JPS56125326A - Preparation of chlorinated phenoxytoluenes in high selectivity - Google Patents

Preparation of chlorinated phenoxytoluenes in high selectivity

Info

Publication number
JPS56125326A
JPS56125326A JP2955980A JP2955980A JPS56125326A JP S56125326 A JPS56125326 A JP S56125326A JP 2955980 A JP2955980 A JP 2955980A JP 2955980 A JP2955980 A JP 2955980A JP S56125326 A JPS56125326 A JP S56125326A
Authority
JP
Japan
Prior art keywords
compound
high selectivity
chlorinated
coexistence
sulfur
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2955980A
Other languages
Japanese (ja)
Other versions
JPS6366817B2 (en
Inventor
Zenichi Yoshida
Susumu Kato
Takuya Fujiki
Yasuhiro Amamiya
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Chemical Co Ltd
Asahi Kagaku Kogyo Co Ltd
Original Assignee
Asahi Chemical Co Ltd
Asahi Kagaku Kogyo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Co Ltd, Asahi Kagaku Kogyo Co Ltd filed Critical Asahi Chemical Co Ltd
Priority to JP2955980A priority Critical patent/JPS56125326A/en
Publication of JPS56125326A publication Critical patent/JPS56125326A/en
Publication of JPS6366817B2 publication Critical patent/JPS6366817B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To obtain the titled compound useful as an intermediate for a fungicide in high selectivity, by chlorinating the methyl group in the side chain of a phenoxytoluene with chlorine selectively in the coexistence of a sulfur-containing compound, organic halogen compound, and radical reaction initiator.
CONSTITUTION: A compound, e.g., m-phenoxyltoluene, etc., shown by the formula I (R1 and R2 are H, halogen, alkyl, halogenoalkyl, acyl, CN, NO2, aryl, aralkyl, alkoxyl, alkoxycarbonyl) is reacted with chlorine in the coexistence of one or more sulfur-containing compounds, e.g., sulfenamides, etc., an organic halogen compound, e.g., carbon terachloride, and a radical reaction initiator, e.g., azobisisobutyronitirile, etc. at 0W150°C so that the methyl group in the side chain of the compound shown by the formula I is chlorinated selectively. Simultaneously the formation of phenoxyphenyltrichloromethanes as by-products is suppressed to give compounds shown by the formulas II and III in high selectivity in high yield.
COPYRIGHT: (C)1981,JPO&Japio
JP2955980A 1980-03-07 1980-03-07 Preparation of chlorinated phenoxytoluenes in high selectivity Granted JPS56125326A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2955980A JPS56125326A (en) 1980-03-07 1980-03-07 Preparation of chlorinated phenoxytoluenes in high selectivity

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2955980A JPS56125326A (en) 1980-03-07 1980-03-07 Preparation of chlorinated phenoxytoluenes in high selectivity

Publications (2)

Publication Number Publication Date
JPS56125326A true JPS56125326A (en) 1981-10-01
JPS6366817B2 JPS6366817B2 (en) 1988-12-22

Family

ID=12279489

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2955980A Granted JPS56125326A (en) 1980-03-07 1980-03-07 Preparation of chlorinated phenoxytoluenes in high selectivity

Country Status (1)

Country Link
JP (1) JPS56125326A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01261343A (en) * 1988-04-12 1989-10-18 Daiso Co Ltd Preparation of bis(trichloromethyl)diphenyl ether
JPH01261342A (en) * 1988-04-12 1989-10-18 Daiso Co Ltd Preparation of bis(trichloromethyl)diphenyl ether
JP2000505477A (en) * 1996-03-19 2000-05-09 ジヤンセン・フアーマシユーチカ・ナームローゼ・フエンノートシヤツプ Condensed imidazole derivatives as multidrug resistant transformants
WO2022230745A1 (en) * 2021-04-27 2022-11-03 株式会社Adeka Compound, curable composition and cured product

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56122325A (en) * 1980-02-29 1981-09-25 Asahi Kagaku Kogyo Kk Highly selective preparation of chlorinated phenoxytoluene
JPS5840934A (en) * 1981-09-03 1983-03-10 Sony Corp Controlling circuit of frequency characteristic

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56122325A (en) * 1980-02-29 1981-09-25 Asahi Kagaku Kogyo Kk Highly selective preparation of chlorinated phenoxytoluene
JPS5840934A (en) * 1981-09-03 1983-03-10 Sony Corp Controlling circuit of frequency characteristic

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01261343A (en) * 1988-04-12 1989-10-18 Daiso Co Ltd Preparation of bis(trichloromethyl)diphenyl ether
JPH01261342A (en) * 1988-04-12 1989-10-18 Daiso Co Ltd Preparation of bis(trichloromethyl)diphenyl ether
JP2000505477A (en) * 1996-03-19 2000-05-09 ジヤンセン・フアーマシユーチカ・ナームローゼ・フエンノートシヤツプ Condensed imidazole derivatives as multidrug resistant transformants
WO2022230745A1 (en) * 2021-04-27 2022-11-03 株式会社Adeka Compound, curable composition and cured product

Also Published As

Publication number Publication date
JPS6366817B2 (en) 1988-12-22

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