JPS58156192A - Heat transfer device by use of solid/gas reversible reactant - Google Patents
Heat transfer device by use of solid/gas reversible reactantInfo
- Publication number
- JPS58156192A JPS58156192A JP3780982A JP3780982A JPS58156192A JP S58156192 A JPS58156192 A JP S58156192A JP 3780982 A JP3780982 A JP 3780982A JP 3780982 A JP3780982 A JP 3780982A JP S58156192 A JPS58156192 A JP S58156192A
- Authority
- JP
- Japan
- Prior art keywords
- hopper
- heat
- temperature
- heat exchanger
- hoppers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D19/00—Regenerative heat-exchange apparatus in which the intermediate heat-transfer medium or body is moved successively into contact with each heat-exchange medium
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Sorption Type Refrigeration Machines (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は固体、気体可逆反応物質による熱移動V7tw
の改誠に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention provides heat transfer V7tw by solid, gaseous reversible reactants.
Concerning the change of faith.
従来のこのm装置では、吸熱、発熱物質たる合金粉末は
流動せず、熱交換謀体を切り換えることKよって2櫨合
金間において、水素との化合、分解による吸熱、放熱の
り逆反応を行なわせていた。In this conventional device, the alloy powder, which is an endothermic and exothermic substance, does not flow, and by switching the heat exchange mechanism, a reverse reaction occurs between the two Hashira alloys by combining with hydrogen, absorbing heat through decomposition, and dissipating heat. was.
併し、このMIIKよると、合金充填容器が周期的に温
度変化するため、得られる温度が不安定でコントロール
することが困難である他、顕熱ロスが大きく、熱伝導、
熱伝達が感いなどの欠点があった。However, according to this MIIK, the temperature of the alloy filled container changes periodically, so the temperature obtained is unstable and difficult to control, and sensible heat loss is large, and heat conduction and
There were drawbacks such as poor heat transfer.
本発明は上記欠点を除き、と−トポンプまた冷凍機にお
いて、金属あるいは金属水嵩化物等を流動させることに
より連続311転を可能ならしめ、得られるa!度の標
準化、V−ケンス運転装置の簡素化、装置本体の焼熱ロ
スの減少による熱交換効率を向上させた熱移動装置を提
供することを目的とする。The present invention eliminates the above-mentioned drawbacks and makes it possible to perform continuous 311 rotations in a toto pump or refrigerator by flowing a metal or metal hydride, thereby obtaining a! The purpose of the present invention is to provide a heat transfer device that improves heat exchange efficiency by standardizing the temperature, simplifying the V-can operating device, and reducing heat loss in the device body.
以下本発明の一実施例を図面にもとづいて説明する。An embodiment of the present invention will be described below based on the drawings.
の右側)に位置する第2上ホッパ8.1g2下ホツパ4
とが設けられる。前記第1上ホツパ1と第1下ホツパ2
とは第1該第1上ホツパlと上部水素ガス通路81によ
り連通されるとともに、第2上ロータリバルブ58を介
して第2下ホツパ4と接続される。第1下ホツパ2と第
2下ホツパ4とは下部水素ガス通路82により連通され
る。!U記第1下ホッパ2および第2下ホツパ4は、そ
の下端に夫々第1下ロータリパルプ52、第2下ロータ
リパルプ54が設けられ。2nd upper hopper 8.1g2 lower hopper 4 located on the right side of
and is provided. The first upper hopper 1 and the first lower hopper 2
is communicated with the first upper hopper 1 through the upper hydrogen gas passage 81, and is also connected with the second lower hopper 4 via the second upper rotary valve 58. The first lower hopper 2 and the second lower hopper 4 are communicated through a lower hydrogen gas passage 82. ! The first lower hopper 2 and the second lower hopper 4 are provided with a first lower rotary pulp 52 and a second lower rotary pulp 54 at their lower ends, respectively.
スクリューコンベアたる第1反応物質フィーダ71、第
2反応物質フィーダ72を経て、各第1上ホツパ1.第
2上ホツパ8に連通される。Each first upper hopper 1. It is communicated with the second upper hopper 8.
また、削把第1上ホッパ1.第1下ホッパ2.第2上ホ
ッパ3.第2下ホツパ4には夫々、熱g4人官たる第1
上熱父換′a61、第1下繰交換器62、第2上熱交換
−〇8、第2下熱交換器64が配設されている。前記低
温側の第1上ホツパ1には一逆瓜応物貢たる低温側合金
粉体MA、例えばL4引g、FeTiが収容され、高温
側の第2上ホツパ8にVi島am合金粉停MB例えばC
aN is 、LaN k4.lt hQ、5が収容さ
れる。In addition, the scraping first upper hopper 1. 1st lower hopper 2. 2nd upper hopper3. The 2nd lower hoppa 4 has a 1st person who is a heat g4 officer.
An upper heat exchanger 'a61, a first lower heat exchanger 62, a second upper heat exchanger -08, and a second lower heat exchanger 64 are provided. The first upper hopper 1 on the low-temperature side stores a low-temperature-side alloy powder MA serving as a reverse melonization material, such as L4, FeTi, and the second upper hopper 8 on the high-temperature side stores a Vi island am alloy powder MB. For example, C
aN is, LaN k4. lt hQ,5 is accommodated.
自σ紀上部水本ガス通路81.下部水素ガス通路82は
夫々、フィルタ81m、82mが設けられ、^
気体のめの流通かIIIJ能とされる。Upper Autosigian Mizumoto Gas Passage 81. The lower hydrogen gas passages 82 are provided with filters 81m and 82m, respectively, to allow gas to flow through them.
次に作@utat説明する。Next, I will explain the work @utat.
図において、第1上ホツパ1にMA金合金第2上ホツパ
8 K MB)1m合金を入れ、第1上熱交換話611
@2上熱交換a63を通して夫々熱父換縄体(mFXT
i(1”m )を供iする。そL テ上fE5 MB
比金合金MBと14.とに14離させ、該Htを第1上
ホツパ1内に151Sさせて、MA+)is→MA)i
、の反応を行なわせる。In the figure, MA gold alloy second upper hopper 8 (K MB) 1m alloy is put into the first upper hopper 1, and the first upper heat exchanger 611
@2 The heat exchanger (mFXT)
Provide i(1”m). So L Te upper fE5 MB
ratio metal alloy MB and 14. 14 apart, and the Ht is placed in the first upper hopper 1 for 151S, MA+)is→MA)i
, to carry out the reaction.
第1上熱交m器の熱媒はJ!+温され、第2と無客換t
□
−のp@縄は冷却される。この2つの反応は水素の庄カ
パフンスによって発生される。前記MB 、 MAH8
ij 84・の上ホッパ1.8よル上部ロータリパルプ
61.68を経て夫々下ホッパ2.4に落下導入される
。そして、前記ロータリパルプ61.58を閉止し九と
き第1下ホツパ2ふ第2下ホツパ4とに夫々温度Tmな
る無謀を供給すると、水素圧カバランスにより第1下本
ツバ2内ではMAR,→MA+)1.の反応が行なわれ
る。そして、この解離した比は下部水素ガス通路82を
経て第2ホツパ4゛に入シ、ここでM B +H*−M
BH*の反応が生ずる。そして第1下熱交換−62の熱
媒は冷却されて流出し、第2下熱交換l5i64に供給
された熱gFi温度“rh に上昇して取出される。The heat medium of the first upper heat exchanger is J! + warmed up, second and no customer exchange t
□ − p@ rope is cooled. These two reactions are generated by hydrogen gas. Said MB, MAH8
The pulp from the upper hopper 1.8 of the ij 84 passes through the upper rotary pulp 61 and 68, and is then dropped into the lower hopper 2.4. Then, when the rotary pulp 61, 58 is closed and a temperature Tm is supplied to the first lower hopper 2 and the second lower hopper 4, respectively, MAR, →MA+)1. reaction takes place. Then, this dissociated ratio enters the second hopper 4' through the lower hydrogen gas passage 82, where M B +H*-M
A BH* reaction occurs. Then, the heat medium of the first lower heat exchanger 62 is cooled and flows out, and the heat gFi supplied to the second lower heat exchanger 15i64 rises to the temperature "rh" and is taken out.
1Iff記MA、 MBH*は夫々、第1下ロータリパ
ルプ52、第2下ロータリパルプ64が開かれ、第1反
応物質フィーダ71.第2反応物質フィーダ72を経て
再び第1上ホツパ1および第2上ホツパ8へ返戻され、
上ti30m環を繰り返す。この方式によシT/、Tm
なる低温の熱媒を供給してThなる高温の熱が侮られる
。(ここで温度はT l(Tm(T h の関係にあ
る)
上記によると、合金の粉体がホッパ内を循環されること
くよりホッパ内で発熱吸熱反応を生じ、鵬熱による熱損
失が低減される。そして、得られる温度Thは安定した
温度を保持される。従って、従来のヒートポンプVステ
ムのような無謀の切換は平置で69、合金粉体を流動さ
せることにより熱伝達の向上が期待できる。1Iff MA, MBH*, the first lower rotary pulp 52 and the second lower rotary pulp 64 are opened, respectively, and the first reactant feeder 71. is returned to the first upper hopper 1 and second upper hopper 8 via the second reactant feeder 72,
Repeat upper ti30m ring. According to this method, T/, Tm
By supplying a low-temperature heat medium, the high-temperature heat of Th is underestimated. (Here, the temperature is in the relationship T l (Tm (T h )) According to the above, since the alloy powder is circulated in the hopper, an exothermic endothermic reaction occurs in the hopper, and heat loss due to heat is caused. The resulting temperature Th is maintained at a stable temperature.Therefore, the reckless switching such as the conventional heat pump V stem is not done in a horizontal position69, but the heat transfer is improved by flowing the alloy powder. can be expected.
るtainsられる( Th’)Tm’>TJ’ )。tains (Th')Tm'>TJ').
この際、水素ガスは通路81.82を通じて逆圧流れる
ことになる。At this time, hydrogen gas flows through the passages 81 and 82 under a reverse pressure.
本Vステムはヒートポンプの他脇熱ボイフ、冷房機、冷
凍機にも利用できる。In addition to heat pumps, this V-stem can also be used for side heat boilers, air conditioners, and refrigerators.
なお、本発明は他の固体気体可逆反応物質にも通用され
る。Note that the present invention is also applicable to other solid gas reversible reactants.
本発明は以上の如く構成さ九る合金粉体を循環流動させ
ることにより発熱吸熱反応を同一@器内で行なわせる丸
め、容−の温度が変化せず、容器M熱として奪われる熱
量ロスがなく、得られる温度が安定する。供給無謀の切
換えが装置でV−ケンスの簡素化が図れ、その丸め汚染
ガス、汚染廃液の利用も可能となるのみならず、合金粉
体の流動によって熱伝達の向上が望めるなど多くの効果
を得る仁ととなった。The present invention enables exothermic and endothermic reactions to occur in the same container by circulating and flowing the alloy powder configured as described above, and the temperature of the container does not change, reducing the amount of heat lost as heat from the container. temperature is stable. This device not only simplifies the V-can and makes it possible to use the rounded contaminated gas and waste liquid, but also improves heat transfer through the flow of alloy powder. It became a privilege to gain.
図は本発明の一実施例を示すフロー図である。
A・・・ヒートポンプ、1−J@1上ホッパ、2−・第
1下ホツパ、8−JIS 2 上ホ’) /(,4−m
2下ホツパ、51−・第1上ロータリパルプ、52・
・・第1下ロータリパルプ、5B−・第2上ロータリパ
ルプ、54・・・第2下ロータリバルブ、61・・・第
1上熱交換器、62−・第1下熱交換器、68・・・第
2上熱交換話、64−・第2下熱交換器、71−・第1
反応物質フィーダ、72・・・第2反応物質フィーダ、
81・・・上部水素ガス通路、82−・下部水素ガス通
路代理人 弁理士犬飼新平The figure is a flow diagram showing one embodiment of the present invention. A...Heat pump, 1-J@1 upper hopper, 2--1st lower hopper, 8-JIS 2 upper ho') /(,4-m
2nd lower hopper, 51-・1st upper rotary pulp, 52・
...First lower rotary pulp, 5B--Second upper rotary pulp, 54...Second lower rotary valve, 61...First upper heat exchanger, 62--First lower heat exchanger, 68-・・Second upper heat exchanger story, 64-・Second lower heat exchanger, 71-・First
Reactant feeder, 72... second reactant feeder,
81...Upper hydrogen gas passage, 82--Lower hydrogen gas passage Agent Patent attorney Shinpei Inukai
Claims (1)
ツパの下側で@1上ロータリパルプを介して上下に接続
され、かつ、下端に第1下ロータリバルブをもつ第1下
ホツパと、高温側反応物質を収納し、前記第1上ホシバ
の水平方向に1[しかつ、上ガス通路によシ連通された
第2上ホツパと、該第2上ホツパの下側で第2上ロータ
リパルプを介して上下に接続され、下端に第2下ロータ
リバルグを持ち、かつ、IfmEdMl下ホッパの水平
方向にll111優して下ガス通路によシ連通された第
2下ホツパと、前記各ホッパに内蔵された熱交換−と、
1IiI記第1下ホツパおよび第2下ホツパの物質を各
々、前記第1上ホツパおよび第2上ホツパに移動させる
第1および第2反応物質コンベアとを含むことを特徴と
する固体、気体可逆反応物質による#I移Kh装置。A 11 upper hopper for storing a low-temperature emotion-reactive substance, and a 1st lower hopper which is vertically connected to the lower side of the first upper hopper via @1 upper rotary pulp and has a 1st lower rotary valve at its lower end. , a second upper hopper containing a high-temperature side reactant, horizontally extending from the first upper hopper and communicating with the upper gas passage; A second lower hopper which is vertically connected via a rotary pulp, has a second lower rotary valve at the lower end, and is connected to the lower gas passage in the horizontal direction of the IfmEdMl lower hopper, and each of the above-mentioned hoppers. Built-in heat exchange and
1IiI, a solid gas reversible reaction characterized by comprising first and second reactant conveyors for transferring the materials of the first lower hopper and the second lower hopper to the first upper hopper and the second upper hopper, respectively. #I transfer Kh device by substance.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3780982A JPS58156192A (en) | 1982-03-09 | 1982-03-09 | Heat transfer device by use of solid/gas reversible reactant |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3780982A JPS58156192A (en) | 1982-03-09 | 1982-03-09 | Heat transfer device by use of solid/gas reversible reactant |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS58156192A true JPS58156192A (en) | 1983-09-17 |
JPH0355749B2 JPH0355749B2 (en) | 1991-08-26 |
Family
ID=12507835
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3780982A Granted JPS58156192A (en) | 1982-03-09 | 1982-03-09 | Heat transfer device by use of solid/gas reversible reactant |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS58156192A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5827496A (en) * | 1992-12-11 | 1998-10-27 | Energy And Environmental Research Corp. | Methods and systems for heat transfer by unmixed combustion |
US6797253B2 (en) | 2001-11-26 | 2004-09-28 | General Electric Co. | Conversion of static sour natural gas to fuels and chemicals |
WO2018088196A1 (en) * | 2016-11-09 | 2018-05-17 | 東洋エンジニアリング株式会社 | Chemical heat storage system |
-
1982
- 1982-03-09 JP JP3780982A patent/JPS58156192A/en active Granted
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5827496A (en) * | 1992-12-11 | 1998-10-27 | Energy And Environmental Research Corp. | Methods and systems for heat transfer by unmixed combustion |
US6797253B2 (en) | 2001-11-26 | 2004-09-28 | General Electric Co. | Conversion of static sour natural gas to fuels and chemicals |
WO2018088196A1 (en) * | 2016-11-09 | 2018-05-17 | 東洋エンジニアリング株式会社 | Chemical heat storage system |
JP2018077002A (en) * | 2016-11-09 | 2018-05-17 | 東洋エンジニアリング株式会社 | Chemical heat storage system |
Also Published As
Publication number | Publication date |
---|---|
JPH0355749B2 (en) | 1991-08-26 |
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