JPS5911617B2 - 強化プラスチツクスおよびバインダ−製造用の水性ラテツクス材料 - Google Patents
強化プラスチツクスおよびバインダ−製造用の水性ラテツクス材料Info
- Publication number
- JPS5911617B2 JPS5911617B2 JP49147479A JP14747974A JPS5911617B2 JP S5911617 B2 JPS5911617 B2 JP S5911617B2 JP 49147479 A JP49147479 A JP 49147479A JP 14747974 A JP14747974 A JP 14747974A JP S5911617 B2 JPS5911617 B2 JP S5911617B2
- Authority
- JP
- Japan
- Prior art keywords
- latex
- silicic acid
- polymer
- particles
- organic polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000126 latex Polymers 0.000 title claims description 97
- 239000004816 latex Substances 0.000 title claims description 96
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 21
- 239000011230 binding agent Substances 0.000 title claims description 12
- 239000000463 material Substances 0.000 title claims description 12
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 239000002990 reinforced plastic Substances 0.000 title claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 80
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 72
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 61
- 239000002245 particle Substances 0.000 claims description 41
- 229920000642 polymer Polymers 0.000 claims description 28
- 239000000377 silicon dioxide Substances 0.000 claims description 26
- 238000001035 drying Methods 0.000 claims description 19
- 229920000620 organic polymer Polymers 0.000 claims description 17
- 239000000178 monomer Substances 0.000 claims description 14
- 230000002378 acidificating effect Effects 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 12
- 239000003513 alkali Substances 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 239000002775 capsule Substances 0.000 claims description 8
- 229920003023 plastic Polymers 0.000 claims description 8
- 239000004033 plastic Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 6
- 230000002776 aggregation Effects 0.000 claims description 6
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 230000020477 pH reduction Effects 0.000 claims description 4
- 238000005054 agglomeration Methods 0.000 claims description 3
- 239000008346 aqueous phase Substances 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 2
- 230000002441 reversible effect Effects 0.000 claims description 2
- 230000001939 inductive effect Effects 0.000 claims 1
- 238000006386 neutralization reaction Methods 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 229910052681 coesite Inorganic materials 0.000 description 14
- 229910052906 cristobalite Inorganic materials 0.000 description 14
- 229910052682 stishovite Inorganic materials 0.000 description 14
- 229910052905 tridymite Inorganic materials 0.000 description 14
- 239000004745 nonwoven fabric Substances 0.000 description 12
- 239000000835 fiber Substances 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- 238000005538 encapsulation Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000003973 paint Substances 0.000 description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 7
- 235000019353 potassium silicate Nutrition 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 239000007822 coupling agent Substances 0.000 description 6
- 239000000499 gel Substances 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000000151 deposition Methods 0.000 description 5
- 125000005624 silicic acid group Chemical group 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000000356 contaminant Substances 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 239000000741 silica gel Substances 0.000 description 4
- 229910002027 silica gel Inorganic materials 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 238000004220 aggregation Methods 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000012065 filter cake Substances 0.000 description 3
- 238000005189 flocculation Methods 0.000 description 3
- 230000016615 flocculation Effects 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000002985 plastic film Substances 0.000 description 3
- 229920006255 plastic film Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000003929 acidic solution Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 230000005499 meniscus Effects 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 1
- 229920005789 ACRONAL® acrylic binder Polymers 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910004742 Na2 O Inorganic materials 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000021523 carboxylation Effects 0.000 description 1
- 238000006473 carboxylation reaction Methods 0.000 description 1
- -1 cationic ion Chemical class 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000004482 other powder Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/205—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase
- C08J3/21—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase
- C08J3/215—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase at least one additive being also premixed with a liquid phase
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paper (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Silicon Compounds (AREA)
- Laminated Bodies (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Reinforced Plastic Materials (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE7317389 | 1973-12-21 | ||
| SE7317389A SE430420B (sv) | 1973-12-21 | 1973-12-21 | Sett att framstella ett latexmaterial med modifierade koagulerings- och filmbildningsegenskaper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS50138039A JPS50138039A (enExample) | 1975-11-04 |
| JPS5911617B2 true JPS5911617B2 (ja) | 1984-03-16 |
Family
ID=20319495
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP49147479A Expired JPS5911617B2 (ja) | 1973-12-21 | 1974-12-20 | 強化プラスチツクスおよびバインダ−製造用の水性ラテツクス材料 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US3969295A (enExample) |
| JP (1) | JPS5911617B2 (enExample) |
| AT (2) | AT344984B (enExample) |
| BE (1) | BE823380A (enExample) |
| CA (1) | CA1040772A (enExample) |
| CH (1) | CH606217A5 (enExample) |
| DE (1) | DE2458892C2 (enExample) |
| DK (1) | DK660474A (enExample) |
| FI (1) | FI60570C (enExample) |
| FR (1) | FR2255339B1 (enExample) |
| GB (1) | GB1457690A (enExample) |
| IT (1) | IT1024477B (enExample) |
| NL (1) | NL183194C (enExample) |
| NO (1) | NO140014C (enExample) |
| SE (1) | SE430420B (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE429658B (sv) * | 1978-04-26 | 1983-09-19 | Elektrokemiska Ab | Migreringsobeneget latexmaterial till anvendning som bindemedel for fibrer, pigmentpartiklar m.m. samt sett att framstella detsamma |
| SE429767B (sv) * | 1979-01-18 | 1983-09-26 | Elektrokemiska Ab | Forfarande for framstellning av nalfiltmatta samt nalfiltmatta framstelld enligt forfarandet |
| DE3627469A1 (de) * | 1986-08-13 | 1988-02-25 | Henkel Kgaa | Verfahren zur ueberfuehrung von organophosphonsaeuren in die alkali- oder ammoniumsalze |
| US6953825B1 (en) * | 1995-11-22 | 2005-10-11 | Cabot Corporation | Treated carbonaceous compositions and polymer compositions containing the same |
| CN102153792B (zh) * | 2011-03-17 | 2012-07-18 | 株洲安宝麟锋新材料有限公司 | 湿法混炼天然橡胶料的制备方法 |
| CN114956094A (zh) * | 2021-02-24 | 2022-08-30 | 中国石油化工股份有限公司 | 白炭黑纳米分散液及其制备方法与应用 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2467339A (en) * | 1944-11-17 | 1949-04-12 | Monsanto Chemicals | Vinyl aromatic compositions containing colloidal silica |
| US2560043A (en) * | 1947-06-26 | 1951-07-10 | Firestone Tire & Rubber Co | Method of reinforcing rubberlike materials |
| US2616860A (en) * | 1951-09-06 | 1952-11-04 | Us Rubber Co | Reinforcing synthetic rubber |
| US2885366A (en) * | 1956-06-28 | 1959-05-05 | Du Pont | Product comprising a skin of dense, hydrated amorphous silica bound upon a core of another solid material and process of making same |
| US2964490A (en) * | 1957-03-12 | 1960-12-13 | Us Rubber Co | Butadiene copolymer rubber-silica masterbatch and process of preparation |
| NL133443C (enExample) * | 1961-08-21 | |||
| NL283139A (enExample) * | 1962-03-17 | |||
| NL131624C (enExample) | 1965-04-12 | |||
| DE1802761A1 (de) * | 1968-10-12 | 1970-06-11 | Deutsche Gold- U. Silber-Scheideanstalt, Vorm. Roessler, 6000 Frankfurt | Verfahren zur Herstellung pulverfoermiger Kautschukvormischungen |
| US3817911A (en) * | 1972-04-07 | 1974-06-18 | L Taylor | Direct synthesis of composite materials |
-
1973
- 1973-12-21 SE SE7317389A patent/SE430420B/xx unknown
- 1973-12-21 CA CA216,403A patent/CA1040772A/en not_active Expired
-
1974
- 1974-12-06 US US05/530,504 patent/US3969295A/en not_active Expired - Lifetime
- 1974-12-09 GB GB5305574A patent/GB1457690A/en not_active Expired
- 1974-12-12 DE DE2458892A patent/DE2458892C2/de not_active Expired
- 1974-12-13 NL NLAANVRAGE7416305,A patent/NL183194C/xx not_active IP Right Cessation
- 1974-12-16 IT IT54576/74A patent/IT1024477B/it active
- 1974-12-16 BE BE151526A patent/BE823380A/xx not_active IP Right Cessation
- 1974-12-18 DK DK660474A patent/DK660474A/da not_active Application Discontinuation
- 1974-12-19 AT AT1017574A patent/AT344984B/de active
- 1974-12-19 FI FI3692/74A patent/FI60570C/fi active
- 1974-12-19 AT AT1017574A patent/ATA1017574A/de unknown
- 1974-12-19 CH CH1696074A patent/CH606217A5/xx not_active IP Right Cessation
- 1974-12-20 JP JP49147479A patent/JPS5911617B2/ja not_active Expired
- 1974-12-20 FR FR7442168A patent/FR2255339B1/fr not_active Expired
- 1974-12-20 NO NO744620A patent/NO140014C/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL183194C (nl) | 1988-08-16 |
| CH606217A5 (enExample) | 1978-10-31 |
| BE823380A (fr) | 1975-04-16 |
| CA1040772A (en) | 1978-10-17 |
| NO140014B (no) | 1979-03-12 |
| FR2255339B1 (enExample) | 1979-08-24 |
| NL183194B (nl) | 1988-03-16 |
| FR2255339A1 (enExample) | 1975-07-18 |
| DE2458892C2 (de) | 1986-04-24 |
| US3969295A (en) | 1976-07-13 |
| JPS50138039A (enExample) | 1975-11-04 |
| FI369274A7 (enExample) | 1975-06-22 |
| NL7416305A (nl) | 1975-06-24 |
| SE7317389L (enExample) | 1975-06-23 |
| NO744620L (enExample) | 1975-07-21 |
| FI60570C (fi) | 1982-02-10 |
| IT1024477B (it) | 1978-06-20 |
| AT344984B (de) | 1978-08-25 |
| SE430420B (sv) | 1983-11-14 |
| ATA1017574A (de) | 1977-12-15 |
| DE2458892A1 (de) | 1975-07-03 |
| GB1457690A (en) | 1976-12-08 |
| DK660474A (enExample) | 1975-09-01 |
| NO140014C (no) | 1979-06-20 |
| FI60570B (fi) | 1981-10-30 |
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