-earth-modified alumina, process for making such catalysts, and oxychlorination processes using them |
| US5004849A (en) * | 1989-12-15 | 1991-04-02 | Vulcan Chemicals | Manufacture of perchloroethylene and trichloroethylene by catalytic oxychlorination, and improved catalysts therefor |
| US5113027A (en) * | 1989-12-15 | 1992-05-12 | Vulcan Materials Company | Oxychlorination process using a catalyst which comprises copper chloride supported on rare-earth modified alumina |
| US5098878A (en) * | 1989-12-15 | 1992-03-24 | Vulcan Materials Company | Oxychlorination catalyst compositions and process of making same |
| FR2663629B1 (fr) * | 1990-06-25 | 1992-12-18 | Atochem | Procede et catalyseur d'oxychloration, leur application a la production du 1-2 dichloroethane. |
| ES2026073A6 (es) * | 1991-01-03 | 1992-04-01 | Aiscondel Sa | Procedimiento para la preparacion de un catalizador para la oxicloracion del etileno. |
| US5292703A (en) * | 1992-07-28 | 1994-03-08 | The Geon Company | Catalyst and process for oxychlorination of ethylene to EDC |
| US5395406A (en) * | 1993-05-11 | 1995-03-07 | Exxon Research And Engineering Company | Structurally modified alumina supports, and heat transfer solids for high temperature fluidized bed reactions |
| KR100453095B1 (ko) * | 1996-03-21 | 2005-05-03 | 인겔하드 코포레이션 | 구리/크롬촉매용도에적합한크롬비함유촉매의제조방법및이것의용도 |
| ITMI20012241A1 (it) * | 2001-10-25 | 2003-04-25 | Sued Chemie Mt Srl | Catalizzatori per l'ossiclorurazione dell'etilene a 1,2-dicloroetano |
| US6680279B2 (en) * | 2002-01-24 | 2004-01-20 | General Motors Corporation | Nanostructured catalyst particle/catalyst carrier particle system |
| ITMI20030630A1 (it) * | 2003-03-31 | 2004-10-01 | Sued Chemie Mt Srl | Catalizzatori per ossiclorurazione dell'etilene a 1,2-dicloroetano. |
| ITMI20042317A1 (it) | 2004-12-02 | 2005-03-02 | Sued Chemie Mt Srl | Catalizzatori per l'ossiclorurazione dell'etilene a 1,2-dicloroetano |
| KR100843599B1 (ko) | 2005-12-28 | 2008-07-03 | 주식회사 엘지화학 | 천연가스중의 메탄을 이용한 비닐클로라이드 단량체의 합성방법 |
| KR101017302B1 (ko) * | 2006-08-29 | 2011-02-28 | 주식회사 엘지화학 | 포화탄화수소로부터 클로로 화합물을 제조하는 방법 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57136943A (en) * | 1981-01-15 | 1982-08-24 | Ici Ltd | Oxychlorinating catalyst |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE636856A (https=) * | 1962-09-01 | 1900-01-01 | ||
| IT1030646B (it) * | 1974-10-04 | 1979-04-10 | Sir Soc Italiana Resine Spa | Procedimento er la produzione di dicloroetano |
| US4124534A (en) * | 1976-10-20 | 1978-11-07 | Diamond Shamrock Corporation | High temperature chlorination catalyst |
| EP0057796B1 (en) * | 1981-01-15 | 1985-11-27 | Imperial Chemical Industries Plc | Catalyst, catalyst support and oxychlorination process |
-
1983
- 1983-03-22 IT IT20198/83A patent/IT1163160B/it active
-
1984
- 1984-03-20 EP EP84400556A patent/EP0119933B1/en not_active Expired
- 1984-03-20 DE DE8484400556T patent/DE3462434D1/de not_active Expired
- 1984-03-21 JP JP59052446A patent/JPS59179155A/ja active Granted
-
1985
- 1985-06-07 US US06/742,238 patent/US4587230A/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57136943A (en) * | 1981-01-15 | 1982-08-24 | Ici Ltd | Oxychlorinating catalyst |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4747552A (en) * | 1984-07-31 | 1988-05-31 | Takao Takasaki | Roll grinding blade |
| JPS63294949A (ja) * | 1987-02-13 | 1988-12-01 | エニチェム スインセシス エス・ピー・エー | オキシ塩素化触媒、その製造方法、及びそれを使用するエチレンのオキシ塩素化 |
| JP2002503536A (ja) * | 1998-01-08 | 2002-02-05 | イーヴィーシー・テクノロジー・アクチエン・ゲゼルシャフト | 触媒、その製造方法、および1,2−ジクロロエタンの合成におけるその使用 |
| JP2011083751A (ja) * | 2009-10-19 | 2011-04-28 | Jgc Catalysts & Chemicals Ltd | オキシクロリネーション用触媒の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3462434D1 (en) | 1987-04-09 |
| EP0119933A3 (en) | 1984-12-12 |
| US4587230A (en) | 1986-05-06 |
| EP0119933A2 (en) | 1984-09-26 |
| IT8320198A0 (it) | 1983-03-22 |
| EP0119933B1 (en) | 1987-03-04 |
| JPH0361499B2 (https=) | 1991-09-20 |
| IT1163160B (it) | 1987-04-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |