JPS5721380A - Preparation of glycidyl acrylate or methacrylate - Google Patents

Preparation of glycidyl acrylate or methacrylate

Info

Publication number
JPS5721380A
JPS5721380A JP9481480A JP9481480A JPS5721380A JP S5721380 A JPS5721380 A JP S5721380A JP 9481480 A JP9481480 A JP 9481480A JP 9481480 A JP9481480 A JP 9481480A JP S5721380 A JPS5721380 A JP S5721380A
Authority
JP
Japan
Prior art keywords
reaction
organic layer
neutralization
reaction system
air
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP9481480A
Other languages
Japanese (ja)
Other versions
JPH0120152B2 (en
Inventor
Naomitsu Takashina
Shigeru Shiokawa
Naoki Iwasaki
Rokuro Fujita
Takeaki Takaoka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Gas Chemical Co Inc
Original Assignee
Mitsubishi Gas Chemical Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Gas Chemical Co Inc filed Critical Mitsubishi Gas Chemical Co Inc
Priority to JP9481480A priority Critical patent/JPS5721380A/en
Priority to DE19813126943 priority patent/DE3126943A1/en
Priority to NL8103285A priority patent/NL192039C/en
Publication of JPS5721380A publication Critical patent/JPS5721380A/en
Publication of JPH0120152B2 publication Critical patent/JPH0120152B2/ja
Granted legal-status Critical Current

Links

Abstract

PURPOSE: To obtain the aimed substance in high purity and yield, by blowing air into the neutralization reaction system of an acrylic acid or methacrylic acid with an alkali metallic (bi)carbonate and the subsequent esterification reaction system, and adding water to the reaction product solution, separating the organic layer, and distilling the organic layer.
CONSTITUTION: Acrylic acid or methacrylic acid is neutralized with an alkali metallic (bi)carbonate in an epihalohydrin in excess, and the resultant alkali metallic salt of the acid is reacted with an epihalohydrin in the presence of a catalyst to give the titled ester. In the process, air is blown into the reaction solution in the neutralization reaction system and the esterification reaction system, and water is added to the reaction solution after the completion of the reaction to separate the organic layer. The separated organic later is then distilled to afford the aimed substance. Preferably, a polymerization inhibitor is present in the reaction systems of both the neutralization and the esterification reactions.
EFFECT: The emulsification of the reaction solution in the subsequent washing with water is inhibited by blowing the air into the system.
COPYRIGHT: (C)1982,JPO&Japio
JP9481480A 1980-07-11 1980-07-11 Preparation of glycidyl acrylate or methacrylate Granted JPS5721380A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP9481480A JPS5721380A (en) 1980-07-11 1980-07-11 Preparation of glycidyl acrylate or methacrylate
DE19813126943 DE3126943A1 (en) 1980-07-11 1981-07-08 Process for preparing glycidyl acrylate or glycidyl methacrylate
NL8103285A NL192039C (en) 1980-07-11 1981-07-09 Process for preparing glycidyl acrylate or glycidyl methacrylate.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9481480A JPS5721380A (en) 1980-07-11 1980-07-11 Preparation of glycidyl acrylate or methacrylate

Publications (2)

Publication Number Publication Date
JPS5721380A true JPS5721380A (en) 1982-02-04
JPH0120152B2 JPH0120152B2 (en) 1989-04-14

Family

ID=14120516

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9481480A Granted JPS5721380A (en) 1980-07-11 1980-07-11 Preparation of glycidyl acrylate or methacrylate

Country Status (1)

Country Link
JP (1) JPS5721380A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102757409A (en) * 2012-07-19 2012-10-31 湖南罗比特化学材料有限公司 Preparation method of glycidyl acrylate
JP2014084316A (en) * 2012-10-26 2014-05-12 Mitsubishi Gas Chemical Co Inc Method for producing glycidyl methacrylate
WO2014148301A1 (en) * 2013-03-22 2014-09-25 三菱レイヨン株式会社 Process for producing glycidyl (meth)acrylate

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3922310B2 (en) * 1995-08-25 2007-05-30 三菱瓦斯化学株式会社 Method for producing glycidyl ester of acrylic acid or methacrylic acid

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102757409A (en) * 2012-07-19 2012-10-31 湖南罗比特化学材料有限公司 Preparation method of glycidyl acrylate
JP2014084316A (en) * 2012-10-26 2014-05-12 Mitsubishi Gas Chemical Co Inc Method for producing glycidyl methacrylate
WO2014148301A1 (en) * 2013-03-22 2014-09-25 三菱レイヨン株式会社 Process for producing glycidyl (meth)acrylate
US9303003B2 (en) 2013-03-22 2016-04-05 Mitsubishi Rayon Co., Ltd. Process for producing glycidyl (meth)acrylate
JPWO2014148301A1 (en) * 2013-03-22 2017-02-16 三菱レイヨン株式会社 Method for producing glycidyl (meth) acrylate

Also Published As

Publication number Publication date
JPH0120152B2 (en) 1989-04-14

Similar Documents

Publication Publication Date Title
FR2592040B1 (en) PROCESS FOR THE SYNTHESIS OF (METH) ACRYLIC ANHYDRIDES
JPS5721380A (en) Preparation of glycidyl acrylate or methacrylate
JPS5498718A (en) Recovery of acrylic acid
JPS5517307A (en) Preparation of glycidyl ester of acrylic or methacrylic acid
JPS578787A (en) Esterification by enzyme
ES8400727A1 (en) Process for making allylic esters of tetrabromophthalic acid.
CA1061355A (en) Process for producing glycidyl methacrylate
JPS5721379A (en) Preparation of glycidyl acrylate or methacrylate
JPS55122740A (en) Preparation of acrylate or methacrylate
JPS56164142A (en) Stabilization of still residue of distillation
JPS5565224A (en) Production of polyester di(meth)acrylate
JPS54157520A (en) Recovery of dimethylformamide
JPS53144524A (en) Production of methacrylic ester
JPS5223019A (en) Process for preparation of -beta hydroxyalkylacrylate of -beta hydroxyalkylmethacrylate
JPS56127329A (en) Preparation of monochloroacetic acid
GB841521A (en) Improvements in or relating to processes for the preparation of esters of acrylic and methacrylic acids
JPS5721339A (en) Esterification of organic carboxylic acid
JPS53121090A (en) Production of polymerizable composition
JPS5257135A (en) Esterification process
JPS54157504A (en) Preparation of carboxylic acid
SU567718A1 (en) Method of preparing dimethacryl esters of alcylene glycols
JPS5585540A (en) Separation of cis- and trans-1-methyl-4-isohexyl- cyclohexanecarboxylic acid
JPS53105471A (en) Preparation of cyclic ethers
JPS5581873A (en) Preparation of cis-epoxysuccinate
JPS56151496A (en) Treatment of crude sucrose fatty acid ester