JPS5655326A - Preparation of orthomethylated phenol - Google Patents

Preparation of orthomethylated phenol

Info

Publication number
JPS5655326A
JPS5655326A JP13091279A JP13091279A JPS5655326A JP S5655326 A JPS5655326 A JP S5655326A JP 13091279 A JP13091279 A JP 13091279A JP 13091279 A JP13091279 A JP 13091279A JP S5655326 A JPS5655326 A JP S5655326A
Authority
JP
Japan
Prior art keywords
oxide
phenol
atom
methanol
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP13091279A
Other languages
Japanese (ja)
Other versions
JPS6049168B2 (en
Inventor
Yoshiaki Annen
Kazunori Takahata
Katsuo Taniguchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Petrochemical Industries Ltd
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Priority to JP54130912A priority Critical patent/JPS6049168B2/en
Priority to US06/149,583 priority patent/US4329517A/en
Priority to EP80301618A priority patent/EP0019476B1/en
Priority to DE8080301618T priority patent/DE3066141D1/en
Publication of JPS5655326A publication Critical patent/JPS5655326A/en
Publication of JPS6049168B2 publication Critical patent/JPS6049168B2/en
Expired legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To obtain the titled compound industrially advantageously useful as a raw material for resins, etc., by reacting a phenol having hydrogen at orthoposition with methanol in the presence of a catalyst consisting of iron oxide, a metallic oxide, e.g., gallium oxide, etc. and chromium oxide under heating.
CONSTITUTION: In the presence of a catalyst consisting of (a) iron oxide, (b) a metallic oxide selected from the group consisting of gallium oxide, germanium oxide, yttrium oxide, niobium oxide, hafnium oxide, tantalum oxide, and bismuth oxide and (c) chromium oxide, preferably in blending ratio of a (a) to (b) and (c) of 1g iron atom of (a) to 0.005W0.15g atom of (b) and 0.001W0.05g atom of (c), a phenol (e.g., phenol, o-cresol) having one or more hydrogens at orthopositions is reacted with methanol under heating preferably at 300W400°C in gas phase, to give the desired compound useful for preparing a polyphenylene resin, etc. in high activity and selectivity while preventing the decomposition of methanol and preserving prolonged life of catalyst.
COPYRIGHT: (C)1981,JPO&Japio
JP54130912A 1979-05-16 1979-10-12 Process for producing orthomethylated phenols Expired JPS6049168B2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP54130912A JPS6049168B2 (en) 1979-10-12 1979-10-12 Process for producing orthomethylated phenols
US06/149,583 US4329517A (en) 1979-05-16 1980-05-14 Process for production of mono- or di-ortho-methyl-substituted phenols by catalytic methylation and catalyst therefor
EP80301618A EP0019476B1 (en) 1979-05-16 1980-05-16 Catalyst and process for producing ortho-methyl substituted phenols using it
DE8080301618T DE3066141D1 (en) 1979-05-16 1980-05-16 Catalyst and process for producing ortho-methyl substituted phenols using it

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP54130912A JPS6049168B2 (en) 1979-10-12 1979-10-12 Process for producing orthomethylated phenols

Publications (2)

Publication Number Publication Date
JPS5655326A true JPS5655326A (en) 1981-05-15
JPS6049168B2 JPS6049168B2 (en) 1985-10-31

Family

ID=15045634

Family Applications (1)

Application Number Title Priority Date Filing Date
JP54130912A Expired JPS6049168B2 (en) 1979-05-16 1979-10-12 Process for producing orthomethylated phenols

Country Status (1)

Country Link
JP (1) JPS6049168B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57126436A (en) * 1981-01-28 1982-08-06 Mitsui Toatsu Chem Inc Preparation of o- and p-alkylated phenol
JPS5925341A (en) * 1982-08-04 1984-02-09 Mitsui Petrochem Ind Ltd Preparation of ortho-substituted phenols
JPH0377839A (en) * 1989-08-22 1991-04-03 Mitsubishi Gas Chem Co Inc Ortho-alkylation
JP2002097165A (en) * 2000-04-20 2002-04-02 Sumitomo Chem Co Ltd Method for producing orthoalkylated phenols

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57126436A (en) * 1981-01-28 1982-08-06 Mitsui Toatsu Chem Inc Preparation of o- and p-alkylated phenol
JPS5925341A (en) * 1982-08-04 1984-02-09 Mitsui Petrochem Ind Ltd Preparation of ortho-substituted phenols
JPH0377839A (en) * 1989-08-22 1991-04-03 Mitsubishi Gas Chem Co Inc Ortho-alkylation
JP2002097165A (en) * 2000-04-20 2002-04-02 Sumitomo Chem Co Ltd Method for producing orthoalkylated phenols

Also Published As

Publication number Publication date
JPS6049168B2 (en) 1985-10-31

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