JPS5536406A - 3-methyl-5-succinic anhydrous-3-cyclohexene-1,2-dicarboxylic anhydride - Google Patents
3-methyl-5-succinic anhydrous-3-cyclohexene-1,2-dicarboxylic anhydrideInfo
- Publication number
- JPS5536406A JPS5536406A JP10911578A JP10911578A JPS5536406A JP S5536406 A JPS5536406 A JP S5536406A JP 10911578 A JP10911578 A JP 10911578A JP 10911578 A JP10911578 A JP 10911578A JP S5536406 A JPS5536406 A JP S5536406A
- Authority
- JP
- Japan
- Prior art keywords
- cyclohexene
- methyl
- dicarboxylic anhydride
- raw material
- succinic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Furan Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Epoxy Resins (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
NEW MATERIAL:3-Methyl-5-succinic anhydrous-3-cyclohexene-1,2-dicarboxylic anhydride I.
USE: A hardener for epoxy resins, a raw material of plasticizers for polyvinyl chloride, and a raw material of polyesters, polyamide or heat-resistant resins, e.g. polyimides, etc. It has a low melting point and omproved solubility in various solvents compared with the conventional aromatic tetracarboxylic dianhydrides.
PROCESS: 3-Methyl-4-cyclohexene-1,2-dicarboxylic anhydride II is heated under stirring together with maleic anhydride (0.2W5mol on the basis of 1mol of II) at 160W220°C for 2W24hr in the presence or absence of a catalyst to give the compound I.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10911578A JPS5851955B2 (en) | 1978-09-07 | 1978-09-07 | 5-(2,5-dioxotetrahydro-3-furanyl)-3-methyl-3-cyclohexene-1,2-dicarboxylic anhydride |
DE7979103281T DE2964284D1 (en) | 1978-09-07 | 1979-09-05 | 5-(2,5-diketotetrahydrofuryl)-3-methyl-3-cyclohexene-1,2-dicarboxylicanhydride, its use as curing agent for epoxy resins and as raw material for the production of polyimides, epoxy resins containing it, and their use in the preparation of various articles, and powder coating compositions |
EP79103281A EP0009645B1 (en) | 1978-09-07 | 1979-09-05 | 5-(2,5-diketotetrahydrofuryl)-3-methyl-3-cyclohexene-1,2-dicarboxylicanhydride, its use as curing agent for epoxy resins and as raw material for the production of polyimides, epoxy resins containing it, and their use in the preparation of various articles, and powder coating compositions |
US06/072,642 US4271079A (en) | 1978-09-07 | 1979-09-05 | 5-(2,5-Dioxotetrahydrofuryl)-3-methyl-3-cyclohexene-1,2-dicarboxylic anhydride |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10911578A JPS5851955B2 (en) | 1978-09-07 | 1978-09-07 | 5-(2,5-dioxotetrahydro-3-furanyl)-3-methyl-3-cyclohexene-1,2-dicarboxylic anhydride |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5536406A true JPS5536406A (en) | 1980-03-14 |
JPS5851955B2 JPS5851955B2 (en) | 1983-11-19 |
Family
ID=14501930
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10911578A Expired JPS5851955B2 (en) | 1978-09-07 | 1978-09-07 | 5-(2,5-dioxotetrahydro-3-furanyl)-3-methyl-3-cyclohexene-1,2-dicarboxylic anhydride |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5851955B2 (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57121035A (en) * | 1981-01-22 | 1982-07-28 | Dainippon Ink & Chem Inc | Preparation of polyimide resin |
WO1989000564A1 (en) * | 1987-07-10 | 1989-01-26 | New Japan Chemical Co., Ltd. | Process for producing methyltetrahydrophthalic anhydride |
JP2006083128A (en) * | 2004-09-17 | 2006-03-30 | Dainippon Ink & Chem Inc | Bisphenol-type imide compound and method for producing the same |
JP2009084383A (en) * | 2007-09-28 | 2009-04-23 | Sumitomo Bakelite Co Ltd | Epoxy resin powder paint |
WO2011099518A1 (en) | 2010-02-09 | 2011-08-18 | Jx日鉱日石エネルギー株式会社 | Norbornane-2-spiro-α-cycloalkanone-α'-spiro-2''-norbornane-5,5'',6,6''-tetracarboxylic dianhydride, norbornane-2-spiro-α-cycloalkanone-α'-spiro-2''-norbornane-5,5'',6,6''-tetracarboxylic acid and ester thereof, method for producing norbornane-2-spiro-α-cycloalkanone-α'-spiro-2''-norbornane-5,5'',6,6''-tetracarboxylic dianhydride, polyimide obtained using same, and method for producing polyimide |
WO2011099517A1 (en) | 2010-02-09 | 2011-08-18 | Jx日鉱日石エネルギー株式会社 | 5-norbornene-2-spiro-α-cycloalkanone-α'-spiro-2''-5''-norbornene and method for producing same |
KR20150044007A (en) | 2013-10-15 | 2015-04-23 | 닛뽄 가야쿠 가부시키가이샤 | Multifunctional acid anhydride, thermosetting resin composition, prepreg and cured article |
US9456495B2 (en) | 2012-09-26 | 2016-09-27 | Jx Nippon Oil & Energy Corporation | Norbornane-2-spiro-α-cycloalkanone-α′-spiro-2″-norbornane-5,5″,6,6″-tetracarboxylic dianhydride, norbornane-2-spiro-α-cycloalkanone-α′-spiro-2″-norbornane-5,5″,6,6″-tetracarboxylic acid and ester thereof, method for producing norbornane-2-spiro-α-cycloalkanone-α′-spiro-2″-norbornane-5,5″,6,6″-tetracarboxylic dianhydride, polyimide obtained by using the same, and method for producing polyimide |
KR20160143848A (en) | 2014-04-23 | 2016-12-14 | 제이엑스 에네루기 가부시키가이샤 | Tetracarboxylic dianhydride, polyamic acid, polyimide, methods for producing same, and polyamic acid solution |
WO2018173500A1 (en) * | 2017-03-24 | 2018-09-27 | Dic株式会社 | Active ester composition |
-
1978
- 1978-09-07 JP JP10911578A patent/JPS5851955B2/en not_active Expired
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57121035A (en) * | 1981-01-22 | 1982-07-28 | Dainippon Ink & Chem Inc | Preparation of polyimide resin |
JPH0120171B2 (en) * | 1981-01-22 | 1989-04-14 | Dainippon Ink & Chemicals | |
WO1989000564A1 (en) * | 1987-07-10 | 1989-01-26 | New Japan Chemical Co., Ltd. | Process for producing methyltetrahydrophthalic anhydride |
JP2006083128A (en) * | 2004-09-17 | 2006-03-30 | Dainippon Ink & Chem Inc | Bisphenol-type imide compound and method for producing the same |
JP2009084383A (en) * | 2007-09-28 | 2009-04-23 | Sumitomo Bakelite Co Ltd | Epoxy resin powder paint |
WO2011099517A1 (en) | 2010-02-09 | 2011-08-18 | Jx日鉱日石エネルギー株式会社 | 5-norbornene-2-spiro-α-cycloalkanone-α'-spiro-2''-5''-norbornene and method for producing same |
WO2011099518A1 (en) | 2010-02-09 | 2011-08-18 | Jx日鉱日石エネルギー株式会社 | Norbornane-2-spiro-α-cycloalkanone-α'-spiro-2''-norbornane-5,5'',6,6''-tetracarboxylic dianhydride, norbornane-2-spiro-α-cycloalkanone-α'-spiro-2''-norbornane-5,5'',6,6''-tetracarboxylic acid and ester thereof, method for producing norbornane-2-spiro-α-cycloalkanone-α'-spiro-2''-norbornane-5,5'',6,6''-tetracarboxylic dianhydride, polyimide obtained using same, and method for producing polyimide |
US8629303B2 (en) | 2010-02-09 | 2014-01-14 | Jx Nippon Oil & Energy Corporation | 5-norbornene-2-spiro-α-cycloalkanone-α′-spiro-2″-5″-norbornene and method for producing the same |
US9456495B2 (en) | 2012-09-26 | 2016-09-27 | Jx Nippon Oil & Energy Corporation | Norbornane-2-spiro-α-cycloalkanone-α′-spiro-2″-norbornane-5,5″,6,6″-tetracarboxylic dianhydride, norbornane-2-spiro-α-cycloalkanone-α′-spiro-2″-norbornane-5,5″,6,6″-tetracarboxylic acid and ester thereof, method for producing norbornane-2-spiro-α-cycloalkanone-α′-spiro-2″-norbornane-5,5″,6,6″-tetracarboxylic dianhydride, polyimide obtained by using the same, and method for producing polyimide |
KR20150044007A (en) | 2013-10-15 | 2015-04-23 | 닛뽄 가야쿠 가부시키가이샤 | Multifunctional acid anhydride, thermosetting resin composition, prepreg and cured article |
KR20160143848A (en) | 2014-04-23 | 2016-12-14 | 제이엑스 에네루기 가부시키가이샤 | Tetracarboxylic dianhydride, polyamic acid, polyimide, methods for producing same, and polyamic acid solution |
US10513582B2 (en) | 2014-04-23 | 2019-12-24 | Jxtg Nippon Oil & Energy Corporation | Tetracarboxylic dianhydride, polyamic acid, polyimide, methods for producing the same, and polyamic acid solution |
WO2018173500A1 (en) * | 2017-03-24 | 2018-09-27 | Dic株式会社 | Active ester composition |
CN110475798A (en) * | 2017-03-24 | 2019-11-19 | Dic株式会社 | Active ester composition |
Also Published As
Publication number | Publication date |
---|---|
JPS5851955B2 (en) | 1983-11-19 |
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