JPS57188540A - Preparation of cyclopentanone compound - Google Patents
Preparation of cyclopentanone compoundInfo
- Publication number
- JPS57188540A JPS57188540A JP56072447A JP7244781A JPS57188540A JP S57188540 A JPS57188540 A JP S57188540A JP 56072447 A JP56072447 A JP 56072447A JP 7244781 A JP7244781 A JP 7244781A JP S57188540 A JPS57188540 A JP S57188540A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- alkyl
- catalyst
- hydroxycyclopentenone
- alkenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
PURPOSE: To prepare the titled substance having jasmone-like smell and useful as a perfume, in high yield and purity, by the catalytic hydrogenation of an easily synthesizable low-cost hydroxycyclopentenone compound in the presence of a catalyst.
CONSTITUTION: The compound of formula II (R3 is H or alkyl; R4 is H, alkyl, etc.; r3 and R4 are not H at the same time) can be prepared by the catalytic hydrogenation of the hydroxycyclopentenone compound of formulaI(R1 is H, alkyl, or alkenyl; R2 is H, alkyl, alkenyl, alkynyl, aryl, aralkyl, or cycloalkyl; R1 and R2 are not H at the same time) in the presence of an acidic catalyst such as hydrochloric acid, sulfuric acid, phosphoric acid, etc. The compound of formulaIcan be synthesized by the rearrangement reaction of the furan carbinol compound of formula III in a solvent such as water in the presence or absence of a catalyst.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56072447A JPS57188540A (en) | 1981-05-13 | 1981-05-13 | Preparation of cyclopentanone compound |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56072447A JPS57188540A (en) | 1981-05-13 | 1981-05-13 | Preparation of cyclopentanone compound |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57188540A true JPS57188540A (en) | 1982-11-19 |
JPH0214337B2 JPH0214337B2 (en) | 1990-04-06 |
Family
ID=13489546
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56072447A Granted JPS57188540A (en) | 1981-05-13 | 1981-05-13 | Preparation of cyclopentanone compound |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57188540A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5283237A (en) * | 1993-07-01 | 1994-02-01 | International Flavors & Fragrances Inc. | Use in perfumery of 2(1-vinyl-5-hexenyl) cyclopentanone, a process for preparing same, and process intermediates |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5646833A (en) * | 1979-09-25 | 1981-04-28 | T Hasegawa Co Ltd | Preparation of 2-substituted 5-membered cyclic ketone and its intermediate |
-
1981
- 1981-05-13 JP JP56072447A patent/JPS57188540A/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5646833A (en) * | 1979-09-25 | 1981-04-28 | T Hasegawa Co Ltd | Preparation of 2-substituted 5-membered cyclic ketone and its intermediate |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5283237A (en) * | 1993-07-01 | 1994-02-01 | International Flavors & Fragrances Inc. | Use in perfumery of 2(1-vinyl-5-hexenyl) cyclopentanone, a process for preparing same, and process intermediates |
Also Published As
Publication number | Publication date |
---|---|
JPH0214337B2 (en) | 1990-04-06 |
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