JPS57149292A - Novel method of preparing anlide phosphate derivative - Google Patents
Novel method of preparing anlide phosphate derivativeInfo
- Publication number
- JPS57149292A JPS57149292A JP56033734A JP3373481A JPS57149292A JP S57149292 A JPS57149292 A JP S57149292A JP 56033734 A JP56033734 A JP 56033734A JP 3373481 A JP3373481 A JP 3373481A JP S57149292 A JPS57149292 A JP S57149292A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- formula
- anlide
- preparing
- methanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 125000002467 phosphate group Chemical class [H]OP(=O)(O[H])O[*] 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 6
- 150000001875 compounds Chemical class 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 2
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 1
- 230000017858 demethylation Effects 0.000 abstract 1
- 238000010520 demethylation reaction Methods 0.000 abstract 1
- XOMCZFWKJMAIRV-UHFFFAOYSA-N dichlorophosphorylsulfanylbenzene Chemical compound ClP(Cl)(=O)SC1=CC=CC=C1 XOMCZFWKJMAIRV-UHFFFAOYSA-N 0.000 abstract 1
- 230000000855 fungicidal effect Effects 0.000 abstract 1
- 239000000417 fungicide Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 229910017053 inorganic salt Inorganic materials 0.000 abstract 1
- CDZOGLJOFWFVOZ-UHFFFAOYSA-N n-propylaniline Chemical compound CCCNC1=CC=CC=C1 CDZOGLJOFWFVOZ-UHFFFAOYSA-N 0.000 abstract 1
- 150000002903 organophosphorus compounds Chemical class 0.000 abstract 1
- 238000007086 side reaction Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/30—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing aromatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/24—Esteramides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
PURPOSE: A novel compound, as a starting substance, is made to react with an activated from of methanol to effect methoxy group introduction, thus producing the titled compound used as a fungicide for agricultural and horticultural purposes through simple operations in high yield in a short time.
CONSTITUTION: The reaction between a compound of formula II (X is halogen) such as S-phenyl-N-n-propyl-N-phenylthiophosphoroamide chloridate and an activated form of methanol is conducted in a solvent, preferably in the presence of an organic amine or inorganic salt to give the objective compound of formula I. The compound of formula II is novel and prepared by reaction of S-phenylthiophosphorodichloridate with N-n-propylaniline.
EFFECT: The introduction of a methoxy group at the last stage prohibits side- reactions such as demethylation characterized in organic phosphorus compounds.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56033734A JPS57149292A (en) | 1981-03-11 | 1981-03-11 | Novel method of preparing anlide phosphate derivative |
| KR1019820001048A KR830009130A (en) | 1981-03-11 | 1982-03-11 | Process for preparing phosphate anilide derivative |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56033734A JPS57149292A (en) | 1981-03-11 | 1981-03-11 | Novel method of preparing anlide phosphate derivative |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57149292A true JPS57149292A (en) | 1982-09-14 |
| JPS6314718B2 JPS6314718B2 (en) | 1988-04-01 |
Family
ID=12394629
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56033734A Granted JPS57149292A (en) | 1981-03-11 | 1981-03-11 | Novel method of preparing anlide phosphate derivative |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS57149292A (en) |
| KR (1) | KR830009130A (en) |
-
1981
- 1981-03-11 JP JP56033734A patent/JPS57149292A/en active Granted
-
1982
- 1982-03-11 KR KR1019820001048A patent/KR830009130A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6314718B2 (en) | 1988-04-01 |
| KR830009130A (en) | 1983-12-17 |
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