JPH11171544A - チタン含有物質およびその製造方法 - Google Patents
チタン含有物質およびその製造方法Info
- Publication number
- JPH11171544A JPH11171544A JP10233011A JP23301198A JPH11171544A JP H11171544 A JPH11171544 A JP H11171544A JP 10233011 A JP10233011 A JP 10233011A JP 23301198 A JP23301198 A JP 23301198A JP H11171544 A JPH11171544 A JP H11171544A
- Authority
- JP
- Japan
- Prior art keywords
- titanium
- sol
- mol
- thin film
- soln
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010936 titanium Substances 0.000 title claims abstract description 29
- 229910052719 titanium Inorganic materials 0.000 title claims abstract description 29
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims description 27
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000000463 material Substances 0.000 title abstract description 18
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 25
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 19
- 239000011248 coating agent Substances 0.000 claims abstract description 16
- 238000000576 coating method Methods 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 13
- 230000007062 hydrolysis Effects 0.000 claims abstract description 11
- 238000009835 boiling Methods 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims description 22
- 239000000126 substance Substances 0.000 claims description 18
- 238000002834 transmittance Methods 0.000 claims description 9
- 230000003301 hydrolyzing effect Effects 0.000 claims description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract description 30
- 239000002245 particle Substances 0.000 abstract description 29
- 239000010409 thin film Substances 0.000 abstract description 27
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 20
- 230000001699 photocatalysis Effects 0.000 abstract description 18
- 239000000758 substrate Substances 0.000 abstract description 18
- 150000001735 carboxylic acids Chemical class 0.000 abstract description 10
- 238000006298 dechlorination reaction Methods 0.000 abstract description 7
- 238000010438 heat treatment Methods 0.000 abstract description 4
- 238000000909 electrodialysis Methods 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 description 18
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 16
- 239000011521 glass Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000010408 film Substances 0.000 description 6
- 238000009826 distribution Methods 0.000 description 5
- 238000005562 fading Methods 0.000 description 5
- 238000010992 reflux Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000000411 transmission spectrum Methods 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 238000010304 firing Methods 0.000 description 4
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 4
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- 238000002835 absorbance Methods 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- -1 titanium alkoxide Chemical class 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 150000001734 carboxylic acid salts Chemical class 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000005328 architectural glass Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000382 dechlorinating effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10233011A JPH11171544A (ja) | 1997-08-20 | 1998-08-19 | チタン含有物質およびその製造方法 |
| CNB998123706A CN1168663C (zh) | 1998-08-19 | 1999-05-24 | 含钛的细微颗粒物质，水溶胶组合物，含该物质的涂料液，该涂料液的制造方法及有该物质膜的成型制品 |
| CA002343085A CA2343085C (en) | 1998-08-19 | 1999-05-24 | Titanium-containing finely divided particulate material, aqueous sol composition and coating liquid containing same, process for producing same, and shaped article having film thereof |
| CNB2004100558230A CN1310840C (zh) | 1998-08-19 | 1999-05-24 | 无定形含钛的细微颗粒物质及包括由其形成的薄膜的制品 |
| KR1020017001978A KR100630285B1 (ko) | 1998-08-19 | 1999-05-24 | 미세 티탄함유물질, 이를 함유하는 수성졸 조성물 및 코팅액, 이들의 제조방법 및 그 박막을 갖는 성형품 |
| US09/763,172 US6610135B1 (en) | 1998-08-19 | 1999-05-24 | Titanium-containing finely divided particulate material, aqueous sol composition and coating liquid containing same, process for producing same, and shaped article having film thereof |
| EP99919667A EP1127844B1 (en) | 1998-08-19 | 1999-05-24 | Finely particulate titanium-containing substance, coating fluid containing the same, processes for producing these, and molded article having thin film comprising the substance |
| PCT/JP1999/002712 WO2000010921A1 (en) | 1998-08-19 | 1999-05-24 | Finely particulate titanium-containing substance, coating fluid containing the same, processes for producing these, and molded article having thin film comprising the substance |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22339497 | 1997-08-20 | ||
| JP9-223394 | 1997-08-20 | ||
| JP10233011A JPH11171544A (ja) | 1997-08-20 | 1998-08-19 | チタン含有物質およびその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH11171544A true JPH11171544A (ja) | 1999-06-29 |
| JPH11171544A5 JPH11171544A5 (enExample) | 2005-10-27 |
Family
ID=26525449
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10233011A Pending JPH11171544A (ja) | 1997-08-20 | 1998-08-19 | チタン含有物質およびその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11171544A (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002002232A1 (en) * | 2000-06-30 | 2002-01-10 | Ecole Polytechnique Federale De Lausanne (Epfl) | Carboxylate-containing photocatalytic body, manufacture and use thereof |
| JP2005169160A (ja) * | 2003-12-05 | 2005-06-30 | Ishihara Sangyo Kaisha Ltd | 光触媒液状組成物およびそれを用いて形成した光触媒体 |
| JP2005179118A (ja) * | 2003-12-19 | 2005-07-07 | Toho Catalyst Co Ltd | 四塩化チタン水溶液の製造方法 |
| WO2020170918A1 (ja) * | 2019-02-19 | 2020-08-27 | 昭和電工株式会社 | 酸化チタンの製造方法 |
| WO2025211379A1 (ja) * | 2024-04-02 | 2025-10-09 | 三井金属鉱業株式会社 | 金属化合物分散液、及び金属化合物分散液の製造方法 |
-
1998
- 1998-08-19 JP JP10233011A patent/JPH11171544A/ja active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002002232A1 (en) * | 2000-06-30 | 2002-01-10 | Ecole Polytechnique Federale De Lausanne (Epfl) | Carboxylate-containing photocatalytic body, manufacture and use thereof |
| US7081428B1 (en) | 2000-06-30 | 2006-07-25 | Ecole Polytechnique Federale De Lausanne (Epfl) | Carboxylate-containing photocatalytic body, manufacture and use thereof |
| JP2005169160A (ja) * | 2003-12-05 | 2005-06-30 | Ishihara Sangyo Kaisha Ltd | 光触媒液状組成物およびそれを用いて形成した光触媒体 |
| JP2005179118A (ja) * | 2003-12-19 | 2005-07-07 | Toho Catalyst Co Ltd | 四塩化チタン水溶液の製造方法 |
| WO2020170918A1 (ja) * | 2019-02-19 | 2020-08-27 | 昭和電工株式会社 | 酸化チタンの製造方法 |
| KR20210096194A (ko) * | 2019-02-19 | 2021-08-04 | 쇼와 덴코 가부시키가이샤 | 산화티타늄의 제조 방법 |
| CN113260594A (zh) * | 2019-02-19 | 2021-08-13 | 昭和电工株式会社 | 氧化钛的制造方法 |
| JPWO2020170918A1 (ja) * | 2019-02-19 | 2021-09-13 | 昭和電工株式会社 | 酸化チタンの製造方法 |
| WO2025211379A1 (ja) * | 2024-04-02 | 2025-10-09 | 三井金属鉱業株式会社 | 金属化合物分散液、及び金属化合物分散液の製造方法 |
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