JPH1088196A - Detergent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain the subject composition having low viscosity, good squeezability from a container, high spreadability of the detergent liquid in cleaning work and excellent rinsing property by compounding a proper amount of a thickening polysaccharide to specific solid particles, a surfactant and water. SOLUTION: This composition contains (A) 0.1-20wt.% of waterinsoluble or scarcely soluble particles (e.g. particles of a resin such as nylon or silica particles), (B) 0.01-10wt.% of a thickening polysaccharide (preferably guar gum, locust bean gum, etc.), (C) 0.001-20wt.% of a surfactant (preferably an alkyl glucoside having glucose residue as the sugar residue) and (D) water. The component A is preferably spherical particles having an average particle diameter of 1-5μm and a true specific gravity of 0.5-1.5. An organic solvent may be compounded to the composition to improve the detergent power. The amount of the organic solvent is preferably 0.1-20wt.%. The organic solvent is preferably a polyorganosiloxane exhibiting liquid state at normal temperature, a 10-16C straight or branched-chain paraffin, etc. The pH of the objective composition is preferably 5-10.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to an improved and novel
Particularly, the present invention relates to a cleaning composition suitable for cleaning hard surfaces. More specifically, in a dispersion detergent containing water-insoluble or sparingly soluble solid particles in water, after the product has been stored for a long period of time, even if the solid particles separate and settle or float, they do not form strong aggregates, The present invention relates to a detergent composition that can be easily redispersed by shaking lightly during use and has good workability during washing.

[0002]

2. Description of the Related Art In a liquid detergent, a water-insoluble particle such as an abrasive or a opaque agent such as a synthetic resin emulsion is blended for the purpose of enhancing the detergency. Techniques for giving a good liquid feeling and enhancing palatability are already known, and such products are widely distributed.

[0003] In such a solid-dispersed liquid detergent composition, it is common practice to stabilize the dispersion of solid particles by increasing the viscosity of the detergent composition and maintain a uniform dispersion state. However, solid particles with a large specific gravity,
Or, in order to disperse solid particles having a relatively large particle size, a composition having a very high viscosity is obtained, which makes it difficult to take out of the container, poor spreadability of the composition on the surface to be cleaned, and rinsing of the solid particles. It took time, and the workability deteriorated.

[0004] On the other hand, if the viscosity of the composition is kept low, the solid particles separate and settle or float after long-term storage to form strong aggregates. Redispersion was difficult. In addition, even if it is forcibly redispersed and used, it is liable to be clogged at the mouth of the container.

In recent years, for convenience, a trigger type sprayer that can directly apply a cleaning liquid to a surface to be cleaned has been widely used. In such containers, it is impossible to spray a high-viscosity composition, and even if a low-viscosity composition is present, the solid particle dispersion composition may cause the slidability of the sprayer during use. The trouble that the cleaning liquid could not be sprayed became frequent and became a problem.

[0006]

Means for Solving the Problems The inventors of the present invention have conducted intensive studies to obtain a solid particle-dispersed detergent composition excellent in workability. As a result, the present invention comprises specific solid particles, a surfactant and water. By adding an appropriate amount of thickening polysaccharide to the detergent composition, the viscosity of the composition is suppressed to a low viscosity, the squeezing property from the container is good, the cleaning liquid spreads well during work, and the rinsing property is excellent. It was found that a cleansing composition was obtained. Furthermore, when the specific gravity and the particle size of the solid particles used in the detergent composition are large, the solid particles are likely to settle and separate, but even in such a case, the settled particles do not form strong aggregates, and are light. It has been found that it can be easily redispersed only by shaking. Furthermore, surprisingly, even when a detergent composition containing such a thickening polysaccharide is used in a trigger type sprayer, solidity of the sprayer is reduced due to clogging of solid particles or polishing action. The present inventors have found that there is no trouble of worsening and that workability can be remarkably improved, and the present invention has been completed.

That is, the present invention provides the following components (A), (B),
(C) and (D), the content of component (A) is 0.1 to 20% by weight, the content of component (B) is 0.01 to 10% by weight, and the content of component (C) is 0.01 to 20%. % By weight of a cleaning composition. (A) Water-insoluble or hardly soluble solid particles (B) Thickening polysaccharide (C) Surfactant (D) Water

[0008]

Embodiments of the present invention will be described below in detail.

[Component (A)] The cleaning composition of the present invention comprises:
(A) It contains water-insoluble or hardly soluble solid particles as a component. The content of the component (A) in the composition of the present invention is 0.1 to 20.
% By weight, preferably 1 to 10% by weight. When the content of the component (A) is less than 0.1% by weight, the effect of enhancing the detergency by the addition of the solid particles cannot be obtained.

The water-insoluble or hardly-soluble solid particles of the component (A) are not particularly limited as long as they are insoluble or hardly soluble in water and can maintain the shape of the solid particles in the composition. Although not a preferred example, the following (A
-1) to (A-5).

(A-1) Alkyl acrylates and methacrylates having 1 to 8 carbon atoms, mono- and di-alkyl (alkyl groups having 1 to 5 carbon atoms) itaconate and fumarate, maleic anhydride, vinylidene chloride, styrene, divinylbenzene , Vinyl chloride, vinyl acetate, vinyl acetal, ethylene, propylene, butene, butylene, methyl pentene, butadiene, vinyl toluene, acrylonitrile, methacrylonitrile, acrylamide, acrylic acid, methacrylic acid, itaconic acid, fumaric acid, citraconic acid, crotonic acid Acid, β-acryloxypropionic acid,
A monomer containing at least one ethylenically unsaturated monomer selected from the group consisting of hydroxyalkyl (alkyl group having 1 to 6 carbon atoms) acrylate and methacrylate, or a polymer obtained by polymerizing these monomers. The molecular weight of the polymer is preferably from 10 to 10,000,000, more preferably from 10,000 to 1,000,000.

(A-2) A silicone derivative having at least one group selected from structural units represented by the following general formula (I) or (I '). The molecular weight of the silicone derivative is 1000-10
Million is preferred, and 10,000 to 1,000,000 is more preferred.

[0013]

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(Wherein R ₁ , R ₂ and R ₃ are the same or different and each have an alkyl group having 1 to 100 carbon atoms, an alkoxy group, a hydroxyalkyl group, a hydroxyl group, a carboxyl group, a carboxyalkyl group, an N- (2 -Aminoalkyl) aminoalkyl group, aminoalkyl group, amino group, epoxyalkyl group, epoxy group, methylpolyoxyethylenealkyl group, hydroxypolyoxyethylenealkyl group, methylpolyoxyethylene / polyoxypropylene group, hydroxypolyoxyethylene -Represents a polyoxypropylene group, an alkylpolyoxypropylene group, a polyoxyethylene group, a phenyl group or a fluoroalkyl group.) (A-3) Any of nylon, polyester, epoxy, aminoalkyd, urethane, polyacetal, or polycarbonate One or more resins. The molecular weight of the resin is 1000-10
Million is preferred, and 10,000 to 1,000,000 is more preferred.

(A-4) A polyorganosilsesquioxane obtained by hydrolyzing and condensing methyltrialkoxysilane or a partially hydrolyzed / condensed product thereof in an aqueous solution of ammonia or amines. The molecular weight of the polyorganosilsesquioxane is preferably from 10 to 10,000,000, more preferably from 10,000 to 1,000,000.

(A-5) Silica or porous silica, aluminum oxide, magnesium oxide, titanium oxide, aluminosilicate, silicon carbide, calcium carbonate, calcium phosphate, chromium oxide, emery, quartz sand, dolomite, sand,
One or more water-insoluble inorganic substances of natural pulverized material such as shells, mica powder, quartzite, diatomaceous earth, kaolinite, halloysite, montmorillonite, illite, vermiculite Use of the above solid particles alone or in combination of two or more can do.

Although the solid particles are not particularly limited as described above, the solid particles have an average particle size of 0.1 to 10 μm and a true specific gravity because of the ease of redispersion when separated in the detergent composition.
Spherical particles of 0.5 to 2.5 are preferable, and the average particle size is 1 to 5 μm.
Further, spherical particles having a true specific gravity of 0.5 to 1.5 are more preferable.

[Component (B)] The cleaning composition of the present invention comprises:
(B) It contains a thickening polysaccharide as a component. The content of the component (B) in the composition of the present invention is 0.01 to 10% by weight,
~ 1% by weight is preferred. (B) The content of the component is 0.01% by weight.
If it is less than 10%, the redispersibility when the solid particles are separated is insufficient, and if it exceeds 10% by weight, the composition becomes highly viscous, the squeezability from the container deteriorates, or the liquid elongation during the operation is It is not preferable because it becomes worse.

The thickening polysaccharide of the component (B) is a carbohydrate that produces two or more molecules of a monosaccharide by hydrolysis, and an aqueous solution having a viscous liquid property. (B-1) to (B-3).

(B-1) Guar gum, locust bean gum, quince seed gum, tara gum, carrageenan, alginic acid (or a salt thereof), furcellane, agar, arabinogalactan gum, gum arabic, tragacanth gum,
Karaya gum, pectin, starch, xanthan gum, zancort, zanflow, curdlan, succinoglucan, schizophyllan, pullulan, gellan gum, welan gum, ramzan gum, galactomannan, hyaluronic acid (or its salt), chondroitin sulfate (or its salt), chitin,
Chitosan (B-2) Oxidation, methylation, carboxymethylation, hydroxyethylation, hydroxypropylation, sulfated, phosphorylated or cationized derivative of the polysaccharide shown in (B-1) (B-3) carboxymethylcellulose, Water-soluble cellulose derivatives such as methylcellulose, hydroxyethylcellulose, hydroxypropylcellulose and hydroxyethylpropylcellulose The above thickening polysaccharides can be used alone or in combination of two or more. Among these thickening polysaccharides, those having a molecular weight of 100,000 to 10,000,000 are preferable. Particularly preferred among the above thickening polysaccharides are guar gum, locust bean gum, xanthan gum and oxidation, methylation, carboxymethylation, hydroxyethylation, hydroxypropylation, sulfated, phosphorylated, and cationized of these polysaccharides. It is a derivative.

[Component (C)] The cleaning composition of the present invention comprises:
(C) Contains a surfactant as a component. The content of the component (C) in the composition of the present invention is 0.01 to 20% by weight,
5% by weight is preferred. When the content of the component (C) is less than 0.01% by weight, the wettability of the solid particles to water becomes poor, and the compounding becomes difficult. Therefore, when the content exceeds 20% by weight, the detergent composition is formed by a surfactant. Is high in viscosity, workability is deteriorated, foaming is large, and rinsing is difficult.

The surfactant of the component (C) is not particularly limited, but from the viewpoint of wettability of solid particles, washing performance and economic efficiency, alkyl (straight or branched chain having 8 to 18 carbon atoms).
Benzene sulfonate, polyoxyethylene (average number of moles added: 0.5 to 10) Alkyl (linear or branched chain having 8 to 22 carbon atoms) ether sulfate, alkyl (linear or branched chain having 8 to 18 carbon atoms) sulfuric acid Salt, fatty acid (linear or branched chain having 8 to 22 carbon atoms) salt, polyoxyethylene (average addition mole number 0.5
-10) alkyl (linear or branched chain having 8 to 22 carbon atoms) ether carboxylate, alkyl (linear or branched chain having 8 to 22 carbon atoms) sulfonate, alkyl (linear having 8 to 22 carbon atoms) Or branched chains) glycosides (average degree of sugar condensation 1.0 to 10.0),
Fatty acid (linear or branched chain having 8 to 22 carbon atoms) glyceride,
Sorbitan fatty acid (linear or branched chain having 8 to 22 carbon atoms) ester, alkyl (linear or branched chain having 8 to 18 carbon atoms) trimethylammonium salt and alkyl (linear or branched chain having 8 to 18 carbon atoms) dimethyl One or more selected from the group consisting of benzylammonium salts is preferred. Further, when the surfactant is an anionic surfactant,
The counter ion is preferably an alkali metal, an alkaline earth metal, ammonium, an alkanolamine having 1 to 3 carbon atoms,
In the case of a cationic surfactant, the counter ion is preferably a halogen atom or an alkyl sulfate residue having 1 to 6 carbon atoms.

These surfactants can be used alone or in combination.
More than one species can be used in combination. Preferred surfactants among the above are alkyl glycosides,
Particularly, an alkyl glucoside in which the sugar residue is a glucose residue is preferable.

[Component (E)] The cleaning composition of the present invention comprises:
As the component (E), various organic solvents can be blended for the purpose of enhancing detergency. The content of the component (E) in the composition of the present invention is preferably 0.1 to 20% by weight. The component (E) is not particularly limited, but as a preferred example, the following (E-
1) to (E-5). (E-1)-(E-3)
When the compound is a solid at ordinary temperature, the workability at the time of washing is impaired. Therefore, a compound which is liquid at ordinary temperature is preferable.

(E-1) A polyorganosiloxane which has at least one group selected from the structural units represented by formula (I) or (I ') and which is liquid at ordinary temperature is used in the present invention. Specific examples of the polyorganosiloxane include dialkylsiloxane, alkylphenyl silicone, alkyl-modified silicone, alkoxy-modified silicone, hydroxy-modified silicone, carboxy-modified silicone, epoxy-modified silicone, amino-modified silicone, and the like. The compound represented by is particularly preferable.

[0026]

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(Wherein n ₁ and n ₂ are the same or different and
100 represents a number, and m represents a number of 1 to 5000. (E-2) Linear or branched paraffin which is liquid at normal temperature The paraffin used in the present invention has 10 to 16 carbon atoms.
Is particularly preferred, and specific examples thereof include decane, dodecane, tridecane, tetradecane, hexadecane, isodecane, isododecane, isotridecane, isotetradecane, isohexadecane and the like.

(E-3) C10-C which is liquid at normal temperature
60 ester oil Examples of the ester oil used in the present invention include those represented by the following general formula (IV) or (IV ′).

R ₈ COOR ₉ (IV) (wherein R ₈ represents a linear or branched alkyl group or alkenyl group having 7 to 21 carbon atoms, and R ₉ represents a linear or branched chain having 1 to 20 carbon atoms) It represents an alkyl group or an alkenyl group in the chain.)

[0030]

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(Wherein, R ₁₀ , R ₁₁ and R ₁₂ each represent a linear or branched alkyl or alkenyl group having 1 to 20 carbon atoms, and the total number of carbon atoms of R ₁₀ , R ₁₁ and R ₁₂ is Specific examples of these ester oils include isopropyl myristate, isopropyl palmitate, isopropyl isostearate, methyl stearate, butyl stearate, butyl myristate, ethyl linoleate, ethyl linoleate, and oleic acid. Examples include ethyl, myristyl myristate, cetyl palmitate, cetyl isooctanoate, isostearyl palmitate, glycerin tri (2-ethylhexanoate), and glycerin tri (2-hexyldecanoate).

(E-4) Glycol ether represented by the following general formula (II)

[0033]

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(Wherein R ₄ and R ₅ each have 1 to 8 carbon atoms)
A linear or branched alkyl group or a hydrogen atom of R ₆
And R ₇ is other hand either one H indicates a CH _3. q and r each represent a number from 0 to 20. However, both q and r are not 0. Specific examples of glycol ethers include diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, and dipropylene glycol monoethyl ether. Propylene glycol dimethyl ether and the like.

(E-5) Polyhydric alcohol having 4 to 12 carbon atoms Specific examples of the polyhydric alcohol include 3-methyl-1,3
-Butanediol, 2,2,4-trimethyl-1,3-
Pentanediol, 1,8-octanediol, 1,9
-Nonanediol and the like.

The above organic solvents are used alone or in combination of two or more. In these organic solvents, when a water-insoluble or hardly-soluble one is used, the detergent composition separates into two layers of an oil phase and an aqueous phase. Becomes incorporated into the oil phase, and the redispersibility of the solid particles is further remarkably improved. For this reason, a water-insoluble or poorly-soluble organic solvent is particularly preferable.

[Cleaning composition] If the viscosity of the composition in the solid dispersion type cleaning composition is high, it is difficult to take it out of the container, the spreadability of the composition on the surface to be cleaned is poor, or the solid particles are rinsed. It takes time and the workability is significantly impaired. In the prior art, in order to stably disperse solid particles, a high-viscosity composition is often used, and deterioration of workability cannot be avoided.

The present invention provides a solid dispersion detergent composition having good workability by blending the thickening polysaccharide, but the viscosity of the composition is improved by blending the thickening polysaccharide. To increase. However, even with a relatively high viscosity, the workability was good (this is probably because the cleaning composition of the present invention has a different viscosity behavior from the conventional one, but details are not clear). Therefore, it is difficult to uniquely define good workability by the viscosity of the composition, but the preferred viscosity range of the cleaning composition of the present invention is 25 ° C.
In 10 to 1000 cps, more preferably 10 to 100 cps
cps.

The appearance of the detergent composition of the present invention is, in a stationary state, a suspension system in which solid particles are uniformly dispersed, a two-layer separation system in which solid particles float or settle, and a water-insoluble or hardly soluble organic compound. When a solvent is contained, there are a two-layer separation system in which solid particles are contained in an oil phase, and a three-layer separation system in which solid particles are precipitated in an aqueous phase. Among these states, the one that is particularly excellent in workability is the one having the separated form. These separated detergent compositions have low viscosity, excellent workability in washing, and good redispersibility of solid particles from the separated state.

The pH of the detergent composition of the present invention is not particularly limited, but is preferably in the range of 3 to 12, more preferably 5 to 10.

The use form of the cleaning composition of the present invention is not particularly limited, but it is preferable to use it in a trigger type sprayer. Further, as the properties of the cleaning composition when sprayed on the surface to be cleaned, various forms such as foam, mist, and liquid are conceivable, and are not limited by the properties, but in terms of workability during cleaning. It is particularly preferred that the composition is in the form of a mist or liquid.

Although the use of the cleaning composition of the present invention is not particularly limited, it can be used for walls, floors, tatami mats, ceilings, inside and outside homes.
Washing of roofs, washing of bathroom fixtures such as bathroom walls, floors, doors, bathtubs, washbasins, etc., washing of kitchen walls, floors, around sinks, around microwave ovens, ventilation fans, cupboards, chests, table,
Washing of furniture such as desks, chairs, bookshelves, etc., washing of the surface of appliances such as refrigerators, TVs, personal computers, stereos, air conditioners, microwave ovens, washing machines, dryers, lighting equipment, etc. Cleaning of glass used for doors, windows of automobiles, etc., cleaning of screen doors, cleaning of toilet floors, walls, doors, toilets, toilet seats with a cleaning function, heating toilet seats, washing dishes, cooking utensils, automobiles, bicycles Suitable for washing painted surfaces such as motorcycles, plastic surfaces, washing wheels of automobiles, washing around exterior entrances, terraces, fences, fences, gates, and other hard surfaces in general. Further, it is particularly suitable for cleaning painted surfaces of automobile bodies, surfaces of plastic parts, window glass, and wheels.

In practicing the present invention, various substances can be blended as long as the effects of the present invention are not impaired. Examples of such substances include fragrances, pigments, dyes, fungicides, fungicides, solubilizers, chelating agents, antioxidants, pH adjusters, bleaching agents, thickeners, dispersants, ultraviolet absorbers, etc. Is mentioned.

[0044]

The present invention will be described in more detail with reference to the following examples, but the present invention is not limited to these examples.

Example 1 With the formulation shown in Table 1, a cleaning composition of the present invention or a comparative cleaning composition was prepared, and redispersibility and workability were evaluated by the following test methods. Table 2 shows the results.

<Redispersibility test> 80 ml of the detergent composition was added to 100 parts
Place in a centrifuge tube with a stopper of 5,000 ml and centrifuge at 5000 rpm, 1
Centrifugation was performed for 5 minutes to separate solid particles. Thereafter, the mixture was lightly shaken up and down 10 times, and the dispersion state of the solid particles was visually determined according to the following criteria.

A: Completely dispersed. ：: Most solid particles are dispersed, but a very small amount of agglomerates is observed. Δ: About half of the solid particles are dispersed, and about half remain agglomerated. X: Almost no re-dispersion.

<Workability Test> 5 g of the detergent composition was placed on a black acrylic plate, spread over a 50 cm square with a dry towel, and the ease of spreading at that time was determined according to the following criteria. ：: Can be easily spread over the entire surface. Δ: Spread over the entire surface, but difficult to spread. X: It cannot be spread over the entire surface.

[0049]

[Table 1]

Note) * 1: Tospearl 120 / Toshiba Silicone Co., Ltd., spherical particles having an average particle diameter of 2 μm and a true specific gravity of 1.3 * 2: KF-96 / Shin-Etsu Chemical Co., Ltd. * 3: Hydrochloric acid or hydroxylated Uses sodium

[0051]

[Table 2]

Example 2 According to the formulation shown in Table 3, a cleaning composition of the present invention or a comparative cleaning composition was prepared, and the redispersibility and workability were evaluated in the same manner as in Example 1. The results are shown in Tables 4 and 5.

[0053]

[Table 3]

Note) * 3: Same as * 3 in Table 1. * 4: Kelzan AR / manufactured by Kelco * 5: Genugam RL-200 / Copenhagen Pectin Factory * 6: isoprene glycol (3-methyl-1,3 -Butanediol) / Kuraray Co., Ltd. * 7: KF-54 / Shin-Etsu Chemical Co., Ltd.

[0055]

[Table 4]

Note) * 8: molar ratio 60/5/20/5/10, molecular weight about 100,000 * 9: molar ratio 55/5/15/5/10 / crosslinking agent (divinylbenzene) 10

[0057]

[Table 5]

Note: * 8: Same as * 8 in Table 4 * 9: Same as * 9 in Table 4 Example 3 A cleaning composition of the present invention or a comparative composition having the composition shown in Table 6 was prepared, and Example 1 was prepared. The redispersibility and workability were evaluated in the same manner as described above. In addition, the slidability when these cleaning compositions were used in a trigger type spray container was evaluated by the following method. Table 6 shows the results.

<Slidability test> The detergent composition was placed in a commercially available trigger type spray container, stored in a constant temperature room of 20 ° C / 60% RH, and used 50 strokes per day. After one month, the slidability of the trigger was determined according to the following criteria. ：: No abnormality. Δ: The cleaning liquid can be sprayed, but the slidability is clearly deteriorated. X: The cleaning liquid cannot be sprayed.

[0060]

[Table 6]

Note) * 3: Same as * 3 in Table 1 * 4: Same as * 4 in Table 3 * 10: KMP-590 / Shin-Etsu Chemical Co., Ltd., average particle size 2
μm, spherical particles with a true specific gravity of 1.3

──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. ⁶ Identification symbol FI C11D 3:12 3:22 3:43) (72) Inventor Yoshiyuki Nakazawa 1334 Minato, Wakayama-shi, Wakayama Pref.

Claims (13)

[Claims] 1. The composition contains the following components (A), (B), (C) and (D), wherein the content of the component (A) is 0.1 to 20% by weight and the content of the component (B) is 0.01 to 20% by weight. ~ 10% by weight, content of component (C) is 0.01 ~ 20
A cleaning composition characterized in that it is a percentage by weight. (A) Water-insoluble or hardly soluble solid particles (B) Thickening polysaccharide (C) Surfactant (D) Water 2. The composition according to claim 1, further comprising an organic solvent as component (E).
The cleaning composition according to claim 1, which contains 20% by weight. 3. The composition according to claim 1, wherein the component (A) comprises one or more components selected from the group consisting of the following (A-1) to (A-5). Cleaning composition. (A-1) Alkyl acrylates and methacrylates having 1 to 8 carbon atoms, mono- and di-alkyl (alkyl groups having 1 to 5 carbon atoms) itaconate and fumarate, maleic anhydride, vinylidene chloride, styrene, divinylbenzene, vinyl chloride , Vinyl acetate, vinyl acetal, ethylene, propylene, butene, butylene, methylpentene, butadiene, vinyltoluene, acrylonitrile,
From the group consisting of methacrylonitrile, acrylamide, acrylic acid, methacrylic acid, itaconic acid, fumaric acid, citraconic acid, crotonic acid, β-acryloxypropionic acid, hydroxyalkyl (alkyl group having 1 to 6 carbon atoms) acrylate and methacrylate At least one chosen
Monomers containing various kinds of ethylenically unsaturated monomers, or polymers obtained by polymerizing these monomers (A-2) at least one group selected from structural units represented by the following general formula (I) or (I ′) Silicone derivative having one (Wherein R ₁ , R ₂ and R ₃ are the same or different and have 1 to 1 carbon atoms)
100 alkyl, alkoxy, hydroxyalkyl, hydroxyl, carboxyl, carboxyalkyl,
N- (2-aminoalkyl) aminoalkyl group, aminoalkyl group, amino group, epoxyalkyl group, epoxy group, methylpolyoxyethylenealkyl group, hydroxypolyoxyethylenealkyl group, methylpolyoxyethylene / polyoxypropylene group, It represents a hydroxypolyoxyethylene / polyoxypropylene group, an alkylpolyoxypropylene group, a polyoxyethylene group, a phenyl group or a fluorinated alkyl group. (A-3) Any one or more resins of nylon, polyester, epoxy, aminoalkyd, urethane, polyacetal, and polycarbonate. (A-4) Methyl trialkoxysilane or its partially hydrolyzed / condensed product is ammonia or amines. (A-5) Silica or porous silica, aluminum oxide, magnesium oxide, titanium oxide, aluminosilicate, silicon carbide, calcium carbonate, calcium phosphate, oxidized Chromium, emery, quartz sand, dolomite, sand, shells and other natural ground materials, mica powder, quartzite, diatomaceous earth, kaolinite, halloysite, montmorillonite, illite, vermiculite 4. The component (A) having an average particle size of 0.1 to 10 μm,
The cleaning composition according to any one of claims 1 to 3, which is a spherical particle having a true specific gravity of 0.5 to 2.5. 5. The composition according to claim 1, wherein the component (B) comprises one or more components selected from the group consisting of the following (B-1) to (B-3). The cleaning composition according to any one of the preceding claims. (B-1) guar gum, locust bean gum, quince seed gum, tara gum, carrageenan, alginic acid (or a salt thereof), furcelan, agar, arabinogalactan gum, arabic gum, tragacanth gum, karaya gum, pectin, starch, xanthan gum, xancote, Zanflo, curdlan, succinoglucan, schizophyllan, pullulan, gellan gum, welan gum, ramzan gum,
Galactomannan, hyaluronic acid (or a salt thereof), chondroitin sulfate (or a salt thereof), chitin, chitosan (B-2) (B-1) Oxidation, methylation, carboxymethylation, hydroxyethylation of a polysaccharide represented by (B-1), Hydroxypropylated, sulfated, phosphorylated or cationized derivatives (B-3) Water-soluble cellulose derivatives 6. The cleaning composition according to claim 5, wherein the water-soluble cellulose derivative is selected from carboxymethyl cellulose, methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, and hydroxyethylpropyl cellulose. 7. The component (C) is an alkyl (linear or branched chain having 8 to 18 carbon atoms) benzene sulfonate, polyoxyethylene (average addition mole number 0.5 to 10) alkyl (carbon number 8)
Straight-chain or branched-chain) ether sulfate, alkyl (straight-chain or branched-chain having 8 to 18 carbon atoms) sulfate, fatty acid (straight-chain or branched-chain having 8 to 22 carbon atoms), polyoxyethylene ( Average addition mole number 0.5 to 10) alkyl (linear or branched chain having 8 to 22 carbon atoms) ether carboxylate, alkyl (linear or branched chain having 8 to 22 carbon atoms) sulfonate, alkyl (8 carbon atoms) -22 straight-chain or branched chain) glycosides (average degree of sugar condensation: 1.0 to 10.0), fatty acids (straight or branched chains having 8 to 22 carbon atoms) glycerides, sorbitan fatty acids (straight or branched chains having 8 to 22 carbon atoms) ) One or two selected from the group consisting of esters, alkyl (linear or branched chain having 8 to 18 carbon atoms) trimethylammonium salt and alkyl (linear or branched chain having 8 to 18 carbon atoms) dimethylbenzylammonium salt A contract that has the above components Detergent composition according to any one of claims 1 to 6. (When the above surfactant is an anionic surfactant, the counter ion is an alkali metal, an alkaline earth metal, ammonium, or an alkanolamine having 1 to 3 carbon atoms, and when the cationic surfactant is a counter ion, Is a halogen atom or an alkyl sulfate residue having 1 to 6 carbon atoms) 8. The method according to claim 2, wherein the component (E) comprises one or more components selected from the group consisting of the following (E-1) to (E-5). The cleaning composition according to claim 1. (E-1) a polyorganosiloxane which has at least one group selected from the structural units represented by formula (I) or (I ') and is liquid at ordinary temperature. A certain linear or branched paraffin (E-3) an ester oil having 10 to 60 carbon atoms which is liquid at normal temperature (E-4) a glycol ether represented by the following general formula (II) (In the formula, R ₄ and R ₅ each represent a linear or branched alkyl group having 1 to 8 carbon atoms or a hydrogen atom, and one of R ₆ and R ₇ represents H 2 and the other represents CH ₃ . q and r each represent a number of 0 to 20. However, both q and r are not 0.) (E-5) Polyhydric alcohol having 4 to 12 carbon atoms 9. The detergent composition has a viscosity at 25 ° C. of 10
The cleaning composition according to any one of claims 1 to 8, wherein the cleaning composition has a viscosity of ~ 1000 cps. 10. The cleaning composition according to any one of claims 1 to 9, wherein the cleaning composition has a separated form in a standing state. 11. The cleaning composition according to any one of claims 1 to 10, wherein the pH of the stock solution of the cleaning composition is 3 to 12. 12. The cleaning composition according to claim 1, which is used in a trigger type sprayer. 13. The cleaning composition according to claim 1, which is used for cleaning painted surfaces of automobile bodies, surfaces of plastic parts, window glasses or wheels.