JPS54144370A - Preparation of 2-amino-4,5-dicyanoimidazole - Google Patents
Preparation of 2-amino-4,5-dicyanoimidazoleInfo
- Publication number
- JPS54144370A JPS54144370A JP5335878A JP5335878A JPS54144370A JP S54144370 A JPS54144370 A JP S54144370A JP 5335878 A JP5335878 A JP 5335878A JP 5335878 A JP5335878 A JP 5335878A JP S54144370 A JPS54144370 A JP S54144370A
- Authority
- JP
- Japan
- Prior art keywords
- pref
- cyanogen
- reacting
- dicyanoimidazole
- amino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- MLOXIXGLIZLPDP-UHFFFAOYSA-N 2-amino-1h-imidazole-4,5-dicarbonitrile Chemical compound NC1=NC(C#N)=C(C#N)N1 MLOXIXGLIZLPDP-UHFFFAOYSA-N 0.000 title abstract 2
- DPZSNGJNFHWQDC-ARJAWSKDSA-N (z)-2,3-diaminobut-2-enedinitrile Chemical compound N#CC(/N)=C(/N)C#N DPZSNGJNFHWQDC-ARJAWSKDSA-N 0.000 abstract 3
- -1 cyanogen halide Chemical class 0.000 abstract 3
- JMANVNJQNLATNU-UHFFFAOYSA-N glycolonitrile Natural products N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 abstract 3
- 239000007864 aqueous solution Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- ATDGTVJJHBUTRL-UHFFFAOYSA-N cyanogen bromide Chemical compound BrC#N ATDGTVJJHBUTRL-UHFFFAOYSA-N 0.000 abstract 1
- QPJDMGCKMHUXFD-UHFFFAOYSA-N cyanogen chloride Chemical compound ClC#N QPJDMGCKMHUXFD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003814 drug Substances 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Abstract
PURPOSE: To prepare the title compound useful as an intermediate of pharmaceuticals, pesticides, dyes and pigments, directly, economically, in high yield and in an industrial scale, by reacting diaminomaleonitrile with cyanogen halide in the presence of water.
CONSTITUTION: 2-Amino-4,5-dicyanoimidazole of formula is prepared by reacting diaminomalenitrile (1 part by weight) with a cyanogen halide (pref. cyanogen chloride or cyanogen bromide) in the presence of water (usually 2W200 parts, pref. 5W100 parts by weight). The reaction is pref. carried out first by preparing an aqueous solution of a cyanogen halide by the reaction of an aqueous solution of an alkali cyanide such as sodium cyanide, potassium cyanide, etc., with a halogen, and then reacting the solution with diaminomaleonitrile.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5335878A JPS54144370A (en) | 1978-05-04 | 1978-05-04 | Preparation of 2-amino-4,5-dicyanoimidazole |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5335878A JPS54144370A (en) | 1978-05-04 | 1978-05-04 | Preparation of 2-amino-4,5-dicyanoimidazole |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS54144370A true JPS54144370A (en) | 1979-11-10 |
JPS5730105B2 JPS5730105B2 (en) | 1982-06-26 |
Family
ID=12940569
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5335878A Granted JPS54144370A (en) | 1978-05-04 | 1978-05-04 | Preparation of 2-amino-4,5-dicyanoimidazole |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS54144370A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112062722A (en) * | 2019-06-11 | 2020-12-11 | 太仓市茜泾化工有限公司 | Preparation method of 2-amino-4, 5-dicyanoimidazole |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS49126674A (en) * | 1973-04-12 | 1974-12-04 | ||
JPS514171A (en) * | 1974-06-29 | 1976-01-14 | Kyowa Gas Chem Ind Co Ltd | Shinkinafukusokankarubonsanamido oyobi sonoseizoho |
-
1978
- 1978-05-04 JP JP5335878A patent/JPS54144370A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS49126674A (en) * | 1973-04-12 | 1974-12-04 | ||
JPS514171A (en) * | 1974-06-29 | 1976-01-14 | Kyowa Gas Chem Ind Co Ltd | Shinkinafukusokankarubonsanamido oyobi sonoseizoho |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112062722A (en) * | 2019-06-11 | 2020-12-11 | 太仓市茜泾化工有限公司 | Preparation method of 2-amino-4, 5-dicyanoimidazole |
Also Published As
Publication number | Publication date |
---|---|
JPS5730105B2 (en) | 1982-06-26 |
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