JPS5473705A - Production of olefins - Google Patents

Production of olefins

Info

Publication number
JPS5473705A
JPS5473705A JP13713877A JP13713877A JPS5473705A JP S5473705 A JPS5473705 A JP S5473705A JP 13713877 A JP13713877 A JP 13713877A JP 13713877 A JP13713877 A JP 13713877A JP S5473705 A JPS5473705 A JP S5473705A
Authority
JP
Japan
Prior art keywords
tertiary alcohol
methyl
oxyacid
water
boron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP13713877A
Other languages
Japanese (ja)
Other versions
JPS5839133B2 (en
Inventor
Sunao Kyo
Kenichi Hino
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuraray Co Ltd
Original Assignee
Kuraray Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Co Ltd filed Critical Kuraray Co Ltd
Priority to JP52137138A priority Critical patent/JPS5839133B2/en
Publication of JPS5473705A publication Critical patent/JPS5473705A/en
Publication of JPS5839133B2 publication Critical patent/JPS5839133B2/en
Expired legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: The dehydration of a tertiary alcohol of 4W5 carbon stoms is conducted in the presence of an oxyacid of boron and water with heating to produce an olifin suitably used in the preparation of oxo alcohols in high yield with no formation of by-products.
CONSTITUTION: A tertiary alcohol of formula I (R1 is H, methyl) is heated in the presence of water and an oxyacid of boron or boron compound convertible to the oxyacid under the reaction conditions to form an olefin of formula II (Either R2 or R3 is H is and the rest is H or tert. butyl when R1 is H, when R1 is methyl the rest is methyl). The amount of the catalyst is 0.05W2.0 moles per mole of the tertiary alcohol calculated as boric acid. The amount of water is preferably less than 200wt% based on the alcohol. Further the main product changes to diisobutene when the tertiary alcohol is heated over 170°C.
COPYRIGHT: (C)1979,JPO&Japio
JP52137138A 1977-11-14 1977-11-14 Method for producing olefins Expired JPS5839133B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP52137138A JPS5839133B2 (en) 1977-11-14 1977-11-14 Method for producing olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP52137138A JPS5839133B2 (en) 1977-11-14 1977-11-14 Method for producing olefins

Publications (2)

Publication Number Publication Date
JPS5473705A true JPS5473705A (en) 1979-06-13
JPS5839133B2 JPS5839133B2 (en) 1983-08-27

Family

ID=15191700

Family Applications (1)

Application Number Title Priority Date Filing Date
JP52137138A Expired JPS5839133B2 (en) 1977-11-14 1977-11-14 Method for producing olefins

Country Status (1)

Country Link
JP (1) JPS5839133B2 (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5242763A (en) * 1975-09-30 1977-04-02 Seiko Instr & Electronics Ltd Electronic alarm wristwatch

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5242763A (en) * 1975-09-30 1977-04-02 Seiko Instr & Electronics Ltd Electronic alarm wristwatch

Also Published As

Publication number Publication date
JPS5839133B2 (en) 1983-08-27

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