JPS5735530A - Preparation of isoprenoid derivative - Google Patents
Preparation of isoprenoid derivativeInfo
- Publication number
- JPS5735530A JPS5735530A JP11082280A JP11082280A JPS5735530A JP S5735530 A JPS5735530 A JP S5735530A JP 11082280 A JP11082280 A JP 11082280A JP 11082280 A JP11082280 A JP 11082280A JP S5735530 A JPS5735530 A JP S5735530A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- compound expressed
- substituent group
- expressed
- lower alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000003505 terpenes Chemical class 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 239000003699 antiulcer agent Substances 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- -1 tetrahydropyranyloxy Chemical group 0.000 abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- ACTIUHUUMQJHFO-UHFFFAOYSA-N Coenzym Q10 Natural products COC1=C(OC)C(=O)C(CC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C)=C(C)C1=O ACTIUHUUMQJHFO-UHFFFAOYSA-N 0.000 abstract 1
- 229930003448 Vitamin K Natural products 0.000 abstract 1
- 125000004423 acyloxy group Chemical group 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000005530 alkylenedioxy group Chemical group 0.000 abstract 1
- 125000002102 aryl alkyloxo group Chemical group 0.000 abstract 1
- 125000004391 aryl sulfonyl group Chemical group 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- ACTIUHUUMQJHFO-UPTCCGCDSA-N coenzyme Q10 Chemical compound COC1=C(OC)C(=O)C(C\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CCC=C(C)C)=C(C)C1=O ACTIUHUUMQJHFO-UPTCCGCDSA-N 0.000 abstract 1
- 235000017471 coenzyme Q10 Nutrition 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 239000003016 pheromone Substances 0.000 abstract 1
- SHUZOJHMOBOZST-UHFFFAOYSA-N phylloquinone Natural products CC(C)CCCCC(C)CCC(C)CCCC(=CCC1=C(C)C(=O)c2ccccc2C1=O)C SHUZOJHMOBOZST-UHFFFAOYSA-N 0.000 abstract 1
- NPCOQXAVBJJZBQ-UHFFFAOYSA-N reduced coenzyme Q9 Natural products COC1=C(O)C(C)=C(CC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C)C(O)=C1OC NPCOQXAVBJJZBQ-UHFFFAOYSA-N 0.000 abstract 1
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 abstract 1
- 229940035936 ubiquinone Drugs 0.000 abstract 1
- 235000019168 vitamin K Nutrition 0.000 abstract 1
- 239000011712 vitamin K Substances 0.000 abstract 1
- 150000003721 vitamin K derivatives Chemical class 0.000 abstract 1
- 229940046010 vitamin k Drugs 0.000 abstract 1
Landscapes
- Pyrane Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
NEW MATERIAL:An isoprenoid derivative expressed by formula I (R1 is OH, acyloxy, aralkyloxy, lower alkoxyl, tetrahydropyranyloxy, arylsulfonyl, lower alkyl which may be a lower alkylenedioxy as a substituent group or lower alkenyl which may have OH as a substituent group; n is an integer 0W3).
EXAMPLE: 6-Chloro-3,7-dimethyl-1-(p-toluenesulfonyl)-2,7-octadiene.
USE: An synthetic intermediate useful for the fields of vitamin K, ubiquinone, antiulcer agent, perfume or pheromone, and particularly the antiulcer agent itself.
PROCESS: A compound expressed by formula II is reacted with a sulfuryl chloride or chlorine to give the compound expressed by formula I. The resultant compound expressed by formula I is further converted into a compound expressed by formula III (R2 is lower alkyl, phenyl, etc.) useful for the fields described above.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11082280A JPS5735530A (en) | 1980-08-11 | 1980-08-11 | Preparation of isoprenoid derivative |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11082280A JPS5735530A (en) | 1980-08-11 | 1980-08-11 | Preparation of isoprenoid derivative |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5735530A true JPS5735530A (en) | 1982-02-26 |
Family
ID=14545530
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11082280A Pending JPS5735530A (en) | 1980-08-11 | 1980-08-11 | Preparation of isoprenoid derivative |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5735530A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60123430A (en) * | 1983-11-18 | 1985-07-02 | ローン‐プーラン・サント | Manufacture of chlorinated ethylenic derivatives |
| US5176370A (en) * | 1989-12-21 | 1993-01-05 | Dune Co., Ltd. | Torsion spring and cover |
-
1980
- 1980-08-11 JP JP11082280A patent/JPS5735530A/en active Pending
Non-Patent Citations (2)
| Title |
|---|
| JOURUAL OF CHEMICAL SOCIETY PERLCIN 1=1977 * |
| TETRAHEDRON LETTERS=1980 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60123430A (en) * | 1983-11-18 | 1985-07-02 | ローン‐プーラン・サント | Manufacture of chlorinated ethylenic derivatives |
| US5176370A (en) * | 1989-12-21 | 1993-01-05 | Dune Co., Ltd. | Torsion spring and cover |
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