JPS58221338A - Oxygen-rich air supplying device - Google Patents

Oxygen-rich air supplying device

Info

Publication number
JPS58221338A
JPS58221338A JP57105177A JP10517782A JPS58221338A JP S58221338 A JPS58221338 A JP S58221338A JP 57105177 A JP57105177 A JP 57105177A JP 10517782 A JP10517782 A JP 10517782A JP S58221338 A JPS58221338 A JP S58221338A
Authority
JP
Japan
Prior art keywords
oxygen
air
membrane
enriched
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP57105177A
Other languages
Japanese (ja)
Other versions
JPS6214066B2 (en
Inventor
Yutaka Yamamoto
豊 山本
Jiro Sakata
二郎 坂田
Masaharu Sumiyoshi
住吉 正治
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyota Central R&D Labs Inc
Original Assignee
Toyota Central R&D Labs Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyota Central R&D Labs Inc filed Critical Toyota Central R&D Labs Inc
Priority to JP57105177A priority Critical patent/JPS58221338A/en
Priority to GB08315986A priority patent/GB2122103A/en
Publication of JPS58221338A publication Critical patent/JPS58221338A/en
Publication of JPS6214066B2 publication Critical patent/JPS6214066B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • B01D69/125In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
    • B01D69/127In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction using electrical discharge or plasma-polymerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60HARRANGEMENTS OF HEATING, COOLING, VENTILATING OR OTHER AIR-TREATING DEVICES SPECIALLY ADAPTED FOR PASSENGER OR GOODS SPACES OF VEHICLES
    • B60H3/00Other air-treating devices
    • B60H3/0007Adding substances other than water to the air, e.g. perfume, oxygen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02Preparation of oxygen
    • C01B13/0229Purification or separation processes
    • C01B13/0248Physical processing only
    • C01B13/0251Physical processing only by making use of membranes
    • C01B13/0255Physical processing only by making use of membranes characterised by the type of membrane
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F3/00Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems
    • F24F3/12Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00Purification or separation of specific gases
    • C01B2210/0043Impurity removed
    • C01B2210/0046Nitrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00Purification or separation of specific gases
    • C01B2210/0043Impurity removed
    • C01B2210/0051Carbon dioxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F3/00Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems
    • F24F3/12Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling
    • F24F3/14Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification
    • F24F2003/1435Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification comprising semi-permeable membrane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Air Filters, Heat-Exchange Apparatuses, And Housings Of Air-Conditioning Units (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

PURPOSE:To provide an oxygen amplified air supplying device capable of obtaining oxygen amplified air, having a high containing rate of oxygen, from air by a method wherein an oxygen amplifier having an oxygen amplifying film constituted by forming a high-polymerized thin film on a porous supporting film, a fan, taking air from a suction port and sending it by a pressure to the oxygen amplifier, and a suction pump, sucking and filtrating the air sent by pressure to the oxygen amplifier through an oxygen amplifying film, are utilized. CONSTITUTION:The oxygen amplifier 12 is formed by bundling the oxygen amplifying film 10, employing hollow thread-like porous glass as the supporting film. The oxygen amplifying film 10 is opened at the both ends thereof and is held in a sealed condition in the flow path of the air in the vessel 19 by employing seal members 22A, 22B. Air is taken from a suction port 14 by driving the fan 16 and is sent by the pressure into the oxygen amplifier 12 while the air is sucked and filtrated through the oxygen amplifying film 10 by driving the suction pump 18 and, thus, the oxygen-rich air is supplied from a blow off port 20. Gas, except said air, such as nitrogen, carbon mono-oxide, carbon dioxide or the like, for example, are discharged out of a discharging port 24.

Description

【発明の詳細な説明】 ゛本発明は酸素富化空気供給装置、特に清浄化された酸
素富化空気を提供する酸素富化空気供給装置に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an oxygen-enriched air supply system, and more particularly to an oxygen-enriched air supply system that provides purified oxygen-enriched air.

人間が快適に生活し活動するためには、その周囲に清浄
化され所定量の酸素を含んだ空気が存在することが必要
である。従って、入間の生活空間内の空気が汚染された
場合には、速かにその空気を清浄にし必要な酸素を供給
する必要がある。
In order for humans to live and work comfortably, it is necessary that clean air containing a predetermined amount of oxygen exists around them. Therefore, when the air in the room's living space becomes contaminated, it is necessary to quickly purify the air and supply the necessary oxygen.

特K、ある程度密閉された生活空間内においてはこの必
要性が高く、例えば自動車による長距離走行の場合に車
室内への富化空気の供給が要望される。これは、車両内
を冷暖房しながら多数の人間か車両内圧いると、呼気に
よる二酸化炭素00!や喫煙による一酸化炭素COが空
気内圧発生し、その分空気中に含まれる酸素の含有率が
低下し、ドライバの疲労感を促進させ、眠けの原因とな
るからである。従って、車両内の空気から有毒ガス(c
o、Co、 )  を速かに除去し、かつ空気中の酸素
含有率を高めることが安全運転上及び快適なドライブ環
境を得る上でも必要である。
This is particularly necessary in a living space that is somewhat sealed, and for example, when driving a car over long distances, it is required to supply enriched air to the interior of the vehicle. This means that when there are many people inside the vehicle while heating and cooling the vehicle, the amount of carbon dioxide from exhalation is 000! This is because carbon monoxide (CO) caused by smoking and carbon monoxide generates internal air pressure, and the oxygen content in the air decreases by that amount, accelerating driver fatigue and causing drowsiness. Therefore, toxic gases (c) are removed from the air inside the vehicle.
It is necessary to quickly remove O, Co, ) and increase the oxygen content in the air for safe driving and for obtaining a comfortable driving environment.

このため、従来、微細孔フィルタ、電気集塵、活性炭フ
ィルタ等による空調システムが開発され商品化されてお
シ、車両内の汚れた空気の清浄化をかなシの程度まで行
なっている。
For this reason, air conditioning systems using microporous filters, electrostatic precipitators, activated carbon filters, and the like have been developed and commercialized, and have been used to purify the dirty air inside vehicles to a certain extent.

しかし、このような空調システムでは、密閉された車両
空間内に発生する二酸化炭素COや一酸化炭素CO,を
充分に除去することができず、しかも、その構造上空気
中に含まれる酸素含有率を高めることはできなかった。
However, such air conditioning systems cannot sufficiently remove carbon dioxide (CO) and carbon monoxide (CO) generated within the closed vehicle space, and due to their structure, the oxygen content in the air is low. could not be increased.

このため、ドライバは窓を開けて車内の空気を定期的に
入替える必要があり、このようなことは、冷暖房の負担
の増大及び高速道路走行中にあっては安全運転上の問題
等の2次的な諸問題を引きおこす原因となシ、その改良
が求められていた。
For this reason, the driver must open the windows to periodically replace the air inside the car, which increases the burden on air conditioning and raises safety issues when driving on expressways. There was a need to improve this as it was the cause of the following problems.

また、このような車両用に限らず、他の方面からも、汚
れた空気を速かに清浄にし必要な酸素を供給することが
できる装置の開発が望まれている。
Furthermore, the development of a device that can quickly clean dirty air and supply necessary oxygen is desired not only for use in such vehicles but also for other purposes.

本発明はこのような従来の課題に鑑みなされたものであ
シ、その目的は、空気中から酸素を優先的に透過し、清
浄化されかつ酸素の含有率の高い酸素富化空気を得るこ
との可能な酸素富化空気供給装置を提供することにある
The present invention was made in view of such conventional problems, and its purpose is to obtain purified oxygen-enriched air with a high oxygen content by preferentially transmitting oxygen from the air. The object of the present invention is to provide an oxygen-enriched air supply device capable of providing oxygen-enriched air.

この目的達成のため、本発明の装置は、多孔質支持膜上
Km分子薄膜を形成してなる酸素富化膜を有する酸素富
化器と、吸入口々1ら空・気を取込み酸素富化器に加圧
送風する送風器と、酸素富化器に加圧送風された空気を
酸素富化膜を介して吸引透過する吸引ポンプと、を備え
、加圧送風された空気を吸引透過する際酸素富化膜によ
り酸素を優先的に選択透過し、酸素含有率の高い酸素富
化空気を得ることを特徴とする。
In order to achieve this objective, the device of the present invention includes an oxygen enricher having an oxygen enriching membrane formed by forming a thin film of Km molecules on a porous support membrane, and an oxygen enricher that takes in air from each inlet port and enriches oxygen. It is equipped with an air blower that blows pressurized air into the oxygen enricher, and a suction pump that sucks and permeates the air pressurized into the oxygen enricher through an oxygen enrichment membrane. It is characterized by selectively permeating oxygen through an oxygen-enriching membrane to obtain oxygen-enriched air with a high oxygen content.

次に本発明の好適な実施例を説明する。Next, preferred embodiments of the present invention will be described.

本発明は、多孔質支持膜上に高分子薄膜を形成してなる
酸素富化膜が、酸素に対し優れた選択透過特性を示し、
チッ素、−酸化炭素、二酸化炭素、に対し優れた選択分
離特性を示すことに着目してなされたものであシ、その
特徴的事項は、このような酸素富化膜を用いて、空気中
から酸素を優先的に選択透過し、清浄化されかつ酸素の
含有率の高い酸素富化空気を得ることにある。
The present invention provides an oxygen-enriched membrane formed by forming a thin polymer film on a porous support membrane, which exhibits excellent permselective properties for oxygen.
It was developed based on its excellent selective separation properties for nitrogen, carbon oxides, and carbon dioxide. The object of the present invention is to selectively permeate oxygen from the air to obtain purified, oxygen-enriched air with a high oxygen content.

第1図には本発明の酸素富化空気供給装置の好適な実施
例が示されており、実施例の装置は、多孔質支持膜表面
に高分子薄膜をプラズマ重合してなる酸素富化膜10を
有する酸素富化器12と、吸入口14がら空気を取込み
酸素富化器12に加圧送風する送風器16と、酸素富化
器12に加圧送風された空気を酸素富化膜lOを介して
吸引透過する吸引ポンプ18と1、が耐圧容器19内に
備えられ、加圧送風された空気を吸引透過する際酸素富
化膜1GICより酸素を優先的に選択透過し、酸素含有
率の高い酸素富化空気を吹出口20から供給している。
FIG. 1 shows a preferred embodiment of the oxygen-enriched air supply device of the present invention. an oxygen enricher 12 having an oxygen enricher 10; Suction pumps 18 and 1 are provided in the pressure container 19, and when pressurized air is sucked and permeated, they selectively permeate oxygen through the oxygen enrichment membrane 1GIC, thereby increasing the oxygen content. Highly oxygen-enriched air is supplied from the outlet 20.

実施例の酸素富化膜10は、多孔質支持膜として、硼硅
酸ガラス(70重量%810..25重量−B、 o、
、5重量%Na、O)を溶融紡糸シ、シカル後600℃
大気圧下で50時間熱処理を施し、更に96℃のi N
Hat溶液で数時間酸抽出した後、水洗風砕して形成さ
れた中空糸状多孔質ガラスを用いた。
The oxygen enrichment membrane 10 of the example contains borosilicate glass (70% by weight 810..25% by weight-B, o,
, 5 wt% Na, O) was melt-spun and heated at 600°C after sical.
Heat treated at atmospheric pressure for 50 hours, and then heated to 96°C iN
A hollow fiber-like porous glass formed by acid extraction with a Hat solution for several hours, washing with water, and crushing was used.

また、多孔質支持膜上にプラズマ重合される高分子薄膜
としては、有機シリコン化合物、例えばヘキサメチルジ
シロキサンを原料ガスとして用い、とれをプラズマ重合
により多孔質支持膜表面に積層形成している。
Further, as a polymer thin film to be plasma polymerized on a porous support membrane, an organic silicon compound such as hexamethyldisiloxane is used as a raw material gas, and the resulting material is laminated on the surface of the porous support membrane by plasma polymerization.

このような多孔質支持膜表面への高分子薄膜のプラズマ
重合は、多孔質支持膜を反応容器内圧設置し、この反応
容器内に真空排気をしながら原料ガスであるヘキサメチ
ルジシロキサンを0.2)−ルになるように封入調整し
、しかる後13.56 MH2の高周波電界を加えて仁
の原料ガスをゾラズV状態にして約20分間反応させる
ことによシ行なう。
In such plasma polymerization of a thin polymer film on the surface of a porous support membrane, the porous support membrane is placed in a reaction vessel under internal pressure, and while the reaction vessel is evacuated, hexamethyldisiloxane, which is a raw material gas, is injected at 0.00%. 2) Adjust the sealing so that the gas is 1.0-2 mm, and then apply a high-frequency electric field of 13.56 MH2 to bring the raw material gas into the Zolaz V state and allow the reaction to occur for about 20 minutes.

本実施例においては、以上のように中空糸状多孔質ガラ
スを多孔質支持膜として用いて酸素富化膜を形成するた
め、酸素富化膜10は中空糸状の細管形状に形成される
In this example, since the oxygen-enriching membrane is formed using the hollow fiber-like porous glass as the porous support membrane as described above, the oxygen-enriching membrane 10 is formed in the shape of a hollow fiber-like thin tube.

実施例の酸素富化器12は、前述し丸ごとく形成された
中空糸状酸素富化膜lOを1500本程束ねて形成され
ている。そして、その酸素富化膜100両端が第2図に
示すごとく開口された状態で、シール材22A、22B
を用いて容器19の空気流路内に密閉保持されている1
、これにより、この装置の空気流路は、吸入口14側と
、吹出口204Mとが、酸素富化膜10JCよシ分離さ
れることとなり、吸入口14から取込まれた空気は送風
器16により酸素富化膜10の管路内に加圧送風□ され、このように管路内に加圧送風された空気は酸素富
化膜10の管路外部から吸引ポンプ18を用いて吸引透
過される仁ととなる。
The oxygen enricher 12 of the embodiment is formed by bundling approximately 1,500 hollow fiber oxygen enrichment membranes 10, which are formed as a whole as described above. Then, with both ends of the oxygen enriched membrane 100 opened as shown in FIG.
1 which is held hermetically within the air flow path of the container 19 using
As a result, in the air flow path of this device, the inlet 14 side and the outlet 204M are separated by the oxygen enrichment membrane 10JC, and the air taken in from the inlet 14 is sent to the blower 16. The pressurized air is blown into the pipeline of the oxygen-enriching membrane 10 by □, and the air thus blown into the pipeline is suctioned and permeated from outside the pipeline of the oxygen-enriching membrane 10 using the suction pump 18. It becomes Rujin.

ここにおいて、前述したごとく、酸素富化膜10は酸素
を優先的に選択透過するため、加圧送風された空気を酸
素富化膜10を介して吸引透過することによシ得られた
空気は酸素含有率の高いものとなり、吹田口20からは
酸素含有率の高い清浄な空気を得ることができる。
Here, as mentioned above, since the oxygen-enriching membrane 10 selectively permeates oxygen, the air obtained by suctioning and permeating pressurized air through the oxygen-enriching membrane 10 is The air has a high oxygen content, and clean air with a high oxygen content can be obtained from the Suita mouth 20.

また、酸素富化膜10は、前述したごとく、チッ素、−
酸化炭素、二酸化炭素、等を選択分離するため、このよ
うな気体は酸素富化膜10により透過される割合が相対
的に低い。このため、酸素富化膜10によシこのように
選択分離される気体を排出する必要があシ、本実施例に
おいては、酸素富化器12を介して吸入口14と反対側
に排気口24を設けている。
Further, as mentioned above, the oxygen enriched film 10 contains nitrogen, -
Since carbon oxide, carbon dioxide, etc. are selectively separated, the rate of permeation of such gases through the oxygen enrichment membrane 10 is relatively low. For this reason, it is necessary to exhaust the gas selectively separated in this way by the oxygen enrichment membrane 10. In this embodiment, an exhaust port is provided on the side opposite to the inlet port 14 via the oxygen enricher 12. There are 24.

従って、吸入口14から送風器16により取込まれ酸素
富化膜10の管路内に加圧送風される空気は、この酸素
富化膜10の管路内において選択的に分離され、酸素富
化膜10を吸引透過して得られる空気は酸素含有率の高
い酸素富化空気として吹出口20から供給され、とれ以
外の空気、例えばチッ素、−酸化炭素、二酸化炭素等は
排気口24から排出される。
Therefore, the air taken in by the blower 16 from the suction port 14 and blown under pressure into the pipe line of the oxygen-enriching membrane 10 is selectively separated in the pipe line of the oxygen-enriching membrane 10, and is enriched with oxygen. The air obtained by suctioning and permeating through the chemical membrane 10 is supplied from the outlet 20 as oxygen-enriched air with a high oxygen content, and air other than that, such as nitrogen, carbon oxide, carbon dioxide, etc., is supplied from the exhaust port 24. be discharged.

なお、本実施例の装置において、送風器16及び吸引ポ
ンプ18は共通のモータ26によシ駆動され、装置の小
型化が図られている。また、実施例の装置においては、
吸入口14の内部にプレフィルタ2Bが設はシれておシ
、吸入口14から取込まれる空気から塵、埃、オイル分
が除去され、供給装置の内部、特に酸素富化膜が汚れる
のを防止している。
In the apparatus of this embodiment, the blower 16 and the suction pump 18 are driven by a common motor 26, thereby reducing the size of the apparatus. In addition, in the device of the example,
A pre-filter 2B is installed inside the suction port 14 to remove dirt, dirt, and oil from the air taken in from the suction port 14, thereby preventing the inside of the supply device, especially the oxygen enrichment membrane, from becoming contaminated. is prevented.

また、本発明のごとく、酸素富化膜10を介して酸素を
優先的に選択透過する構造のものでは、酸素富化空気を
効率よく得るために、酸素富化膜10の管路内に対して
その管路外すなわち吸引ポンプ側が完全に負の圧力とな
っていることが必要である。このため、本実施例の装置
においては、送風器16及び吸引ポンプ18にベーン型
のポンプあるいはダイヤフラム型のポンプを用いている
In addition, in a structure in which oxygen is preferentially permeated through the oxygen-enriching membrane 10 as in the present invention, in order to efficiently obtain oxygen-enriched air, the inside of the pipe of the oxygen-enriching membrane 10 is It is necessary that the pressure outside the pipe, that is, on the suction pump side, is completely negative. For this reason, in the apparatus of this embodiment, a vane type pump or a diaphragm type pump is used for the blower 16 and the suction pump 18.

本発明は以上の構成からなり、次にその作用を説明する
The present invention has the above configuration, and its operation will be explained next.

本発明の酸素富化空気供給装置は、送風器16を駆動す
るととにより吸入口14がら空気を取込み酸素富化器1
2内に加圧送風し、このように加圧送風された空気を吸
引ポンプ18を駆動することにより酸素富化膜1oを介
して吸引透過し、吹出口20から所定の空気を供給して
いる。
The oxygen-enriched air supply device of the present invention takes in air from the suction port 14 when the blower 16 is driven, and the oxygen enricher 1
2, and by driving the suction pump 18, the pressurized air is sucked and permeated through the oxygen enrichment membrane 1o, and a predetermined amount of air is supplied from the air outlet 20. .

こζにおいて、前述したごとく、酸素富化膜1゜は酸素
を優先的に選択透過し、チッ素、−酸化炭素、二酸化炭
素、等の気体を選択分離する特性があるため、吹出口2
oから供給される空気は、酸素の含有率が高く、−酸化
炭素、二酸化炭素、その他の有害なガスを含まない清浄
な酸素富化空気とがる。
In this ζ, as mentioned above, the oxygen-enriching membrane 1゜ has the characteristic of preferentially permeating oxygen and selectively separating gases such as nitrogen, carbon oxide, and carbon dioxide.
The air supplied from o is clean, oxygen-enriched air that has a high oxygen content and does not contain carbon oxides, carbon dioxide, or other harmful gases.

実験によれば、約10cmの有効長を有する細管状の酸
素富化膜1oを用い、このように形成された酸素富化膜
1oの管路内に送風器16にょシ1、5 kg /イの
高圧空気を加圧送風し、吸引ポンプ18を駆動し20o
トールの吸引透過を行なった場合、吹出口2oからは3
7%の酸素を含んだ酸素富化空気が細管状に形成された
酸素富化膜1゜のモジュール1本当り毎分11以上得ら
れることが確認された。
According to experiments, using a thin tube-shaped oxygen-enriching membrane 1o having an effective length of about 10 cm, a blower 16 was placed in the pipe of the oxygen-enriching membrane 1o formed in this way at a rate of 1.5 kg/i. Blow high pressure air under pressure and drive the suction pump 18 to 20o
When performing suction permeation of Thor, 3
It was confirmed that oxygen-enriched air containing 7% oxygen could be obtained at a rate of 11 or more per minute per module with a 1° oxygen-enriched membrane formed in a tubular shape.

本発明の酸素富化供給装置は、送風器16の圧力を高め
るかまたは酸素富化膜lOの本数を増せば、吹出口20
から供給される酸素富化空気の量を必要に応じて増大さ
せることができるため、その幅広い用途が考えられる。
In the oxygen enrichment supply device of the present invention, if the pressure of the blower 16 is increased or the number of oxygen enrichment membranes 10 is increased, the air outlet 20
Since the amount of oxygen-enriched air supplied by the air can be increased as needed, its wide range of applications is conceivable.

その用途の好適な一例として、酸素富化供給装置を自動
車の空調用に用いることが考えられる。
One suitable example of its use is that the oxygen-enriched supply device is used for air conditioning in automobiles.

一般に成人の呼気には16.4%の酸素0.と4.1%
の二酸化炭素CO,が含まれておシ、車両のごとき密閉
空間においては、二酸化炭素の量が時間的に増大する。
Generally, an adult's breath contains 16.4% oxygen and 0. and 4.1%
In a closed space such as a vehicle, the amount of carbon dioxide increases over time.

この二酸化炭素濃度と人間の暴露時間とは密接な関係が
あシ、二酸化炭素濃度が2−を越えると人間は10分位
で僅かな知覚の変化を覚え、二酸化炭素の濃度が3%を
越えると20分位で人間は気持を混乱させる程度の不快
感を覚える。そして、二酸化炭素濃度が4%を越えると
6分か7分程度で気持を混乱させる不快感を覚えるよう
Kなる。従って、安全運転上、このような車室内の二酸
化炭素濃度を一定値内まで下げる必要がある。この目的
の丸め、本発明の酸素富化空気供給装置を車両用の空調
装置として用いれば、酸素含有率が高い酸素富化空気を
車室内に供給することができる。このようにして、車室
内に酸素含有率の高い空気を供給することによシ、実質
的に二酸化炭素濃度を低下せしめドライバの疲労感の回
復及び眠は防止を図ることができる。
There is a close relationship between this carbon dioxide concentration and the exposure time of humans.When the carbon dioxide concentration exceeds 2-2, humans notice a slight change in perception within about 10 minutes, and when the carbon dioxide concentration exceeds 3%. After about 20 minutes, humans experience a level of discomfort that confuses their feelings. When the carbon dioxide concentration exceeds 4%, it takes about 6 or 7 minutes for the body to become uncomfortable and cause confusion. Therefore, for safe driving, it is necessary to reduce the carbon dioxide concentration in the vehicle interior to within a certain value. To achieve this objective, if the oxygen-enriched air supply device of the present invention is used as an air conditioner for a vehicle, oxygen-enriched air with a high oxygen content can be supplied into the vehicle interior. In this way, by supplying air with a high oxygen content into the vehicle interior, it is possible to substantially reduce the carbon dioxide concentration, thereby recovering the driver's feeling of fatigue and preventing him from falling asleep.

このような車室内への酸素富化空気の供給は、車室内全
体に均一に行なってもよく、また、ドライバおよび必要
を感する者に局部的に行なってもよい。
Such supply of oxygen-enriched air into the vehicle interior may be uniformly provided throughout the vehicle interior, or may be supplied locally to the driver and other persons who feel the need.

なお、本発明の酸素富化空気は、37−程度の酸素を含
む酸素富化空気を供給するため酸素中毒の問題が考えら
れるが、1気圧中において空気中の酸素含有率が40%
程度までは酸素中毒による危険はtlとんど無視できる
ため実用上:何ら問題はない。すなわち酸素中毒は、3
oチ程度の酸素含有率の空気中において150時間位で
症状が発現し、40%程度の酸素含有率の空気中では6
0時間位で症状が発現するにすぎない。しかし、このよ
うな長時間ドライバが連続運転することは考えられず、
従って酸素中毒による危険はtまとんど問題がないと考
えることができるからである。
Note that the oxygen-enriched air of the present invention supplies oxygen-enriched air containing about 37% oxygen, so there may be a problem of oxygen poisoning, but the oxygen content of the air is 40% at 1 atm.
To a certain extent, the danger of oxygen poisoning can be ignored, so in practice: there is no problem. In other words, oxygen poisoning is 3
Symptoms appear after about 150 hours in air with an oxygen content of about 40%, and 6 hours in air with an oxygen content of about 40%.
Symptoms only appear at about 0 hours. However, it is unthinkable for drivers to drive continuously for such long periods of time.
Therefore, it can be considered that there is no danger of oxygen poisoning.

また、本発明の酸素富化空気供給装置を車両用の空調装
置として用いた場合には、本発明の装置は非常に小型軽
量であるため、車両スペースの有効な活用を図る仁とが
できる〇 また、本発明の用途は車両用に限定されるものではなく
、小型軽量な酸素富化空気供給装置として、幅広い用途
が考えられる。
Furthermore, when the oxygen-enriched air supply device of the present invention is used as an air conditioner for a vehicle, the device of the present invention is very small and lightweight, so it is possible to make effective use of vehicle space. Moreover, the application of the present invention is not limited to vehicles, and can be used in a wide range of applications as a small and lightweight oxygen-enriched air supply device.

例えば、本発明を非常用のポータプル呼吸器として用い
れば、高層ビルの火災時にこれを携帯することにより有
毒ガス及び酸素欠乏による電大事故発生を最小限にくい
止めることが可能である。
For example, if the present invention is used as an emergency portable respirator, it is possible to minimize the occurrence of electrical accidents caused by toxic gas and oxygen deficiency by carrying the same in the event of a fire in a high-rise building.

また、海水浴場、ブール等圧設置しておけば、溺水者の
酸素吸入用としても用いることが可能となる。また、本
発明に係るポアタプル吸Mt−標高の高い例えば山小屋
等に設置しておけば、高山病に罹った登山者の酸素吸入
にも用いることができる。
Additionally, if installed at a beach or in a boule with equal pressure, it can be used for oxygen inhalation for drowning people. Furthermore, if the Poataple suction Mt according to the present invention is installed at a high altitude, such as a mountain hut, it can be used for oxygen inhalation by climbers suffering from altitude sickness.

また、本発明の酸素富化空気供給装置をピルまたは家庭
用の空調装置としても用いることも可能であり、この場
合、冷房、暖房された室内の空気をそのtま選択透過し
酸素富化空気を得ることができるため、冷暖房の負担を
軽減する省エネルギ型の空調システムを構成することが
できる。この際空調システムの動作を、周期的な作動、
センサの検出信号による作動、常時作動、手動作動、等
のいずれにも切替可能とすれば便利である。
The oxygen-enriched air supply device of the present invention can also be used as a pill or home air conditioner; in this case, the air in a cooled or heated room is selectively permeated to produce oxygen-enriched air. Therefore, it is possible to construct an energy-saving air conditioning system that reduces the burden of heating and cooling. At this time, the operation of the air conditioning system is controlled by periodic operation,
It would be convenient to be able to switch between operation based on a sensor detection signal, constant operation, manual operation, etc.

なお、本実施例の酸素富化膜10は、多孔質支持膜とし
て一定の条件下で形成される中空糸状多孔質ガラスを用
いたが、これに限らず、他の材料、例えば数十オングス
トローム(X)かう数マイクo/−夕の孔を有する多孔
質フィルムを用いルコとも可能であシ、この場合には多
孔質支持膜は平膜形状となるため、酸素富化膜1oは平
膜状に形成されることとなる。
Although the oxygen enrichment membrane 10 of this example used hollow fiber porous glass formed under certain conditions as a porous support membrane, it is not limited to this, and other materials such as tens of angstroms ( X) It is also possible to use a porous film with several micropores, and in this case, the porous support membrane has a flat membrane shape, so the oxygen enrichment membrane 1o has a flat membrane shape. will be formed.

また、前記実施例においては、酸素富化器の酸素富化膜
を細管伏に形成し、吸入口から送風器を用いて取込まれ
た空気を酸素富化膜の管路内に加圧送風し、加圧送風さ
れた空気を酸素富化膜の管路外部から吸引ポンプを用い
て吸引透過する構造の酸素富化空気供給装置を示したが
、これに限らず、例えば、酸素富化器の酸素富化膜を細
管状に形成し、吸入口から送風器を用いて取込まれた空
気を酸素富化膜の管路外周に加圧送風し、加圧送風され
た空気を酸素富化膜の管路内部から吸引ポンプを用いて
吸引透過する構造としてもよい1゜以上説明したように
、本発明によれば、空気中から酸素を優先的に選択透過
し、有毒ガス等が選択的に分離された酸素含有率の高い
酸素富化空気を小型かつ簡単な装置を用いて得ることが
可能となる。
In addition, in the above embodiment, the oxygen enriching membrane of the oxygen enriching device is formed into a capillary tube, and the air taken in from the suction port using a blower is blown under pressure into the pipe line of the oxygen enriching membrane. Although the oxygen-enriched air supply device has a structure in which pressurized air is sucked and permeated from outside the pipe line of the oxygen-enriched membrane using a suction pump, the device is not limited to this, and can be used, for example, in an oxygen enricher. The oxygen enriched membrane is formed into a thin tube shape, and the air taken in from the inlet using a blower is blown under pressure to the outer circumference of the oxygen enriched membrane pipe, and the pressurized air is enriched with oxygen. As explained above, according to the present invention, oxygen is preferentially permeated from the air, and toxic gases are selectively permeated. It becomes possible to obtain oxygen-enriched air with a high oxygen content separated by using a small and simple device.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の好適な実施例を示す説明図、第2図は
酸素富化器の断面説明図である。 10・・・酸素富化膜、 12・・・酸素富化器、 14・・・吸入口、 16・・・送風口、 18・・・吸引ポンプ。
FIG. 1 is an explanatory diagram showing a preferred embodiment of the present invention, and FIG. 2 is a cross-sectional explanatory diagram of an oxygen enricher. 10... Oxygen enrichment membrane, 12... Oxygen enricher, 14... Suction port, 16... Ventilation port, 18... Suction pump.

Claims (1)

【特許請求の範囲】 (11多孔質支持膜上に高分子薄膜を形成してなる酸素
富化膜を有する酸素富化器と、吸入口から空気を取込み
酸素富化器に加圧送風する送風器と、酸素富化器に加圧
送風された空気を酸素富化膜を介して吸引透過する吸引
ポンプと、を備え、加圧送風された空気を吸引透過する
際酸素富化膜によ如酸素を優先的に選択透過し、酸素含
有率の高い酸素富化空気を得ることを特徴とする酸素富
化空気供給装置。 (2)  特許請求の範囲(1)記載の装置において、
酸素富化器は、多孔質支持膜上にプラズマ重合により高
分子薄膜を形成せしめてなる酸素富化膜を有することを
特徴とする酸素富化空気供給装置。 (3)  特許請求の範囲(1)、(2)のいずれかに
記載の装置において、酸素富化器の酸素富化膜を細管状
に形成し、吸入口から送風器を用いて取込まれた空気を
酸素富化膜の管路内に加圧送風し、加圧送風された空気
を酸素富化膜の管路外部から吸引ポンプを用いて吸引透
過することを特徴とする酸素富化空気供給装置。 (4)特許請求の範囲(1)、(2)のいずれかに記載
の装置において、酸素富化器の酸素富化膜を細管状に形
成し、吸入口から送風器を用いて取込まれた空気を酸素
富化膜の管路外周に加圧送風し、加圧送風された空気を
酸素富化膜の管路内部から吸引ポンプを用いて吸引透過
することを特徴とする酸素富化空気供給装置。
[Claims] (11) An oxygen enricher having an oxygen enriching membrane formed by forming a polymer thin film on a porous support membrane, and an air blower that takes air from an inlet and blows the air under pressure to the oxygen enricher. and a suction pump that suctions and permeates the air pressurized into the oxygen enricher through the oxygen enrichment membrane. An oxygen-enriched air supply device characterized by preferentially permeating oxygen to obtain oxygen-enriched air with a high oxygen content. (2) The device according to claim (1),
The oxygen enricher is an oxygen-enriched air supply device characterized by having an oxygen-enriched membrane formed by forming a thin polymer film on a porous support membrane by plasma polymerization. (3) In the device according to any one of claims (1) and (2), the oxygen enriching membrane of the oxygen enricher is formed into a thin tube shape, and the oxygen enriched membrane is taken in from the suction port using a blower. Oxygen-enriched air characterized by blowing pressurized air into the pipe line of the oxygen-enriching membrane, and sucking and permeating the pressurized air from outside the pipe line of the oxygen-enriching membrane using a suction pump. Feeding device. (4) In the device according to any one of claims (1) and (2), the oxygen enriching membrane of the oxygen enricher is formed into a thin tube shape, and the oxygen enriched membrane is taken in from the suction port using a blower. Oxygen-enriched air characterized by blowing pressurized air to the outer periphery of the pipe of the oxygen-enriching membrane, and sucking and permeating the pressurized air from inside the pipe of the oxygen-enriching membrane using a suction pump. Feeding device.
JP57105177A 1982-06-18 1982-06-18 Oxygen-rich air supplying device Granted JPS58221338A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP57105177A JPS58221338A (en) 1982-06-18 1982-06-18 Oxygen-rich air supplying device
GB08315986A GB2122103A (en) 1982-06-18 1983-06-10 Apparatus for supplying oxygen-enriched air

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57105177A JPS58221338A (en) 1982-06-18 1982-06-18 Oxygen-rich air supplying device

Publications (2)

Publication Number Publication Date
JPS58221338A true JPS58221338A (en) 1983-12-23
JPS6214066B2 JPS6214066B2 (en) 1987-03-31

Family

ID=14400391

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57105177A Granted JPS58221338A (en) 1982-06-18 1982-06-18 Oxygen-rich air supplying device

Country Status (2)

Country Link
JP (1) JPS58221338A (en)
GB (1) GB2122103A (en)

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JPS5462981A (en) * 1977-10-29 1979-05-21 Toyobo Co Ltd Oxygen gas selectively permeable membrane
JPS54103788A (en) * 1978-02-01 1979-08-15 Mitsubishi Rayon Co Ltd Composite hollow yarn and selective gas permeation using same
JPS5644003A (en) * 1979-09-17 1981-04-23 Teijin Ltd Gas enriching device
JPS5691802A (en) * 1979-12-26 1981-07-25 Matsushita Electric Ind Co Ltd Selective gas permeable membrane cell
JPS56157436A (en) * 1980-05-07 1981-12-04 Sumitomo Electric Ind Ltd Preparation of resin composite
JPS5718644U (en) * 1980-07-08 1982-01-30
JPS5781805A (en) * 1980-11-11 1982-05-22 Sumitomo Electric Ind Ltd Gas selective permeable composite membrane and its production

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61293524A (en) * 1985-05-08 1986-12-24 エイ/ジ−・テクノロジ−・コ−ポレ−シヨン Method and apparatus for separation of gas by membrane
JPS6475851A (en) * 1987-09-17 1989-03-22 Hitachi Ltd Air conditioner

Also Published As

Publication number Publication date
JPS6214066B2 (en) 1987-03-31
GB2122103A (en) 1984-01-11
GB8315986D0 (en) 1983-07-13

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