JPS58147535A - Dry sintered friction material - Google Patents

Dry sintered friction material

Info

Publication number
JPS58147535A
JPS58147535A JP2876082A JP2876082A JPS58147535A JP S58147535 A JPS58147535 A JP S58147535A JP 2876082 A JP2876082 A JP 2876082A JP 2876082 A JP2876082 A JP 2876082A JP S58147535 A JPS58147535 A JP S58147535A
Authority
JP
Japan
Prior art keywords
friction material
friction
dry
present
sintered friction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2876082A
Other languages
Japanese (ja)
Inventor
Susumu Usui
薄井 晋
Naohiro Hirose
広瀬 直洋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tungaloy Corp
Original Assignee
Toshiba Tungaloy Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Tungaloy Co Ltd filed Critical Toshiba Tungaloy Co Ltd
Priority to JP2876082A priority Critical patent/JPS58147535A/en
Publication of JPS58147535A publication Critical patent/JPS58147535A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To obtain a dry friction material showing stably a high coefft. of friction, by providing a specified composition contg. Mn to a bronze type dry friction material. CONSTITUTION:The titled material contains, by weight, 60-80% Cu, 3-20% Sn, 3-20% metallic oxide consisting of hard particles with >=4 Moh's hardness, 3-10% graphite, 1-5% MoS2 and <=15% Mn. Mn reduces an oxidized film of other metals during sintering and increases the degree of sintering. Part of Mn is converted into MnO2 and has an effective action of stabilizing the friction surface. Accordingly, by adding an adequate amount of Mn, a dry friction material having a high coefft. of friction and high resistance to heat and water fade phenomena is obtd.

Description

【発明の詳細な説明】 本艷i@tli、ブロンズ系の乾式焼結摩擦材料に関し
、41に高摩擦係数が安定して得られるように改善され
たものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a bronze-based dry sintered friction material that has been improved to stably obtain a high coefficient of friction.

従来、乾式焼結摩擦材料は、摩揶係数および耐焼付性が
高−こと、摩ms数の減少として現れる鵬フェード現象
、水フェード現象等が生じにくい仁となどが要求されて
いる。
Conventionally, dry sintered friction materials have been required to have a high abrasion coefficient and seizure resistance, and to be resistant to the phenomenon of water fade, which appears as a decrease in the number of friction ms, and the like.

しかしながら、従来のブロンズ系の焼結**材料では、
−記gI求【すべて満足するまでKFi至つておらず、
さらに成分組成の面からO!Il1発が簀値されている
However, with conventional bronze-based sintered materials,
-I have not reached KFi until I am satisfied with everything,
Furthermore, it is O from the viewpoint of ingredient composition! One Il shot has been estimated.

本発明は、この要望を構えすためKなされ皮賜ので、ブ
ロンズ系の焼結合金からなる乾式焼結摩擦材料において
、前記焼結合金は、重量比で、銅60〜son、錫3〜
201G、毫−ス値度4以上の硬質粒子からなる金属酸
化物音3〜20−1黒鉛3〜10sに硫化モリブデン1
〜5−およびマンオン15−以下【含む屹式焼結摩−材
at提供するものである。
The present invention has been made in response to this need, and is therefore a dry sintered friction material made of a bronze-based sintered alloy, in which the sintered alloy has a weight ratio of 60 to 60% of copper and 3 to 30% of tin.
201G, a metal oxide consisting of hard particles with a metal oxide value of 4 or more.
The present invention provides a sintered grinding material containing up to 5 and 15 and below.

以下、本*@乾式焼結11*m料について、その概禽會
I!明する。
The following is about the book*@dry sintering 11*m material. I will clarify.

本発明の乾式−転廖榔材料は、マ)9ツクス威分として
ブロンズ系の焼結合金kill用している。
The dry conversion material of the present invention is used as a bronze-based sintered alloy as a matrix material.

その成分組成は、焼結**材料金体に対して、重量比(
以下同じ)て、鋼60〜80%、−3〜20110範I
M會選択している。この範囲の選択1準は、摩11FM
+2)安定性からである。籍に1プaンズ畢のマトリッ
クス材はIH料4戚に係わりを−ち、制一時O摩fi俤
数を安定させ、しかも相手歇とO間の発熱で、表内に一
質O慮化銅皮膜【形成することから、この線質酸化皮膜
が水7エード塊象に対して抵抗性を示す、また熱フェー
ド現象に対しても優れた抵抗性を有し、安定した摩擦面
が得られる。
Its composition is based on the weight ratio (
(same below) steel 60~80%, -3~20110 range I
I have selected M-kai. Selection 1 of this range is 11FM
+2) This is due to stability. The matrix material of 1 ounces is related to the IH material 4, and it stabilizes the temperature during the control period, and the heat generated between the other side and the oscillator causes a constant oscillation within the table. Copper coating [Because it is formed, this linear oxide film shows resistance to water 7ade agglomerates, and also has excellent resistance to thermal fade phenomenon, resulting in a stable friction surface. .

さらに、本発明の乾式焼結J111M材料では、モース
硬[4以上の硬質粒子からなる金I11酸化物【3〜2
0g&含有させている。この含有量の選択基部は、ms
員侑、A温O犀嚢婿動に耐えられることを目安としてい
る。したがって、相手材に対する攻lII性に応じて、
その含有量3〜20−の範囲内で決定される。この場合
、金Jllli[化物としては、シリカ(810m )
、アル2す(ム4sos)、ムライト(3ムjlol−
28101)等から適宜選択される。そして、これらの
金萬峻化物は、摩11%畝會^め、またそo*ysにお
いて発生するφ屑物や反応生成物tかき落す効来を有す
る。このため、ダイヤモンドtloとするモース硬f4
以上が必蚤であり、また量的に少なすぎるとこの効果が
少なく、量的に多trると、相手MV過激に攻撃するた
め3〜20−の範囲が好適する。
Furthermore, in the dry sintered J111M material of the present invention, gold I11 oxide [3 to 2
Contains 0g&. The selection basis for this content is ms
The aim is to be able to withstand the effects of A-Yu, A-Yu, and A-O-Sac. Therefore, depending on the offensiveness against the opponent material,
The content is determined within the range of 3 to 20. In this case, gold Jlli [as a compound, silica (810m2)]
, al2s (mu4sos), mullite (3mujlol-
28101), etc., as appropriate. These gold powders have the effect of scraping off φ waste and reaction products that are generated in the 11% ridges and in the ridges. For this reason, the Mohs hardness f4 with diamond tlo
The above is necessary, and if the quantity is too small, this effect will be small, and if the quantity is too large, the opponent's MV will be attacked radically, so a range of 3 to 20- is suitable.

を九、本発明O乾式焼結摩擦材料は、黒鉛3〜10L二
硫化モリブデン(MO8m )  1〜% 5 *を含
着して−る。これらは、一般にそれぞれの温度域で潤滑
性を発揮し、それぞれの温度域【超えると摩擦係数向上
剤として働くものである。この場合、潤滑成分として一
般的な鉛については、本発明の組成のll4IAfら熱
フエード現象によって^**Sa會−持できないことO
知Ji、に基づき添加されていない、すなわち、本発明
、の乾式焼結摩擦材料は、そO原線係数が約α4〜cL
6でToす、高摩擦係数O部−に属することから、船倉
積極的に排除している。
9. The dry sintered friction material of the present invention impregnates 3-10L of graphite with 1-% 5* of molybdenum disulfide (MO8m). These generally exhibit lubricity in their respective temperature ranges, and act as friction coefficient improvers above their respective temperature ranges. In this case, with regard to lead, which is a common lubricating component, the 114IAf composition of the present invention cannot be maintained due to the thermal fade phenomenon.
The dry sintered friction material of the present invention, which is not added based on the knowledge, has an original coefficient of about α4~cL.
6, and belongs to the high friction coefficient O section, so it is actively excluded from the ship's hold.

さらに、本発明の乾式焼!11摩嚢材料で社、%にマン
ガン會15囁以下添加している。マンガンの添加は、焼
結中他金属の電化皮膜を還元し、焼結性を高める作用が
あるからである。tたマンガン〇一部は、Mnot K
 lk 如摩*trt安定させる有効な作mt有するこ
とからである。
Furthermore, dry baking of the present invention! 11% of the material contains less than 15% manganese. This is because the addition of manganese has the effect of reducing the electrified film of other metals during sintering and improving sinterability. Some of the manganese are Mnot K
This is because it has an effective effect on stabilizing lk Yoma*trt.

したがって、本発明の乾式焼#11革榔材@は、^摩擦
係数を有する材料で必って、熱フエード現象、水フェー
ド現象に対する抵抗性が鳥<、他方相手材に対する攻撃
性が改善されているものである。
Therefore, the dry-burned #11 leather material of the present invention is a material with a coefficient of friction, which has excellent resistance to heat fade and water fade, and on the other hand, has improved aggressiveness against the mating material. It is something that exists.

次に、本@明乾式焼結摩擦材料における一実施例につい
て説明する。
Next, an example of the present @ light dry sintered friction material will be described.

試料としては、本発明の乾式焼結摩擦材料および従来の
比較材料tそれぞれ製造した。すなわち、本発明に係る
鳴のがム〜Cであ抄、従来の比較材料に係るものがD 
−Gで、それぞれ次表に示すような成分組m(単位重量
−)tNする。
As samples, a dry sintered friction material of the present invention and a conventional comparative material t were manufactured. That is, the sound according to the present invention is excerpted from M~C, and the one related to the conventional comparative material is D.
-G, the component set m (unit weight -) tN as shown in the following table, respectively.

表 次に上記ム〜GKりい°C1定連摩II試験機において
2つの試験片會摺速20TV/−・C1向圧5%の条件
下で、相手材(FC−20)に押付は性能比値した。
The following table shows the performance of two test pieces pressed against the mating material (FC-20) under the conditions of sliding speed 20TV/-・C1 counter pressure 5% in the above GK Ri ° C1 constant continuous friction II test machine. It was a ratio.

この結果、本発明のム〜OKついては、!@捧係数が目
的とじ7t 0.4〜0.6の範囲内にめり、tた摩耗
率4夾川上さしつかえない#@目内にあつ曳。
As a result, the present invention is OK! @The coefficient was within the range of 7t 0.4 to 0.6, and the wear rate was 4.

したがって、ム〜Cについては、いずれt優れた性*r
示し、物にIn添加による効果が#IX看であった。こ
れに対し、従来例のD%lri相手板に対する攻撃性が
なかった賜の01耐熱フエード性の点で十\劣る結果を
示した。さらKs P#i、耐熱フェード性で良好であ
ったが、相手板の攻撃性が大であり、Gvi、耐熱フェ
ード性で優れるものの相手板の攻撃性が非常に大であっ
た。
Therefore, for M~C, eventually t superior property*r
The effect of adding In to the material was #IX. On the other hand, 01 showed inferior results in terms of heat fade resistance because it did not have the aggressiveness against the D%lri counterpart plate of the conventional example. Furthermore, although Ks P#i and heat resistance to fade were good, the aggressiveness of the opponent board was large, and although Gvi and heat resistance to fade were excellent, the aggressiveness of the opponent board was very large.

なお% MnO&加量については、別途に各欄の試験音
したが、その結果15囁以下が好適範囲であることも判
明した8%[15慢を超えるものは、焼結時に浸出しが
起!P111結の作業性t−急くすることから排除し友
、を友、金属酸化物Kkしては、ムライト等について3
1」途試験したが、モース硬度で4以上のものが好適す
ることも判明した。
Regarding % MnO & loading, we conducted a separate test sound in each column, and as a result, it was found that 15% or less is the suitable range of 8% [If it exceeds 15%, leaching will occur during sintering! P111 Workability of binding - Eliminate from haste, remove metal oxides, mullite, etc. 3
1", and it was found that a Mohs hardness of 4 or more is suitable.

本発明は、以上睨明したように、ブロンズ系の乾式焼結
摩擦材料について、マンガンを添加した%足の成分組成
にすることによって、以下に示す効果が得られるもので
ある。
As discussed above, the present invention provides the following effects by adding manganese to a bronze-based dry sintered friction material.

(11AJIII侭数を有する乾式焼結摩擦材料が提供
されること1本究明では約0.4〜0.6の高摩擦係数
が得られ、耐熱7エード性も優れるものである。
(Providing a dry sintered friction material having a friction coefficient of 11AJIII) According to this research, a high coefficient of friction of about 0.4 to 0.6 is obtained, and the heat resistance is also excellent.

これは、藷に^速摺動化でも安定した摩III面が得ら
れることt意味し、自動単用KFi、*に好適なものと
いえる。
This means that a stable friction surface can be obtained even at high speed sliding, and it can be said to be suitable for automatic single-use KFi.

12+  相手板に対する攻撃性が改善された乾式焼結
摩擦材料が提供されること、一般的には、原振係数が高
ければ、掌耗量が多くなり、これに伴って相手板に対す
る攻撃性も増加する。しかし、本発明では、4悔係数が
高い反面、その摩耗量率4抑えられているものである。
12+ To provide a dry sintered friction material with improved aggressiveness against the opponent plate; in general, the higher the original oscillation coefficient, the greater the amount of wear on the palm, and the more aggressiveness against the opponent plate. To increase. However, in the present invention, although the coefficient of wear is high, the wear rate is suppressed to 4.

シ九がって、攻撃性に対する改善からいわゆる鳴きの減
少にもつながる−のである。
In turn, improvements in aggression can also lead to a reduction in so-called barking.

(3)水フェード現象に内しても改善された乾式焼結摩
擦材料が提供されること。本発明では、ブロンズ系のマ
トリックス全ペースにしていることおよびマンガンを添
加したことにより、水フェード現象に対して4抵抗性が
あり、特KIK出形の二輪自動車には好適する。この場
合相手板としてステンレス鋼tf用すれば、蒙の問題も
同時に鱗決される。
(3) A dry sintered friction material is provided which is improved even under the water fade phenomenon. In the present invention, by using a bronze-based matrix as a whole and adding manganese, it is resistant to water fading and is particularly suitable for KIK shaped two-wheeled vehicles. In this case, if stainless steel TF is used as the mating plate, the problem of metallization will be solved at the same time.

Claims (1)

【特許請求の範囲】 ブロンズ系の焼結合金からなる乾式焼結摩擦材料におい
て、 前記焼結合金は、重量比で、銅60〜80−1化モリブ
デン1〜5チおよびマンガン15−以下を含むことt%
黴とする乾式*緒摩擦材料。
[Claims] A dry sintered friction material made of a bronze-based sintered alloy, wherein the sintered alloy contains 60 to 80 copper, 1 to 5 molybdenum monide, and 15 or less manganese in weight ratio. t%
A dry friction material that produces mold.
JP2876082A 1982-02-26 1982-02-26 Dry sintered friction material Pending JPS58147535A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2876082A JPS58147535A (en) 1982-02-26 1982-02-26 Dry sintered friction material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2876082A JPS58147535A (en) 1982-02-26 1982-02-26 Dry sintered friction material

Publications (1)

Publication Number Publication Date
JPS58147535A true JPS58147535A (en) 1983-09-02

Family

ID=12257358

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2876082A Pending JPS58147535A (en) 1982-02-26 1982-02-26 Dry sintered friction material

Country Status (1)

Country Link
JP (1) JPS58147535A (en)

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