JPS5690055A - Novel preparation of aziridine-2-carboxylic acid salt - Google Patents

Novel preparation of aziridine-2-carboxylic acid salt

Info

Publication number
JPS5690055A
JPS5690055A JP16768179A JP16768179A JPS5690055A JP S5690055 A JPS5690055 A JP S5690055A JP 16768179 A JP16768179 A JP 16768179A JP 16768179 A JP16768179 A JP 16768179A JP S5690055 A JPS5690055 A JP S5690055A
Authority
JP
Japan
Prior art keywords
aziridine
alkali
carboxylic acid
earth
acid salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP16768179A
Other languages
Japanese (ja)
Other versions
JPS6039354B2 (en
Inventor
Ryuichi Mita
Chojiro Higuchi
Toshio Kato
Nobuyuki Kawashima
Teruhiro Yamaguchi
Shosuke Nagai
Takao Takano
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Toatsu Chemicals Inc
Original Assignee
Mitsui Toatsu Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Toatsu Chemicals Inc filed Critical Mitsui Toatsu Chemicals Inc
Priority to JP54167681A priority Critical patent/JPS6039354B2/en
Priority to EP19800304439 priority patent/EP0030474B1/en
Priority to US06/214,728 priority patent/US4393000A/en
Priority to EP80304440A priority patent/EP0030475B1/en
Priority to DE8080304440T priority patent/DE3067054D1/en
Priority to DE8080304439T priority patent/DE3061695D1/en
Priority to AU65259/80A priority patent/AU536508B2/en
Priority to MX10155580U priority patent/MX6502E/en
Priority to CA000366597A priority patent/CA1161854A/en
Publication of JPS5690055A publication Critical patent/JPS5690055A/en
Publication of JPS6039354B2 publication Critical patent/JPS6039354B2/en
Expired legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To obtain the titled compound which is an intermediate for an agricultural chemical, a medicine, etc. readily in high yield, by reacting an easily preparable and inexpensive α-halogenoacrylonitrile as a raw material with ammonia, and then with an alkali earth metal hydroxide.
CONSTITUTION: An α-halogenoacrylonitrile as a raw material is reacted with ammonia in water or an organic solvent to give an α-halogeno-β-aminopropionitrile, which is, without isolation from the reaction system, treated with an alkali (earth) metal hydroxide in the presence of water subsequently to afford an alkali (earth) metallic salt of aziridine-2-carboxylic acid. The reaction proceeds in a greatly simplified process under mild conditions, and the reaction operation is simple.
USE: An intermediate for an α-amino acid, e.g. serine.
COPYRIGHT: (C)1981,JPO&Japio
JP54167681A 1979-12-10 1979-12-25 New method for producing aziridine-2-carboxylate Expired JPS6039354B2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
JP54167681A JPS6039354B2 (en) 1979-12-25 1979-12-25 New method for producing aziridine-2-carboxylate
EP19800304439 EP0030474B1 (en) 1979-12-10 1980-12-09 Process for the production of dl-serines
US06/214,728 US4393000A (en) 1979-12-12 1980-12-09 Cyclization process for producing aziridine-2-carboxylic acid or its salts
EP80304440A EP0030475B1 (en) 1979-12-10 1980-12-09 Process for producing solutions of aziridine-2-carboxylic acid salts
DE8080304440T DE3067054D1 (en) 1979-12-10 1980-12-09 Process for producing solutions of aziridine-2-carboxylic acid salts
DE8080304439T DE3061695D1 (en) 1979-12-10 1980-12-09 Process for the production of dl-serines
AU65259/80A AU536508B2 (en) 1979-12-12 1980-12-10 Aziridine-2-carboxylic acid
MX10155580U MX6502E (en) 1979-12-12 1980-12-11 PROCEDURE FOR PREPARING AZIRIDIN-2-CARBOXYL ACID SALT
CA000366597A CA1161854A (en) 1979-12-12 1980-12-11 Process for producing aziridine-2-carboxylic acid or its salts

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP54167681A JPS6039354B2 (en) 1979-12-25 1979-12-25 New method for producing aziridine-2-carboxylate

Publications (2)

Publication Number Publication Date
JPS5690055A true JPS5690055A (en) 1981-07-21
JPS6039354B2 JPS6039354B2 (en) 1985-09-05

Family

ID=15854244

Family Applications (1)

Application Number Title Priority Date Filing Date
JP54167681A Expired JPS6039354B2 (en) 1979-12-10 1979-12-25 New method for producing aziridine-2-carboxylate

Country Status (1)

Country Link
JP (1) JPS6039354B2 (en)

Also Published As

Publication number Publication date
JPS6039354B2 (en) 1985-09-05

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