JPS5490196A - Novel 1,n6-etheno-2-iodo-adenosine-3',5'-cyclic phosphoric acid,its salt,and their preparation - Google Patents

Novel 1,n6-etheno-2-iodo-adenosine-3',5'-cyclic phosphoric acid,its salt,and their preparation

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Publication number
JPS5490196A
JPS5490196A JP15654077A JP15654077A JPS5490196A JP S5490196 A JPS5490196 A JP S5490196A JP 15654077 A JP15654077 A JP 15654077A JP 15654077 A JP15654077 A JP 15654077A JP S5490196 A JPS5490196 A JP S5490196A
Authority
JP
Japan
Prior art keywords
formula
salt
phosphoric acid
compound
etheno
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP15654077A
Other languages
Japanese (ja)
Inventor
Nobuyuki Yamatsugu
Motohiko Kato
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kikkoman Corp
Original Assignee
Kikkoman Corp
Kikkoman Shoyu KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kikkoman Corp, Kikkoman Shoyu KK filed Critical Kikkoman Corp
Priority to JP15654077A priority Critical patent/JPS5490196A/en
Publication of JPS5490196A publication Critical patent/JPS5490196A/en
Pending legal-status Critical Current

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  • Saccharide Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

NEW MATERIAL:1,N6-Etheno-2-iodo-adenosine-3',5'-cylic phosphoric acid of formula I: (Z1 is H, alkali metal, or organic ammonium group) or its salt.
USE: Biochemical reagents, e.g. a reagent for measuring phosphodiesterase activity, anticarcinogens, coronary vasodilators, blood platelet agglutination suppressants, diuretics, and antiallergic agants, having fluorescence.
PROCESS: A compound of formula II or its salt is reacted with I2 or an iodide of the formula Z2I (Z2 is H or alkali metal) in an aqueous solution at 5W50°C preferably 15W25°C for 0.5W24hr to give the compound of formula I or its salt. The compound of formula II is obtained by reaction of a compound of formula A: (X is 3-β-D-ribofuranosyl-3',5'-cyclic phosphoric acid) with chloroacetaldehyde, followed by hydrolysis and cyclization.
COPYRIGHT: (C)1979,JPO&Japio
JP15654077A 1977-12-27 1977-12-27 Novel 1,n6-etheno-2-iodo-adenosine-3',5'-cyclic phosphoric acid,its salt,and their preparation Pending JPS5490196A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15654077A JPS5490196A (en) 1977-12-27 1977-12-27 Novel 1,n6-etheno-2-iodo-adenosine-3',5'-cyclic phosphoric acid,its salt,and their preparation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15654077A JPS5490196A (en) 1977-12-27 1977-12-27 Novel 1,n6-etheno-2-iodo-adenosine-3',5'-cyclic phosphoric acid,its salt,and their preparation

Publications (1)

Publication Number Publication Date
JPS5490196A true JPS5490196A (en) 1979-07-17

Family

ID=15630019

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15654077A Pending JPS5490196A (en) 1977-12-27 1977-12-27 Novel 1,n6-etheno-2-iodo-adenosine-3',5'-cyclic phosphoric acid,its salt,and their preparation

Country Status (1)

Country Link
JP (1) JPS5490196A (en)

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