JPH11116417A - Miticidal agent - Google Patents

Miticidal agent

Info

Publication number
JPH11116417A
JPH11116417A JP27573497A JP27573497A JPH11116417A JP H11116417 A JPH11116417 A JP H11116417A JP 27573497 A JP27573497 A JP 27573497A JP 27573497 A JP27573497 A JP 27573497A JP H11116417 A JPH11116417 A JP H11116417A
Authority
JP
Japan
Prior art keywords
hyssop
agent
oil
house
mites
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP27573497A
Other languages
Japanese (ja)
Other versions
JP3928224B2 (en
Inventor
Hitoshi Kawada
均 川田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Priority to JP27573497A priority Critical patent/JP3928224B2/en
Publication of JPH11116417A publication Critical patent/JPH11116417A/en
Application granted granted Critical
Publication of JP3928224B2 publication Critical patent/JP3928224B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To obtain a miticidal composition effective for controlling mites, especially dust mites in house by using hyssop oil as a component. SOLUTION: The objective miticidal composition contains 0.1-50 wt.% of hyssop oil which is an essential oil of hyssop and produced by the steam distillation of raw or dried hyssop grass. The composition further contains usually a proper carrier and, as necessary, dispersing agent, wetting agent, thickener, antioxidant, ultraviolet absorber, etc., and is used in the form of oil solution, emulsifiable concentrate, suspension, aerosol preparation, fumigating agent, heat-evaporation agent, etc. The miticidal composition is especially effective for the control of Epidermoptidae, Acaridiae, Glycyphagidae, An ascidae named Marunikudani, Cheyletidae, Ornithomyssus bacoti, Haplochthoniidae, Pyemotidae, Sarcoptidae, etc., living in house.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は殺ダニ組成物及び殺
ダニ方法に関する。
The present invention relates to acaricidal compositions and acaricidal methods.

【0002】[0002]

【発明が解決しようとする課題】本発明は、ダニ、特に
屋内に生息する塵性ダニを防除するのに有効な殺ダニ組
成物及び殺ダニ方法を提供することを目的としてなされ
たものである。
SUMMARY OF THE INVENTION An object of the present invention is to provide a miticidal composition and a miticidal method which are effective for controlling mites, especially dust mites living indoors. .

【0003】[0003]

【課題を解決するための手段】本発明によれば、ヒソッ
プ油を有効成分として含有する殺ダニ組成物が、優れた
殺ダニ組成物であるというものである。
According to the present invention, an acaricide composition containing hyssop oil as an active ingredient is an excellent acaricidal composition.

【0004】本発明において用いられるヒソップ油(Hy
ssop oil)は、ヒソップ(Hyssopusofficinalis L.)と
いう植物の精油であり、ヒソップの生草又は乾草を水蒸
気蒸留することにより得られる。また、ヒソップ油は市
販されており、市場で入手することもできる。
Hyssop oil (Hy) used in the present invention
Ssop oil) is an essential oil of a plant called Hyssopusofficinalis L., and is obtained by steam-distilling raw or hay of Hyssop. Hyssop oil is commercially available and can be obtained on the market.

【0005】[0005]

【発明の実施の形態】本発明の殺ダニ組成物はヒソップ
油そのものであってもよいが、通常は有効成分であるヒ
ソップ油の他に適当な担体、必要により分散剤、湿潤
剤、増粘剤、酸化防止剤、紫外線吸収剤等の製剤用補助
剤を含有し、油剤、乳剤、懸濁剤、エアゾール製剤、燻
煙剤、加熱蒸散剤等の各種製剤形態をとるものであり、
本発明の殺ダニ組成物中、ヒソップ油は通常 0.1〜50
重量%含有される。
BEST MODE FOR CARRYING OUT THE INVENTION The acaricidal composition of the present invention may be hyssop oil itself. Usually, in addition to the active ingredient hyssop oil, a suitable carrier, if necessary, a dispersant, a wetting agent, a thickener, Agents, antioxidants, UV absorbers and other formulation aids, and take various formulation forms such as oils, emulsions, suspensions, aerosol formulations, smokers, and heat transpirants,
In the acaricidal composition of the present invention, hyssop oil is usually 0.1 to 50.
% By weight.

【0006】製剤化の際に用いられる担体としては、炭
化水素類(例えば、トルエン、キシレン、メチルナフタ
レン、フェニルキシリルエタン、ケロセン、ヘキサン、
シクロヘキサン等)、エーテル類(例えば、ジエチルエ
ーテル、エチレングリコールジメチルエーテル、テトラ
ヒドロフラン、ジオキサン等)、ケトン類(例えば、ア
セトン、メチルエチルケトン、メチルイソブチルケト
ン、シクロヘキサノン、イソホロン等)、アルコール類
(例えば、メタノール、エタノール、イソプロピルアル
コール、ヘキサノール、エチレングリコール等)、アミ
ド類(例えば、N,N−ジメチルホルムアミド、N,N
−ジメチルアセトアミド等)などの液体担体、タルク、
ベントナイト、クレー、カオリン、珪藻土、シリカ、バ
ーミキュライト、パーライトなどの固体担体が挙げられ
る。また、本発明の殺ダニ組成物がエアゾール製剤であ
る場合には、窒素、炭酸ガス、ジメチルエーテル、LP
G等の気体担体を噴射剤として含有する。
[0006] Carriers used in the formulation include hydrocarbons (for example, toluene, xylene, methylnaphthalene, phenylxylylethane, kerosene, hexane,
Cyclohexane, etc.), ethers (eg, diethyl ether, ethylene glycol dimethyl ether, tetrahydrofuran, dioxane, etc.), ketones (eg, acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, isophorone, etc.), alcohols (eg, methanol, ethanol, Isopropyl alcohol, hexanol, ethylene glycol, etc.), amides (eg, N, N-dimethylformamide, N, N
Liquid carrier such as dimethylacetamide), talc,
Examples include solid carriers such as bentonite, clay, kaolin, diatomaceous earth, silica, vermiculite, and pearlite. When the acaricidal composition of the present invention is an aerosol preparation, nitrogen, carbon dioxide, dimethyl ether, LP
A gas carrier such as G is contained as a propellant.

【0007】本発明の殺ダニ組成物が非燃焼型燻煙剤で
ある場合には、有効成分の他に発泡剤を含有する。該発
泡剤としては例えば、アゾジカルボンアミド、アゾビス
イソブチロニトリル、2−(カルバモイルアゾ)イソブ
チロニトリル、ジニトロソペンタメチレンテトラミン及
びp,p'−オキシ−ビス(ベンゼンスルホニルヒドラジ
ド)等の熱分解により窒素を発生し得る有機発泡剤など
が挙げられる。該非燃焼型燻煙剤の使用に際しては、例
えば、特公昭59-49201号公報に記載されるような隔壁で
区分された容器の一方に顆粒状の燻煙剤を入れ、他方に
酸化カルシウムを入れておき、使用時に酸化カルシウム
に水を加え、この時の化学反応熱を利用してダニ防除を
行うという方法が便利である。
[0007] When the acaricidal composition of the present invention is a non-combustion type smoke agent, it contains a foaming agent in addition to the active ingredient. Examples of the foaming agent include azodicarbonamide, azobisisobutyronitrile, 2- (carbamoylazo) isobutyronitrile, dinitrosopentamethylenetetramine and p, p'-oxy-bis (benzenesulfonylhydrazide). An organic foaming agent capable of generating nitrogen by thermal decomposition is exemplified. When using the non-combustion type smoke agent, for example, a granular smoke agent is put in one of the containers divided by a partition wall as described in JP-B-59-49201, and calcium oxide is put in the other. Beforehand, it is convenient to add water to the calcium oxide at the time of use, and use the heat of chemical reaction at this time to control mites.

【0008】一方、本発明の殺ダニ組成物が燃焼型燻煙
剤である場合には、有効成分の他に通常、過塩素酸カリ
ウム、硝酸カリウム、塩素酸カリウム等の酸素供給剤、
糖類、澱粉等の燃焼剤、さらに必要により、硝酸グアニ
ジン、ニトログアニジン、ジシアンジアミド、リン酸グ
アニル尿素、スルファミン酸グアニジン等の発熱調整剤
や塩化カリウム、塩化ナトリウム、四三酸化鉄、酸化
銅、酸化クロム、酸化鉄、塩化鉄、活性炭等の酸素供給
剤分解用助剤、パーライト、珪藻土、タルク、クレー等
の無機担体を含有し、これらの各成分を混合し、水を加
えて混練、顆粒状に成型、乾燥といった通常の方法によ
り製造される。
[0008] On the other hand, when the acaricidal composition of the present invention is a combustion-type smoke-absorbing agent, an oxygen-supplying agent such as potassium perchlorate, potassium nitrate, or potassium chlorate is usually used in addition to the active ingredient.
Combustion agents such as saccharides and starch, and, if necessary, exothermic regulators such as guanidine nitrate, nitroguanidine, dicyandiamide, guanylurea phosphate, guanidine sulfamate, potassium chloride, sodium chloride, ferric oxide, copper oxide, and chromium oxide , Iron oxide, iron chloride, an auxiliary agent for decomposition of oxygen supply agents such as activated carbon, and an inorganic carrier such as pearlite, diatomaceous earth, talc, clay, etc., mixing these components, adding water, kneading and granulating. It is manufactured by ordinary methods such as molding and drying.

【0009】尚、本発明の殺ダニ組成物は有効成分とし
てヒソップ油を含有するものであるが、さらに、他の殺
ダニ活性成分(例えば、ペルメトリン、エンペントリン
等のピレスロイド化合物)、共力剤、殺菌剤、防黴剤等
を含有させたものであってもよい。
The acaricidal composition of the present invention contains hyssop oil as an active ingredient, and further contains other acaricidal active ingredients (for example, pyrethroid compounds such as permethrin and empentrin), synergists, It may contain a bactericide, a fungicide and the like.

【0010】本発明の殺ダニ組成物は、特に、屋内に生
息するダニ、例えば、コナヒョウヒダニ、ヤケヒョウヒ
ダニ等のヒョウヒダニ類、コウノホシカダニ、ケナガコ
ナダニ、ムギコナダニ等のコナダニ類、チリニクダニ、
イエニクダニ、サヤアシニクダニ等のニクダニ類、マル
ニクダニ類、ミナミツメダニ、クワガタツメダニ、フト
ツメダニ、ホソツメダニ、アシナガツメダニ等のツメダ
ニ類、イエダニ、トリサシダニ、ワクモ、スズメサシダ
ニ等のイエダニ類、イエササラダニ類、シラミダニ類、
ヒゼンダニ類などを防除するのに有効である。
The acaricidal composition of the present invention is particularly useful for indoor mites, such as Dermatophagoides, Dermatophagoides, Dermatophagoides and Dermatophagoides, Dermatophagoids such as Dermatophagoides farinae, Dermatophagoides farinae, Dermatophagoides farinae, and the like.
House dust mites such as house dust mite, Cyperus sylvestris, maricus mites, southern house mites, stag beetle mite, red house mite, red house mite, house mite such as house mite, house mite, trifoliate mite, house mites, house mite, house mite, house mite
It is effective for controlling scabies and the like.

【0011】本発明の殺ダニ組成物をダニの生息する
畳、絨毯等に直接施用する場合、その施用量は、通常1
2当たりヒソップ油の量にして 0.1〜50g程度であ
る。また、燻煙又は燻蒸によりダニを防除する場合、施
用量は通常1m3当たりヒソップ油の量にして1〜 300m
g程度である。
When the acaricidal composition of the present invention is directly applied to tatami mats, carpets and the like in which mites live, the application amount is usually 1
The amount of hyssop oil is about 0.1 to 50 g per m 2 . In the case of controlling mites by smoke or fumigation, the application rates are. 1 to 300 meters usually in the amount of 1 m 3 per hyssop
g.

【0012】[0012]

【実施例】以下、本発明を実施例にてより詳細に説明す
る。まず、本発明の殺ダニ組成物の製造例を示す。 製造例1 ヒソップ油20重量部、酸化亜鉛 0.5重量部及びα−澱
粉2重量部にアゾジカルボンアミドを混合して全体を 1
00重量部とし、水を加えて混練、押出機で顆粒状に成形
し、乾燥して本発明の殺ダニ組成物(燻煙剤)を得る。
The present invention will be described below in more detail with reference to examples. First, a production example of the acaricidal composition of the present invention will be described. Production Example 1 20 parts by weight of hyssop oil, 0.5 part by weight of zinc oxide and 2 parts by weight of α-starch were mixed with azodicarbonamide to give a total of 1 part.
The mixture is kneaded with water, kneaded with water, formed into granules by an extruder, and dried to obtain the acaricidal composition (smoking agent) of the present invention.

【0013】製造例2 ヒソップ油 1.5g、アゾジカルボンアミド 2.5g、ニト
ロセルロース 1.5g、フタル酸ジブチル 0.4g、酸化亜
鉛 0.54g、パーライト 2.56g及びポリビニルアルコー
ル1.0gを混合し、水を加えて混練、押出機で顆粒状
に成形し、乾燥して本発明の殺ダニ組成物(燻煙剤)を
得る。
Production Example 2 1.5 g of hyssop oil, 2.5 g of azodicarbonamide, 1.5 g of nitrocellulose, 0.4 g of dibutyl phthalate, 0.54 g of zinc oxide, 2.56 g of perlite and 1.0 g of polyvinyl alcohol were mixed, and water was added. It is kneaded, formed into granules by an extruder, and dried to obtain the acaricidal composition (smoking agent) of the present invention.

【0014】製造例3 ヒソップ油10重量部と樟脳 100重量部とを混合し、5kg
/cm2の圧力で加圧打錠することにより、常温で揮散さ
せて使用するための殺ダニ組成物を得る。
Production Example 3 10 parts by weight of hyssop oil and 100 parts by weight of camphor were mixed, and 5 kg
By compressing under pressure at a pressure of / cm 2 , an acaricidal composition is obtained which is volatilized and used at room temperature.

【0015】製造例4 ヒソップ油10重量部とナフタレン 100重量部とを混合
し、5kg/cm2の圧力で加圧打錠することにより、常温
で揮散させて使用するための殺ダニ組成物を得る。
Production Example 4 10 parts by weight of hyssop oil and 100 parts by weight of naphthalene were mixed and pressed under a pressure of 5 kg / cm 2 to form an acaricidal composition for volatilization at room temperature for use. obtain.

【0016】製造例5 ヒソップ油 10 重量部とパラジクロルベンゼン 100重量
部とを混合し、5kg/cm2の圧力で加圧打錠することに
より、常温で揮散させて使用するための殺ダニ組成物を
得る。
Preparation Example 5 Acaricidal composition for use by mixing 10 parts by weight of hyssop oil and 100 parts by weight of paradichlorobenzene and compressing and compressing under a pressure of 5 kg / cm 2 at normal temperature to be volatilized. Get things.

【0017】次に、ヒソップ油を用いる本発明の殺ダニ
方法を、試験例で示す。 試験例1 ヒソップ油をアセトンで希釈し、クラフト紙に1m2
たりヒソップ油の量にして50gとなるように、滴下、
含浸させ、乾燥した。得られたクラフト紙を2cm×1.5c
m に切って直径 3.5cmのアルミ皿上に置き、容積 200cm
3のプラスチックケース内に入れた。さらに、別に直径
3.5cmのアルミ皿2個を用意し、該アルミ皿上には各々
濾紙を敷き、濾紙外周にはダニの逃亡防止用に粘着剤を
塗布し、濾紙上にコナヒョウヒダニを適当数(20〜5
0頭)放した。また、湿度調節用に飽和硝酸アンモニウ
ム水溶液を入れたカップを上記プラスチックケースの底
部に置き、蓋をした。4日後に顕微鏡でダニを観察し、
数えたところ、100%の殺ダニ率であった。また、製
造例3〜5で得られた殺ダニ組成物の各々1gを用いて
試験例1と同様の試験を行ったところ、全て100%の
殺ダニ率であった。
Next, the acaricidal method of the present invention using hyssop oil will be described by test examples. Test Example 1 Hyssop oil was diluted with acetone, and dropped on kraft paper so that the amount of the hyssop oil was 50 g per 1 m 2 .
Impregnated and dried. 2cm × 1.5c of the obtained kraft paper
m, place on a 3.5 cm diameter aluminum dish,
Put it in the plastic case of 3 . In addition, separate diameter
Two 3.5 cm aluminum dishes were prepared, filter paper was spread on each of the aluminum dishes, an adhesive was applied to the periphery of the filter paper to prevent mites from escaping, and an appropriate number (20 to 5) of Dermatophagoides farinae was placed on the filter paper.
0) released. A cup containing a saturated aqueous solution of ammonium nitrate for humidity control was placed on the bottom of the plastic case, and the lid was closed. Four days later, the mites were observed under a microscope,
Counting showed a 100% miticide rate. When the same test as in Test Example 1 was performed using 1 g of each of the acaricidal compositions obtained in Production Examples 3 to 5, all the miticidal rates were 100%.

【0018】[0018]

【発明の効果】本発明の殺ダニ組成物は、ダニ、特に屋
内に生息するダニを防除するうえで、極めて有効であ
る。
Industrial Applicability The acaricidal composition of the present invention is extremely effective in controlling ticks, especially those that live indoors.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】ヒソップ油が有効成分として含有されてな
ることを特徴とする殺ダニ組成物。
An acaricidal composition comprising hyssop oil as an active ingredient.
【請求項2】ヒソップ油を用いることを特徴とする殺ダ
ニ方法。
2. A method for killing mites, characterized by using hyssop oil.
JP27573497A 1997-10-08 1997-10-08 Acaricidal composition Expired - Fee Related JP3928224B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP27573497A JP3928224B2 (en) 1997-10-08 1997-10-08 Acaricidal composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP27573497A JP3928224B2 (en) 1997-10-08 1997-10-08 Acaricidal composition

Publications (2)

Publication Number Publication Date
JPH11116417A true JPH11116417A (en) 1999-04-27
JP3928224B2 JP3928224B2 (en) 2007-06-13

Family

ID=17559651

Family Applications (1)

Application Number Title Priority Date Filing Date
JP27573497A Expired - Fee Related JP3928224B2 (en) 1997-10-08 1997-10-08 Acaricidal composition

Country Status (1)

Country Link
JP (1) JP3928224B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001000049A1 (en) * 1999-06-28 2001-01-04 Ecosmart Technologies, Inc. Pesticidal compositions containing plant essential oils against mites
US7037535B2 (en) 2002-11-19 2006-05-02 Kimberly-Clark Worldwide, Inc. Method and composition for neutralizing house dust mite feces
US7585518B2 (en) 2002-11-19 2009-09-08 Kimberly-Clark Worldwide, Inc. Products and methods for maintaining or increasing ceramide levels in skin
US8846116B2 (en) 2003-07-22 2014-09-30 Kimberly-Clark Worldwide, Inc. Wipe and methods for improving skin health

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112450229B (en) * 2020-12-09 2021-06-15 华南农业大学 Plant essential oil type ultraviolet sterilization synergist and ultraviolet combined sterilization method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001000049A1 (en) * 1999-06-28 2001-01-04 Ecosmart Technologies, Inc. Pesticidal compositions containing plant essential oils against mites
US7037535B2 (en) 2002-11-19 2006-05-02 Kimberly-Clark Worldwide, Inc. Method and composition for neutralizing house dust mite feces
US7585518B2 (en) 2002-11-19 2009-09-08 Kimberly-Clark Worldwide, Inc. Products and methods for maintaining or increasing ceramide levels in skin
US7838025B2 (en) 2002-11-19 2010-11-23 Kimberly-Clark Worldwide, Inc. Products and methods for maintaining or increasing ceramide levels in skin
US8846116B2 (en) 2003-07-22 2014-09-30 Kimberly-Clark Worldwide, Inc. Wipe and methods for improving skin health
US10022308B2 (en) 2003-07-22 2018-07-17 Kimberly-Clark Worldwide, Inc. Wipe and methods for improving skin health

Also Published As

Publication number Publication date
JP3928224B2 (en) 2007-06-13

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