JPH04103502A - Mite-controlling agent for indoor use - Google Patents
Mite-controlling agent for indoor useInfo
- Publication number
- JPH04103502A JPH04103502A JP2222184A JP22218490A JPH04103502A JP H04103502 A JPH04103502 A JP H04103502A JP 2222184 A JP2222184 A JP 2222184A JP 22218490 A JP22218490 A JP 22218490A JP H04103502 A JPH04103502 A JP H04103502A
- Authority
- JP
- Japan
- Prior art keywords
- mite
- controlling agent
- mites
- indoor use
- isopropyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000642 acaricide Substances 0.000 claims abstract description 10
- UFHLMYOGRXOCSL-UHFFFAOYSA-N isoprothiolane Chemical compound CC(C)OC(=O)C(C(=O)OC(C)C)=C1SCCS1 UFHLMYOGRXOCSL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004480 active ingredient Substances 0.000 claims description 3
- 241000238876 Acari Species 0.000 abstract description 17
- 150000001875 compounds Chemical class 0.000 abstract description 11
- 239000000428 dust Substances 0.000 abstract description 7
- 239000005885 Buprofezin Substances 0.000 abstract description 6
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 239000000843 powder Substances 0.000 abstract description 5
- 239000008187 granular material Substances 0.000 abstract description 2
- 239000004563 wettable powder Substances 0.000 abstract description 2
- IHEQCJRWLURURV-UHFFFAOYSA-N 3-propan-2-yl-6,10-dioxa-1,4-dithiaspiro[4.5]decane-7,9-dione Chemical compound S1C(C(C)C)CSC11OC(=O)CC(=O)O1 IHEQCJRWLURURV-UHFFFAOYSA-N 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 239000004495 emulsifiable concentrate Substances 0.000 abstract 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 19
- 239000000203 mixture Substances 0.000 description 14
- 241000238710 Dermatophagoides Species 0.000 description 7
- 239000002609 medium Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 230000000895 acaricidal effect Effects 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000001963 growth medium Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000005909 Kieselgur Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- -1 dispersing aids Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011835 investigation Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000003898 horticulture Methods 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000002903 organophosphorus compounds Chemical class 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical class [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 239000002728 pyrethroid Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- 206010012438 Dermatitis atopic Diseases 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000916145 Tarsonemidae Species 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 201000009961 allergic asthma Diseases 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- 201000008937 atopic dermatitis Diseases 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は屋内用ダニ防除剤に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to an indoor mite control agent.
近年、生活様式、住宅構造の変化などにより、家庭内に
チリダニ、コナダニ、ホコリダニ等のダニ類が発生し、
居住者に不快感をもたらすのみならず、アレルギー性喘
息、アトピー性皮膚炎などの原因となり社会問題となり
つつある。In recent years, due to changes in lifestyles and housing structures, dust mites, dust mites, dust mites, and other mites have appeared in homes.
Not only does it cause discomfort to residents, it also causes allergic asthma, atopic dermatitis, etc., and is becoming a social problem.
従来より、このようなダニ類に対する防除剤としては、
たとえばフェニトロチオン、ダイアジノン等の有機リン
化合物、レスメスリン、パーメスリン等のピレスロイド
化合物などが知られていて、乳剤、油剤等の形で直接噴
霧処理したり、防虫紙、カーペット等への含浸、燻煙等
の方法で用いられている。Conventionally, as a control agent for such mites,
For example, organic phosphorus compounds such as fenitrothion and diazinon, and pyrethroid compounds such as resmethrin and permethrin are known. used in the method.
［発明が解決しようとする課題１
しかしながら、有機リン化合物は一般に毒性の高いもの
が多く、また特有の悪臭を有するものが多い。[Problem to be Solved by the Invention 1] However, many organic phosphorus compounds are generally highly toxic, and many have a unique bad odor.
また、ピレスロイド化合物は一般に低毒性であるものの
、コナダニ、ツメダニに対する効果の点で必ずしも充分
とは言えない。Furthermore, although pyrethroid compounds generally have low toxicity, they are not necessarily sufficiently effective against white mites and black mites.
［課題を解決するための手段］
本発明者らは上記問題点を解決するために鋭意検討した
結果、２−タシャリ−ブチルイミノ−３−イソプロピル
−５−フェニル、３，４゜５．６−テトラヒドロ−２Ｈ
−１，３，５−チアジアジン−５−オン（以下ブプロフ
ェジンという）およびジイソプロピル−１，３−ジチオ
ラン−２−イリデン−マロネート（以下イソブロチオラ
ンという）が屋内塵性ダニ類の防除に極めて有効である
ことを見出し本発明を完成したものである。[Means for Solving the Problems] As a result of intensive studies to solve the above problems, the present inventors found that 2-tashary-butylimino-3-isopropyl-5-phenyl, 3,4°5.6-tetrahydro -2H
-1,3,5-thiadiazin-5-one (hereinafter referred to as buprofezin) and diisopropyl-1,3-dithiolane-2-ylidene-malonate (hereinafter referred to as isobrothiolane) are extremely effective in controlling indoor dust mites. This discovery led to the completion of the present invention.
したがって、本発明の屋内用ダニ防除剤はブプロフェジ
ンまたは／およびイソブロチオランを有効成分として含
有することを特徴とする。Therefore, the indoor mite control agent of the present invention is characterized by containing buprofezin and/or isobrothiolane as an active ingredient.
本発明で使用するブプロフェジンは特開昭５４−３０８
３号公報で農園芸用殺虫殺ダニ剤として、またイソブロ
チオランは特開昭５０−１００２２９号公報で農園芸用
殺虫殺ダニ剤として公知の化合物であるが、これらが室
内塵性ダニ類に有効であることは従来の知見からは全く
予想できなかったことである。The buprofezin used in the present invention is disclosed in Japanese Patent Application Laid-open No. 54-308.
3 as an insecticide and acaricide for agriculture and horticulture, and isobrothiolane is a compound known as an insecticide and acaricide for agriculture and horticulture in Japanese Patent Application Laid-Open No. 100229/1983, but these compounds are known to be effective against indoor dust mites. The fact that it is effective is something that could not have been expected from conventional knowledge.
本発明において対象となる屋内塵性ダニ類としては、例
えばコナヒヨウヒダニ、ヤケヒヨウヒダニ等のヒヨウヒ
ダニ類、ケナガコナダニ、ムギコナグニ等のコナダニ類
、チリニクダニ、イエニクダニ等のニクダニ類、クワガ
タツメダニ、フトツメグニ等のツメダニ類、イエササラ
グ二類などが挙げられる。Indoor dust mites that are targeted in the present invention include, for example, Dermatophagoides mites such as Dermatophagoides nigricans and Dermatophagoides nigricans, Dermatophagoides mites such as Dermatophagoides nigricans, Dermatophagoides erectus mites, Mugi mites, etc.; Examples include the following.
本発明の殺ダニ剤は前記化合物をそのまま適用すること
もできるが、通常好ましくは適当な担体その他の配合剤
を用いて使用目的に応じ各種の形態例えば粉剤、水和剤
、粒剤、乳剤、液剤、懸濁剤、エアゾール剤等として使
用される。液状の担体としては、水、四塩化炭素、塩化
メチレン、二塩化エチレン、エチルアルコール、イソプ
ロピルアルコール、エチレングリコール、プロピレング
リコール、ジエチルエーテル、ジオキサン、テトラヒド
ロフラン、アセトン、シクロヘキサノン、酢酸エチル、
ジブチルフタレート、トルエン、キシレン、ケロシン、
及びメチルナフタレンなどの棺媒が適当であり、そして
これらの一種または二種以上の混合物が用いられる。The acaricide of the present invention can be applied as the above-mentioned compound as it is, but it is usually preferable to use suitable carriers and other compounding agents to form various forms depending on the purpose of use, such as powders, wettable powders, granules, emulsions, etc. Used as liquids, suspensions, aerosols, etc. Liquid carriers include water, carbon tetrachloride, methylene chloride, ethylene dichloride, ethyl alcohol, isopropyl alcohol, ethylene glycol, propylene glycol, diethyl ether, dioxane, tetrahydrofuran, acetone, cyclohexanone, ethyl acetate,
dibutyl phthalate, toluene, xylene, kerosene,
and methylnaphthalene are suitable, and one or a mixture of two or more of these may be used.
また固体の担体としてはカオリン、ベントナイト、タル
ク、軽石、シリカ、炭酸カルシウム、活性炭、ケイソウ
土、植物性粉末等が適当であり、そしてこれらの一種ま
たは二種以上の混合物が用いられる。Suitable solid carriers include kaolin, bentonite, talc, pumice, silica, calcium carbonate, activated carbon, diatomaceous earth, and vegetable powder, and one or a mixture of two or more of these may be used.
また配合剤としては湿潤剤、展着剤、分散助剤、乳化剤
、安定剤または懸濁剤が用いられ、そしてこれらの一種
または二種以上の混合物が用いられる。これらは通常こ
の分野で用いられるものが使用できる。Further, as compounding agents, wetting agents, spreading agents, dispersing aids, emulsifiers, stabilizers, or suspending agents are used, and one or a mixture of two or more of these is used. Those commonly used in this field can be used.
本発明のダニ防除剤中の使用量はその剤型や適用対象、
適用方法、適用場所等に応じて適宜選択されるが、通常
、有効成分がブプロフェジンの場合には、使用濃度が１
ゴ当たり ０．００１〜Ｉｇ、イソブロチオランの場合
には、 ０．０１５〜２ｇの範囲で使用される。The amount used in the mite control agent of the present invention depends on its dosage form and application target.
It is selected as appropriate depending on the application method, application location, etc., but usually when the active ingredient is buprofezin, the concentration used is 1.
In the case of isobrothiolane, it is used in a range of 0.001 to 2 g per gram.
〔処方例１
次に本発明の殺ダニ剤の処方例を示すが、本発明はこれ
らのみに限定されるものではない。[Formulation Example 1 Next, prescription examples of the acaricide of the present invention will be shown, but the present invention is not limited to these.
処方例１
本発明化合物 ５０部ケイソウ
土・クレーの混合物 ４５部ポリオキシエチレ
ンノニルフェニル
エーテル ５部以上を均
一に混合粉砕して水和剤とする。Formulation Example 1 Compound of the present invention 50 parts Diatomaceous earth/clay mixture 45 parts Polyoxyethylene nonylphenyl ether 5 parts or more are uniformly mixed and pulverized to prepare a wettable powder.
処方例２
本発明化合物 ２０部テトラヒ
ドロフラン ２０部キシレン
４５部ポリオキシエチレンノニル
フェニル
エーテルとアルキルベンゼンスルホ
ン酸の混合物 １５部を均一に
混合溶解して乳剤とする。Formulation Example 2 Compound of the present invention 20 parts Tetrahydrofuran 20 parts Xylene
45 parts of a mixture of polyoxyethylene nonylphenyl ether and 15 parts of alkylbenzene sulfonic acid are uniformly mixed and dissolved to obtain an emulsion.
処方例３
本発明化合物 ４部ケイソウ土
・クレー・タルクの混合物 ９５部ステアリン酸カルシ
ウム １部以上を均一に混合溶解して粉剤
とする。Formulation Example 3 Compound of the present invention 4 parts Mixture of diatomaceous earth, clay and talc 95 parts Calcium stearate 1 part or more are uniformly mixed and dissolved to form a powder.
処方例４
本発明化合物 ２部ブロビレン
グリコールモノメチル
エーテル ７５部を溶解し
たものに噴射剤として
液化石油ガス２３部を加えて全量を１００容量部として
加圧充填してエアゾールとする。Formulation Example 4 Compound of the present invention 2 parts 75 parts of brobylene glycol monomethyl ether are dissolved and 23 parts of liquefied petroleum gas is added as a propellant to make the total amount 100 parts by volume, and the mixture is filled under pressure to obtain an aerosol.
次に本発明殺ダニ剤の効果について試験例を挙げて説明
するが、これらのみに限定されるものではない。Next, the effects of the acaricide of the present invention will be explained using test examples, but the effects are not limited to these.
試験例１
ダニの培地（マウス飼料：エビオス＝ｌ：１）に所定濃
度の２倍のアセトン希釈薬液を等量処理し、風乾してア
セトンを揮散後、その５０ｍｇにケナガコナダニを含む
培地（５６，７頭／１００ｍｇ） ５０ｍｇを混合して
１０ｍ℃の管ビンに入れ、管ビンの下部を、飽和硝酸カ
リウム水溶液に浸し、２８℃、湿度７５〜８５％の恒温
、恒温室に保管した。調査は所定日数後に培地１００ｍ
ｇ中の生存ダニ数を計数した６１区３連制、結果を表１
に示す。Test Example 1 A mite culture medium (mouse feed: Ebios = 1:1) was treated with an equal amount of acetone diluted drug solution twice the predetermined concentration, air-dried to volatilize the acetone, and 50 mg of the medium containing woolly mites (56, 7 cows/100 mg) were mixed and placed in a 10 m°C tube bottle, the lower part of the tube bottle was immersed in a saturated potassium nitrate aqueous solution, and stored in a thermostatic chamber at 28°C and humidity of 75-85%. The survey will be carried out on 100 m of culture medium after a specified number of days.
The number of living mites in 61 wards was counted in triplicate, and the results are shown in Table 1.
Shown below.
表１
試験例２
ダニの培地（マウス飼料：エビオス＝１＝１）に所定濃
度の２倍のアセトン希釈薬液を等量処理し、風乾してア
セトンを揮散後、その５０ｍｇにコナヒヨウヒダニを含
む培地（６１，３頭／１００ｍｇ） ５０ｒａｇを混合
して１０ ｒｎＡの管ビンに入れ、管ビンの下部を、飽
和硝酸カリウム水溶液に浸し、２８℃、湿度７５〜８５
％の恒温、恒温室に保管した。調査は所定日数後に培地
１００ｍｇ中の生存ダニ数を計数した。１区３連制、結
果を表２に示す。Table 1 Test Example 2 A mite culture medium (mouse feed: Ebios = 1 = 1) was treated with an equal amount of acetone diluted chemical solution twice the predetermined concentration, air-dried to volatilize the acetone, and 50 mg of the medium was treated with a medium containing Dermatophagoides diluted ( 61.3 head/100mg) 50rag was mixed and placed in a 10 rnA tube bottle, the lower part of the tube bottle was immersed in a saturated potassium nitrate aqueous solution, and the temperature was kept at 28℃ and humidity 75-85℃.
% and stored in a constant temperature room. In the investigation, the number of surviving mites in 100 mg of the medium was counted after a predetermined number of days. Table 2 shows the results of three consecutive races in one ward.
表２
１００ｍｇをひろげて置き、ふたをして２８℃、湿度７
５〜８５％の恒温、恒湿室に保管した。調査は所定日数
後に培地１００ｍｇ中の生存ダニ数を計数した。１区３
連制、結果を表３に示す。Table 2 Spread out 100mg, cover with a lid, and keep at 28℃ and humidity 7.
It was stored in a constant temperature and humidity room of 5 to 85%. In the investigation, the number of surviving mites in 100 mg of the medium was counted after a predetermined number of days. Ward 1 3
The results are shown in Table 3.
表３
試験例３
直径９ｃｍのシャーレ中の直径８．５ｃｍの濾紙に所定
濃度のアセトン希釈薬液を１．５ｍＩ２処理し、風乾し
てアセトンを揮散後、処理濾紙中央にケナガコナダニを
含む培地（５６，７頭７１００ｍｇ）Ｃ）無処理区の固
体数（３運平均偵ン
試験例４
ダニの培地（マウス飼料：エビオス＝１１）に所定濃度
の２倍のアセトン希釈薬液を等量処理し、風乾してアセ
トンを揮散後、その５００ｍｇにコナヒヨウヒダニを含
む培地（５９３頭／ １００ｍｇ） ５００ｍｇを混合
して１０ ｎｌの管ビンに入れ、管ビンの下部を、飽和
塩化ナトリウム水溶液に浸し、２８°Ｃ，湿度７５〜８
５％の恒温、恒温室に保管した。調査は所定日数後に培
地１００ｍｇ中の生存ダニ数を計数した。１区３連制、
結果を表４に示す。Table 3 Test Example 3 A filter paper with a diameter of 8.5 cm in a Petri dish with a diameter of 9 cm was treated with 1.5 ml of acetone diluted chemical solution of a predetermined concentration, air-dried to volatilize the acetone, and a medium (56, 7 animals 7100 mg) C) Number of individuals in untreated area (3 luck average reconnaissance test example 4) Treat the tick culture medium (mouse feed: Ebios = 11) with an equal amount of acetone diluted chemical solution with twice the prescribed concentration and air dry. After volatilizing the acetone, mix the 500 mg with 500 mg of a culture medium containing Dermatophagoids nigricans (593 heads/100 mg), place the mixture in a 10 nl tube, immerse the lower part of the tube in a saturated aqueous sodium chloride solution, and store at 28°C and humidity. 75-8
It was stored in a thermostatic room with a constant temperature of 5%. In the investigation, the number of surviving mites in 100 mg of the medium was counted after a predetermined number of days. 1st ward triple system,
The results are shown in Table 4.
表４Table 4
Claims (1)
フェニル、３，４，５，６−テトラヒドロ−２Ｈ−１，
３，５−チアジアジン−５−オンまたは／およびジイソ
プロピル−１，３−ジチオラン−２−イリデン−マロネ
ートを有効成分として含有することを特徴とする屋内用
ダニ防除剤。2-Tashary-butylimino-3-isopropyl-5-
Phenyl, 3,4,5,6-tetrahydro-2H-1,
An indoor mite control agent characterized by containing 3,5-thiadiazin-5-one or/and diisopropyl-1,3-dithiolan-2-ylidene-malonate as an active ingredient.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2222184A JP3049564B2 (en) | 1990-08-23 | 1990-08-23 | Indoor dust mite control agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2222184A JP3049564B2 (en) | 1990-08-23 | 1990-08-23 | Indoor dust mite control agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04103502A true JPH04103502A (en) | 1992-04-06 |
| JP3049564B2 JP3049564B2 (en) | 2000-06-05 |
Family
ID=16778476
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2222184A Expired - Lifetime JP3049564B2 (en) | 1990-08-23 | 1990-08-23 | Indoor dust mite control agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3049564B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651342A (en) * | 2012-08-31 | 2014-03-26 | 江苏长青农化股份有限公司 | Wettable powder with buprofezin content being 25 percent |
-
1990
- 1990-08-23 JP JP2222184A patent/JP3049564B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651342A (en) * | 2012-08-31 | 2014-03-26 | 江苏长青农化股份有限公司 | Wettable powder with buprofezin content being 25 percent |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3049564B2 (en) | 2000-06-05 |
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