JPS58185452A - アルカリ金属アルミノホウケイ酸ホトクロミツクガラス - Google Patents
アルカリ金属アルミノホウケイ酸ホトクロミツクガラスInfo
- Publication number
- JPS58185452A JPS58185452A JP58033677A JP3367783A JPS58185452A JP S58185452 A JPS58185452 A JP S58185452A JP 58033677 A JP58033677 A JP 58033677A JP 3367783 A JP3367783 A JP 3367783A JP S58185452 A JPS58185452 A JP S58185452A
- Authority
- JP
- Japan
- Prior art keywords
- glass
- less
- silver
- alkali metal
- photochromic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011521 glass Substances 0.000 title claims description 78
- 229910052783 alkali metal Inorganic materials 0.000 title description 16
- 150000001340 alkali metals Chemical class 0.000 title description 15
- 239000000203 mixture Substances 0.000 claims description 26
- 229910052709 silver Inorganic materials 0.000 claims description 22
- 239000004332 silver Substances 0.000 claims description 21
- -1 silver halide Chemical class 0.000 claims description 19
- 239000010949 copper Substances 0.000 claims description 17
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 15
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 10
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 7
- 239000013078 crystal Substances 0.000 claims description 7
- 239000007800 oxidant agent Substances 0.000 claims description 7
- 229910052794 bromium Inorganic materials 0.000 claims description 6
- 239000000460 chlorine Substances 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 5
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- 229910052740 iodine Inorganic materials 0.000 claims description 4
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Chemical compound O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 claims description 4
- 229910021607 Silver chloride Inorganic materials 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 229910052593 corundum Inorganic materials 0.000 claims description 3
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 claims description 3
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 3
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 claims description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 2
- 101100348017 Drosophila melanogaster Nazo gene Proteins 0.000 claims description 2
- 229910021612 Silver iodide Inorganic materials 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 239000011630 iodine Substances 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims description 2
- 229940045105 silver iodide Drugs 0.000 claims description 2
- 229910000314 transition metal oxide Inorganic materials 0.000 claims description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 2
- VAYROLOSUUAGTR-UHFFFAOYSA-N [Ag].[I] Chemical compound [Ag].[I] VAYROLOSUUAGTR-UHFFFAOYSA-N 0.000 claims 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 8
- 239000011159 matrix material Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 230000005855 radiation Effects 0.000 description 5
- 238000007792 addition Methods 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000006121 base glass Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000005562 fading Methods 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 239000005368 silicate glass Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- GOLCXWYRSKYTSP-UHFFFAOYSA-N Arsenious Acid Chemical compound O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
- BYFGZMCJNACEKR-UHFFFAOYSA-N aluminium(i) oxide Chemical compound [Al]O[Al] BYFGZMCJNACEKR-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 229910000423 chromium oxide Inorganic materials 0.000 description 2
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000005337 ground glass Substances 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 241001137251 Corvidae Species 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 238000003426 chemical strengthening reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000006125 continuous glass melting process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/04—Compositions for glass with special properties for photosensitive glass
- C03C4/06—Compositions for glass with special properties for photosensitive glass for phototropic or photochromic glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US353199 | 1982-03-01 | ||
| US06/353,199 US4390635A (en) | 1982-03-01 | 1982-03-01 | Alkali metal aluminoborosilicate photochromic glasses |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58185452A true JPS58185452A (ja) | 1983-10-29 |
| JPH0247416B2 JPH0247416B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1990-10-19 |
Family
ID=23388143
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58033677A Granted JPS58185452A (ja) | 1982-03-01 | 1983-03-01 | アルカリ金属アルミノホウケイ酸ホトクロミツクガラス |
Country Status (4)
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02296747A (ja) * | 1989-05-10 | 1990-12-07 | Corning Inc | 高屈折率フォトクロミックガラス |
| JP2018138514A (ja) * | 2011-11-30 | 2018-09-06 | コーニング インコーポレイテッド | 着色アルカリアルミノケイ酸塩ガラス物品 |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4549894A (en) * | 1984-06-06 | 1985-10-29 | Corning Glass Works | Ultraviolet absorbing photochromic glass of low silver content |
| FR2584706B1 (fr) * | 1985-07-11 | 1991-08-16 | Corning Glass Works | Verre photochromique a eclaircissement rapide |
| FR2634752B1 (fr) * | 1988-07-29 | 1992-09-18 | Corning France | Verres photochromiques a indice de refraction eleve |
| US5275979A (en) * | 1992-10-30 | 1994-01-04 | Corning Incorporated | Colored glasses and method |
| US5381193A (en) * | 1993-02-22 | 1995-01-10 | Corning Incorporated | Protective filter lenses |
| FR2717915B1 (fr) * | 1994-03-22 | 1996-06-07 | Corning Inc | Verres photochromiques à haut indice. |
| US5534041A (en) * | 1994-11-07 | 1996-07-09 | Corning Incorporated | Method of making laser eyewear protection |
| US5541142A (en) * | 1995-07-31 | 1996-07-30 | Corning Incorporated | Method of making a color filter by precipitation of Cu2 O from a glass matrix |
| US6711917B2 (en) | 2000-09-15 | 2004-03-30 | Guardian Industries Corporation | Photochromic float glasses and methods of making the same |
| US20040198582A1 (en) * | 2003-04-01 | 2004-10-07 | Borrelli Nicholas F. | Optical elements and methods of making optical elements |
| US8455157B1 (en) * | 2007-04-26 | 2013-06-04 | Pd-Ld, Inc. | Methods for improving performance of holographic glasses |
| EP3347315B1 (en) | 2015-09-11 | 2020-07-15 | Corning Incorporated | Multi-pane window with a low emissivity layer and a photochromic glass |
| US10618839B2 (en) | 2016-11-30 | 2020-04-14 | Corning Incorporated | Low emissivity coatings with increased ultraviolet transmissivity |
| CN115215543A (zh) * | 2022-07-20 | 2022-10-21 | 昆明理工大学 | 一种稀土离子掺杂光致变色玻璃及其制备方法与应用 |
| CN116217079A (zh) * | 2022-12-26 | 2023-06-06 | 昆明理工大学 | 一种响应紫外光建筑玻璃的制备方法及应用 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3208860A (en) * | 1962-07-31 | 1965-09-28 | Corning Glass Works | Phototropic material and article made therefrom |
| US3252374A (en) * | 1962-02-15 | 1966-05-24 | Corning Glass Works | Means for controlling the light transmission of a phototropic glass structure |
| US3306833A (en) * | 1963-03-08 | 1967-02-28 | Corning Glass Works | Method of making a phototropic glass article |
| US4001019A (en) * | 1972-03-08 | 1977-01-04 | Hoya Glass Works, Ltd. | Reversible light sensitive glass |
| US4190451A (en) * | 1978-03-17 | 1980-02-26 | Corning Glass Works | Photochromic glass |
| SU724465A1 (ru) * | 1978-09-04 | 1980-03-30 | Предприятие П/Я Р-6681 | Фотохромное стекло |
| US4284686A (en) * | 1980-06-09 | 1981-08-18 | Corning Glass Works | Spectacle lenses to reduce discomfort from aphakia and certain eye diseases |
-
1982
- 1982-03-01 US US06/353,199 patent/US4390635A/en not_active Expired - Lifetime
-
1983
- 1983-02-28 DE DE8383301051T patent/DE3376828D1/de not_active Expired
- 1983-02-28 EP EP83301051A patent/EP0087967B1/en not_active Expired
- 1983-03-01 JP JP58033677A patent/JPS58185452A/ja active Granted
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02296747A (ja) * | 1989-05-10 | 1990-12-07 | Corning Inc | 高屈折率フォトクロミックガラス |
| JP2018138514A (ja) * | 2011-11-30 | 2018-09-06 | コーニング インコーポレイテッド | 着色アルカリアルミノケイ酸塩ガラス物品 |
| US11420899B2 (en) | 2011-11-30 | 2022-08-23 | Corning Incorporated | Colored alkali aluminosilicate glass articles |
| US11851369B2 (en) | 2011-11-30 | 2023-12-26 | Corning Incorporated | Colored alkali aluminosilicate glass articles |
| US11912620B2 (en) | 2011-11-30 | 2024-02-27 | Corning Incorporated | Colored alkali aluminosilicate glass articles |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3376828D1 (de) | 1988-07-07 |
| JPH0247416B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1990-10-19 |
| EP0087967B1 (en) | 1988-06-01 |
| US4390635A (en) | 1983-06-28 |
| EP0087967A1 (en) | 1983-09-07 |
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