JPH1088194A - Detergent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain the subject composition having excellent cleaning power to fixed oily stain and giving an excellently finished surface without damaging the cleaning surface by compounding a chain hydrocarbon and a cyclic hydrocarbon at a specific ratio in addition to a surfactant. SOLUTION: This composition contains (A) a surfactant (preferably a straight- chain alkylbenzenesulfonic acid salt, alkylsulfuric acid salt, etc.), (B) a chain hydrocarbon (preferably dodecane, tridecane, etc.), (C) a cyclic hydrocarbon (preferably benzene, α-pinene, etc.) and (D) water. The amount of the component A is 0.01-50wt.%, the sum of the components B and C is 0.1-50wt.% and the weight ratio of B/C is (1-10,000)/1. The preferable state of the components B and C in use is a solubilized system in water or an emulsified dispersion system as an O/W-emulsion. The detergent power is further improved by adding 0.5-10wt.% of insoluble or scarcely soluble solid particles such as silica. The pH of the objective composition is preferably 5-10.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cleaning composition having excellent detergency for oily dirt adhered to an object to be cleaned. More specifically, it is an aqueous detergent composition containing a chain hydrocarbon and a cyclic hydrocarbon at a specific ratio, and has excellent detergency for an object to be cleaned, particularly oily dirt fixed on a hard surface. The present invention relates to a cleaning composition which does not cause damage and has excellent finish.

[0002]

2. Description of the Related Art
A great deal of effort has been required to wash and remove the fixed oily dirt. For example, in the kitchen, oil stains due to splashing of cooking oil during cooking are commonly found around the range, walls, floors, etc., and such oil stains are oxidized under the influence of heat, light, etc. It becomes a denatured oil stain. To remove the denatured oil stain, a method of rubbing with a detergent containing a large amount of an abrasive such as a cleanser, and swelling and dissolving the denatured oil stain with an alkaline detergent containing a water-soluble solvent such as carbitols. And the like. However, in the case of the former method, there is a problem in that the surface to be cleaned is scratched by the abrasive and the luster of the surface to be cleaned is lost, and there is a problem that rinsing requires much labor. In the latter case, if the surface to be cleaned is a painted surface or a resin such as ABS resin, if the cleaning liquid remains on the surface to be cleaned, cracks, cracks, etc. may occur, which is a problem, There was a problem that hand washing was likely to occur with the cleaning liquid.

[0003] In addition, sebum dirt and soap dirt accumulate on fixtures such as floors, walls, basins and chairs in bathroom washing areas, and sticky dirt that is difficult to remove is formed. For cleaning such dirt, a method of rubbing with a cleaning agent containing a large amount of an abrasive such as a cleanser, a chelating agent, an acidic to neutral cleaning agent containing a water-soluble solvent such as carbitol and the like. And a method of dissolving and removing it. However, in the case of the former method, there is a problem in that the surface to be cleaned is scratched by the abrasive and the gloss of the surface to be cleaned is lost,
There was a problem that rinsing was labor intensive. Further, in the latter case, there is a problem that the cleaning power is not sufficient, the dirt needs to be kept in contact with the cleaning liquid for a long time, and it is necessary to physically rub the dirt, which requires much labor.

Further, on the painted surface of the body of an automobile, a so-called scale stain, which is a so-called scale stain, which is a composite of an oily substance contained in wax and the like and an oily substance and carbon contained in exhaust gas and the like is formed. Is done. To remove water stains, carefully polish with wax containing an abrasive,
A method of dissolving and removing dirt with an aqueous cleaning agent containing an abrasive and a water-soluble solvent such as carbitol is used. However, the former method requires once washing the car to remove dust and dirt, then it is necessary to thoroughly wipe off the water, and furthermore, it must be carefully polished with wax, which requires a great deal of labor and time, and furthermore, when the surface to be cleaned is large. Had a problem that the finish was likely to be uneven. In the latter case, there is a problem that the coating surface is easily damaged by the solvent.

[0005]

Means for Solving the Problems The inventors of the present invention have studied diligently to obtain a cleaning composition which is excellent in cleaning ability of the adhered oily stain, does not damage the surface to be cleaned and has excellent finish. As a result, it has been found that an aqueous detergent composition containing a chain hydrocarbon and a cyclic hydrocarbon at a specific ratio achieves such an object. Further, when specific solid particles are contained in the detergent composition, it has been found that the detergency is further improved, the damage due to the solid particles is suppressed to a low level, and the finish is good. Was completed.

That is, the present invention provides the following components (A), (B),
(C) and (D), the content of component (A) is 0.01 to 50% by weight, the total content of components (B) and (C) is 0.1 to 50% by weight, and the content of component (B) is It is intended to provide a detergent composition characterized in that the component (C) is blended at a weight ratio of component (B) / component (C) = 1/1 to 10,000 / 1.

(A) Surfactant (B) Chain hydrocarbon (C) Cyclic hydrocarbon (D) Water The present invention further comprises, as a component (E), water-insoluble or hardly soluble solid particles of 0.1 to 0.1%. The present invention provides a detergent composition containing 50% by weight.

[0008]

Embodiments of the present invention will be described below in detail.

[Component (A)] The cleaning composition of the present invention comprises (A)
Contains a surfactant as a component. In the composition of the present invention
The content of the component (A) is from 0.01 to 50% by weight, preferably from 0.1 to 10% by weight. If the content of the component (A) is less than 0.01% by weight, it becomes difficult to solubilize, emulsify, or disperse the oily components (B) and (C), and the two layers are separated promptly during use. As a result, the usability is poor and the cleaning power is insufficient. On the other hand, if it exceeds 50% by weight, the effects of the components (B) and (C) are adversely affected, and the detergency decreases.

Although the surfactant of the component (A) is not particularly limited, one or two or more selected from the group consisting of the following (A-1) to (A-4) are used as a component. Are preferred.

(A-1) The following general formula (I), (II) or (I
II) The compound represented by the formula, a linear or branched fatty acid salt having 8 to 20 carbon atoms, an α-olefin sulfonate having 8 to 20 carbon atoms, an alkane sulfonate having 8 to 20 carbon atoms, and a straight chain One or more anionic surfactants selected from the group consisting of alkyl (C6-C18) benzenesulfonates (provided that the salt is an alkali metal salt, an alkaline earth metal salt, an ammonium salt, Alkanolamine salts of formulas 1 to 5).

[0012]

Embedded image

(Wherein, R ₁ is a linear or branched alkyl or alkenyl group having 8 to 20 carbon atoms, R ₂ is a linear or branched alkylene group having 2 to 4 carbon atoms, and g is 0 or Number of one, h
Is a number of 0 to 5, i is a number of 0 to 10 as an average value, M is an alkali metal, an alkaline earth metal, ammonium or an alkanolamine having 1 to 5 carbon atoms, and R ₃ is a straight chain having 5 to 15 carbon atoms. Or, a branched alkyl or alkenyl group, R ₄ is the same as R ₃ or a hydrogen atom. Examples of the compound represented by the general formula (I), (II) or (III) include alkyl sulfate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl ether acetate, and alkyldiphenyl ether disulfonate. Can be

(A-2) One or more cationic surfactants selected from the group consisting of compounds represented by the following general formula (IV) or (V).

[0015]

Embedded image

(Wherein R ₁ , g and h have the same meanings as described above, R ₅ represents a methyl group or a linear or branched alkyl or alkenyl group having 6 to 11 carbon atoms, and X represents a halogen. Represents an atom or an alkyl sulfate residue.) Examples of these cationic surfactants include alkyl trimethyl ammonium salts, alkyl dimethyl benzyl ammonium salts, and dialkyl dimethyl ammonium salts.

(A-3) The following general formulas (VI), (VII) and (VII)
1 selected from the group consisting of compounds represented by I) or (IX)
One or more nonionic surfactants.

[0018]

Embedded image

(Wherein, R ₁ , g, h and R ₂ have the same meanings as above, j is an average number of 1 to 100, R ₆ is a hydroxyl group or a linear or branched group having 1 to 18 carbon atoms.) Chain alkoxy group, n
Is an average number of 1 to 10, p is an average number of 0 to 10, k is an average number of 0 to 5, G is a residue derived from a reducing sugar having 5 to 6 carbon atoms, m Is a number from 1 to 5 on average, R ₇ , R ₈ and
R ₉ is an acyl group having 8 to 22 carbon atoms or a hydrogen atom,
q, r and s represent numbers from 0 to 100 on average. However, (I
In the formula (X), at least one of R ₇ , R ₈ and R ₉ has 8 carbon atoms.
To 22 acyl groups. Examples of these nonionic surfactants include polyoxyethylene alkyl ether, alkyl polyglycoside, fatty acid diethanolamide, and fatty acid monoglyceride.

(A-4) One or more amphoteric surfactants selected from the group consisting of compounds represented by the following general formulas (X) or (XI).

[0021]

Embedded image

(Wherein R ₁ , g and h have the same meanings as above, R ₁₀ and R ₁₁ are an alkyl group or alkanol group having 1 to 3 carbon atoms, t is a number of 0 or 1, and Y is A hydrogen atom or a hydroxyl group, u is a number from 0 to 5, Z is COO ^- or S
O ₃ ^- is shown. ) These amphoteric surfactants include alkyl betaines,
Examples include alkylhydroxysulfobetaine, amidopropylbetaine, tertiary amine oxide, amidopropyldimethylamine oxide and the like.

In the present invention, particularly preferred component (A) is linear alkylbenzene sulfonic acid among the above (A-1) to (A-4) in view of economy, emulsifying power of oily component and detergency. 1 selected from the group consisting of salts, alkyl sulfates, polyoxyethylene alkyl ether sulfates, fatty acid salts, alkyl glycosides, and polyoxyethylene alkyl ethers
Species or two or more of them are constituents.

[Components (B) and (C)] The detergent composition of the present invention contains a chain hydrocarbon as the component (B) and a cyclic hydrocarbon as the component (C). The chain hydrocarbon of component (B) is
Although the component (C) exerts a remarkable detergency by interaction with the cyclic hydrocarbon, the effect is manifested when the total content of the component (B) and the component (C) in the composition of the present invention is 0.1 to 0.1. 50% by weight, preferably 0.5 to 10% by weight, and the mixing ratio of the component (B) and the component (C) is expressed by a weight ratio of the component (B) / the component (C) = 1/1 to 10,000 / 1, preferably 100/100. It needs to be 1 to 10,000 / 1.
If the total content of component (B) and component (C) is less than 0.1% by weight, sufficient detergency will not be exhibited, and if it exceeds 50% by weight, an oily feeling will remain on the surface to be cleaned after cleaning, which is not desirable in terms of touch. The weight ratio of component (B) / component (C) is 1/1 to 10,000 / 1.
If it is out of the range, a sufficient synergistic effect cannot be obtained.

The chain hydrocarbon of the component (B) used in the present invention is not particularly limited. However, considering the process of distribution and use as a commercial product, those having a low boiling point have a high risk of ignition. Those having a high boiling point are not preferred because they tend to remain on the surface to be cleaned. The preferred range of the boiling point is 70 to
The temperature is 350 ° C, more preferably 120 to 290 ° C. Saturated hydrocarbons are preferred because chain hydrocarbons having an unsaturated bond are reactive and may have restrictions in handling and formulation.

Specific examples of the chain hydrocarbon (B) used in the present invention include hexane, 2-methylpentane,
2,2-dimethylbutane, 2,3-dimethylbutane, heptane, 2-methylhexane, 3-methylhexane,
2,4-dimethylpentane, octane, 2,2,4-trimethylpentane, nonane, 2,2,5-trimethylhexane, decane, undecane, dodecane, tridecane,
Tetradecane and the like are mentioned, and dodecane, tridecane, tetradecane and the like are particularly preferable.

The cyclic hydrocarbon as the component (C) used in the present invention is not particularly limited, but includes benzene, alkylbenzene having at least one alkyl group having 1 to 18 carbon atoms as a substituent, cyclohexylbenzene, Styrene, naphthalene, biphenyl, tetralin, cyclohexane, methylcyclohexane, ethylcyclohexane,
Preferably, one or more components selected from the group consisting of p-menthane, bicyclohexyl, cyclohexene, decalin, α-pinene, β-pinene, dipentene, limonene, camphene, terpinolene and β-caryophyllene are preferred. Especially benzene, alkylbenzene, α-pinene, β-pinene, dipentene, limonene,
Campfen, terpinolene, β-caryophyllene are preferred.

[Component (D)] The cleaning composition of the present invention is an aqueous composition and contains water as the component (D). . Also
The dissolved state of the component (B) and the component (C) is preferably a solubilization system in water when used, or an emulsified dispersion system as an O / W emulsion.

[Component (E)] The detergent composition of the present invention further comprises, as a component (E), 0.1% water-insoluble or hardly soluble solid particles.
By adding the content of 50 to 50% by weight, preferably 0.5 to 10% by weight, the detergency can be further improved. (E)
By increasing the content of the components to 0.1% by weight or more, an effect of improving detergency can be obtained.

In the case of the conventional cleaning composition, when solid particles are blended, the cleaning power is improved depending on the shape, particle size and hardness of the solid particles, but the surface to be cleaned itself is damaged and gloss is increased. There was a disadvantage that it was lost. However, by adding the component (E) to the cleaning composition of the present invention, the detergency due to solid particles can be suppressed to a remarkably low level while improving the detergency.

The water-insoluble or hardly soluble solid particles of the component (E) used in the present invention may be any as long as they are insoluble or hardly soluble in water and can maintain the shape of the solid particles in the composition. Although not limited, the following (E-1) ~
It is preferable to use one or more selected from the group consisting of (E-5) as a component.

(E-1) Alkyl acrylates and methacrylates having 1 to 8 carbon atoms, mono- and di-alkyl (alkyl groups having 1 to 5 carbon atoms) itaconate and fumarate, maleic anhydride, vinylidene chloride, styrene, divinylbenzene , Vinyl chloride, vinyl acetate, vinyl acetal, ethylene, propylene, butene, butylene, methyl pentene, butadiene, vinyl toluene, acrylonitrile, methacrylonitrile, acrylamide, acrylic acid, methacrylic acid, itaconic acid, fumaric acid, citraconic acid, crotonic acid Acid, β-acryloxypropionic acid,
A monomer containing at least one ethylenically unsaturated monomer selected from the group consisting of hydroxyalkyl (alkyl group having 1 to 6 carbon atoms) acrylate and methacrylate, or a polymer obtained by polymerizing these monomers. The molecular weight of the polymer is preferably from 10 to 10,000,000, more preferably from 10,000 to 1,000,000.

(E-2) A silicone derivative having at least one group selected from the structural units represented by the following general formula (XII) or (XIII). The molecular weight of the silicone derivative is 1000-10
Million is preferred, and 10,000 to 1,000,000 is more preferred.

[0034]

Embedded image

(Wherein R ₁₂ , R ₁₃ and R ₁₄ are the same or different and each have an alkyl group having 1 to 100 carbon atoms, an alkoxy group,
Hydroxyalkyl group, hydroxyl group, carboxyl group, carboxyalkyl group, N- (2-aminoalkyl) aminoalkyl group, aminoalkyl group, amino group, epoxyalkyl group, epoxy group, methylpolyoxyethylenealkyl group, hydroxypolyoxyethylene It represents an alkyl group, a methylpolyoxyethylene / polyoxypropylene group, a hydroxypolyoxyethylene / polyoxypropylene group, an alkylpolyoxypropylene group, a polyoxyethylene group, a phenyl group or a fluorinated alkyl group. (E-3) Nylon, polyester, epoxy, amino alkyd, urethane, polyacetal or polycarbonate resin. The molecular weight of the resin is 1000-10
Million is preferred, and 10,000 to 1,000,000 is more preferred.

(E-4) A polyorganosilsesquioxane obtained by hydrolyzing and condensing methyltrialkoxysilane or a partially hydrolyzed / condensed product thereof in an aqueous solution of ammonia or amines. The molecular weight of the polyorganosilsesquioxane is preferably from 10 to 10,000,000, more preferably from 10,000 to 1,000,000.

(E-5) Silica or porous silica, aluminum oxide, magnesium oxide, titanium oxide, aluminosilicate, silicon carbide, calcium carbonate, calcium phosphate, chromium oxide, emery, quartz sand, dolomite, sand,
A water-insoluble inorganic substance of at least one of natural pulverized materials such as shells, mica powder, quartzite, diatomaceous earth, kaolinite, halloysite, montmorillonite, illite, and vermiculite.

Further, those having high detergency are those having an average particle size of solid particles of 0.01 to 15 μm and / or those having a true specific gravity of 0.5 to 2.5. Particularly, the detergency enhancing effect is high when the average particle diameter is 1 to 5 μm and the true specific gravity is 0.5 to
1.5. Further, in the cleaning composition of the present invention, the scratching property is reduced irrespective of the shape of the solid particles,
The level is low especially when the shape is spherical.

[Detergent Composition] The properties of the detergent composition of the present invention are not particularly limited, but are relatively unstable in an O / W emulsifying system as compared with a solubilized state or a stable emulsified state. When left to stand, it is in a state of being separated into two or three or more layers, and a system that is shaken at the time of use and brought into an emulsified state is more excellent in detergency.

Although the use of the cleaning composition of the present invention is not particularly limited, it can be used for walls, floors, tatami mats, ceilings, inside and outside homes.
Washing around houses such as roofs, washing around bathrooms such as bathroom walls, floors, doors, bathtubs, basins, and other bathroom equipment, kitchen walls, floors, sinks, around microwave ovens, etc. Cleaning around kitchen, cupboards, chests, tables, desks, chairs, bookshelves and other furniture, refrigerators, TVs, personal computers, stereos, air conditioners, microwave ovens, washing machines, dryers, lighting equipment and other appliances Surface cleaning, dwelling windows,
Washing of glass used for doors, furniture doors, car windows, etc., washing of screen doors, toilet floors, walls, doors,
Washing of toilets such as toilets, toilet seats with a washing function, heating toilet seats, etc., washing of dishes and cooking utensils, washing of painted surfaces and plastic surfaces of cars, bicycles, motorcycles, etc., washing of car wheels, around entrances, terraces, Fence, fence,
Suitable for cleaning exteriors such as around gates and other hard surfaces. Furthermore, the painted surface of the car body,
Particularly suitable for cleaning plastic part surfaces, window glass and wheels.

The pH of the cleaning composition of the present invention is not particularly limited, but is preferably in the range of 3 to 12, and more preferably 5 to 10.

In practicing the present invention, various substances can be blended as long as the effects of the present invention are not impaired. Examples of such substances include fragrances, pigments, dyes, fungicides, fungicides, solubilizers, chelating agents, antioxidants, pH adjusters, bleaching agents, thickeners, dispersants, ultraviolet absorbers, etc. Is mentioned.

[0043]

The present invention will be described in more detail with reference to the following examples, but the present invention is not limited to these examples.

Example 1 A cleaning composition of the present invention or a comparative composition was prepared with the composition shown in Table 1, and a bath dirt cleaning power test was carried out by the following method to evaluate the cleaning power. Table 2 shows the results.

<Bath dirt cleaning power test> A polypropylene basin having been used in a general household for about three months and having bath dirt such as soap scum attached thereto was sponged with 5 g of a detergent solution using a sponge.
It was rubbed lightly for 1 minute and the detergency was evaluated. In addition, the dirt used for the evaluation was subjected to evaluation after confirming in advance that it could not be rubbed off with water.

The evaluation points were visually judged according to the following criteria. A: Dirt completely removed. ：: Three-quarters or more of stains were removed. Δ: Only less than half of the stains were removed. X: Dirt was not removed at all.

[0047]

[Table 1]

Note) * 1: Neoperex F-25 / manufactured by Kao Corporation * 2: Emar 20C / manufactured by Kao Corporation * 3: Tospearl 120 / manufactured by Toshiba Silicone Co., Ltd., average particle diameter 2 μm, true specific gravity 1.3 spherical particles * 4: Use hydrochloric acid or sodium hydroxide

[0049]

[Table 2]

Example 2 A cleaning composition of the present invention or a comparative composition was prepared according to the formulation shown in Table 3, and a heat-modified oil stain cleaning power test was carried out by the following method.
The detergency was evaluated. Table 4 shows the results.

<Heat-denatured oil stain cleaning power test> Tempura oil was uniformly applied to an iron plate and baked at 180 ° C for 30 minutes to prepare a heat-denatured oil stain which was almost uniformly formed into a film. The stained iron plate was fixed, and a cleaning solution was dropped on the plate. After leaving the plate to stand for 40 seconds, the floated stains were gently rubbed with absorbent cotton, and the cleaning power was visually judged according to the following evaluation criteria.

A: Dirt was completely removed. ：: Three-quarters or more of stains were removed. Δ: Only less than half of the stains were removed. X: Dirt was not removed at all.

[0053]

[Table 3]

Note) * 1: Same as * 1 in Table 1.

[0055]

[Table 4]

Example 3 A cleaning composition of the present invention or a comparative composition was prepared according to the formulation shown in Table 5, and a detergency test was conducted by the following method to evaluate detergency. Table 6 shows the results.

<Test Method for Detergency of Water Scale> A white melamine-baked painted plate (JIS G 3141 standard test plate, manufactured by Nippon Test Panel Osaka Co., Ltd.) was purchased from a commercially available car wax (manufactured by Shuraster Inc., trade name: Impact Master Finish). )), Mounted on the roof of the car, about 3 months,
The vehicle traveled an average of 20 km or more a day to prepare water stains. After confirming that the dirt could not be rubbed off by washing with water, it was rubbed with a sponge containing 5 g of a cleaning solution for 3 minutes to evaluate the detergency. The evaluation points were visually judged according to the following criteria.

A: Dirt was completely removed. ：: Three-quarters or more of stains were removed. Δ: Only less than half of the stains were removed. X: Dirt was not removed at all.

[0059]

[Table 5]

Note) * 4: Same as * 4 in Table 1. * 6: Average condensation degree of glucose residue = 1.35 * 7: Tospearl 145 / manufactured by Toshiba Silicone Co., Ltd., average particle size 4.5 μm, true specific gravity 1.3 Spherical particles

[0061]

[Table 6]

Claims (13)

[Claims] (1) The composition contains the following components (A), (B), (C) and (D), wherein the content of the component (A) is 0.01 to 50% by weight and the content of the component (B) is
The total content of component (C) is 0.1 to 50% by weight, and component (B)
Component (C) is compounded at a weight ratio of component (B) / component (C) = 1.
/ 1 to 10,000 / 1. (A) Surfactant (B) Chain hydrocarbon (C) Cyclic hydrocarbon (D) Water 2. The cleaning composition according to claim 1, further comprising 0.1 to 50% by weight of water-insoluble or hardly-soluble solid particles as the component (E). 3. The chain hydrocarbon of the component (B) has a boiling point of 70 to 3
The cleaning composition according to claim 1 or 2, which is a saturated chain hydrocarbon at 50 ° C. 4. The chain hydrocarbon of component (B) has a boiling point of 120 to
The cleaning composition according to claim 1 or 2, which is a saturated chain hydrocarbon at 290 ° C. 5. Component (C) is benzene, alkylbenzene having at least one alkyl group having 1 to 18 carbon atoms as a substituent, cyclohexylbenzene, styrene, naphthalene, biphenyl, tetralin, cyclohexane, methylcyclohexane, ethylcyclohexane, p-menthane, bicyclohexyl, cyclohexene, decalin,
The composition according to any one of claims 1 to 4, wherein the composition comprises one or more components selected from the group consisting of α-pinene, β-pinene, dipentene, limonene, camphene, terpinolene, and β-caryophyllene. The cleaning composition according to the above. 6. The method according to claim 1, wherein the component (A) comprises one or more components selected from the group consisting of the following (A-1) to (A-4). The cleaning composition according to claim 1. (A-1) a compound represented by the following formula (I), (II) or (III), a linear or branched fatty acid salt having 8 to 20 carbon atoms, an α-olefin having 8 to 20 carbon atoms One or more anionic surfactants selected from the group consisting of sulfonates, alkane sulfonates having 8 to 20 carbon atoms, and linear alkyl (6 to 18 carbon atoms) benzene sulfonates (however, And the salt is an alkali metal salt, an alkaline earth metal salt, an ammonium salt or an alkanolamine salt having 1 to 5 carbon atoms.) Embedded image (Wherein, R ₁ is a linear or branched alkyl or alkenyl group having 8 to 20 carbon atoms, R ₂ is a linear or branched alkylene group having 2 to 4 carbon atoms, g is a number of 0 or 1) , H is a number from 0 to 5, i is a number from 0 to 10 as an average value, M is an alkali metal,
Alkaline earth metal, ammonium or alkanolamine having 1 to 5 carbon atoms, R ₃ represents a straight-chain or branched alkyl or alkenyl group having 5 to 15 carbon atoms, and R ₄ represents the same as R ₃ or a hydrogen atom . (A-2) One or more cationic surfactants selected from the group consisting of compounds represented by the following general formulas (IV) or (V). Embedded image (Wherein, R ₁ , g and h have the same meanings as described above, R ₅ represents a methyl group or a linear or branched alkyl group or alkenyl group having 6 to 11 carbon atoms, and X represents a halogen atom or an alkyl group. (A-3) represents one or more nonions selected from the group consisting of compounds represented by the following general formulas (VI), (VII), (VIII) or (IX). Surfactant. Embedded image (Wherein R ₁ , g, h and R ₂ have the same meanings as described above;
Is an average number of 1 to 100, and R ₆ is a hydroxyl group or a carbon number of 1 to 18
Linear or branched alkoxy group, n is 1 on average
Number of ~ 10, p is the number of 0 ~ 10 on average, k is 0 ~ 0 on average
G is a residue derived from a reducing sugar having 5 to 6 carbon atoms, m is a number of 1 to 5 on average, and R ₇ , R ₈ and R ₉ are each an acyl group having 8 to 22 carbon atoms. Or, a hydrogen atom, q, r and s represent a number of 0 to 100 on average. However, in equation (IX),
At least one of R ₇ , R ₈ and R ₉ is an acyl group having 8 to 22 carbon atoms. (A-4) One or more amphoteric surfactants selected from the group consisting of compounds represented by the following general formulas (X) or (XI). Embedded image (Wherein, R ₁ , g and h have the same meanings as above, R ₁₀ and R ₁₁ are alkyl groups or alkanol groups each having 1 to 3 carbon atoms, t is a number of 0 or 1, Y is a hydrogen atom or hydroxyl, u is the number of 0 to 5, Z is COO ^- or SO ₃ ^- shows a). 7. The composition according to claim 2, wherein the component (E) comprises one or more components selected from the group consisting of the following (E-1) to (E-5). The cleaning composition according to any one of the preceding claims. (E-1) Alkyl acrylates and methacrylates having 1 to 8 carbon atoms, mono- and di-alkyl (alkyl groups having 1 to 5 carbon atoms) itaconate and fumarate, maleic anhydride, vinylidene chloride, styrene, divinylbenzene, vinyl chloride , Vinyl acetate, vinyl acetal, ethylene, propylene, butene, butylene, methylpentene, butadiene, vinyltoluene, acrylonitrile,
From the group consisting of methacrylonitrile, acrylamide, acrylic acid, methacrylic acid, itaconic acid, fumaric acid, citraconic acid, crotonic acid, β-acryloxypropionic acid, hydroxyalkyl (alkyl group having 1 to 6 carbon atoms) acrylate and methacrylate At least one chosen
(E-2) at least one group selected from structural units represented by the following general formula (XII) or (XIII) Having a silicone derivative (Wherein, R ₁₂ , R ₁₃ and R ₁₄ are the same or different and each have an alkyl group having 1 to 100 carbon atoms, an alkoxy group, a hydroxyalkyl group, a hydroxyl group, a carboxyl group, a carboxyalkyl group, an N- (2-aminoalkyl ) Aminoalkyl group,
Aminoalkyl group, amino group, epoxyalkyl group, epoxy group, methylpolyoxyethylenealkyl group, hydroxypolyoxyethylenealkyl group, methylpolyoxyethylene / polyoxypropylene group, hydroxypolyoxyethylene / polyoxypropylene group, alkylpoly It represents an oxypropylene group, a polyoxyethylene group, a phenyl group or a fluorinated alkyl group. (E-3) Nylon, polyester, epoxy, amino alkyd, urethane, polyacetal or polycarbonate resin of at least one kind. (E-4) Methyl trialkoxy silane or its partial hydrolysis / condensate is converted to ammonia or amines Polyorganosilsesquioxane (E-5) silica or porous silica obtained by hydrolysis and condensation in an aqueous solution of, aluminum oxide, magnesium oxide, titanium oxide, aluminosilicate, silicon carbide, calcium carbonate, calcium phosphate, oxidized Chromium, emery, quartz sand, dolomite, sand, shells and other natural ground materials, mica powder, quartzite, diatomaceous earth, kaolinite, halloysite, montmorillonite, illite, vermiculite 8. The cleaning composition according to claim 7, wherein the component (E) has an average particle diameter of 0.01 to 15 μm of the water-insoluble or hardly-soluble solid particles. 9. The cleaning composition according to claim 7, wherein the true specific gravity of the water-insoluble or hardly-soluble solid particles of the component (E) is 0.5 to 2.5. 10. The water-insoluble or hardly soluble solid particles of the component (E) have an average particle size of 1 to 5 μm and a true specific gravity of 0.5 to 5 μm.
The cleaning composition according to any one of claims 7 to 9, which is 1.5. 11. The cleaning composition according to claim 7, wherein the water-insoluble or hardly-soluble solid particles of the component (E) have a spherical shape. 12. The cleaning composition according to claim 1, wherein the properties of the cleaning composition are in two or three or more layers. 13. The cleaning composition according to claim 1, which is used for cleaning painted surfaces of automobile bodies, surfaces of plastic parts, window glasses or wheels.