JPS5668624A - Preparation of 2-aryl ethanol - Google Patents
Preparation of 2-aryl ethanolInfo
- Publication number
- JPS5668624A JPS5668624A JP14354979A JP14354979A JPS5668624A JP S5668624 A JPS5668624 A JP S5668624A JP 14354979 A JP14354979 A JP 14354979A JP 14354979 A JP14354979 A JP 14354979A JP S5668624 A JPS5668624 A JP S5668624A
- Authority
- JP
- Japan
- Prior art keywords
- organic base
- hydrogen
- acid
- catalyst
- containing compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain a 2-aryl ethanol useful as an intermediate for a spice material, agricultural chemical, or drug by one step in high selectively and in high yield, by reducing an arylacetic acid with hydrogen in the presence of a rhenium catalyst and a proper organic base.
CONSTITUTION: An arylacetic acid, e.g., phenylacetic acid, p-methylphenylacetic acid, shown by the formula ArCH2COOH (Ar is aromatic hydrocarbon group of mono ring or condensed ring) is reduced with hydrogen in a solvent, e.g., dioxane, etc. in the presence of a rhenium catalyst, e.g., dirhenium heptoxide, and an organic base in an amount 10-4W10 times, preferably 10-2W1 time molar ratio to the catalyst, preferably at 100W180°C at a hydrogen partial pressure 80W200atm. for 0.1W10hr to give the desired compound. A nitrogen-containing compound, e.g., triethylamine, pyrimidine, etc. and a phosphorus-containing compound, e.g., triphenylphosphine, tri-n-butylphosphine, etc. is used as the organic base.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP54143549A JPS6033370B2 (en) | 1979-11-05 | 1979-11-05 | Method for producing 2-aryl ethanol |
US06/203,486 US4317918A (en) | 1979-11-05 | 1980-11-03 | Process for preparing alcohols |
EP80106823A EP0028422B1 (en) | 1979-11-05 | 1980-11-05 | Process for preparing alcohols from carboxylic acids and process for preparing carboxylic acids |
DE8080106823T DE3065195D1 (en) | 1979-11-05 | 1980-11-05 | Process for preparing alcohols from carboxylic acids and process for preparing carboxylic acids |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP54143549A JPS6033370B2 (en) | 1979-11-05 | 1979-11-05 | Method for producing 2-aryl ethanol |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5668624A true JPS5668624A (en) | 1981-06-09 |
JPS6033370B2 JPS6033370B2 (en) | 1985-08-02 |
Family
ID=15341322
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP54143549A Expired JPS6033370B2 (en) | 1979-11-05 | 1979-11-05 | Method for producing 2-aryl ethanol |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6033370B2 (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61116394U (en) * | 1984-12-29 | 1986-07-23 | ||
JPH0423247Y2 (en) * | 1985-10-30 | 1992-05-29 | ||
JPH0422356Y2 (en) * | 1986-03-28 | 1992-05-21 | ||
JPS62197391U (en) * | 1986-06-04 | 1987-12-15 | ||
JPH0261395U (en) * | 1988-10-27 | 1990-05-08 | ||
JPH055194U (en) * | 1991-06-27 | 1993-01-26 | 株式会社スタツフ | Musical instrument toy |
-
1979
- 1979-11-05 JP JP54143549A patent/JPS6033370B2/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
JPS6033370B2 (en) | 1985-08-02 |
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