JPS58157930A - Dry sintered friction material - Google Patents

Dry sintered friction material

Info

Publication number
JPS58157930A
JPS58157930A JP3848782A JP3848782A JPS58157930A JP S58157930 A JPS58157930 A JP S58157930A JP 3848782 A JP3848782 A JP 3848782A JP 3848782 A JP3848782 A JP 3848782A JP S58157930 A JPS58157930 A JP S58157930A
Authority
JP
Japan
Prior art keywords
dry
friction
sintered
friction material
resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3848782A
Other languages
Japanese (ja)
Inventor
Susumu Usui
薄井 晋
Naohiro Hirose
広瀬 直洋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tungaloy Corp
Original Assignee
Toshiba Tungaloy Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Tungaloy Co Ltd filed Critical Toshiba Tungaloy Co Ltd
Priority to JP3848782A priority Critical patent/JPS58157930A/en
Publication of JPS58157930A publication Critical patent/JPS58157930A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To obtain the titled friction material made of a sintered Cu alloy having a relatively high coefft. of friction and improved attacking action on its opposite material by blending Cu with Sn, Zn, a metallic oxide consisting of hard particles, graphite, MoS2, Pb and Mn in a prescribed weight ratio. CONSTITUTION:This dry sintered friction material is made of a sintered Cu alloy consisting of, by weight, 60-80% Cu, 3-10% Sn, <=15% Zn, a metallic oxide consisting of hard particles such as Al2O3, 3-10% graphite, 1-5% MoS2, <=8% Pb and <=15% Mn. This friction material has a relatively high coefft. of friction such as about 0.4-0.5, resistance to thermal and water fading phenomena, improved attacking action on its opposite material, and improved squeaking resistance.

Description

【発明の詳細な説明】 本発明は、銅系の乾式焼結摩擦材料に関し、特に摩mA
畝が安定して得られるとともに、相手材に対する攻撃性
が改豊さ五るようにし穴ものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a copper-based dry sintered friction material, in particular
It is a hole-shaped material that not only provides stable ridges, but also improves its aggressiveness against the mating material.

従来、乾式焼結摩擦材料は、摩擦係数および耐2貝 焼付性が高いこと、摩擦−数O減少として現れる熱フエ
ード現象、水フェード現象等が生じにくいことなどが請
求されている。
Conventionally, dry sintered friction materials have been claimed to have a high coefficient of friction and high anti-seizure properties, and to be less prone to thermal fade phenomena, water fade phenomena, etc., which appear as a decrease in friction number O.

しかしながら、従来の銅系O焼結摩擦材料ではyii紀
豊求【すべて満足するまでには至ってνらず、さらに成
分組成の面からon発が要望されている。
However, conventional copper-based O sintered friction materials have not yet been able to satisfy all of the requirements, and furthermore, from the viewpoint of component composition, on-sintering is desired.

不発明は、このg1望會満九す友めになされた一〇で、
銅系O焼結合金からなる乾式m*摩崖材料において、鍵
記flaM合金は、重量比で、銅60〜80%、錫3〜
10慢、亜#&15−以下、硬質粒子からなる金属酸化
物3〜20悌、黒16B〜10−1二硫化モリブデンl
〜sL鉛8−以下およびマ/ガン15−以下を含む乾式
焼結摩擦材料【提供する4ので心る。
Non-invention is the 10 that was done to this g1 hope meeting nine friends,
In the dry m* machining material made of copper-based O sintered alloy, the key flaM alloy has a weight ratio of 60 to 80% copper and 3 to 3% tin.
10 arrogant, sub-# & 15- or less, metal oxide consisting of hard particles 3-20, black 16B-10-1 molybdenum disulfide l
Dry sintered friction material containing up to 8 sL lead and up to 15 m/m lead.

以下、本発明乾式焼結摩擦材料について、その概念t1
1!明する。
The concept t1 of the dry sintered friction material of the present invention will be explained below.
1! I will clarify.

本発明の乾式焼結摩擦材料は、マトリックス成分として
銅、錫および亜鉛からなる焼結合金′ft適用している
。その成分組成は、焼結摩擦材料全体に対して、重量比
(以下同じ)で、銅60〜803頁 一1錫3〜1G−およびJJ&15−以下の範囲tJu
l<している。この範囲の選択基準は、摩擦向の安定性
からである。特にこれらのマトリックス材は材料強度に
係わりtもち、制動時の摩擦係数を安定させ、しかも相
手板との間の発熱で、tlWJK硬質の酸化銅皮膜【形
成することから、この硬質酸化皮膜が水7エード塊象に
対して抵抗性を示す。
The dry sintered friction material of the present invention uses a sintered alloy consisting of copper, tin and zinc as a matrix component. Its composition is based on the weight ratio (the same applies hereinafter) to the entire sintered friction material, and ranges from 60 to 803 copper - 3 to 1 G - and JJ
l< is doing. The selection criteria for this range is based on stability in the frictional direction. In particular, these matrix materials are related to material strength, stabilize the friction coefficient during braking, and also form a hard copper oxide film due to the heat generated between it and the mating plate, so this hard oxide film is Shows resistance to 7ade agglomerates.

また熱フエード現象に対して4優れた抵抗性含有し、安
定した摩I1面が得られる。この場合、亜鉛は、錫に対
する置換の意味かめ抄、性能t−落さない範囲内として
添加されたものである。
It also has excellent resistance to thermal fading and provides a stable surface. In this case, zinc was added as a substitute for tin, and within the range of not deteriorating the performance.

さらに、不発#4の乾式焼結摩俸材料では、アルミナ(
izsom )、シリカ(51oz ) 、ムライト(
3ムを冨012810m )等O酸質粒子からなる金属
酸化1113〜20−含有させている。この含有量の選
択基準は、扁貢荷、^温のJIl擦瘤動に耐えられるこ
とt目安としている。シ友がって、相手材に対する攻−
性に応じて、その含有量が3〜2〇−の範囲内で決定さ
れる。この場合、これらの金属は化物は、541I係数
會^め、またその摩秦において発生する薔着物や反乙生
成−tかき落す効果を有する。そして、量的に少なすぎ
るとこの効果が少なく、量的に多すぎると相手@を過激
に攻撃するため、3〜20−の範囲が好適する。なお、
金属酸化物の硬度は、ダイヤモンド11Gとするモス硬
度で4以上のものが好適する。
Furthermore, in the dry sintered abrasive material of unexploded #4, alumina (
izsom), silica (51oz), mullite (
The metal oxide 1113-20 consisting of O acidic particles such as 012810m) is contained. The selection criteria for this content is based on the fact that it can withstand JIl friction motion under heavy load and temperature. Join forces and attack the opponent's materials.
The content is determined within the range of 3 to 20, depending on the nature. In this case, these metal compounds have the effect of scraping off the 541I coefficient and the rosy deposits and anti-T formations that occur in the matrix. If the amount is too small, this effect will be small, and if the amount is too large, the opponent will be violently attacked, so a range of 3 to 20- is suitable. In addition,
The hardness of the metal oxide is preferably 4 or more on the Moss hardness, which is rated as diamond 11G.

また、本発明の乾式焼結摩IIK材料は、黒鉛3〜10
−1二硫化モリブデン(MoElm)  1〜15%お
よび鉛(pb)s−以下tt有している。これらは、一
般にそれぞれの温厩域eatsで1滑性【発揮し、それ
ぞれの111f域【超えると摩擦係数向上剤として動く
賜のである。この場合、#ilf#成分として一般的な
釦は、その−市において軍−係数の低下があるが、その
反面鳴きの改善および耐摩耗性の改善が1侍されるもの
である。したがって、本発明の軛式焼結摩俸材料は、そ
の孝m係数が約0.4〜0.5と比較的高く、他方相手
材に対する攻撃性および鳴きが改善されているものであ
る。
In addition, the dry sintered IIK material of the present invention has a graphite of 3 to 10
-1 Molybdenum disulfide (MoElm) has 1-15% and lead (PB) s- or less tt. These generally exhibit lubricity in their respective warm ranges, and act as friction coefficient improvers when exceeding their respective 111f ranges. In this case, a general button as an #ilf# component has a decrease in the force coefficient, but on the other hand, there is an improvement in squealing and wear resistance. Therefore, the yoke-type sintered abrasive material of the present invention has a relatively high filtration coefficient of approximately 0.4 to 0.5, and has improved aggressiveness and squealing against mating materials.

さらに、本発明の乾式植M摩覇材料では、籍にマンガン
t15fA以下i6加している。マンカンの5貞 徐卯は、喘績中・1畠金属OJ化皮膜會還元し、焼結1
トヲ尚める作用があるからである。またマンガンの一部
は、Mn01にな抄摩11面會安定させる有効な作用を
有することからである。
Furthermore, in the dry-planted M polishing material of the present invention, manganese t15fA or less i6 is added to the material. Mankan's 5 Tei Xuu is currently in the process of reducing 1 metal OJ coating and sintering 1
This is because it has a soothing effect. This is also because a part of manganese has an effective effect of stabilizing the paper-milling surface of Mn01.

このようなことから、本発明の乾式−績廖揶材料は、比
較的41!II係数が高い材料であって、熱7エード現
象、水フェード現象に対する抵抗性が^く、油力相手材
に均する攻撃・性および鳴きが改善されているものであ
る。
For this reason, the dry-processing material of the present invention has a comparatively 41% strength. It is a material with a high II coefficient, has high resistance to thermal 7-ade phenomena and water fade phenomena, and has improved attack and resistance to hydraulic partner materials and squeaking.

次に、蛋晃明乾式焼績摩捧材料における一実施例につい
て#i明する。
Next, an example of the dry-fired burnished material produced by Tan Komei will be explained.

試料としては、不発−の乾式焼結l1111I材料およ
び従来の比較材椅tそれぞれ製遺した。すなわち本発明
に轟るものがム〜Dであや、従来の比較材料VC障るも
のが罵〜Gで、それぞれ次真に示す↓うな成分組成(単
位重電−)1+する。
The samples were an unexploded dry sintered l1111I material and a conventional comparative material. In other words, the material that is appealing to the present invention is M~D, and the one that is unfavorable to the conventional comparative material VC is A~G, each of which is shown in the next row.

6頁 表 次に、上記ム〜Gについて定連式摩−g−一で性能比較
した。これは、2つの試植片虻?(1!−20からなる
相手板fc押付けたものでめシ、そのときの条件は、摺
速が20n/sea、−圧が5〜である。
Table on page 6Next, the performance of the above M-G was compared using a fixed series M-g-1. Are these two trial plant flies? (The mating plate fc made of 1!-20 was pressed against it, and the conditions at that time were a sliding speed of 20 n/sea and a -pressure of 5~.

この結果、本発明のA−Dはいずれ一〇、4〜0.5の
一一円にある比較的^い屡−係数を鳴し、かつ相手板金
攻撃することが・1いとともに、耐熱)“ニード性にお
いても優れるものであった。また鳴きのレベルでも気に
ならないwi<以上のものでめった。
As a result, the A-D of the present invention has a relatively high coefficient of 10,4 to 0.5, and is difficult to attack the opponent's sheet metal and is heat resistant). “It was also excellent in terms of needability.It was also rare that the squeal level was above wi<, which was not bothersome.

7頁 これに対し、従来列の1は、相手1Iit−攻撃しない
が、耐熱フェード性でヤ\劣る結果【示し、νtま、耐
4ノエード性で優れるものでめるが、相手&倉大きく攻
撃するものであった。さらに、Gは耐熱フェード性で優
れるものの、相手板を非常に攻撃した。
Page 7 On the other hand, 1 in the conventional column does not attack the opponent 1 Iit, but has inferior heat fade resistance. It was something to do. Furthermore, although G had excellent heat fade resistance, it attacked the opponent's board extremely well.

なお、本発明の乾式**摩榔材料では、Mn@加のfJ
J果が1著で6抄、Mnの゛添署量について、別途に各
樟の試験tしたが、そO!1釆1s−以下が好適範1で
あることも’N明した0%に1S1!l超えるものは、
焼結時に浸出しが起抄、焼結の作業性ki&くすること
から排除した。
In addition, in the dry-grinding material of the present invention, fJ of Mn@Ka
There were 6 papers in one book by J., and a separate test was conducted for each of the Mn's signatures, but it was O! It is also clear that the preferred range is 1 s- or less for 1 button. 1S1 to 0%! l Anything that exceeds
The leaching during sintering has been eliminated because it impairs the workability of papermaking and sintering.

また、金属酸化1に関して別途試1itL友が、モース
硬度で4以上のもOが好蟲し、ムライト等の金X*化物
についても過用できることが判明した。
In addition, in a separate test with respect to metal oxide 1, it was found that O having a Mohs hardness of 4 or more was preferable, and that it could also be used excessively for gold X* compounds such as mullite.

本発明は、以上脱刷したように、銅系の乾式焼結摩擦材
料について、マンガン會添加し九特定の成分組成にする
ことによって、以下に示す効果が得られるものである。
In the present invention, as described above, the following effects can be obtained by adding manganese to a copper-based dry sintered friction material to obtain a specific component composition.

特開昭58−157930(3) ill  安定しrtg連係象k・にする乾式焼結摩擦
材料が提供されること。本発明では約0.4〜05と比
較的摩擦係数が高く、耐熱7エード性も優れる−のであ
る。これは、特に高速*#化ても安定した*m面が得ら
れることを意味し、自動重用には、%に好適なものとい
える。
JP-A-58-157930 (3) ill A dry sintered friction material which is stable and exhibits an rtg-coupled phenomenon k. The present invention has a relatively high friction coefficient of approximately 0.4 to 0.05, and excellent heat resistance. This means that a stable *m surface can be obtained even at high speed *#, and it can be said that it is suitable for automatic heavy use.

(2)相手板に対する攻撃性および鳴きが抜書された乾
式焼結摩擦材料が提供されること、一般的には、摩擦係
数が烏ければ、IIg1粍重がチ〈なり、これに伴って
相手板に対する攻撃性および鳴きも増加する。しかし、
本発明では摩mis数が高い反向ぞの摩耗量率も抑えら
れているものでるる、したがって、攻撃性に対する抜書
からいわゆる鳴きの減少にもつながるものでおる。
(2) A dry sintered friction material is provided that is characterized by its aggressiveness and squeaking against the opposing plate; in general, if the coefficient of friction is low, the IIg1 weight becomes low, and along with this, the Aggression and barking towards the board also increases. but,
In the present invention, the rate of wear on the opposite side where the number of friction points is high is also suppressed, and therefore, it also leads to a reduction in so-called squealing due to the lack of aggressiveness.

(3)  水フェード塊象に対しても抜書された乾式焼
結41I材料が提供されること1本発明では、銅系のマ
トリックス管ベースにしている仁とおよびマンガンを添
加したことにより、水フェード現象に対しても抵抗性が
委勧、特に塵出杉の二輪車には好適する。この場合相手
板としてステンレス鋼t9貞 使用すnば、錆のr[+!も同時に解決される。
(3) A dry sintered 41I material is provided which is also suitable for water fade agglomerates. 1. In the present invention, by adding nickel and manganese to a copper-based matrix tube base, water fade is achieved. It is also recommended for its resistance to phenomena, making it particularly suitable for motorcycles made of dusting cedar. In this case, if you use stainless steel T9 steel as the mating plate, there will be no rust. will be resolved at the same time.

Claims (1)

【特許請求の範囲】[Claims] (1)銅系の焼結合金からなる乾式m**擦材料におい
て、 前記焼結合金は、重量比で、鋼6G〜80−1錫3〜i
 o *、亜鉛15−以下、硬質粒子からなる金j14
酸化−3〜20−1黒鉛3〜10−1二硫化モリブデン
1〜5−および鉛8−以下および1ンガン15−以下を
書むことt%黴とする乾式焼結摩擦材料。 +2)繭記金JIIfR化物は、毫−ス一度で4以上の
硬質粒子からなっていることを脣倣とする特許a車の軛
囲第1項記義の乾式情緒摩擦材料。
(1) In a dry m** rubbing material made of a copper-based sintered alloy, the sintered alloy has a weight ratio of 6G to 80-1 of steel, 3 to 1 of tin,
o *, zinc 15- or less, gold j14 consisting of hard particles
A dry sintered friction material containing -3 to 20-1 oxide, 3 to 10-1 graphite, 1 to 5 molybdenum disulfide, and 8 to 15% of lead and 1 to 15% of mold. +2) The dry emotional friction material described in Paragraph 1 of the Patent A Car Yoke is based on the fact that the JIIfR compound is made up of 4 or more hard particles at one time.
JP3848782A 1982-03-11 1982-03-11 Dry sintered friction material Pending JPS58157930A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3848782A JPS58157930A (en) 1982-03-11 1982-03-11 Dry sintered friction material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3848782A JPS58157930A (en) 1982-03-11 1982-03-11 Dry sintered friction material

Publications (1)

Publication Number Publication Date
JPS58157930A true JPS58157930A (en) 1983-09-20

Family

ID=12526611

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3848782A Pending JPS58157930A (en) 1982-03-11 1982-03-11 Dry sintered friction material

Country Status (1)

Country Link
JP (1) JPS58157930A (en)

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