TW415964B - Liquid detergent composition for hard surface and method for cleaning hard surface - Google Patents

Abstract

The present invention provides detergent compositions for hard surfaces which can clean without pre-washing a hard surface having particulate solid dirt thereon even with a small amount of water or a detergent without marring the hard surface, whereby the process of washing hard surfaces can be made easier or simpler, the labor necessary for the washing can be remarkably reduced, and the washing of a hard surface can be accomplished without impairing the beautiful appearance thereof, and methods for washing hard surfaces. Specifically, a liquid detergent composition for hard surfaces which can clean a hard surface having particulate solid dirt thereon by applying to the surface and wiping the resulting surface to remove the dirt from the surface, wherein the composition comprises a liquid washing medium, and globular particles having a mean particle diameter of 0.01 to 15 mu m and being insoluble in the liquid washing medium, with the provisos that the content of the globular particles in the composition is 0.1 to 30% by weight and that the viscosity of the composition is 2 to 500 cps as determined at 20 DEG C in a uniformly stirred state; and a process for cleaning hard surfaces with this detergent composition.

Description

415964 A7 B7 Printed by the Central Standards Bureau of the Ministry of Economic Affairs® ζ Industrial Consumer Cooperatives V. Description of the Invention (1) Technical Field of the Invention The present invention is a hard surface liquid cleaner composition for cleaning the surface of hard materials such as automobile bodies, and Cleaning methods for hard surfaces. More specifically, it is about the hard surface of solid particle dirt, which can be directly cleaned with the minimum amount of water without pre-cleaning with water, and the hard surface will not be caused by solid particles cold matter. Damaged, liquid cleaner composition for hard surface that can clean the surface and hard surface cleaning method. The previous technology has always had 'hard surfaces with solid particles and dirt from home dust, soil, sand, etc.' such as car bodies, etc. The materials are clean, and both the hard surfaces must be protected from solid particle damage and the surfaces must be clean Therefore, it is necessary to remove the solid particle dirt by circulating the remaining water, or to remove other dirt before cleaning it. Furthermore, the cleaning materials (cloth, paper, non-woven fabric, sponge, etc.) used during cleaning may cause damage to hard surfaces. However, in general, where a hard surface is used as a cleaning object, it is impossible to use a large amount of water, and the use of a large amount of water may significantly damage the workability. This is generally the case for hard surface cleaners that are commercially available for this purpose. Generally, to prevent hard surface damage caused by friction between solid particles / hard surfaces, a lubrication method can be used. The lubricant is adsorbed on the surface of the solid particles and the hard surface, and the damage is prevented by the formation of a full pressure-resistant slippery film. Therefore, the adsorption force of both solid particles / hard surfaces that are in contact with each other is high, and the adsorption film is made under local pressure-4-J ----.---- 1 ^ -------- --- it (Please read the notes on the back before filling out this page} This paper size is applicable to China National Standard String (CNS) A # specifications (2 丨 〇 &gt; &lt; 297) 415964 Work of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the Consumer Cooperative Association A7 B7 V. Description of the Invention (2) Non-destructive lubricant is necessary; for this purpose, the molecular structure of the lubricant must not deform under the local pressure caused by contact, and the lubricant molecules are to each other The friction between them is small. However, this will increase the amount of lubricant absorbed on the surface being cleaned. Although the ability to prevent damage is increased, the residue of the lubricant itself will cause cold dyeing. For example 'When using grease for the purpose of preventing damage', it increases manual erasure and has a low effect of preventing damage. In addition, grease residues can cause contamination, and the removal of this pollutant is not easy to achieve. In addition, 'The lubricating film is not easy to break under local pressure, Increase the ability to prevent damage 'but the fiber used in the wiping operation with cloth, etc., the shear resistance of the lubricant is too high' Even if the wiping cleaning is about 0lm2, it is not practical to work ' The feasibility is very low. JP-A-58-154774 is a polishing composition containing organic fine powder having a spherical or near-spherical shape with a particle size of less than 1000 microns. JP-A-61-159474 is a disclosure of wax (6) Polishing agent composition produced by polymethylsilsesquioxane. -Hachi-2-117979 series discloses a polishing agent composition containing wax and / or waxy substance and silicon rim powder. However, 'these techniques are polishing compositions mainly composed of waxes, and there is no intention in the present invention to clean the surface where solid particle dirt is present. DISCLOSURE OF THE INVENTION Therefore, the object of the present invention is to provide a It does not need to be cleaned in advance, and does not need to use a large amount of water and lotion. It can clean the hard surface contaminated by solid particles without damage, and the cleaning process is very simple. This paper is in accordance with China's national standard ( CNS) Α4 gauge ^ 格 （2 丨 0X297mm ij ·. I- I »H 1 m I-1 II 111 l ^ i I -li 1 ^ 1 ^^ 1 m ^^ 1 1 ^ 1 In ^^ 1 0¾ ·?-- Rui &lt; Please read the precautions on the back before filling this page) 41SQ64 V. Description of the invention (3 A7 B7 ----- The reduction of the printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs and the appearance of the cleaned surface Without bruising, it can be used as a final cleaning engineer ... hard detergent surface cleaning agent & and hard surface cleaning method The existence of particle dirt, hard / surface, and rubbing and cleaning with a small amount of liquid does not cause damage to the surface. It was found that the use of a pen containing a specific mosquito particle and a specific domain 1 composition was used for cleaning. , Has a high degree of damage prevention performance, at the same time has good workability and cleaning power, and maintains the beauty of the surface being cleaned, has a great effect, thus completing the present invention. That is, the present invention provides a liquid cleaner composition for a hard surface, which is suitable for a hard surface where solid particle dirt is present, and the hard surface is cleaned by wiping off the dirt, and the hard surface is a liquid cleaner composition The object is characterized by containing a liquid cleaning medium of rhenium, and (b) spherical particles having an average particle size of 0.001 to 15 μπ1 insoluble in the liquid cleaning medium, and the content of the component (b) in the composition is oi to 30. % By weight, the state after uniform stirring, the viscosity at 20 ° C is 2 ~ 500cps «In addition, the above-mentioned liquid cleaner composition for a hard surface provided by the present invention has another feature of the above-mentioned ⑻ and (b) Among the components, a liquid lubricating component as the component (c) is added, and the mixing ratio (C) / (b) (weight ratio) of the rhenium component and the (C) component is 0.01 to 10 β. Also, the present invention provides In the above-mentioned liquid cleaner composition for hard surface, a surfactant may be added as component (d) to the above-mentioned components (i) and (c). 6 This paper size is applicable to China National Standard (CMS) A4 (210X297). %) ---------— ^ 1 ------ Order I-^ ----- 0 (please first Read the notes on the back and fill in this page again) 415964 A7 B7 Five Standards of the Ministry of Economic Affairs, Central Standards and Consumers' Cooperatives, Yin Ben Invention Description (or polymer dispersant, or a mixture thereof. In addition, the present invention provides a method for cleaning hard surfaces It is characterized in that the above-mentioned detergent composition is used for a hard surface where solid particle dirt exists, and the hard surface is cleaned by wiping off the dirt; in particular, it provides a method for cleaning a car body, which will contain ⑻Liquid cleaning medium, ⑹Spherical particles with an average particle size of 0 which are insoluble in the liquid cleaning medium, and (c) a liquid polyorganosiloxane oil at 20 ° C, a liquid detergent composition [combination The content of the rhenium component in the product is 0 to 30% by weight, and the compounding ratio of the (b) component to the (c) component (c) / (b) (weight ratio) = 00 to 〇, in a uniformly stirred state , 20 ° c viscosity is 2 ~ 50 ° Cps] Used to clean the car body with solid particle dirt without cleaning beforehand, and wipe off the dirt at the same time. In the present invention, spherical particles with high mobility are applied to the hand. Partially pressurized in the form of solid dirt particles The result is that the contact rate with the hard surface of the surface to be cleaned tends to be extremely low (cyclic dilution effect) and the free movement of a large number of particles in the cleaning solution, so that the hand is applied. The stress is dispersed, thereby further reducing the contact pressure (contact pressure reducing effect) of the abrasive particles during contact and thereby preventing damage. In the present invention, the particles used can fully move freely, and prevent the particles sufficiently. The injury effect is very important. To achieve this, the most important thing is that the 20X viscosity of the liquid detergent composition system of the present invention must be a low viscosity of 2 ~ 50 cps; The particles must have a shape that is difficult to interact with and agglomerates are difficult to form in the liquid (that is, the paper size of the paper is applicable to the Chinese National Standard (CNS) A4 specification (2 丨 〇 X 297 mm) ί --- r-- -------- tr ------ φ, (Please read the note on the back before filling out this page) V. Description of the invention (6 415964 A7 B7 Printed by the Bayer Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs In order not to hinder the free movement of the particles And without damaging the surface being cleaned and increase the cleaning power, is to add water or more preferably an organic solvent as the cleaning liquid medium. In addition, if such an organic solvent is used in combination with the aforementioned liquid lubricating component (such as polyorganosiloxane oil), the viscosity of the liquid lubricating component can be reduced. Since the mobility of the particles is further improved, it is expected that a better prevention Traumatic advantages. In combination with a surfactant and a polymer dispersant, the agglomeration of the particles is prevented to ensure substantial free movement, and at the same time, the dispersion of solid particles and dirt is promoted, which has the advantages of better wound prevention and cleaning power. Forming energy of fluorescent implementation The following is a detailed description of embodiments of the present invention. The cleaning composition of the present invention contains a liquid cleaning medium as a rhenium component. The liquid cleaning medium in the present invention is a liquid solvent having a boiling point of less than 300eC, which is easy to remove solid particles and dirt. Specifically, for example, there is water, an organic solvent having a boiling point of 70 to 30 (rc, a boiling point of less than 3otrc). Silicone oil (one or more than two such as ring-shaped silicon bugs, volatile dimethylsiloxane, etc.). Among them, water or a mixture of water and an organic solvent is preferred, and water and a mixture of organic solvents are more preferred. Moreover, the mixing ratio of the mixture of water and organic solvent is water: organic solvent (weight ratio) = 5 ~ 20: 1 is better β. Furthermore, the form of the mixture, whether it is an emulsification system, a solubilization system, or a separation Either a system or the like is preferable. The organic solvent used in the present invention is a hydrocarbon solvent having 8 to 20 carbon atoms, and the following ether solvent β CH3 (CH2) p0 (CH2CH20) q ( C3H60) r (CH2) sR4 (III) (where R4 represents Η, CH3, or OH, and p'q, 1 *, and s represent integers 0 to 20, respectively) -9- This paper standard applies to Chinese national standards Rate (CNS) A4 wash grid (21〇 × 29 · 7 mm) ----------- Ί --- install ------ 1T-: ----- line (please read first Read the precautions on the back and fill in this again. 1) Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Printed by the Shellfish Consumer Cooperative 415964 A7 ___________B7 V. Description of the invention (7) Specific examples of these organic solvents can be listed as decane, ten-burn , Dodecane, Tridecane, Tetradecane, Isostamidine and other hydrocarbon solvents' diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol di Acid solvents such as diethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, and dipropylene glycol dicarboxylic acid, among which hydrocarbon solvents are particularly preferred. The detergent composition of the present invention contains ⑹ The component 'is a spherical particle which is insoluble in the above-mentioned cleaning solvent and has an average particle diameter of 0.01 to 15 &quot; m. The spherical particle used in the present invention contains a body shape which is conventionally different from a spheroid; as follows The definition of the degree of sphericity is related to the mobility and non-agglutination of the particles, and the one with a sphericity of 90 or more is preferred. &Lt; Sphericity &gt; 100 photos were randomly selected Overlapping particles, the particle projection image depicts a circle or the circumscribed circle of the projected image. Between the concentric circle made with a radius of 90% of the circumscribed circle and the circumscribed circle, the entire shape of the projected image outline is included. The number of the particles is regarded as the sphericity of the particles. The average particle diameter of the spherical particles used in the present invention is 0 01 ~ 15 # m, preferably 0.1 ~ 10 μιη, and more preferably 1 ~ 5 μιη. If the average particle diameter is within the range of 0.01 to 15 μηι, then by the efficiency of the number of particles per unit weight, or by the same size as the solid particle dirt generally existing on the hard surface as the cleaned surface, The cleaning efficiency of such solid particle dirt will become good. In addition, the average particle diameter of the spherical particles in the present invention can be expressed as follows -10- This paper / C degree applies the Chinese National Standard (CNS) Α4 grid (210X297 mm) f 碕 Read the precautions on the back first Fill out this page} _ _ .. _ _ 415964 A7 ----- -B7_ printed by the Central Standards Bureau of the Ministry of Economic Affairs of the Shellfish Consumer Cooperatives V. Description of the invention (8) method for determination. &lt; Measurement method of average particle diameter &gt;-The particles are completely dispersed with ultrasonic waves in a dispersion solvent of water, methanol 'i% Ci2h25〇 (CH2CH2〇) 6H aqueous solution, and then light-scattered particle diameter The distribution measuring device (HORIBA LA-5OO) measures the particle size. In addition, the weight ratio of the particles / dispersion solvent can be determined by the concentration of the particle size distribution measuring device (a), and the particles are gradually added to the dispersion solvent before the display reaches "optimum". From the obtained particle diameter, a volume-based average particle diameter was calculated and used as the average particle diameter in the present invention. However, when the average particle diameter is a, when the maximum particle diameter measured is larger than a + a / 2 or the minimum particle diameter is smaller than aa / 2, assuming that the standard deviation of the measured particle is β, only The volume-based average particle diameter was calculated again from the particles having a particle diameter within a- to a + &lt; 5 · Fanyuan as the average particle diameter in the present invention. · Furthermore, the specific gravity of the spherical particles of the present invention is in order to have a moderate contact rate with a hard surface in the cleaning solution during cleaning, and a moderate cyclic motion in the cleaning solution. The specific gravity is in the range of 0.5 to 2.5. It is better, and more preferably 0.5 ~ 1.5. Furthermore, in order to improve the mobility on a hard surface, the cohesion between the particles is preferably low. The particles that can achieve this purpose have a surface energy of 60 dyne / cm or less. In addition, the so-called surface energy in this article refers to the radon measured by the following methods. <Measurement method of solid surface energy> The surface tension γ is considered to be equivalent to the equivalent of the London dispersion force (/) and is equivalent to -11-This paper size is applicable to China National Rubbing (CNS) A4 (210X297 mm) 1 HI binding. Thread (please read the precautions on the back before filling out this page) Yin Gong Consumer Cooperative, Central Standards Bureau, Ministry of Economic Affairs, India 415964 A7 ____ B7 V. Description of the invention (9) For other polar items (γρ) 。 = Yd + Yp ⑴ Furthermore, by measuring the contact angles of two liquids (distilled water and diiodide system) known / to γP, (b ^ c ^ aOvV + on the solid surface can be calculated from dCbi-aOY * 1 + = 〇⑵ (b2 + c2 + a2) YV + c2 (b2-a2) Yd + b2 (c2-a2) Yp-a2b2c2- 0 (3) (lMhJl + cosG!) a2 = (1 / 4) y2 (Hc〇s02) bi] 〆b2 = Y2d cl = YlP C2 = γ2P θΐ: contact angle on the solid surface of distilled water Θ2: contact angle on the solid surface of diiodomethane • surface tension of distilled water Υι = 72.8 dyne / cm Yid = 22.1 dyne / cm 7ιρ = 50.7 dyne / cm • Surface tension of diiodomethane Y2 = 50.8 dyne / cm? 2d = 44.1 dyne / cm Y2P = 6.7 dyne / cm Dispersion force component (Yd) and polar force component (γρ) of the surface tension can be calculated by substituting into the formula ⑴. Furthermore, in the present invention, even when spherical particles are wiped out, It keeps free movement without being deformed under pressure, so it has excellent anti-injury effect; and, it is ____ -12- (gift by 2Ι0 ×)-I--U ---- i equipment ------ -IT —.----- line (please read the note on the back before filling in this page) 415964 A7 ________ B7 V. Description of the invention (1〇) The particle itself does not cause pimple on the surface being cleaned. The elastic modulus is preferably 10-1000 kg / mm2, more preferably 50-500 kg / mm2, and most preferably 100-300 kg / mm2. In addition, the elastic modulus of the present invention is as follows Measured by the method shown below. &Lt; Measurement method of elastic modulus &gt; The powder was measured for the compression displacement of each particle using a small compression tester PCT_200 (manufactured by Shimadzu Corporation), and the particle diameter was 1 °. The load at% deformation is calculated by the following formula, E 値, which is the elastic modulus of the particles. However, this measurement must be performed at 20 ~ 25T. As 3~ΙΟμιη. If the particle size is not within this range, the particle size is 3 to 10 μm. The elastic modulus of the particle is a F · Compression force (kg) S: Compression deformation amount (min) E: Particle's compressive elastic modulus (elastic modulus, kg / mm2) R: particle radius (mm) 3 xFx (1- (0.38) 2)

V2xS15 xVR. In order for the spherical particles according to the present invention to meet the above conditions, the constituent material is preferably selected from one or two or more of the following ① ~ ⑧ groups as constituent components, and ②'④, ⑥'⑦ It is better to choose from '⑧, and the best from among ② and ④. ①From the specifications of acrylic acid and methacrylic acid (the number of carbons in the base group, the mono- or dialkyl esters of itaconic acid or fumaric acid (the number of carbons in the alkyl group, the maleic acid, Partial-Ethyl-Ethylene-Ethylene, Ethyl-Ethylene, Ethyl-Ethylbenzene, Ethyl-Ethylene, Vinyl Acetate, Ethylene Acetal, Ethylene, Propylene, Butene, Isobutylene, Methylpentane 13- This paper is for China Gujia Standard (CNS) A4 specification (21〇 &lt; 297 mm) ---- I— n I / — 装 II — ^ ——1 I line (Please read the note on the back before filling in this Page) Printed by the Central Laboratories of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives. Printed by the Central Government of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives, Benben 415964 A7 B7. 5. Description of the invention (11) Butadiene, butadiene, vinyl toluene, acrylonitrile, methyl Acrylonitrile, acrylamide, acrylic acid, methacrylic acid, itaconic acid, fumaric acid 'citraconic acid, crotonic acid, β-acrylic acid oxypropionic acid, acrylic acid and methacrylic acid In the group of carbon number 1 to 6>, at least one kind of polymer obtained by polymerizing an ethylenically unsaturated monomer is selected. ② It is represented by the following general formulas ⑴ and (Γ). The silicone resin formed by the constituent units shown below [eg Cambodia Riffel R · 925 'R-93〇, R ~ 935 (Toray Dow Corning Co., Ltd. is made by Pugg Company)]

Ri R3-Si-(I)

(In the formula, R !, R2, and R_3 represent the same or different alkyl group, alkoxy group, hydroxyalkyl group, hydroxy group, siloxane group, carboxyl group, carboxyalkyl group, N- (2-Aminealkyl) amine alkyl, amine alkyl, amine, epoxy alkyl, epoxy, methyl polyoxyethylene alkyl, hydroxy polyoxyvinylfluorenyl 'methyl polyoxyethylene .Polyoxypropylene, hydroxypolyoxyethylene. Polyoxypropylene, alkylene oxide, polyethylene oxide, phenyl, or fluorocarbon.) ③ Nylon, polyester, epoxy resin, Any one or more resins among urethane, polyurethane, polyacetic acid, or polycarbonate. ------------ ^ ------- V ------ line (please read the precautions on the back before filling in this page) -14 * Ministry of Economic Affairs Central Standard Dead work consumer cooperative print 415964 at ______B7_ V. Description of the invention. (12) ④ Methyltrialkoxysilane or part of it is hydrolyzed. Condensate, hydrolyzed in ammonia or amine aqueous solution The obtained polyorganosilsesquioxane [for example, East Spal 103, 105, 108, 120, Π0, 145, 2000B (manufactured by Toshiba Silicon Co., Ltd.), KMP-590, KMP-590C (Shin-Etsu Chemical Industry Co., Ltd. Ltd.)]. ⑤ Oxidized sand or porous oxidation. ⑥ The polymer produced by copolymerizing the ethylenically unsaturated monomer described in ① above with the silicone derivative monomer composed of the structural unit represented by the above formula and formula (1,). ⑦ The resin of ③ above, the polyorganosilsesquioxane of ④, or the silicon oxide or porous silicon oxide of ⑤ use the ethylenic unsaturated monomer described in ① above and / or the formula (I) and formula above A polymer obtained by denaturing a silicone derivative monomer having a constitutional unit represented by (Γ) [for example, using a silanol group 'addition polymerization acrylic acid on the surface of an organosilsesquioxane / silica / porous silica, Polymers such as methacrylic acid and polymethylhydroxysiloxane are incorporated into the main chain of the resin in the above (3), and the ethylenic unsaturated monomers described in (1) are included in the main chain of the resin described in (1) or the above formulae (I) and (Γ). A polymer produced by a silicone derivative monomer composed of the indicated constituent units [for example, after the reaction site is formed by partial oxidation of the main chain, addition reaction of epoxy groups, etc., addition polymerization of acrylic acid, methacrylic acid, Polymethylhydroxysiloxane and other polymers]. The detergent composition of the present invention contains 0.1 to 30% by weight of the aforementioned spherical particles. If the content of spherical particles is less than 0.1% by weight, the number of particles will be less than that of solid particles generally existing on the surface to be cleaned. Thus, the abrasion resistance for the purpose of the present invention will be significantly reduced. good. If it exceeds 30 weight 0 / 〇, since the amount of the particles in the complex solution becomes too large, the mobility of the particles is reduced -15- IL --- ^ ------ equipment ------ order-- ^ ----- line (please read the note on the back before filling out this page) This paper standard is Ningguo National Standard (CNS) A4 specification (2Ϊ0 × 297). Production A7 B7 V. Description of the invention (13) The damage prevention property decreases at the same time, and it becomes difficult to remove the particles after cleaning, resulting in reduced workability, which is not good. Regarding the viscosity of the detergent composition of the present invention, in order to improve the free movement of spherical particles and more effectively prevent injuries, the viscosity at 20 ° C must be within the range of 2 to 500 cps in a uniform stirring state, with a range of 3 to 10 〇cps is more preferable, and 3 ~ 50 cps is more preferable. In the present invention, the viscosity is measured by the following method: β &lt; Method for measuring viscosity> A 100 ml sample is placed in a beaker (inner diameter φ 3 · 6 cm, height 13 cm) for viscosity measurement. Diffuse the beaker in a constant temperature water bath of 200m for more than 30 minutes, and confirm that the liquid temperature of the sample becomes 20x: After that, cover it with a cover plate, etc., and shake the whole body vigorously for more than 30 times to make it uniform. After shaking, the No. 1 rotor of a b-type viscometer (manufactured by Tokimec Inc) was rotated at 60 rpm within 10 seconds, and the number indicated by the pointer after 1 minute was the viscosity in the present invention. Cleaner composition 2 (If the viscosity of TC is less than 2 cps, the mobility of the spherical particles is too high, it will become difficult to wipe the spherical particles themselves with a wiping material, resulting in reduced cleaning power, while dispersing from the hand Before the stress, the particles have been removed and the damage prevention effect is low. Moreover, if it is higher than 500 cps, the mobility of the spherical particles will be reduced, and the dilution effect and local pressure dispersion effect will be low. At the same time, the sliding property of the material used for wiping will be low. It becomes worse, the force required during operation is significantly increased, and the force required to maintain the material is also increased. As a result, the vertical stress on the hard surface is increased too much, but it promotes the damage effect. Moreover, the composition above 500cps The erasability is also worse, resulting in lower workability and lower cleaning power. In the case where the cleaning composition of the present invention is used in a spray container, it is __ -16- this paper Huai ruler and the universal nail store national grave standard ( CNS) A4 size (210X297 public seam f

{谙 Coaxing the precautions on the back of the page and then hurting this page. J U9 · D Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 ---__ —__ B7_ 5. Explanation of the invention (14) Self-spraying container When the narrow nozzle is sprayed, a wide area spray can be obtained and a pressurized gas (10kg / crn2) generally used by humans or households is used. Therefore, the viscosity of the composition should be less than 200 cps, and preferably less than 〇〇〇cps. It is better to be below 50 cps. If it exceeds 200 CpS, it is practically impossible to eject for the reasons described above. In order to improve the effect of the cleaning liquid of the cleaning composition of the present invention, it is necessary to contain a liquid lubricating component as the component (c). The liquid lubricating component used in the present invention is a so-called low dryness liquid component having a boiling point of 300 ° C or more and a viscosity of 500 ° Cps or less. Specifically, it is 2 (rc is liquid and has a boiling point Silicone oils above 300 ° C, such as polyorganosiloxane oils. The component (c) does not contain so-called waxes, and specifically does not contain carnauba wax, cotton wax and other vegetable waxes. Animal waxes such as beeswax and wool wax (lanolin); mineral waxes such as lignite soil and refined floor wax; petroleum waxes such as paraffin wax, microcrystalline wax, polyethylene wax and their oxides; or synthetic waxes Etc. Because these waxes are easy to contain the returned dirt, the performance as a cleaning agent is low. In the present invention, 2 (TC) is a liquid polyorganic second oxygen used as the component (c) The alkane oil can be exemplified by the constituent units represented by the above formula (I) and formula (Γ), in which the organic group of the polyorganosiloxane oil is selected from alkyl groups having 1 to 1 carbon atom, Amine alkyl, n- (2-amine alkyl) amine alkyl, fluorenyl polyoxyethylene alkyl, alkoxy, epoxy alkyl, carboxyalkane One or more of the phenyl group and the phenyl group are preferred. In addition, in order to improve the mobility of the spherical particles, the polyorganosiloxane oil has a viscosity of 2 to 5000 cps at 25 ° C. The invention is used in the present invention Specific examples of polyorganosiloxane oils are dialkylsiloxy-17- this paper-like ^ Applicable to Chinese National Standard (CNS) A4iUS · (210X297 male if) * --- „------ pack- ----- Order 丨: ----- line (please read the notes on the back before filling in this tile) Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 415964 A7 ________B7 V. Description of the Invention (15) Alkanes , Alkyl phenyl silicone, alkyl modified silicone, alkoxy modified silicone, hydroxy modified silicone, carboxy modified silicone, epoxy modified silicone, amine modified silicone, and the like. A compound represented by the following formula (II) is particularly preferred: CH3 CH3 CHj II! CH3 (CH2) nl-Si〇- (SiO) ra-Si- (CH1) n2CH3 (Π)

! I I C H 3 C H 3 CH 3 (wherein ~ and !!:; is 〖~ 100, m represents an integer of 1 ~ 5 000). Such polyorganosiloxane oils can be used, for example, on the market under the following trade names: KF56, KF-412, KF-413, KF-414, KF50, KF53, KF54, KF56, KF994, KF995, KF9937, X22-161AS, X22-161A, X22-161B, KF8012, KF393, KF859, KF860, KF86, KF867, KF869, KF880, KF8002, KF8004, KF8005, KF858, KF864, KF865, KF868, KF_3, KF-105 X22-163A, X22-163B, X22-163C, KF-10 (H, KF1 (H, X22-169AS, X22-169B, KF-102, X22-162A, X22-162C, X22-3701E, X22-3710, X22-160AS, KF6001, KF6002, KF6003, X22-4015, KF-857, KF862, KF8001, X22-3667, X22-3939A (made by Shin-Etsu Chemical Industry Co., Ltd.), TSF-451, TSF4700, TSF4701 (Toshiba Silicone (Manufactured by a company limited by shares). The content of the component (c) in the cleaning composition of the present invention is preferably such that the above 0) component to component weight ratio (c) / (b) = 0.01 to 10, so that The ratio is more preferably from 0 to 5. Also, the cleaning composition of the present invention contains an organic solvent having a pour point of 70 to 300 ° C as a component, water and water. 50 ~ 97 weight -18- This paper size is applicable to China National Standards (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page). 17 M 415964 A7 ___ B7 V. Description of the invention (16)% 'Spherical particles as component (b) 1 to 10% by weight and polyorganic organic oxygen shuttle oil as component (c) 1 to 10% by weight The cleaning compound of the present invention preferably contains a surfactant or a polymer dispersant or a mixture thereof as the component (d). That is, in the state where the spherical particles exist alone, or Either or both of the liquid lubricating component and the organic solvent of the polyorganic sand oxygenated oil are added to the spherical particles, and any one or more selected from a surfactant and a polymer dispersant are used. It is easy to emulsify, disperse or re-disperse spherical particles in water to facilitate the preparation of β. In the cleaning composition of the present invention, the content of the surfactant is preferably 0.0000 to 5% by weight, and 0.01 to 2 Weight. / „Is better. Also, polymer dispersant The content is preferably from .0.001 to 3% by weight, and more preferably from 0.001 to 1% by weight. The surfactant used in the present invention is preferably an anionic or non-ionic surfactant. Specifically, the surfactant may be selected from alkylbenzene sulfonate, alkyl sulfonate, polyoxyalkylene ether sulfonic acid. The average bond length of one or more of the groups consisting of salts, alkyl polysaccharides, fatty acid salts, alkyd sweet and sour, anthocyanic acid alkyl esters, and polyoxyethylene ethyl esters is in carbon. The number of atoms is preferably in the range of 18. The polymer dispersant used in the present invention is made from acrylic acid and methacrylic acid (1 to 8 carbons in the burning group), itaconic acid or fumaric acid mono- or di-baking (alkane Carbon number of the group is 1 to 5), maleic anhydride, vinylidene diene, styrene, divinylbenzene, ethylene gas, vinyl acetate, ethylene acetal, propylene, butene, isobutylene, methylpentyl Olefin, butadiene, vinyl toluene, propylene, such as methacrylonitrile, acrylamine, acrylic acid, methyl acrylic acid '-19- (CNS) A4S: (210X 297 ^ il-- ~- -L --- U ------ ^ ------ ~. 玎 ------ ^ 1. (Please read the notes on the back before filling this page) 415964 Central Bureau of Standards, Ministry of Economic Affairs A7 _B7 printed by Beigong Cooperative Co., Ltd. V. Description of the invention (17) Itaconic acid, fumaric acid, rotonic acid, crotonic acid, dot-acrylic acid oxypropionic acid, acrylic acid and methacrylic acid hydroxy Alkyl esters (carbon number 6 of alkyl groups), vinylpyrrolidine and its derivatives are selected and polymerized from at least one monomer containing ethylenically unsaturated monozine. The molecules of these polymer dispersants _ The amount is preferably 100 ~ 100,000, and More preferably, it is 10,000 to 50,000, and the most preferable is 3,000 to 10,000. Furthermore, the polymer dispersant of the present invention can use the following viscosity-increasing polysaccharides ① ~ ③. ① Guar gum and locust dansheng , Quince seed gum, tare gum, carrageenan, alginic acid (or its salt), Furcellaran, frozen agar, arabinose galactan, gum arabic , Tragacanth, karaya gum, pectin, powder, xanthan gum, zankert sugar, zanfulou sugar, cadaver sugar, amber tincture Glucan, melphalan sugar, sprout pullulan, geranium gum, vilan gum, lam gum, galactomannan, uric acid (Or its salt), chondroitin sulfate (or its salt), chitin, and chitosan. ② Oxidation, methylation, carboxymethylation, hydroxyethylation, hydroxypropylation, and sulfate of the above polysaccharides , Acidified or cationized derivatives. ③ Carboxymethyl cellulose, methyl cellulose, hydroxyethyl cellulose, hydroxypropyl Vitamins, ethyl ethyl cellulose, and other water-soluble derivatives. The molecular weight of the polysaccharides from 1 to 3 above is preferably 100,000 to 1 million. The main polysaccharides are shown in the table below. I --- -· ------- Installation ------ Order ------- Line IΓ (Please read the precautions on the back before filling out this page) -20- CNS) Man 4 Wei (210X297 mm) A7 B7 V. Description of the invention (18) Numbered material name Trade name system contact 1 KdxanT Hungry Min Division ^ 2 Old Kdoogd Kyle Pleasure Division ^ &quot; 3 Filan KIA96 News Kdco) ^ Division ^ 4 掰 解 IA KIA112 Xun ^ Kdco) ^ Division '~~~ ^ 5 Guar gum GenugumCH-200 Copenhagen Manufacturing Company —'-6 hydroxypropyl dagger guar J ^ 8111 Copenhagen Manufacturing company ^ 7 Carboxymethyl via propyl gelatin Ji ^ kr8600 Seoul company 8 Cationic strips Seoul Shaa013S Silk company 'I,-9 KdgpnHV 10 GemipectinJM Copenhagen Manufacturing Company ~~ 11 Antlers GenugdWR-78 Copenhagen Manufacturing Company ^ 12 MaproLBGlac Silk Corporation ^ 13 SpinogLim 14 Germinated short spore sugar ftihilanPI-20 Lion business Weifenyou ~~~ 15 within Biohyaluro nicacid ---_ ~~~ —___ Asahi ib »is owned by i1gen Corporation ^ 16 hydroxyethyl cellulose HECDaicdSP500 Daicil Corporation 17 Carboxymethyl Paper Wisona CMC Daicd 1220 Daicel Chemical Industry Co., Ltd. If there is a weather company, please read the note ^^ on the back before writing this page). Installation. —F Line I. The Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs printed the hard surface cleaning method of the present invention. Detergent composition is a method for cleaning a hard surface on the hard surface where solid particles are present, and at the same time by removing the dirt. However, a preferred embodiment of the cleaning method of the present invention is a liquid cleaning medium containing rhenium, (b) spherical particles having an average particle size of 0.01 to 15 μm insoluble in the liquid cleaning medium, and (c) 2 0 ° C is a liquid detergent composition of polyorganosiloxane oil in liquid form. [The content of the component (b) in the composition is -21-this paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7 415964 V. Description of the invention (19) The quantity is 0.1 ~ 30 weight. /. , (B) and (c) component mixing ratio ⑹ / ⑹ (weight) · 〇 10 10, in a uniform stirring state, 20 * C viscosity of 2 ~ 500 cps, it is used in the presence of solids without prior cleaning The car body of particle dirt, meanwhile, it is a kind of cleaning method for car cars. The application method of the cleaner composition for hard surfaces of the present invention is not particularly limited, and methods such as coating with a wiping material, or spreading by spraying can be used. In the present invention, when it is clear that the hard surface is cleaned, the above-mentioned spherical particles must have a certain ratio of the fixed surface or more or the amount of dirt; the amount of clean 1 spherical particles relative to the hard surface, if the weight is 〇〇5_5 Coffee 2, or in terms of projected area, the extended projection area of spherical particles is 30 to 300% of the surface area of the hard surface, the effect will be better. 'The better is 0.2-2g / m2 when measured by weight, Or in terms of projected area, within the range of 50% to 200%, such a cleaning effect will be particularly good. The 'extended projection area' is calculated by the following method. &lt; Calculation method of extended projected area &gt; Hard surface area for cleaning a compounding amount of solid particle composition a% b The amount of the composition used for cleaning is equivalent to an average projected area of 1 g of particles * dcm2 / g, then

(Extended projected area of particles) X c X 100 m (ratio of extended projected area of particles to the area of the hard surface to be cleaned d X c X —A = —— 100 X 100 = 1 ^ 〇 / 0 bb 22- This paper Dimensions are applicable to China National Standards (CNS) 4 rules (21 OX297 mm) J -------- installed 'order. 1) line (please read the note on the back before filling this page) Printed by the Central Laboratories of the Ministry of Economic Affairs and the Consumer Cooperative Cooperative, printed by the Central Laboratories of the Ministry of Economic Affairs and printed by the Shellfish Consumer Cooperatives of the Ministry of Economic Affairs A7 ____ B7_ V. Description of the Invention _ (20) * Equivalent to the average projected area of 1 g particles d cm2 / g 'Find it with the following formula. The average particle size of the particles is e cm. The density of the particles is fg / cm3 (equivalent to the volume of 1 g of particles) = f X 1 g = fcm3 (equivalent to the volume of 1 particle) = 1 3 3 = one; re cm 6 £ is equivalent to the number of particles of 1 g ^ = — 7V ^ 6 Since (equivalent to the projected area of 1 particle) = π ($ 3 _ _ 2 2 —cm 4 2, 1 6f

λ d cm2 / g == 77ce x ~ ^ T ° 4 m 3f 2 / = —— cm Vg 2e The pH of the cleaning agent composition of the present invention is not particularly limited, and it is preferably in the range of pH = 3 ~ 12, Even better is 5 ~ Zanfanyuan. The use form of the detergent composition of the present invention is not particularly limited, and it is suitable to supply it using a trigger sprayer. The character of the cleaner composition when sprayed on the surface to be cleaned can be considered as a bubble-like "mist-like" liquid state, etc. Although it is not limited by the properties, but from the viewpoint of workability during cleaning, it is "mist-like" Or liquid. · The hard surface cleaned by the cleaning method of the present invention is not particularly limited, and examples include glass, stainless steel, artificial marble, acrylic, ABS and other plastics, metal, wood, plastic and other resin-coated or metal-plated surfaces, etc. . Specifically, it is suitable for cleaning the inside and outside walls of the residence, the floor, tatami, -23- This paper size is applicable to China National Standard (CNS) A4 specification (2 丨 0X297 mm). ----- line (please read the precautions on the back before filling this page) 415964 A7 B7 Printed by the Central Interpretation Bureau of the Ministry of Economic Affairs Shellfish Consumer Cooperatives V. Invention Description (21) Smallpox: Cleaning of roofs, kitchens, etc. Cleaning of walls, floors, around stoves, exhaust fans, etc., cleaning of sideboards, wardrobes, cupboards and other furniture, refrigerators 'TV M.,' chairs, code computers, stereos, air-conditioning, electric: stoves Machine: The cleaning of the surface of electrochemical products such as dryers and lighting appliances is used to clean the windows, doors, drinking buckles, self-decorated doors, car windows, etc., and screens and screens. , Bath when ^ ^ Luo Zhiyou floor 'walls, doors' and toilets with cleaning functions, toilets with poly insulation function, cleaning of tableware, conditioning appliances' coating surfaces of cars, trains, motorcycles, etc. Surface &amp; Cleaning, Cleaning of Automobile Tires' Exterior Entrance The surroundings, balconies, fences, fences, and gates are cleaned in four shapes, and other solid particles (hard surfaces) are present. Also, it is suitable for cleaning the car body's painted surface, plastic parts, window glass and wheels It is especially suitable for the cleaning of automobile bodies. When the present invention is implemented, various substances can be blended within the range that does not impair the purpose and effect of the present invention. These substances include, for example, perfume pigments, dyes, and tick agents. Agent 'Solubilizer, Clamping Agent, Antioxidant, Impotence' • Peripheral finishing agent, bleaching agent, viscosity reducing agent, dispersant, ultraviolet absorber, etc. If the cleaning agent composition of the present invention is used, there is a dust from home The hard surface of the solid particles and dirt of the soil and sand can be cleaned with cloth / non-woven fabric without cleaning in advance, and the amount of impregnation of the coating / dispersion or erasing material is less than 50 g per lm2 hard surface. Paper / sponge / leather / synthetic leather or the wiping material whichever comes first to wipe off the dirt, while preventing damage to hard surfaces.

Implementing your I — 1 · * The present invention can be explained in more detail by the following examples, however, the present invention is not 24-L --- r ---- 丨 --- J ---- Order ---- --- line (please read the note on the back before filling this page) This paper _ Applicable (CNS) A4 ^ (210X297 ^ «) Printed by the Central Standards Bureau of the Ministry of Economic Affairs Shellfish Consumer Cooperative A7 ______B7 V. Description of the invention ( 22> These examples are limited. Example 1 The spherical particles shown in Table 1 and the compounding ingredients shown in Table 2 were used to prepare the detergent composition of the present invention and for comparison. The compounding ingredients 1 shown in the compounding system ^ 42 and the comparative compounding systems 1 to 30 of the present invention are combined with the spherical particles related to the present invention shown in Table 1 to prepare the detergent compositions shown in Tables 7 to 10 (the rest are Water), and its damage prevention performance was evaluated by the following method. The results are shown in Tables 7 to 10. In addition, the viscosity of the detergent composition at 20ttC prepared in the same manner is shown in Tables η to 14. &lt; Wipe clean Evaluation method of time-proofing properties> A black acrylic plate was coated with a mixture of rapeseed oil: carbon black = 9: 1 (weight ratio) at lg / m2, and then dried at 60 × This acrylic sheet was further spread with a 0.01% alcohol dispersion of "7 kinds of JIS test dust particles" (manufactured by Iwamoto Minerals Co., Ltd.) at an amount of 10 g / m2, and dried at 60 ° C for 24 hours. The various detergent compositions were spread at 10 g / m2, and then a cotton towel was hung on the weight of g weight / cm2, and the dust particles for testing were completely wiped out. The above-mentioned treatment with the detergent composition Acrylic sheet and acrylic sheet treated with water only were measured at 60. The gloss (using the specular gloss measuring device described in JISZ 8741) was calculated using the following calculation formula. When (untreated pressure Gloss of acrylic sheet) (gloss when treated with water) = gw (gloss when treated with mixed solution) = scratch prevention index at 〇1) x 100 G, -Gw -25- This paper ruler is for remote use China National Standard (CNS) Α4ίλ # (210/297 male thin) I --- ^ ---- 丨 install ------- order 丨 ----- line (please read the precautions on the back first) (Fill in this page) V. Description of the invention (23) J315 β Η 13 13 Ξ 2 B11 C310 B 9

E3S B 7 A7 B7

B 5 ΰ G B 1 13 2

No. Suddenly Yan-7-

0SS Tungsten &gt;? 屮 屮 i &gt; f7ii 屮 ΒΞ &gt; νίί 屮

tsxei-T ^ Ιί ss ^ s fen # -9 ^ 3 \ Miscellaneous heat efficiency ^^ Game ¾ (Please read the precautions on the back before filling this page) Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 30

7G 76 42

2CO 45 39 41 40 35 25 43 39 33 Know: »菡: t (dy = / cm) 100 19 21 21 15 10 .97 05 38 38 P98 p§ — L ----- load ----- 1 Order ------ line ---------- ^ --- 95 100 97 95 £ 95

9G 100 100 900 100 100 97 95 38 ¾¾¾ ， 26- This paper size applies to China National Standard (CNS) A4 (2 丨 0 X: 297 mm) 415964 A7 B7 (2 V. Description of the invention (24 notes) Moore Ratio of 60/5/20/5 ⑴, molecular weight of about 100,000 55/5 / 15'5 / 10 / Crosslinking agent (diethylbenzene) 10 Xing: in the film = electron micrograph taken by a scanning electron microscope … In the film, randomly select 100 particles that are not weighted with each other and cast the image material W or the material _. Between the concentric circle with a radius of 90% and the circumscribed circle, all the shapes of the image contour are controlled. The number of those included is taken as the sphericity of the particles. The following definitions are the same.

Jt nn I-~~ I i— I! N tn ^ —1 ~~ Line (Please read the precautions on the back before filling out this page) Central Consumer Affairs Bureau, Ministry of Economic Affairs, Employees' Cooperatives, India Ben-27, this paper is ambivalent SS transfer standard (CNS) Ya 4 threats (210X297 mm) A7 B7 Five printed by the Central Bureau of Standards of the Ministry of Economic Affairs and printed by the Industrial and Commercial Cooperatives (25) Table 2 Compounding ingredients Nα Compounding ingredient names Compounding ingredients 1 Various types shown in Table 1 Spherical particle compounding component 2 Diethylene glycol monobutyl ether compounding component 3 Diethylene glycol dimethyl ether compounding component 4 Propylene glycol monomethyl ether compounding component 5 Propylene glycol monoethyl ether compounding component 6 Dipropylene glycol monomethyl ether. Compounding component 7 benzene Tris (ethylene glycol) with rhenium ingredient 8 decane, boiling point 174 ° C compounding ingredient 9. Dodecane, boiling point 21VC compounding ingredient 10 tetradecane, boiling point 250 × Γ — compounding ingredient 11 isoparaffin, boiling point 262 ° C compounding ingredient 12 Di-f-based siloxane (50cst) at 25 ° C Compounding ingredient 13 Dimethylsiloxane (100cst) 251: Compounding ingredient 14 Dimethyl dreamoxane (200 cst) 25 * C Compounding ingredient 15 Dimethylsiloxane (500cst) 25 ° C Compounding ingredient 16 Dimethylsiloxane l00〇cst25 ° C) Compound 17 Poly (diphenyl dreamoxane 'benzylmethylsilica pit' dimethyl crushed oxane) * ι Compound 18 Poly (N- (2-aminemethyl) ) Aminopropyl * methylsiloxane compounding ingredient 19 Polyethylene polydimethylsiloxane embedded copolymer '* 3 · · ---, Compounding ingredient 20 Poly (hydroxyalkylmethylsiloxane * dimethylformaldehyde) Silicone ------- Compounding ingredient 21 Dicarboxyethyl polydimethylsiloxane * 5 '-~~~~ --- Compounding ingredient 22 贰 (2,3-propylene oxide) polydimethylsiloxane Slope compounding ingredient 23 alkyl (c12.14) sodium benzene sulfonate-compounding ingredient 24 Sodium (Ci2.14) sodium sulphate ~~~~~ '^ compounding ingredient 25 carboxyalkanemonoethylammonium salt (Cu: ) ~~-Compounding ingredient 26 Carboxene monoethanolamine salt (Cl8) _ ^-Compounding ingredient 27 Alkyl (C12., 4) glucose 甞 ^ ~ Compounding ingredient 28 Polyacrylic acid ---- ~ Compounding ingredient 29 acrylic acid 'cis Butene difluorene copolymer ^ ~~ Compounding ingredient 30 poly 6 birrolidine &quot; &quot; ^ ~--28-This paper size is commonly used by China Zhou Jiazheng Standard (CNS) A4 specification (210 X 297 mm) 丨 i 丨Clothes ------ 丨 Order ------ Line (Please read the notes on the back before filling this page) A7 B 7 V. Description of the invention (26) Note) * 1: Poly (diphenylsiloxane. Phenylmethyl oxo ^ 'monomethyllithium oxygen appearance) represented by the following chemical formula (IV), phenyl / Methyl radical ratio = 2/8, refractive index is 1.480, viscosity is 1 75 cst (25 ° C), KF-54 CH3 CHj ch3 c6h5 ch3 manufactured by Shin-Etsu Chemical Co., Ltd. I 1 I! I CHa-Si-〇- CSi-〇) a- (Si-〇) b- (Si-〇) c -Si-CH3 III! I ch3 ch3 c6h5 C6Hs ch3 (IV) (a, b, c are integers of 0 or more, any of which is i or more) e * 2: Poly (NO amine ethyl) amine propyl. Methylsiloxane / dimethylsiloxane) represented by the following chemical formula (V), the amine equivalent is 6125 g / mol, refraction The rate is 1.40 'and the viscosity is 60 cst (25 ° C). It is made by Shin-Etsu Chemical Co., Ltd. kf-393 printed by CHF ch3 ch3. Ch3 IJII CH3-Si-0- (Si -0) a- (Si-0) b-Si-CH3 IIII. CH: CH3 C3Hs CH3 I NH I C2H4NH2 (V) (a is an integer of 0 or more, b is an integer of 1 or more). * 3 The polyethylene polydimethylsiloxane block copolymer represented by the following chemical formula (VI), the composition ratio of silicone / polyethylene is 98/2 (weight ratio), and the molecular weight is about 2000-29- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm)

Jn. N I n-&quot; &quot; &quot; Installation * IJ ~ ϋ Ί— n IH cable (Please read the precautions on the back before filling this page) 415964 A7 B7 V. Description of the invention (27) CH, CH3 CH3 III CH3- (CH2) a-Si- (Si-〇) b ~ Si- (CH2) a-CH; II! CH3 ch3 ch3 cvix (A = 40 ~ 50, b is an integer greater than 0). * 4: Poly (hydroxyalkylmethylsiloxane. Dimethylsiloxane) represented by the following chemical formula (VII). The viscosity is 170 cst (25 ° C) and the refractive index is 1.412.

CH3 CH: I

ch3 ch3I I

CH3-Si-〇- (Si-〇) a- (Si-O) b-S1-CH3 II i 1 CH, CH3 (CH2) c ch3l OH evil) (a / b = 40, c is an average of 30 ). * 5: Dicarboxyethyl polydimethylsiloxane is represented by the following chemical formula (VIII), the equivalent of the radical is 15,000 g / mo, the refractive index is 1.42, and the viscosity is 100 cst (25 eC). ) II II— IIJ:-Order I ~~ (please read the notes on the back before filling this page) Printed on the Consumer Cooperatives of the Central Government Bureau of the Ministry of Economic Affairs ch3 ch3 ch3 III H00CC2H4-Si- (Si-0) b-Si-C2H4C00H III CH3 CHa CH3 (Vlll) (a = 40 ~ 50, b is an integer of 0 or more). * 6 ·· The equivalent of 贰 (2,3-epoxypropyl) polydimethylsiloxane pits represented by the following chemical formula (lx) is 2790 g / mol, the refractive index is 1,409, and the viscosity is 103 cst (25eC) -30 paper size coffee t off (210X297, ^ 964964 A7 B7 V. Description of the invention (28 ch3 ch3 ch3 II I t CH2-CHCH2-Si- (Si-〇) a-Si-CH2CH—CH2 III \ / CH3 ch3 CH3 〇 \ v (IX) (a is an integer of 1 or more),-(Please read the precautions on the back before filling out this page) -s Printed by the Shellfish Consumer Cooperative of the Central Government Bureau of the Ministry of Economic Affairs- 31 This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 415864 A7 B7 V. Description of the invention. (29) Printed by the Consumer Cooperatives of the Central Government Bureau of the Ministry of Economic Affairs (次 Εί) D &gt; RJ- i 、 R ίτ ~ CJt ►— · ο «5 ca * ~ 3 σϊ tn 1 CO ro — 〇 ο ο ο ο Ο CD 〇ο Ο O 〇oo-1 1 cn NJ cn Ci on each tn Οι CJl tn tn cn 〇〇 C no tn o tn two cn tn m n &gt; tn tn ri $ cn CO i = M r〇PO f〇CO ΓΟ · &amp; &gt; · N3 to σ &gt; ro ro 〇〇fO ◦ —-Γ --- ^ 丨--- 丨 Installation --- ^ ---- Order ------ line (please read the precautions on the back before filling in this education) -32- This paper ruler is applicable to Chinese national standard (CNS &gt; A4 specification (210X297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 415964 A7 _______B7 V. Description of the invention (30) E3 S. 〇ϊ &gt; * D &gt; σ &gt; cn CO r〇ro c〇CO CO tO ro cn CO tn ro to CO Γ-3 ro r〇H * · »f— · ►— · j 1 ~ O j 〇 &gt; ~ r— · oc * oo CJ o 〇o 〇ooo-cn ro cn CO CJ &gt; cn cn Cl — »ce ◦ • Ξ 二 Γ〇CO 二 ϋί tn tn g tn fO cn fO Cv3 r〇Ca9 'm ro err CO ca ro CJ ro CO p 1—« ro o ο ω —-K — ^ ------ &quot;,玎; ------ 0 (Please read the precautions on the back before filling out this page) L ___- 33- The paper size applies to the Chinese National Standard (CNS) A4 specifications (210X297 mm) Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 415964 A7 _____B7 V. Description of the invention _ (31)

(Time θ) D &gt; Λ, η &gt; ro ro CO to ro ΓΟ μ CO c〇 二 on 二 οο 2 5 oo —: 1 ~ ο 5 S ο ο Ξ Ο ο s CJ 5 Ο s Ξ 5 a ro C * 2 Mo Cn &lt; / &gt;-^ 3 cn VI OO cn es cn 3 ΟΊ 二 cn ΓΟ at οι tn CJ υ X 〇 &gt; ΟΙ Di o cn port UT 〇a cn Ξ 3: cn g 'ΓΟ ιη ro to C ^ 3 CO a general fC cn g ΓΌ CO CO CO W ---- r ---- 丨 install -------- ^ order ------- line (please read the precautions on the back before (Fill in this page) -34- This paper size is in accordance with Chinese National Standard (CNS) A4 (210X297mm) 415964 Α7 Β7 V. Description of the invention (32) D &gt; 0 Poem S D &gt; CO ¢ £ 5 c〇oo CO CO cn coon to CO ro CO t * 0 CO to CQ s cc Ξ Ξ 5 o Ξ soo a o 5 ooso — CN3 Office CX! CT &gt; cn cn tn C, tn tn tn CJl VI Ol cn cn VT cn tJl cn tn tn cc CO, ΞII CO CJ C * 3 l ± k. CO u cn cn cn tn C ^ l cn cn VT t / &gt; 'Z 〇l &gt; Cl to ro to ro to fO 一一 t— • —— &quot; — · 1— · oo 〇g ro ro tO a— ►— · 1— · 一 — &gt; — — ··· ro c〇 to 么 — fO &lt; LP 一 CO O * — to J = »po ro oo popop CN3 ςΰ ρ ρ Ξ po -35- This paper size applies to the Chinese national standard (CNS &gt; Μpresent grid (2 丨 0X297 mm) (Please read the precautions on the back before filling out this page)-Binding-Order-Thread. 415964 A7 B7 V. Description of the Invention (33) it 0 AC D &gt; ^ Np 16 17-15 14 13 12 1G 11 22 13 18 23 19 17-(^^ 穿 ^^) (&gt; Jingcai Fei 屮) (^ 静 才 欢 ^) (^ 静 穿 ^^) (&gt; 鄯 ^ 谗 屮) (^ 静 ^ 街 ·? ') ( ^ 部 ^ 你 -f ·) (^ 铁 ^ 费 ^) (^ 静 ^ 弹 ^) (^ 静 牙 杂 ^) (^ 静 ^ 费 ^) 5 (^ Discussion ^ !! ^^)-—0- --L .----- Installation --------- Ordering (please read the precautions on the back before filling out this page) Printed by the Consumer Consumption Cooperative of the Central Echelon Bureau of the Ministry of Economic Affairs -36 -This paper size is in accordance with Chinese National Standard (CNS) A4 specifications (210 &gt; &lt; 297 mm) 5. Description of the invention (34) Α7 Β7 Printed by the Central Consumers Bureau of the Ministry of Economic Affairs, Consumer Cooperative, Zhejiang D &gt; R: ίΐ CT3 cn fa j Oi hi CO ro CO r〇οα Γ to ro tyi N3 ΓΟ ro to CS3 ΓΌ 〇CO —1 φ £ ^-«3 t—» cn c〇03 Number of added particles 0 (Γ flame-3.7 (without particles added) "-G · 5 (without Added particles) -S- 9 (without added particles) B. 5 (without added particles) 18. 2 (without added particles) IS. 4 (without added particles) 11 · 3 (without added particles) 10. 2 (without added Particles) 23. 1 (No particles added) · 8. 7 (No particles added) 1G. S) (No particles added) Π. 5 (No particles added) CF —j ςο 73. 5 —J CiO • fh -J CTi —J c «j -J CT oo Cn CO tv3 CQ. 4 GO. 7 C9, 7! En co .J» k. C3 ▲ G4. 7 Ξ 79,0 CC ce C3 o ca 〇-J OO CO c 〇es CT3 〇cr &gt; ro cn ro o G3. 0 G3. 1 cn oo CJt oa CJl DG. 7 6G. G cn O o oo ¢ 7¾ Ci CO 6L 3 S CD. 1 CT CO 〇GG. 2 G8. 8 σϊ to CV3 G4. 3 cr ςο co C4 ca CO c〇—J • CO GO c? 0〇cn C9 OO zjy 00 〇1 Ol co 03 Ol 0〇σΐ cn 〇a 58.5 54.6 OS CO 80.9 1 oo o CO 82-2 81. 0 Bl · 2 * -3 tn OJ 09 t— · o 51. 5 vt A. 51. 5 CJl • ~ · CO CO 03 o H- &gt; tn ΓΟ U1 Office ro cn ΟΙ Each Ol o • C k π »— * ro runs C3 o 47. 0 4G. D 4G- 7 runs CT &lt; 〇 丨 43 · G C7 t— ^ Jam tn 03 cn CO 〇a cn to o 03 Im · —j 77. 4- J —a -J —3 C &gt; 3 -4 to o 03 t— · tn I .-- l ·) -------- install ----- 1 order ------ line {Please read the notes on the back before filling this page) This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 415964 A7 B7 V. Description of the invention (35) Off-line consumption by the Central Standards Bureau of the Ministry of Economic Affairs Cooperative printed D &gt; Ri Sf ro ro c〇ro to to Ξ 5 5 cn 一 Ξ Ξ C3 〇d -j 87.2 0 * -J ΓΟ -j CO-~ 3 CO -J &lt; JD ΓΟ c〇 «〇CO CO cs o -Ί C5 -j ο Cn) CO '' J CO CO -j mta- tn to cn -j cs 1- Number of added particles 5 ΞΞ25259.7 〇CO CJ1 81. 8 '82. 0 81.9 | 81. 7 CD 〇81. 9 8L5 1 81.G 82. 0. SL9 1 -J ChJ c〇c〇--4 CO Ol -3 CO CD-~ 3 CO -J as CO 05 CT. C3 CO cn ►- · ~~ l t- ·-*-3 K- · -3 CO -J -〇- ^ 3 -a ro '-J ro -J -J *-&lt; T &gt; ccs pb. CT C3 crs Cn CO CJ5 CO OO CD CS CJ CO CO «3 a ο er &gt; CTi ca -4 CO C3 〇a DO CCr CO C a OO -3 tn OO -J c〇OO -4 CT C * 3-^ 3 OO cq -¾ to 〇〇CTJ 3 ce C〇-'jo ro -3 CO ro ς »OC 2 Ο Ο -3 -J 〇CD CO C3 〇CO OO ◦ CT to CC cn co to CTi ts o CO 〇〇〇o CT5 &lt; £? CO -J o CD o CTJ CO o Cl rsS 07 o to 〇c CT o 03 tn OC A CO -J c〇CO -'J o «-J c〇09 -J os • Ό CO ◦ ¢ -5 CO -J CJ &gt; 〇-J ro 'J cr &gt; 0¾ a CT CT o C5 OC o CT3 CO GG 8 cs 〇〇Q cn CO CD —3 Ci σϊ -J Ci CO CT CD -〇CS 〇〇-'J * -3 〇〇〇〇-J -J o -4 〇-o * ^ CO CO C5 C3 m CQ CO &lt; J5 o &lt; 〇C3 CO oo CS 〇CC C9 〇〇H- * 09 CO cn Ca Ό 0〇CO 〇a *-· &lt; ^ 3 CO ►- · to CO 1- * OO ro o 09-^ 3 -1 CO CO-^ ac〇Co-* 4 ςο -J CO &lt; s &gt; CO Office C3 OO -J cri • OO Ci tn Cl tn Ca »ΟΪ cn &lt; 75 C5 tn CJ a tn tn PO cn o CT &gt; £ w &lt; n C3 CJ1 CO &lt; ΓΪ · & &gt; CO cn 〇〇tn c «n 〇〇〇〇〇oe cn CO CO in CO -4 ca &lt; 〇ς» ― Ci &gt; ζ £ &gt; 〇〇〇03 OO CO ¢ 0 0〇CD OO 〇a CO OO oa O ◦ ca CO CO 〇t- OO C3 CO OO 〇CO o to cc C £) CO CO M 〇〇o CQ do 1— CC C £ &gt; C3 o ο to ς〇〇CO ςπ VI -or〇in o Ol o tn-^ 3 〇UT -J ro tn cn -J to tn-* 〇o U1 £ &gt; &gt; Ul VI -vj tjy r ~ »w tn H- · tn tn 1— -J cs 1--K- · CT5 C7J r〇Cl o CJ ΟΪ oo Cl oo to CT o tn CO CO CT 〇CO cn o 1- »CJl u? CO o &lt; 〇o C3 o CO cn o cn CO Oi to cn also CO ct Jh. cn Λκ ro ΰ? ro 57.3 cn -3 ▲ Οϊ to to CJT ro U1 CO CJ »to tn H- 03 cn 1 ~ · 09 cn h-« CO cn rs3 o oi CO tn to ts3 tn • c ^ o -J CD Office 00 · £ »-J -oo B13 CO 〇l ro tn &gt; Ck &lt; a CO 〇T oo ππ ro &lt; £ &gt; OS 〇T o to cn o »-· A o CO o ro CJl o ts3 V» -cn ro cn 03 45, 0 1 ~ * 94.6 o CO oe tn C3 c〇oo CO C7 »CO 〇a 03 tv3 OS a to 09 ro cn VI cp OO tn o 〇〇oo OO a CO OO ca 05-^ ϊ -4 -A -1 -j ci c; CJl 0 L--U __ ^ ----- installed ----- Ί order (please read the precautions on the back before filling in this page) This paper size applies to China National Standard (CNS) A4 specifications ( 210X297 mm) 415964 A7 ____B7 V. Description of the invention (36) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs-paper g: 凇 □ &gt; SI «5% Ού cr &gt; CO CJ1 CO CO CO c〇fO u CJ ΓΟ CO r〇CO Γ〇 r〇cr &gt; to CC crt OC &lt; 75 CO CO &lt; so ao o tn CO -4 c〇k— · G〇σ &gt; CO 〇 □ σι c〇〇a 〇〇C〇CT 03 03-** 4 〇0 □ «ΤΪ 〇 σ 00 »— · c〇Ci C £ &gt; ce Cl Cc OO CTJ ce C &quot; &gt; -jc〇CD CO C3 Number of particles added δ CO CD ¢ 3 ΰο CO CO CO ΰο oa CO ro C〇C5 ◦ oc〇o oa 〇〇CD OO £ &gt; CO CO 〇oe CO CO 00 CO ce £ &gt; ca ς〇o 0 〇〇〇〇〇〇〇 Ce 〇- ^ j C £ 3 〇FNi OC cn 〇03 CO Ja ^ CO Oa Office c〇Oa Office CT &gt; CO 〇〇〇ao CO 03 oo o 00 OO 0〇c〇CO 00 oe 00 01 0 CO Ca o cn 〇Cc C £ &gt; 85. 0 5 &lt; 〇o en cjy tS O cs 05 cs &lt; Λ C7S CO CT CO 05 CO σ »CO to« Ο CO Ci · £ »ro C3 CT U1 CO c« cn CO cn CO C5 CT &gt; Free O tn 96. 2 C5 -4 σ &gt; ο C3 —J o ¢ 3 '• -I C3 —3 —a CT C3 -J-^ 3 o »3 Ο cr? —3 O oa —3 CT Oa —J Cl CT Cl a Oo —J CT 〇◦ —j CT -jc: 7ϋ, 7 C = C ~ I 〇Q oo o 03 OO ro CD A 〇a 1— 〇 &gt; cc »— to 〇 a μ- to cc • b · C〇— a 〇 □ • b · C〇j *. 0 □ N— tn 00 Ce &lt; -n OC N3 CE cn c〇c = 0 c «tn 0〇00〇 二U7 o〇 such as CO oa CT CO A CO ca CQ • Cw ro ca Mod C5 CQ ifik. C5 GO 2 CJ1 o〇σ »σο GO ^ h. Rc OC · £ &gt; CT Cc Mod f〇8 Male 3 port ce ς 9 C2 oo oa &lt; n &lt; 〇 &gt; o CO &lt; 〇Ό c〇o 09 &lt; 〇03 OO &lt; 〇CD θα ¢ 0 CD c〇oo 03 ς〇cn 0〇3 CO tr &gt; 0 o〇CO CD CO 0 0 Oa 〇CO ◦ OCOC 90. 0 B3 CO h— * OC 1— c〇—j 1— -4 cn t— »tn 1— tn ►— · o —1 1—- -J 0 —J 1— * 〇〇-*-J * &gt; q -J C71 • a »es o ¢ 0 ¢ 0 O CO ◦» ~ 〇oo —3 &lt; 〇oo —Ϊ CO OO oo oc 〇 CO CO -J CO CO o ¢ 0 «0 0 ¢ 2 oa-&gt;] 0 00 00 ¢ 0 oa 00 CD CO 〇〇 &lt; £ &gt; 〇〇CO CC CO CO 0 BiO c? CO 1— cn CO o CTJ CO o σϊ TO a &gt; cr &gt; CO CO »— * ro cn cn to 0〇σ &gt; r〇CO CT Cn3 ar〇〇σ ar〇 ** q ro CO 03 ro 00 C3 to Ci M -J 63. 1 62. 7 C3 oo G5. 0 Οΐ ¢ / 1 65. 8 G5. 8 G5, 8 65.9 65. 9 o 0¾ 0 65. 9 66. 3 〇OS ro CT σϊ o 03 C3 ro 〇OT Cl cn CO CT C? Σϊ Cl to 03 fO ¢ / 1 CJ ai c〇tn ai &lt; r &gt; VI CJ »to at ¢ 7¾ CD tn ro O CJl -0 0 —3 1 ^ · nn —jp £ k. '• O CO tn UJ cn-^ 1 tn 〇57. 4 D13 tn c〇CJ1 C9 CJ1 &lt; s CJl OO £ --j VI CJ1 Κ »tn Vi fO tn Vi ►— t / l oo til Cl to &lt; JX &lt; J1 cn H— cn C / l 0 W1 • Ch ς〇CJ1 CJ1 〇ϋΐ yi K ^ &gt; tn cn VI CO BM ca ▲ tn CO ▲ CD «e ^ CD ►— · CO CO ▲ o CO C-3 to c〇 ¢ 0 • fk VT ◦ Cl &lt; s &gt; iJl CO 〇σ CO -J c〇CO • ΰ» ¢ 3 C5 tn 0Ί.8 cn 9 3 A SNC standard bid country-country I use Xο one centimeter (please read the precautions on the back before filling in this f)-equipment · V. invention description (37 A7 B7 &lt; st t ~~ * ί '

After (CPS) 0 (^^^^ +) 3 (^^ Λ-Α-? *) 5 (^^^ 律 ^) G (^^^ 货 ^) 8 (^ 静 ^ 舞 -ϊ ·) 9 (^ 静 ^ 常 ^) 4 (^ 静 都 涉 4) 1 (^^^ 1 ^^) 6 (^^^^-7-) 5 {米 节 穿 微 中} D (^ 静 穿 ^^) 0 (^^^^ 4) 1 (Jie Jing Chuan 捃 屮) 1 (^^^^^) 3 Eight ^^^^^ 5 5 (^ 静 ^ 律 ^), 1 (外 静 &quot; ^^) L (^ 静 ^ 微 ^) (Please read the precautions on the back before filling out this page]. Packing. Order printed by the Central Consumers ’Bureau of the Ministry of Economic Affairs and Consumer Cooperatives -40- This paper size applies to Chinese National Standards (CNS) A4 specification (210 X 297 mm) 415964 A7 B7 V. Description of the invention (38) Printed by the Consumers ’Cooperative of the Central Government Bureau of the Ministry of Economic Affairs

D &gt; RJ CT tn c〇ΡΌ-cn 07 cn ΟΊ ΟΊ 03 Oi CJ1 ro C3 03 cn Ο cn VI ΓΟ CO C3 C3 c〇03 CD t〇cn C3 cn &lt; J \ TO 〇tn CO ea CO CJ &gt; cjy c · »CO c: * &gt; q CO tO 〇σ CO tn a t- Cn 〇 ^ k. Q cn -4 CO o ca Ol a. c〇o C3 CH cn CO cs C3 tn C £ lo CJ1 o tn OS CO i- * CT -J oc? CT cn 〇1 cn ▲ N5 〇-a ro Ό3 CO ς CT m CO each CO r〇ro CJ1 Mod 00 01 C9 cn • 〇s CTJ o Mod ts3 o to ca π t- * o CO c ^ t CO σϊ cn CO cn CO C3 ca i- * »-· σι r〇σ &gt; CJ Mod to CO o &lt; n 03 [S3 〇tn tn o« ^ n C3 c〇cs σί Ol CO C9 CO cn tn tn ro cn OD 1-- CC • Ck c〇CJ1 ts3 CJ1 ◦ to 〇tr &gt; e〇-3 on ca ►- CJT. · F 谇 沔 ic PS) D &gt; RJ Co tO CO r 〇〇ΰ tS3 ro σ &gt; CC Cl Μ ro CO rc f〇ίΌ ΓΌ ο Oo c * &gt; o &gt; O Details O to 0 &gt; 1 〇Ί to Ca o &gt; tn /-&quot; S &gt; 馋 ο : Static tn o CO s &gt; ft cn 1-0 &gt; 谗 to c〇 &gt; &amp; W CO ΓΌ &gt; ¥ t ΟΙ • «&quot; N &gt; CO cs tn &gt; i fi ·} £ (C PS) 1 ..------- ^ ----- install ---'---- order ------ line (please read the note on the back before filling in this I) 5. Invention Instructions (39) A7 B7 Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, D &gt; R! Operation μ f \ 5 to to M (v &gt; 5 Ξ c; H- * cc &gt; 〇a CJ cn to CO CO Oo —0 —) o to PO ro ro C3 Mody era vi c * o-} cn CS3 --3 to cn CTJ 〇Λ ro t \ 3 Cn ro CF5 O to o &gt; — CO -J CO ro ¢ 3 tn es FREE-b- 掂 羿 3f η ο 〇tfi each cn ΓΌ CO CM cn c〇03 tJ &gt; -'ϊ &lt; y &gt; CO CO to CO to-^ 3 · £ »· C = &gt; Ol ro &lt; 7 »CO w 07 fO CO« 〇CJ CO CO tn c〇to 4 &amp;. — ro C = i to CJ CO fO t \ 3 -o CT C © ΐ- Ο-&gt; ϊ οι tn -^ 3 o K ^ · c〇N- · 0〇NU c〇oo 〇a Oa N- &gt; &lt; a CO C * &gt; 〇to Ln ΓΌ cn ►— * k— · σβ CO -vj ro CO CD CO ro cn ro Cl CTi Cl -J o »—» ο C7i CO oo oo c〇CT ro Ck cr &gt; K- CO Oo ta CO CO σ &gt; ro o C3 ΓΌ o Ci Co 〇CO ro vy &lt; u tn CJ cs * &gt; 3 C3 C7 &gt; C3 to tv3 〇g ji. S ►— · * · * cn C9 CO OCt o CO each C口 OO tn 0〇o tn Oi oo ro ro o tn to CO 1 ~ »o a. Cn cn &lt; 3 CO CT og CJ 03 CO CO Mod CT M fO OS C &lt; J cn Oi CJ CO &gt; — σ &gt; CO 〇o tn Oi σ &gt; CO to ro o CO CJ1 t— »ro OJ CT cn ro OS f ° cn 03 Ci ro ΓΟ ro tn-Ca to yi ¢ 7¾ ro tCk. O CO CO ro &gt; Ck ro 〇 &gt; CT 〇aoo CO to 1— »OO to CO ooo to ro CO e〇cs C3 CO tO CJ1 to -J g. σι 1— · g OO 2 tn tn ^ £ w &gt; Cx oa s ►— cn 09 cjn oa «Ji o tvS CO o CO ts3 H- * o as ¢ -3« 3 OO g CO o in CD oa C5 cn to 〇 &gt; — · ►- «o cn tn CO o CT3 0〇 ^-1— * CJ to cn CT oo a ro ro r— * βϊ each 03 tn CO (S3 CD CZJ 03 C9 s Oo ◦ «DO ro goi— to VI * -J e〇 么 CO oo O 09 〇03 a -j PO CO CJ1 00 CO COCO t— · o tn CO C £ J μ-X —J ca 〇p 〇l ς-ϊ to CJ1 CO CO c &gt; CO ca CJ CO t \ 3 s tV3 tn tO C3 0〇1— cn V »—J ot VI to CO cn N3 &lt; J5 CO ο ο ro CO each o CJ CJ t— · CO 〇3 CO oo CO F ° CJ1 Η» ο CO CO CO &gt; — »I-— o CO CO cn ►— · h— · £ &gt; »-4 Ca cr &gt; oa CJl Cji to o 〇 &gt; to 1— · &lt; jy CO cn CTi a cn t— public 〇C3 Ol C9 ro cn oa ro Q〇A -4 oo CO CO CCS two OQ CO 0¾ -q ro CO CO CO 1— · 03 ca to CO) — * »£ &gt; &gt;. cn c * 5 CO &lt; u ro to each 03 o tO ΰα ςη PO oo 07 • £ ^ ro ΓΟ CO —J CT ◦ CO ro cn o ro C * 3 m cn 'ts5-^ 1 »P- ΓΟ —1 —J r ~» CJ1 〇Ck3 o tn ΡΌ CO &amp; A ro ◦ to C〇p C9 03 CO «£ D 〇► — CJ1 OQ to ◦ Cj ^ o CO es &gt; —J 〇CO σ &gt; c〇 »Ck. Tn oo p—» oa to OO do CJ1 o MC «3 -J fO ◦ p ^. C〇U o CJ fO cu tn 1¾ 1 '---------- install ------ 丨 order 丨 ------- line (please read the notes on the back before filling this page) This paper size 逋Use China National Standard (CNS) A4 specification (2I0X297 mm) V. Description of the invention (40A7 B7 Printed and printed by employees' consumer cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 锊 Ο o CO o & J 00 C * 3 CO CT CO cn c〇hC ^ C〇CO CO to CO 〇J ro 〇ro Co ho CJ CT ΪΝ3 cn ro GO C3 tn C * 3 CTi ro r〇cn fO 02 CJ cn CO 00 ^ -3 tsi CJ ca C iS CO CO r〇c〇〇a to ro g ££> 〇CQ ro — 0 0 tS5 C ^ &gt; OO CO f〇tn ro CO ww Cn cr &gt; H— CJI cn CO H— Ci C7 are all 4 * l Dare S? Jue A 0 XJ tn v »^ Μ a CO s CO CS CO ro ΓΟ V- CO (Jl tNj fO Ci 1— · oa to CO CJ Cs3 ai CO to CO ro 1— * ro DO« £ 3 aa to -J tn Co r-3 〇oa 1 ~ ro 0¾ each CO &lt; 0 to oa s CO each to o 〇lr〇CO CO cn ro CO 1- ◦ 00 00 CT3 r〇to 0 ro &lt; = &gt; CO ◦ 0 fO 00 ca σι IO Office H— u CO i £] &gt;. ro 〇- ^ j □ 0 CO to a -A CJ CO CT C9 e〇c »0 —J 0 fsD CO C7 ΓΌ fO A CO CO ta CD o ca to to cn CO 0 ω cn c〇fO Cl ro co 〇〇 »CO-« 5 fO CO tn fO ω »3 to C3 〇CJ N3 c &gt; oa CO f〇 ¢ 0 to NJ -»CO 0 CO c» n ro CO ro VI CO oo ΓΟ &lt; 〇cs &quot; -0 C3 09 oa s CJ ro tJl Office CO CT CO tn Ξ 1— cO ►— 〇f \ 3 CO ro ro C3 s tn u 0 0 ro Cl tn ^ k. CO each ro 〇CO s ΓΌ CO ΓΟ CO to CD o • £ te o -J c? to CO O CO CO CJ tn σι ςο c〇0 ts3 1 ~ »ΓΟ C * i * -qc〇PO tN3 to 〇〇to 〇OO to CO 00 ro Co ci 0 CO • fi ^ r to cn CJ CO 0 ro 〇as PO or〇to ◦ c5 Luat \ D s-«J CO ro CO CJ1 fv? CO p ~ · cn s to CO cn two CT ts &gt; 0 C5 J &gt;. w 0 to PO CO CO £ · 0 to C3 CJ \ ΐύ 〇Q 〇CO CTJ OJ 0 ro 0 cs 0 CO tn as Ni C \ 3 CO S3 t \ 3 CO to to ts3 ca ro o each oo to cn CO 60 ςη σ &gt; ― CX &gt; CO 0 t ~ · ro CT Ck3 〇C3 cn CO oo CO ro tn &gt; f &gt;.-> &CO; «Ο CO 00 PO tn t * n CO tv3 Ca CO to CO CO &gt; ^ &gt; &gt; CO cn ►— * cn CO ro write ΓΟ CO to CO 〇ig to ΓΟ CO to CO CJl * »〇CD 〇〇ro CO to CO CO 09 Πη PC 00 t ^. * £ &gt; n ro CO 00 CO • fib cn 00 cn cn ro ro C7? R ~ * 〇CO 00 〇〇C9 C3 C3 to -vj o CO cn CO -J a ΓΟ -0 ¢ 0 CD C-] θα oo ω CO ^ h. &lt; 〇K- depleted CO ro CO oa private CO C3 CO tJl CO CT -O to CO 05 —3 each to CO £ -Π CO 〇CJ 1— CO ro s to · ro tn 0 C3 〇fO tz »ro»-* c- &gt; CO CD cn tss to -Ό σ3 CJ C9 fO ro cn CO CD H— CO GO ro m VI CO 03 ro ca Q〇Cd OO CO 00 CO ro ca —q ca CO C ^ I to ω ro to 0 c〇cn —1 to C TS Cl C = 3 CO c〇Γ〇 〇〇CO (S3 h- · CO CJ VI Office tvS H- · t- · cn CO es CO 〇to PO c〇03 S 0 0 &lt; jy &lt; 0 cn 07 0¾ CO C3 CO a male tn h— c〇CO ro IS3 C3 ¢ 3 〇 »CO CO CO &quot;« 1 C3 00 H— CO 03 CO C3 CO CO o CJ to X *. C〇VI (Ό c〇CO CA C &lt; 3 tO &gt; A &gt; · &gt;-* (s5 GO-^ 1 H—to to private o fO 〇e CO tn CJ CO fO CO a PO CO tn -v | CO s Cn Cn to σ &gt; Co (T &gt; £ · 0 0 U1 fO p ㈡ CO CO cn -o CJ ce »r〇CJ CO 〇σ cn ro r〇i \ S ·-CO cn CO -0 H— 09 00 CO fO &gt; &. ca ro CO 〇T CO tn to 01 01 «〇to VI &lt; 0 ¢ 0 ◦ r〇CJ1 PO CO cn CT · £ &gt; · ro CO *« a to H- * -vj w ㈡ Λ- to to ¢ 3 u C3 &lt; s CO cn ▲ ΓΟ σ &gt; ClS CO c〇CJ ro ΪΌ s tvi u ro a CD fO to to &lt; 0 0 ts C3 cn cn 〇〇cn 00 CJ A to ro to ro 0 CJ S3 tn I j — i L ---- I installed ------- order ------ line L (Please read the precautions on the back before filling this page) This paper size applies to Chinese national standards (CNS ) A4 specification (2I0X297 mm) 415964 A7 B7 V. Description of the invention (41 ) Example 2 The granules shown in Tables 15 to 17 and the compounding ingredients shown in Table 18 were used to prepare the cleaner composition of the present invention and for comparison. That is, the mixing ingredients 31 shown in Tables 19 to 20 in the compounding systems 1 to 37, and the spherical particles related to the present invention shown in Tables 15 to 17, or comparative particles, are prepared to prepare the cleaning agents shown in Tables 19 to 20. combination. The damage prevention performance was evaluated in the same manner as in Example 1. The results are shown in Tables 21 to 26. β I ------------------------- Order ---- line (Please read the precautions on the back before filling this page) Economy Printed by the Central Consumer Standards Bureau of the Ministry of Consumers' Cooperatives-44- This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) V. Description of the invention (42) A7 B7 Printed by the Central Standards Bureau of the Ministry of Economic Affairs Consumer Cooperatives Table 15 Average tensile diameter of the Na shape material (dyn / cm) True specific gravity True sphericity B1-1 Ball voltaic polyethylene 0.005 33 0,98 96 Comparative product Bi-2 Ball voltaic polyethylene 3 98 Inventive product Bl-3 Spherical seat polyethylene 20 20 In comparison with κ product B2, l Bulb &amp; gasification ethylene 0.005 39 1.38 96 In comparison with imitation product B2-2 Bulb particle gasification ethylene 3 93 Inventory product B2 -3 Spherical slider gasified ethylene 20 91 Comparative product B3-1 Spherical slider polyester 0.005 43 1.38 96 Comparative B3-2 Sprocket polyester _ 3 98 Clothing invention B3-3 Spherical seat polyester 20 91 Higher polymerization degree than hinged product B4-1 Spherical puller ^ 2 f Cai M (power judgment network 0,005 25 0.97 97 higher than that of school product B4-2 spherically fused strainer 2 98 The product B4 · 3 of the present invention has a high degree of polymerization of polydiphenylene 1P radicals, '20 90 than KK product B5-1, spherical puller polystyrene 0.005 35 1.05 97, compared to fake product B5-2, ball fuser polystyrene Ethylene 0.01 98 Inventive product B5-3 Spherical polystyrene 0.1 99 Inventive product B5-4 Spherical polystyrene 0.5 98 Table Inventive product B5-5 Spherical slider Zuphan 6ene 2 100 ¥ Invention Product B5-6. Ball volts framed stupid 4 100 Clothing invention B5-7 Ball volts gathering-B-10 95 The present invention B5-8 spherical blaze polystyrene-20 92 Comparative product B6-1 Ball voltaine C finely divided T base Bingkun shouting deep copolymer * 丨 0.005 40 1.10 97 better than β product B6-2 Ball voltaic Bing Hui than 55 «48 ^? Acrylic acetyl succinates "Products 0.01 100 The product B6-3 of the present invention B6-3 Allyl propionate 33 ^ B-cylinder Bakelite copolymer 1 0.1 100 The product B6-4 of the present invention Glycylic acid-rich deep-release copolymer * 1 0.5 i〇o Shenyang Riyuepin E6-5 Spherical lacquer propyl two-spot probe / T-based acrylic deep-deep copolymer 1-2 2 The present invention B6- 6 Spherical puller Propionate 63ΛΓ Base Field Copolymer * 丨 4 99 The product of the present invention BW spherical puller is reduced by two groups of cat's prop field ^ 6 # copolymer of tenyl propene * 10 96 s 11 product of the present invention B6-8 ball Fu seat 位 Kun breaking linen quilt / T-based acrylic acid ^ brand ^ brand B copolymer * 丨 20 90 ratio fake * 1: Molar ratio 60/5/20/5/10, molecular weight about 10 Wan 1 .---- rr ----- meal -------- ΪΤ ------ 0 (please read the precautions on the back before filling this page) -45- National Standards (CNS) Α4Ϊ1 (210X297 mm) Printed by the Central Standards Bureau of the Ministry of Economy, Printed by the Shellfish Consumer Cooperative, 415964 A7 __B7 V. Description of the Invention (43) Table 16 The average drawing diameter of the material of the Mα shape (&quot; m) Energy (dyn / tm) True specific gravity True sphericity B7-1 Spherical puller Jiaoqing Cup W Chong ^ ^ Gong inner touch 5W Ji Bingkun's bed affiliate total $ 2 * 0.005 41 1.15 99 than β 品 Β7-2 Spherical ί Lizi transfer of acrylic acid Bing Kun ΛΓ group two series was' ^ prison T-based propylene phenyl ethylene copolymer 3 100 This is the B7-3 globulin cross flag acrylic acid free radical 呙Broken ... Soft Methyl Propylene_Stupid Ethylene Dragon: 20 95 Than Counterfeit Β8-1 Spherical puller cross-linked tauyl propionate 0.005 39 1. 21 98 Than β product BS-2 Professional puller crosslinked methacrylate 3 100 Clothing invention product B8-3 Spherical puller crosslinked methyl Acrylic acid ester · 20 93 than product β9-1 ball m '0.005 45 1.21 92 ratio &amp; product B9-2 spherical seat 3 96 mechanical products, β9-3 ball volta 20 90 Β10-1 spherical ball Polysilsesquioxane 0.005 28 1.3 90 Comparative product B10-2 Polysilsesquioxane 3 95 Ball product Polysilsesquioxane 20 91 In comparison product B11 -1 Spherical puller polycondensation '0.005 42 1.18 98 Comparison product B11-2 Spherical puller polycondensation path 3 100 The present invention &amp; 1W Spherical puller polyfluorene iridium _ 20 99 Comparative product Β2-12-1 Spherical puller Polycarbonate (Polycarbonate Λ carbonic acid tank) 0. 005 43 U9 96 Than the product B12-2 Spherical puller «Breaking acid as (Polycarbonate 3 97 acid this product? Moon product B12-3 Ball Vola Sub: ¾ Carbonate A Ethyl Acetate) 20 91 Phantom B13-1 Spherical Lazier Silica 0.005 76 2.3 91 Phantom B13-2 Spherical Lithium Silica 3 95 This product B13-3 Ball Zirconium silicon oxide 20 94 Pseudolite Β4-14-1 Spherical fibrous porous silicon oxide 0.005 76 2.0 90 Pyramid B14-2 Spherical slider porous silica 3 91 Inventive product B14-3 Spherical slider porous Silicon oxide 20 is better than KK product B15-1 Silaz silicone resin 0.005 30 1.3 92 compared to β product B15-2 Silaz silicone resin 3 95 The product of the present invention Beta 15-3 ball voluminous silicone resin 20 91 ratio Counterfeit * 2: Mole ratio 55/5 / 丨 5/5/10 / Crosslinking agent (divinylbenzene) 10 _ 一 --- r: ------Packing ------ Order ------ line (please read the precautions on the back before filling this page) -46- This paper size is applicable to China National Standard (CNS) A4 ^ fM 210X297 mm) 415964 A7 B7 V. Description of Invention (44 ) Table 17 Average diameter (ym) surface energy (dyn / cra) of Na-form material in Lazizi. True specific gravity sphericity R1. Undetermined. Polyethylene 3 33 0. 98. 38 Acetate 3 39 1.38 42 Than product R3 Amorphous puller polyacetate 3 43 1,38 53 Than product R4 Amorphous puller Yu M Hepi Sanshen Silicone domain; (Crushed W rubber) 3 25 0. 97 85 than β product R5 amorphous puller polyphenylene Ethylene 3 35 1.05 61 Comparing product R6 Amorphous puller and two acrylic fine brand series ^ Base Lianghui for stupid ethylene copolymer 3 40 1.10 53 Comparing product R7 Amorphous puller Crosslinked diacrylate / acrylic acid / formaldehyde Methyl Propionate / T-Based Acrylic Acid / Styrene Copolymer 3 41 1.15 65 Than 12 products R8 Amorphous puller cross-linked methacrylate 3 39 L 21 57 Than fake E9 Amorphous puller Polyamine® Polytetramethylene cyanide 'hexamethylene T amine T acid -----3 45 1.21 43 Than KK' product R10 Uncle shaped polysilsesquioxane 3 28 1.3 81 Comparable product R11 Unshaped Polyacetal_: 3 42 1.18 52 Comparative product R12 Polymorph acid ester (poly double powder A breaking acid) · 3 43 1.19 38 Polymorph R13 amorphous fiber ... Silicon oxide 3 76 2.2 25 comparison product R14 1 amorphous zirconium porous silicon oxide 3 76 2.2 18 ratio β product R15 amorphous zirconium silicone resin 3 30 1.3 83 comparison standard R16 amorphous zirconium oxide 3 78 2.7 16 ratio 玟Product R17 • Unshaped bentonite 3 31 — 15 Comparative product R18 Unshaped bentonite talc 3 73 — 18 Comparing products-— .-ml ^^^ 1 Γ ^ -i I a ^ nt 1 ^ 1 (Please Read the back first Please fill in this page for the matters needing attention) Printed by the Shelling Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs * 1: Mole ratio 60/5/20/5/10, molecular weight about 100,000 * 2: Mole ratio 55/5 /丨 5/5 / 1CV cross-linking agent (divinylbenzene) 10-47-This paper size is applicable to China National Standard (CNS) A4 specifications (210 X: 297 mm) 415964 A7 B7 V. Description of the invention (45) Printed by the Central Labor Bureau of the Ministry of Economic Affairs, Consumer Cooperatives. Table 18 Compounding ingredient No. Compounding ingredient name Compounding ingredient 31 Various particle compounding ingredients shown in Table 15-17 32 Diethylene glycol monoethyl ether ... Compounding ingredient 33 Monoethylene glycol monobutyrate blending ingredient 34 Diethylene glycol dimethyl ether blending ingredient 35 26 Dioxane 6 ether blending ingredient 3S Malonase monomethyl ether blending ingredient 37 Propylene glycol monoacetate blending ingredient 38 Dioxanediol Monomethyl ether blending ingredient 39 • —Propyl alcohol 5¾ blending ingredient 40 dipropylene glycol difluorene ether blending ingredient 41 stupid (ethylene glycol) blending ingredient 42 hexane boiling point blending ingredient 43 ^ alkane boiling point 174 ° C — blending Component 44 Dodecane boiling point 2I5 * C Compound 45 Tetradecane boiling point 250X; 46 Isoparaffin boiling point 262 ° C Compounding ingredient 47 Dimethyl oxane (100cst25 ° C) Compounding ingredient 48 Dimethyl dream oxane (200cst25 ° C). Compounding ingredient 49 monomethylsiloxane (500cst25 * C) Compounding ingredient 50 Dimethylsiloxane (1000 cst25O) ′ Compounding ingredient 51 Poly (diphenyl dream pit * Phenylmethyl step oxygen pit · Dimethyl pore pit Compound 52 poly (N- (2- Aminoethyl) Aminopropyl · Pyridoxane / Dimethyloxy Pitch Mixing Ingredient 53 Polyethylene Polydimethyloxane Block Polymer, Compounding Ingredient 54 Oxygen τ dimethylsiloxy complex 55 Dicarboxyethyl polydimethylsiloxane_ One complex 56 Poly (methyl polyethylene oxide propyl · methyl attack oxygen pit / dimethyl siloxy Alkane) * 7 Compounding ingredient 57 贰 a3 · Epoxypropyl) Polydimethylsilicone Thermal compounding ingredient 58 Poly (¾ethylmethylsiloxanyl) amine P-methyl-methyl ) ** -48- The size of this paper is applicable to the Chinese national standard (CNS) Α4 (2 [0 × 297mm) ί-l H. ^ — 1- —--I-_ (Please read the notes on the back first Fill in this X) 415964 A7 ___ B7 V. Invention Ming (46) Note) * 6 - the same as in Table 2 * 1 to * 6. * 7: The poly (methyl polyoxyethylene ethoxylate. Fluorenyl oxynitride / monomethyl serotonin) represented by the following chemical formula (X) has a dryness of 320 〇8! (25. (^) , The refractive index is 1 439 ch3 ch3 ch3 ch3 I i II CH3-Si-〇- (Si-〇) a-(Si-〇) b -Si ~ CH3 (X) IIII ch3 ch3 c3h6 ch3 • (C2H4〇) c I ch3 (a = 3 ~ 10, b = 1 ~ 3, dO ~ 17) * 8: Poly (carboxyethylfluorenylsiloxane · n- (2-aminoethyl)) represented by the following chemical formula (XI) Oxygen burning of methacrylic tomb. Dioxo oxygen generation slope), viscosity is 100 cst (25 eC) 1: 1 I ht.L · ---------------------------- Order (please read the notes on the back before filling out this page) CH, CHs CH3 CH3 II by the Central Ministry of Economics and Employees 'Cooperatives. 丨' I CH3 * SiO_ (Si-0) a _ (Si_0) b ~ (Si-〇) c -Si &quot; CH3 IIII CH3 CH3 CjH6 C2H4COOH I NH I C2MH2 (a = 3 ~ 10, b = 1 ~ 3, c '3) -49- Chinese paper standard (CNS) ) A4 grid (210X297 mm) line (XI) 415964 V. Description of the invention (47) Printed by the Central Bureau of Standards of the Ministry of Economic Affairs and Consumer Cooperatives A7 B7 (Zixiaoyan Island D &gt; Rf. Cooperative Department 18 Cooperative Department 17 K-series 1G fit 15 Coordinate system 14 Coordinate system 13 Coordinate system 12 Coordinate system 11 Coordinate system ίο 1 Coordinate system g Coordinate system 7 Coordinate system GS Hehe system 5 Coordinate system 4 K Coordinate system 3 K Coordinate system 2 Coordinate system 1 ffi Taiwan system Nα 1 — · H— »~~» 1 ~ * 5 a 1— * 1 ~ 'μ— 1— Ξ CJ R; D &gt; cn CO ro tn CO two tn CJ cn tn CJ CT Cn CO tn CO cc 07 CO cc? CTF ς / 1 cn cn JX cn Mod tn cn s Cn g. CJ1 Si Ol Lan cn CJl cn cn CJl cn Cl tn tn Ol cn C / 1 «-Π cn * try cn cn tn g Cn cn CO 〇- &gt; CJ t / 1 CJl LTi O oc I *** _— ^ —------ install -------- order ------ line (please read first Please fill in this page again if you need to pay attention to this page) -50- This paper uses the Chinese National Standard (CNS &gt; A4 size (210X297mm) A7 B7 V. Description of the invention (48) Printed by the Staff Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs system

(Speaking) *: &gt; 19 ~ 20, ^ g &amp; Life &gt; Shirts &gt; Zheyang 涣 Cen Yanya (Second B) D &gt; 冏. 3 n R1 m RI R! M R! R! R! R! R; R ; F 〇 &gt; α &gt; Porch D &gt; D) &gt; Porch 0 &gt; Porch D | &gt; □ &gt; □ &gt; D &gt; D &gt; Porch D SH 淞 取 洳 ii-CO CO CO fs ro ro CJl ΕΌ ro 〇1— »1 5 1— · 〇◦» — · 5 ►w · o ¥ ~~ »—— κ— Ξ t— 5 t— * CO *»-»CO to CO c〇ω CO cn 吕 C * 1 cn tn C-Π 〇Ί t-Π On Ol TO CJ1 cn CTI (LTl CJl U1 til CJl Cn ΟΙ CJ1 S £: H ^ Cjn &lt; Ti cn &gt; Ck cc ο • Ck co cn o CJT cjl Ol &lt; JX tn CJ1 ro cn CJ1 err CO CJi tn U1 til cn CJ1 Ol CJ1 tn cn cr &gt; tn ς ^ 1 aj U1 C &quot; l CJ1 CO snf AF ικπ &gt; ^ φΝα (Please read the notes on the back before filling out this page)-Binding · Order This paper size applies to China National Standards (CNS) A4 specifications (210X297 Gongchu) -51-415964 A7 B7 V. Description of invention (49) The compound number evaluated by adding each 彳 i particle is I 2 3 4 5 6 7 8 9 10 Π 12 13 B1-1 24.0 24. B 24.4 23.1 24.3 24.5 22, 7 23.7 25.1 22.2 19.0 25.6 2B · 1 01-2 80,1 82.8 81.4 77.0 80. 9 8L B 75 · 7 79.2 83.5 73, 9 63, 5 85. 3 87.0 B1-3 23.0 29.0 28.5 26.9 23.3 28 * 6 26.5 27.7 29, 2 25, 9 22, 2 29.8 30.5 B2-1 24.7 25.5 25 · 1 217 25.0 25, 2 23, 4 24.4 25.8 22. 8 19. 6 26.3 26.9 B2-2 82.3 85.2 83.8 79, 2 83.2 R1 77.9 SL4 85.9 76. 1 65.3 87, 7 89.5 B2- 3 28.8 29.8 29.3 27.7 29. 1 29 * 4 27.2 28.5 30,1 26,6 22.8 30.7 31.3 B3- 1 23.5 24.3 23.8 22.6 23.7 24,0 22.1 23,2 24.5 21. 6 IB. 6 25. 0 25.5 B3-2 78.2 3L0 79.6 75, 2 79.1 79.9 74.0 77.4 81.6 72, 3 62, 1 83. 3 85. 1 B3-3 27.3 28.3 27, 8 26.3 27 · 7 28.0 25.9 27.1 28. 5 25 · 3 21.7 29. 1 29. 8 B4-1 26.5 27.4 26.9 25.5 26 * 8 27.0 25.0 26, 2 27.6 24.5 21.0 28.2 28.8 B4- 2 88.3 91.3 89.8 84.9 89.2 90.1 83,4 87,3 92.1 81.5 70.0 94.0 95.9 B4-3 30.9 31,9 31.4 29,7 31.2 31.5 29.2 30.5 32.2 28.5 24.5 32.9 33. e Β5Ί 28,7 29.7 29,2 27.6 29.0 29,4 27.2 28.4 30 · 0 26.5 22.8 30.6 31.3 B5-2 49.6 51.3 50, 4 47.7 50, 1 50, 7 46.9 49 · 1 51.7 45.8 39.4 52.8 53.9 B5-3 56.0 58.0 57. 0 53.9 56.6 5L2 53. 0 55.4 58. 5 51. 8 44.5 59.7 60. 9 B5-4 61.8 64.0 62 · 9 59.4 62, 5 63, 2 58.4 61 · I 64.5 57.1 49, 0 65.8 67, 2 B5-5 71; 8 74.3 73 '1 69.1 72, 6 73.4 68.0 71 · 1 75.0 66, 4 57.0 76.5 78. 1 B5-6 70.4, 72.9 71.6 67, 7 71.2 71.9 66.6 69.6 73.5 65.0 55.9 75.0 76.6 B5-7 58.9 61.0 59.9 56.7 59.6 60.2 55.7 58.3 6L5 54.5 46.8 62. 8 64.1 B5; 8 36.7 37.9 37.3 35.2 37.0 37.4 34.6 36 2 38. 2 33. 8 29. 0 39.0 39.8 B6-1 38.2 39.5 38. 8 36, 7 38, 6 39 · 0 36.1 37.8 39. 8 35. 3 30. 3 40.7 41, 5 B6-2 57.3 59. 3 58,3 55. 1 57.9 58.5 54.2 56.7 59.8 52.9 45. 4 61. 1 62.3 B6-3 65. 7 68.0 66.9 63, 2 66, 4 67. 1 62.1 65 · 0 68.6 60.7 52, 1 70.0 7L4 B6- 4 68,0 70.4 69,2 65.4 68.7 69.5 64.3 67.3 71.0 62.8 54,0 72,4 73.9 B6-5 76.4 79.0 77, 8 73.5 77.2 78. 1 72.2 75.6 79 · 7 70.6 60.6 81.4 83.1 S6-B 74.9 77.5 76 , 2 72.0 75, 7 76.5 70 · 8 74, 0 78.2 69.2 59.4 79. 8 81.4 B6-7 66, 5 68.8 67.6 63. 9 67.2 67, 9 62.9 65.8 69.3 61.4 52.7 70.8 7 ?. 3 B6-3 33.3 34.4 33.8 32.0 33.6 34.0 3L5 32.9 34,7 30.7 26.4 35.4 3G, 2 Β7Ί 23.2 24.0 23.6 22,3 23.4 23,7 21.9 22.9 24.2 21A 18,4 24.7 25.2 B7-2 77.3 80 · 0 78.7 74.4 78. 1 T9.0 73.1. 6. 5 80.7 71 · 4 61.3 82.4 84.1 1 B7-3 27.0 28.0 2T.5 26.0 27.3 27.6 25.6 26, a 28.2 25.0 21.4 28.8 29.4 B3-I 24 · a 25.7 25.3 23.9 25.1 25.4 23.5 24 · 5 25,9 22. 9 19.7 26.4 27.0 08-2 B2. 8 85.6 84, 2 79.6 83.7 84, 6 78, 3 8L9 86.4 76.5 65.7 88.2 90.0 B3-3 29 0 30. 0 29.5 27.9 29, 3 29. 6 27. 4 23. 7 30, 2 26. 7 23, 0 30, 8 31.5 B9-1 19. G 20.3 20.0 18.9 19.9 20. 1 18.6 19.4 20.5 IS. 1 15.6 20.9 21-4 B9-2 65.5 67,8 66.6 63.0 66.2 66.9 61.9 64.8 68.3 60.5 51.9 M · 7 71.2 BQ * 3 22,9 23.7 23.3 22.0 23.2 23.4 21. 6 22.7 23.9 21.2 18.2 24.4 24. D B10- 1 27 · 3 28.2 27.8 26.2 27, 6 27.9 25 · 8 27, 0 28.4 25.2 21., 29.0 29.7 7 B10-2 90.9 94, 1 92.5 87, 5 91.9 92. 9 86.0 90 · 0 94, 9 84. 1 72, 2 96. 9 98.9 B10-3 3L8 32.9 32, 4 30.6 32.2 32 · 5 30.1 3L5 33.2 29. 4 25.3 33.9 34.6 -52- This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm) *-. I nn ml I--In '一 _SJI II 1 ^ 1 (Please read the precautions on the back before filling out this page) 、 Printed by the Bayer Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy 415964 A7 A7 B7 (50) Table f Li Na Na damage index is evaluated by adding various particles 14 15 16 17 13 19 20 21 22 23 24 25 B1-1 22.4 25, 3 25, 8 25. 3 23.0 26.1 23.7 25.5 25.3 23,7 24.0 25.4 B1-2 74.8 84.4 86.1 84.4 76. 6 87.0 79.2 85.3 84.4 79.2 80,1 84,8 &amp; Bu 3 26.2 29. 5 30.1 29.5 26.8 30.4 27.7 29. 8 29.5 27.7 28. 0 29 · 7 B2-1 23.1 26.0 26.5 26.0 23.6 26.8 24.4 26.3 26.0 24.4 24.7 26.2 B2-2 76. 9 86. 8 88, 6 86. 8 78.7 89.5 8 L4 87 · 7 86.8 81.4 82, 3 87.3 B2-3 26.9 30-4 31,0 30.4 27-5 31 · 3 28.5 30.7 30.4 28.5 28. 8 30-5 B3-1 21,9 24.7 25.2 24.7 22.4 25.5 23, Z 25. 0 24.7 23.2 23.5 24.9 B3-2 73 · 1 82.5 84.2 82. 5 74. 8 85.0 77, 4 Β3. 3 82. 5 77.4 78.2 82.9 B3-3 25.6 28.9 29.5 28. 8 26.2 29.7 27. 1 29.1 28.9 27. 1 27, 4 29, 0 B4-1 24.7 27.9 28. 4 27, 9 25. 3 28.7 26. I 28.2 27.9 26, 2 26.4 23. I B4-2 82.5 93.0 94.9 93. 0 84.4 95.9 87, 3 94. 0 93.0 87.3 88.2 93.5 B4-3 28. 9 32. 6 33.2 32.5 29.5 33.6 30. 5 32.9 32.6 30. 5 30.9 32.7 B5- 1 26.9 30, 3 30. 9 30. 3 27, 5 31.2 28.4 30.6 30. 3 28.4 28.7 30, 5 B5-2 46. 3 52. 3 53.4 52. 3 47.4 53.9 49, 0 52, 8 52. 3 49.0 49. 6 52. 6 B5-3 52. 4 59.1 60. 3 59 · 1 53. 6 60-9 55.4 59.7 59. 1 55.4 56. 1 59.4 B5-4 57.8 65.2 66.5 65. 2 59.1 67.2 61.1 65.8 6 5.1 6L 1 61.8 65. 5 B5-5 67 · 1 75, 8 77.3 75. 8 68.7 78.1 71. 1 76. 5 75.8 71.1 71.9 76. 2 B5-6 65.8 74, 2 75. 8 74.2 67 · 3 76, 5 69,7 75 · 0 74,2 69.7 70.4 74. 6 B5-7 55.1 62. 1 63.4 62. 1 56.3 64.0 58,3 62,8 62.1 5B.3 5B.9 62.4 B5-8 34.2 38.7 39.4 38. 6 35 · 1 39.8 36, 2 39. 0 38, 6 36.2 36. 6 38.8 B6-1 35.7 40. 3 41.1 40. 3 36.5 41.5 37.8 40.7 40.3 37.8 38.2 40, 5 B6-2 53.5 60.4 61.7 60.4 54.8 62.3 56,7 61. 0 60.4 56.7 57. 3 60, 7 B6-3 61.4 69. 3 70.7 69.3 62. 8 71.4 65.0 70, 0 69.3 65, 0 65. 7 69.6 B6 * 4 63.6 71. 7 73, 2 71. 7 65.0 73.9 67.3 72. 4 71.7 67, 3 68. 0 72.0 B6-5 71. 4 SO. 6 82. 2 80. 5 73. 1 811 75.5 81. 4 80.6 75, 6 76.4 81,0 B6- 6 70.0 79.0 80.6 79. 0 71,6 B1.4 74,0 79.7 78.9 74,0 74.9 79.4 B6-7 62. 1 70. 1 71. 5 70. 1 G3. 6 72.2 65.7 70, 8 70. 1 65 , 7 6G.5 70.4 B6-8 31. 1 35 * 1 35.8 35, 1 31.8 36.1 32.9 35, 4 35.1 32.9 33.3 35.2 B7-1 21.7 24.5 24.9 24.4 22.2 25.2 22. 9 24.7 24.5 22, 9 23.2 24.6 B7- 2 72.3 S1.5 83.2 81.5 73.9 84 · 0 76.5 82 · 3 8L5 76.5 77.3 8L9 B7-3 25.3 28.5 29.1 28.5 25.9 29.4 26. 8 28.8 28, 5 26, 7 27, 1 28 · 7 B8-1 23.2 26.2 26 · 7 26.2 23.8 27.0 24.6 26, 5 26.2 24.5 24.8 26.3 B8-2 77.4 87. 3 89. 1 87.3 79.2 90.0 81.9 88.2 87.3 81.9 82.8 87. 7 B8-3 27.1 30. 6 31.2 30. 5 27.7 31, 5 28.6 30. 8 30.5 28.6 28, 9 30. 7 B9-1 18.4 20,7 21.1 20.7 18, Β 21.3 19.4 20.9 20.7 19.4 19.6 20.8 B9-2 61.2 69.0 TO. 4 69. 1 62, 6 71.2 64.8 69.8 69.0 64.8 65. 5 69.4 B9-3 2 \ Λ 24. 1 24.7 24.1 21.9 24.9 22. 7 24.4 24, 2 22. 6 22. 9 24.3 BUM 25.5 28.7 29.4 28.7 26, 1 29.7 27.0 29.1 28.8 27.0, 27, 3 28.9 B10-2 85.0 95.9 97.9 95, 9 '87,0 98.9 90. 0 96,9 95.9 90.0- 91. 0 96, 4 B10-3 29.7 316 34.3 33, 6 30.4 34.6 31.5 33.9 33.6 31. 5 31. 8 33, 7 f .. —ϊ-«Γ» · ΪΓ1 I '-1--- I (Please read the notes on the back before filling this page) Order _ -53- This paper size is free to use Chinese National Standard (CNS) A4 specification (210X297 mm) 415964 A7 B7 V. Description of invention (51) Central of Ministry of Economy Standard Bureau ’s Consumer Cooperatives print Razita injury prevention indexes? The system of c? Was evaluated by adding various particles. No. 26 27 28 29 30 31 32 33 | 34 1 35 | 36 37 B1-1 24,2 26,3 25,8 23.4 26.6 24,2 26.0 25,8 24,2 24.5 25.9 24.7 B1-2 80.9 87.9 86. I 78. 1 88,7 80.fi 87.0 86.1 80.8 8L7 B6.5 82.5 B1-3 28.3 30.7 30. 1 27-3 31.0 28. 2 30.4 30.1 28.3 25 .5 30.3 28.9 BZ-1 24.9 27. 1 26. 6 24. 1 27.4 24.9 26.8 26.5 24.9 25. 1 26.7 25.4 B2-2 83.2 90.4 88.5 80. 3 91.3 83. 0 89 * 4 88,5 83.0 84.0 89. 0 84.9 B2-3 29. 1 3L6 3L0 Ξ8 · 1 31.9 29.0 3L3 31.0 29 '' 29.4 31. 2 29.7 B3-1 23.7 25. S 25.2 22.9 26.0 23, 7 25.5 25.2 23.7 23. 9 25.4 24.2 B3-2 79.1 85.8 84Α 76.3 86.7 78.9 85,0 84. {78.9 79. 8 84.6 80.7 B3-3 .27.6 30-1 29.4 26.7 30. 3 27. 6 29.7 29. 4 27, 6 27. 9 29.6 28.2 B4-1 26.7 2.9. 0 28.4 25. 8 29. 3 26.7 28. 8 28, 5 26. 7 27. 0 28.6 27. 3 B4-2 89. 2 96.8 94, 9 86. 1 97. 8 89.0 95.9 94.9 89.0 90. 0 95.4 91.0 B4-3 31 · 2 33. 9 33. 2 30, 1 34 · 2 31.1 33.6 33.2 31 · 1 31.5 33.4 31.8 B5-1 29.0 31.5 30.9 28.0 3L9 29,0 31.2 30.9 29. 0 29.3 31.1 29.6 B5-2 50 · 1 54.4 53.3 48.4 55.0 50.0 53,8 53.3 50,0 50 · 5 53.6 51.1 B5-3 56.6 61. 5 60. 3 54. 7 62. 2 56.5 60 60.3 56.5 57.2 60.6 57. Β B5-4 62.4 67.8 66,5 60. 3 68.5 62.4 67. 1 66.4 62.4 63. 0 66.8 63. 7 B5-5 72.6 78.9 77. 3 70. 1 79.7 72.5 78.1 77.3 72, 5 73.3 77. 7 74 · 1 B5-6 71. 2 77.3 75. 7 68.7 78.1 71. 1 76.5 75.7 71.1 7L8 76.1 72.6 B5-7 59.5 64. T 63.4 57.5 65.3 59,5 64.0 63.3 59.4 60.1 63.7 60.7 B5-S 37.0 40.2 39.4 35.8 40.6 37.0 39, 8 39.4 37 · 0 37.4 39.6 37,8 BG-1 38.6 4L9 41.1 37.3 42,4 38. 5 41,5 41.1 38.5 39. 0 41. 3 39.4 B6-2 57.9 62,9 61. 6 55. 9 63.5 57.8 62. 2 61.6 57.8 58.4 62.0 59.1 B6-3 66.4 72.1 70, 7 64. 1 72.8 66. 3 7L4 70. 7 66.3 67.0 71.0 67, 8 B6-4 68, 7 74 · 7 73. I 66. 3 75.4 68.6 73.9 73.1 68.6 69.3 73.5 70, 1 B6-5 77.3 83.9 82.2 74.5 Β4.7 77. 1 83.0 82.2 77 · 1 77 · 9 82.6 78. 8 B6-6 75.7 Β2.2 80.5 Τ3. 1 83.0 and 5. 5 81.3 80.5 75.5 76.4 8L0 77.2 B6-7 67,2 73'0 7L5 64.9 73,7 6L 1 72,2 71.5 67.1 67. S 7L9 68.5 B6-8 33, 6 36,5 35,8 32.5 36,9 33.5 36. 1 35. 8 33.6 33.9 35.9 34.3 B7-1 23.4 25.4 24, 9 22.6 25. 7 23, 4 25. 2 24.9 23 · 4 23.6 25. 1 23.9 B7-2 78.1 84.9 83. J 75, 4 85.7 78.0 84.0 83.2 73. 0 78.9 83.6 79.7 B7-3 27.3 29.7 29. 1 26.4 30, 0 27.3 29.4 29. 1 27.3 27.6 29.2 27.9 88-1 25, 1 27.2 26, 7 24.2 27.5 25, 1 27, 0 26.7 25.0 25.3 26,8 25.6 B8-2 83. 7 90. 8 39. 0 80.8 9L8 83.5 89.9 89.0 83.5 84, 4 39.5 85.3 BS-3 29.3 31, 8 31. 2 28 · 3 32. I 29, 2 3L5 31. 2 29.2 29.5 31. 3 29.9 B9-1 19.8 21.6 21. 1 19. 1 21.8 19 · 8 2L3 21 · 1 19.8 20.0 2L2 20.2 B9-2 66. 2 71. 9 70. 4 63.9 72.6 66.1 71. 2 70.4 66 , 1 66,8 70. 8 67.5 B9-3 23. 1 25.2 24.6 22.3 25, 4 23. 1 24 · 9 24.7 23, 1 23.4 24.8 23, 6 B1CM 27.5 2 29.9 29.3 26.6 30.3 27.5 29.6 29.3 27.5 271 29: 5 28. 1 B10-2 91.9 99.9 97. Β 88. 7 99.9 91, 8 98.8 97.8 9L8 92.8 98.3 93.8 B10-3 32. 2 34. 9 34. 2 31. 1 35. 3 32. 1 34 6 34. 2 32. 1 32.5 34.4 32.8 -54- This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) I--ί ------- t ----- --IT ------ line (please (Please read the notes on the back and fill in this page) 415964 A7 B7 V. Description of the invention (52) Table 2 4 The cooperative system evaluated by adding various particles and printed by Lazi Na anti-injury index by the Central Standards Bureau of the Ministry of Economic Affairs, Shelley Consumer Cooperative_ Number 1 2 3 4 5 6 7 8 9 10 11 12 13 BI1-1 16,9 17.5 17.2 16.3 17.1 17,3 16.0 16.7 17.6 15.6 13.4 18.0 18.4 B11-2 56.4 5B.4 57.4 54.2 57.0 57.6 53.3 55,8 58.8 52.1 44.8 60.1 61.3 B11-3 19.7 20, 4 20. 1 19.0 20. 0 20.2 18.7 19.5 20.6 18, 2 15.6 21.0 21.5 B12-1 18.0 IB. 6 Ιβ.3 17.3 18.2 18-4 17.0 17.8 18.8 16.6 14.3 19, 2 19.6 B12-2 60.0 62 · 1 61,1 57.8 60,7 6L4 56.8 59.4 62.6 55.5 47.6 63.9 65.3 B12-3 21.0 21.7 21.4 20.2 2L2 21.5 19.9 20.7 21. 9 19.4 16.6 22.4 22. S B13-1 15.5 16.1 15.a 14,9 15.7 15.9 14,7 15.4 16,2 14.3】 2 · 3 16.6 16.9 BI3-2 5L8 53.7 52. Β 49.8 52.4 52.9 49.0 5L3 54,1 47.9 4L1 55.2 56,4 B13-3 18.1 18.8 18.4 17.5 18.3 18.5 17.2 17.9 18.9 16.8 UA 19.3 19. T B14-1 15.0 15.5 15.3 14.4 15.2 15.3 14.2 14.8 15.7 13.8 1L9 16.0 16.3 B14-2 50.0 51,8 50. D 48.1 50,6 5L1 47.3 49.5 52.2 46.2 39.7 53,3 54.4 B14-3 17.5] 8. 1 17.8 16.8 17.7 17.9 16.5 17.3 18.3 16.2 13.9 18.6 19.0 B15-1 26.2 27. 1 26, 6 25.2 26, 4 26, 7 24.7 25. 9 27, 3 24.2 20.8 27. 9 28.5 B15-2 87.3 90.4 88, 9 84.0 88.3 89, 2 82.6 86.4 91.1 80, 7 69, 3 93.0 94, 9 B15-3 30.5 31.6 31-1 29.4 30.9 31.2 28.9 30.2 31.9 28.2 24.2 32.6 33.2 R1 3 £ U 40.4 39,8 37.6 39.5 39-9 37,0 38.7 40.8 36.1 31.0 41.6 42.5 R2 41.1 42.6 41.9 39.6 41.6 42.0 38.9 40.7 42.9 38.0 32.6 43.8 44.8 R3 13,2 13.7 13.4 12.7 13.4 13.5 12.5 13.1 13.8 12.2 10,5 14.1 14.4 R4 44,1 45.6 44. θ 42.4 44.6 45.1 41.7 43. 6 46,0 40.8 35,0 47 · 0 48,0 R5 35.9 37 · 1 36.6 34.5 36.3 36.7 34.0 35.5 37.5 33.2 28.5 38.3 39,1 R6 38.2 39.5 38.8 36. S 38. 6 39.0 36. 1 37.8 39.9 35.3 30.3 40.7 4L5 R7 33.7 40.0 39.3 37.2 39.1 39.5 36.5 38. 2 40.3 35.7 30.7 4L2 42.0 R8 ΜΑ 42,8 42.1 39.8 41.8 42.3 39.1 40.9 43.2 3B. 2 32.8 44. 1 45.0 R9 32.7 33, 9 33.3 31.5 33.1 33.4 30.9 32.4 34.1 30.2 26.0 34.9 35 * 6 R10 45, 5 47. 1 46.3 43 .8 46.0 46.5 43.0 45.0 47, 4 42.0 36, 1 48.4 49.5 R11 28, 2 29. 1 28, 6 27.1 28.5 28.8 26.7 27.9 29.4 26.0 22.4 30.0 30.7 R12 30.0 31.0 30.5 28.9 30.3 30.7 28.4 29.7 31, 3 2L7 23.8 32.0 32.6 R13 25.9 26.8 26.3 24.9 26.2 26,5 24.5 25.6 27.0 23,9 20,5 27.6 28.2 R14 25,0 25.9 25.4 24.1 25.3 25.5 23.6 24,7 26.1 23.1 39.8 26.6 27.2 R15 43.6 45-2 44.4 42.0 44.1 446 41.3 43.2 45.6 40.3 34.6 46.5 47.5 R16 27.5 28.4 27, 9 26.4 27, 8 28.1 26.0 27.2 28.7 25, 4 21.8 25.2 29.9 R17 28.0 28.9 28.5 26.9 28.3 28.6 26.4 27, 7 29.2 25.9 22.2 29.8 30.4 R18 26.9 27.9 27.4 25.9 27. 3 27, 5 j 25. 5 26, 7 28, 1 24 · 9 21.4 28, 7 29.3 | &gt; -------- ^ ---- 丨 install ------ 丨 order ------ line (please read the precautions on the back before filling this page) -55- This paper size applies to Chinese National Standards (CNS &gt; A4 specifications (210X297 ^ cent)) Consumers' Cooperatives of the Central Procurement Bureau of the Ministry of Economic Affairs Printed 415964 A7 ____B7 V. Description of the invention (53) Table 2 5 The pull-in Nα damage prevention index was added with various particles and was evaluated as if the combination number is 14 15 16 17 18 19 20 21 22 2 3 丨 24 25 Β11-Ι 15,8 17.8 18.2 17.8 16.1 18.4 16.7 18.0 17.8 16,7 1G.9 IT. 9 Β11-2 52 · 7 59.5 60.7 59.4 54.0 61.3 55.8 60. 1 59 * 5 55.8 56 · 4 59.8 Beta 11-3 18.4 20.8 21.2 20.8 18.9 21.4 19.5 21.0 20. S 19.5 19.7 20.9 Beta 12-1 16.8 19.0 19.4 19.0 17.2 19.6 17.8 19.2 19.0 17.8 18.0 19. 1 Beta 12-2 56. 1 63. 3 64.6 63.3 57.4 65.2 59,4 63.9 63.3 59.4 60.0 63.6 Β12-3 19.6 22.1 22 · 6 22.1 20.1 22.8 20.7 22.4 22, 1 20.8 21.0 22.2 Β13-1 14,5 16.4 16.7 16,4 R9 16.9 15.4 J6.6 16,4 15.4 15,6 16. 5 Beta 13-2 48.4 54.6 55.8 54.6 49.6 56.4 51.3 55-2 54.7 51.3 51.8 54.9 Beta 13-3 16.9 19.1 19.5 19.1 17.4 19.7 17,9 19.3 19. 1 17.9 18.1 19.2 Beta 14-1 14.0 15.8 16.1 15.8 14.3 16.3 14.8 15.9 15.8 14.8 15.0 15.9 ΒΗ-2 46.8 52.7 53.8 52.8 47.8 54. 4 49.5 53.3 52. S 49 * 5 50.0 53.0 Β14-3 16.3 18.5 18.8 18.5 16.7 19.0 17.3 18.6 18-5 17.3 17.5 18.5 Β15-1 24.5 27.6 28.2 27.6 25.1 28.5 25.9 27,9 27.6 25.9 26.2 27.7 Β15-2 81 · 6 92.1 93.9 92.1 83.5 94.9 86.4 93.0 92, 1 86.4 87.3 92.5 ΒΙ5-3 28.5 32. 2 32.9 32.2 29, 2 33.2 30.2 32.5 32, 2 30, 2 30.5 32.4 R1 36.6 41, 3 42.1 41.2 37.4 42, 5 38.7 41.7 4L2 38.7 39.1 41-5 Η2 38.5 43.4 44,3 43.4 39.3 44.7 40.7 43.8 83.4 40.7 41.2 43.6 R3 12.4 13.9 14.2 13,9 12.6 14,3 13.1 14 · 1 14.0 13.1 13.2 14.0 R4 41.2 46.5 47,5 46,5 42,2 47.9 43.6 47.0 46.5 43.6 44,1 46, 7 R5 33.6 37.9 38.7 37.9 34.3 39.1 35.5 38.2 37, 9 35.5 35, 9 38,0 R6 35.7 40.3 41.1 40.3 36.5 41.5 37.8 40.7 40.3 37.8 38.2 40, 5 R7 36, 1 40 · 7 41.6 40 · 8 37.0 42.0 38 · 2 41.2 40.7 38.2 38.6 40.9 R8 38.7 43,6 44.5 43. G 39. G 45.0 40.9 44.1 43.6 40.9 ΑΙΑ 43.8 R9 30.6 34.5 35.2 34,5 31.3 35,6 32.4 34.9 34.5 32.4 32,7 34.7 R10 42.5 47.9 48.9 47.9 43.5 49.4 45.0 48.4 47.9 45.0 45.5 48-2 fill 26.3 29, 7 30.3 29.7 37.0 30.7 27 · 9 30 · 0 29.7 27 · 9 28.2 29.9 R12 28.0 31.6 32, 3 3L6 2B.7 32.6 29.7 32.0 31.6 29.7 30, 0 31.8 R13 24.2 27.3 27,9 27,3 24.8 28.2 25.6 27.6 27.3 25.6 25.9 27.4 R14 23.4 26.4 26.9 26.4 23.9 27.2 24.7 26.6 26.4 217 25,0 26 * 5 R15 40.8 46 · 0 47,0 4 6.0 41.8 47.5 43.2 46. 5 46.0 43.2 43.6 46.3 Ri6 25. 6 29.0 29.6 28.9 26.3 29, 8 27. 1 29.3 28.9 21Λ 27.4 29.1 RI7 26.2 29.5 30.1 29.5 26.7 30.4 27.7 29.8 29.5 27.7 '28 .0 29.7 R18 25.2 28.4 29,0 28.4 25.8 29.3 26,7 28.7 28.4 26,7 26,9 28.6 ---------- 1¾ .------ Γ-1T ------ ^ (Please read the note on the back first Please fill in this page again for details) -56- This paper size is applicable to Chinese Family Standards (CNS) A4 specifications (210X297mm) Five 'invention description (54) A7 B7 Printed Form of Employees' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 2 6 Pull The Ntt anti-wounding index is evaluated by adding various particles. The number is 26 27 28 29 30 31 32 33 34 35 36 37 B11-1 17.1 18.5 18.2 16.5 18.7 17.1 18.3 18.2 17,0 17.2 18.3 17,4 B11-2 57.0 61.9 60, 6 55.0 62.5 56. 9 61.3 60.6 56.9 57.5 61.0 58.2 B11-3 19.9 21.7 21,2 19.2 21.9 19.9 21.4 21.2 19, 9 20. 1 21.3 20.3 ΒΪ2-1 18.2 19.8 19.4 17,5 20.0 18.1 19.5 19.3 18.2 IS. 4 19-4 13.5 B12-2 60.7 65.9 64.6 58.6 66.5 60.6 65.2 64.5 60. 5 61.2 64.9 61.9 B12-3 2L2 23.1 22.6 20, 5 23.3 21.2 22.8 22.6 2L 2 21.4 22.7 21.7 B13-1】 5,7 17.1 16.7 15. 1 17.2 15,7 16.9 16.7 15.7 15. 9 16.8 16.0 B13-2 52.4 56.9 55,7 50 · 6 57.5 52.3 56.3 55.8 52,3 52. 9 56.0 53,4 B13-3 18.3 19.9 19.5 17.7 20.1 18.3 19.7 19.5 18. 3 18.5 19.6】 8-7 B14-1 15.1 16.5 16.1 14.6 16.6 15.1 16.3] 6 · 1 15.1】 5,3 16.2 15 · 4 B14-2 50.5 54.9 53.8 48.8 55.4 50.5 54,3 53,8 50.5 51.0 54.1 51.6 B14-3 17.7 19.2 18.8 17. 1 19,4 17.6 19.0 18,8 17.7 17.8 18.9 IS. 0 B15-1 26.4 28.7 28.1 25.6 29.1 26.4 28.4 28.2 26.4 26.7 28,3 27.0 0 B15-2 88.3 95.8 93.9 85.2 96.8 88,1 94.9 93.9 88.1 89,1 94.4 90.0 B15-3 30 33.5 32 · 9 29.8 33.9 30.8 33.2 32 · 9 30.8 31, 1 33.0 31.5 R1 39.5 42.9 42.1 38, 2 43.4 39.5 42. 5 42.1 39, 5 39.9 42.3 40.3 R2 41.6 45.2 Chem 3 40.1 45, 6 41.5 44.7 44.2 41.5 42 0 44.5 42.4 R3 13.3 14.5 14.2 12.9 14.6 13.3 14.4 14.2 13,3 13.5 14.3 13.6 R4 44-6 45.4 47.4 43.0 48.9 44,5 47.9 47.4 44.5 45. Q 47 ·? 45.5 R5 36.3 39.4 38,6 35.0 39.fi 36.2 39 · 0 38.6 36, 2 36.6 38.8 37.0 fi6 38.6 41, 9 4L1 37,3 42.4 38 .5 41.5 4L1 3δ · 5 38.9 41.3 39.4 R7 39.1 42,4 41.6 37 · T 42.9 39.0 42.0 41.5 39.0 39.4 41,8 39.8 R8 4L8 45 · 4 44.5 40.3 45.9 41.7 45,0 44.5 4L7 42.2 44,7 42.6 R9 33.1 36.0 35 · 2 31.9 36, 3 33 · 0 35.6 35.2 33.0 33.4 35.4 33, 7 RIO 46.0 49, 9 48.9 44.4 50.4 45.9 49, 4 48.9 45.9 46.4 49 · 1 45.9 Rll 28. 5 31.0 30.3 27.5 31.3 28.4 30 · 6 30.3 28.4 28.7 30.5 29.1 R12 30.3 32.9 32.2 29.3 33, 2 30.2 32.6 32, 2 30.3 30.6 32, 4 30.9 R13 26, 2 28.4 27.8 25.3 28.7 26. 1 28, 1 27.8 26. 2 26.4 28.0 26.7 R14 25.3 27,4 26 · -9 24.4 27, 7 25-2 27. 1 26. 9 25.2 Z5. 5 27.0 25, 8 R15 44.1 47.9 46.9 42.6 48.4 44.0 47.4 47.0 44. 0 44.5 47, 2 45.0 R16 27. 8 30.2 29.5 26.8 30.4 27,7 29.8 29,5 27.7 28.0 29.7 28.3 R17 28. 3 30.7 30.1 27.3 31,0 28.2 30.4 30. 1 28.2 28,5 &quot; 30.3 28.8 R18 27. 2 29.6 29.0 26. 3 29. 9 27.2 29.3 29 0 27-2 27. 5 29. 1 27.8 -57- This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 1--r .--- I Packing ------- Order- ---- ^-line (Please read the notes on the back first (Fill in this page) 415964 Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives A7 B7 V. Description of the invention (55) Example 3 Use spherical particles shown in Table 27 with the proportions shown below to modulate Table 2 8 Detergent composition shown. Table 28 shows the viscosity of this detergent composition at 20 ° C and the damage prevention index evaluated in the same manner as in Example 1. &lt; Combination composition of cleaning agents &gt; I vr I ------- installation ----- 1 order ------ line (please read the precautions on the back before filling this page) -58- particles 7.0% dimethylsilane (500 cst, 25 ° C 5.0% isoparaffin, boiling point 2625C 10.0% alkyl (c12_14) glucoside 2.0% sodium polyacrylate (molecular weight 3000) 0.5% ion exchange water balance table 27 particles No. Shape Material (l ^ ginm2) Surface Energy (φη / αη) Average Grain # (μηι) 眞 Specific Gravity. B16 Ryko High Polymerization Polydimethyl Fragment View 23 25 3 0.97 98 B17 Ryiko has half of the wealth 125 28 3 1.3 95 B18 butyl acrylate / ethylene 4〇 / 5〇 copolymer 180 36 3 1.08 100 B19 纲 i child polystyrene 400 35 2 1.05 (00 B20 立 styrene / butyl acrylate / diethylene Benzene = 70 ^ 20/10 copolymer 600 42 3 1.15 100 This paper size applies to Chinese National Standard (CNS) A4 specification (210XW7 mm) 415964 Α7 Β7 Example 4 5. Description of the invention (56) Main Λ Ο --- --- Particle number B16-B17 B18 B19 B20 Dryness (cps) 211.6 49.8 159.7 232.1 231.9 Anti-injury index 75.9 96.2 89.6 73.8 — '— .. 70.5 Using the ingredients shown in Table 29 and the ratios shown in Table μ, the cleaning composition of the present invention or for comparison shown in Table 29 is prepared. The thus obtained detergent composition has a viscosity of 2 (TC, and The scores of the cleansing power and workability evaluated by the following methods are shown in Table 29. &lt; Cleaning power evaluation method &gt; By the same method as that of the damage prevention performance evaluation method of Example 1, the same dirt (canola oil / Carbon black, 7 kinds of dust particles for JIS test) were attached to white acrylic plates of 10 cm x 20 cm in the same amount. Various detergent compositions were dispersed thereon in an amount of 10 g / m2; A 2 x 5 cm velvet towel is folded in half in the length direction, and a load of 10 g weight / m2 is hung, and wiped 3 times thoroughly and evenly. At this time, the removal rate of cold objects is divided into 5 grades according to the following criteria It is evaluated visually. Furthermore, this evaluation is repeated five times to calculate the average 値, which is the allowable score of the cleaning power of the present invention β 1: The dirt cannot be removed at all 2: The dirt is removed and not removed The area ratio is ι / 4 or more 3: The area ratio of dirt removal to unremoved is 2/4 or more 4: Loss removal The area ratio that has not been removed is 3/4 or more 5: Dirt cannot be removed at all _ -59- This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 public envy ---- I- t --..-- --- install --- * ----- order ------ line (please read the precautions on the back before filling out this page) Central Government Bureau of the Ministry of Economic Affairs Shellfish Consumer Cooperation Du printed 415964 A7- -------- B7 V. Description of the invention (57) — ^ 1 I &lt; Workability evaluation method &gt; fmx㈣black acrylic plate 'distributes the various g / m of the detergent composition core &lt; Use a 40x4om lint towel to fold it into 40%, and a group of five women of 155 165 cm in height and 45 to 50 kg in weight cleans the detergent composition completely. At this time, the workability was evaluated in 5 grades according to the following allowable price benchmark, and the average score of 5 people was taken as the workability score of the present invention. 1 · It is impossible to completely remove 2: It is heavier than when wiped with water 3: It is the same as when wiped with water 4: It is lighter than when it is wiped with water 5: It is the same as when wiped with dry ) Packing-Ordered by the Pai Gong Consumer Cooperative of the Central Procurement Bureau of the Ministry of Economics-60-This paper size applies to the Chinese National Standard (CNS) A4_ (210x297 mm) V. Description of the invention (58) A7 B7 71 ^ 7 Xue Yi · 'Viscosity (2 (TC, CPS) (Second Bi Beer) 铒. □ □ &gt; Garden Bucket // Ion Exchange Water Gelatin * 3 Polyacrylic Acid Sodium ( Molecular weight 30U0) Alkyl glucoside (Cl 2-1 4) 晷 Paraffin wax (boiling point 2f32 ° C) Ethanol-denatured polysiloxane * 2 Cyclotetrakis (dimethylsiloxane) Dimethylsiloxane Clcst, 25. .) Dimethylsiloxane (lOOcst, 25 ° C) Spherical trash '1 1— * Γ〇CO balance! I to CO CO CJT 〇►— · f〇00 One comparison school product CO t ~ · OJ CO CO cn balance 1 CO 00 P &gt; ~ ► I— · C73 Cn3 male §. cn ΟΊ po CO balance 1 CO CO CJH p »~ · ΓΟ CO 1 ~» CT5 OJ 〇〇tCte. oo 18.3 balance &lt; 〇EV CO 0 CO 00 0 Mod C? 43.2 balance 0.08 't CO ς- FREE 〇t— * 03 CT5 cjn CO on 62.8 balance 0.09 0.06 CO CO p ΓΟ CO CT CJ3 »c ^ t— * GJ oo w cr &gt; balance 0.15 0. 06 to CJ 〇CO CT CO CO CD 182.1 balance ρ &gt; CO 0. 06 CO CO p 1 ~ * · ΓΌ CO CTi CO OJ 384.3 balance ο CD S r〇CO CD CO to Ci CO ^ ~~ »r ° nCx 621.8 balance ρ &gt; σ &gt; &lt; z &gt; ο CJ5 c〇.c〇 &lt; Z &gt; c〇CO K— 〇5 \. \ rt / κ Π i-LIxgu -61-This paper size applies to China National Standard (CNS) A4 (210X297 mm)- -„—— TL; --- 丨 install -----. 丨 order ------ line (please read the precautions on the back before filling in this page) 415964 A7 、 Invention Note (59) Note) This 2 Methylpolysiloxane network polymer, spherical particles, average particle size 2μηη, elastic modulus 1 20 kg / mm2, surface energy 30 dyn / cm, specific gravity 1.3, sphericity 95, Shin-Etsu Chemical Industry KMP-590 poly (aminopropyl · fluorenylsiloxane / di Methylsiloxane), ICF-868 manufactured by Shin-Etsu Chemical Co., Ltd., KelXan HI-—WE I a ^ i— m · I (Please read the note on the back before filling out this page} Economy Ministry of Standards and Technology Bureau of the People's Republic of China Shellfish Consumer Cooperation Du Printing Pack-62- This paper Λ degree applies to Chinese national standards (CNS &gt; A4 size (210X297 mm)

Claims (1)

Section 861 Printed by the Shell Standard Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 1. A liquid cleaner composition for hard surfaces, which is suitable for hard surfaces where solid particle dirt is present, and for cleaning hard surfaces by wiping off dirt, its characteristics The liquid cleaner composition for hard surfaces contains a liquid cleaning medium selected from water, an organic solvent having a boiling point of 70 to 300 ° C, and a silicone oil having a boiling point of less than 300 ° C; and ⑹ is insoluble In the liquid cleaning medium, spherical particles having an average particle diameter of 5 μm, the content of the component (b) in the composition is from 0.1 to 30 weight. /. , And under uniform stirring, the viscosity at 20 ° C is 2 ~ 500 cps. 2. The liquid cleaner composition for hard surfaces according to item 1 of the patent application scope, which further contains a liquid lubricant component, and the compounding ratio (c) / (b) ( Gravity ratio) = 0.01 ~ 10. 3. The liquid cleaner composition for hard surface according to item 2 of the patent application, which further contains (d) a surfactant or a polymer dispersant or a mixture thereof. 4_ The detergent composition according to any one of the items 1 to 3 of the scope of the patent application, wherein the surface energy of the constituent material of the spherical particles is 60 dyn / cm or less "5. According to the items 1 to 3 of the scope of the patent application The detergent composition of any one, wherein the true specific gravity of the spherical particles is 0.5 to 2.5. 6. The detergent composition according to any one of the claims 1 to 3, wherein the elastic modulus of the spherical particles is 10 to 1000 kg / mm2. 7. The detergent composition according to any one of claims 1 to 3 in the scope of the patent application, in which the constituent material of the spherical particles is a silicone resin 'or a silicone resin composed of constituent units represented by the following formulae and (Γ) Trialkoxysilane or its partially hydrolyzed 'condensate is hydrolyzed in an aqueous solution of ammonia or amine, and the resulting polycondensation (please read the precautions on the reverse side before filling out this page) ) Α4 Specification (21〇; 7)-Application 861 Printed by the Shell Standard Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 1. A liquid cleaner composition for hard surfaces, which is suitable for hard surfaces where solid particle dirt is present, and for cleaning hard surfaces by wiping off dirt, its characteristics The liquid cleaner composition for hard surfaces contains a liquid cleaning medium selected from water, an organic solvent having a boiling point of 70 to 300 ° C, and a silicone oil having a boiling point of less than 300 ° C; and ⑹ is insoluble In the liquid cleaning medium, spherical particles having an average particle diameter of 5 μm, the content of the component (b) in the composition is from 0.1 to 30 weight. /. , And under uniform stirring, the viscosity at 20 ° C is 2 ~ 500 cps. 2. The liquid cleaner composition for hard surfaces according to item 1 of the patent application scope, which further contains a liquid lubricant component, and the compounding ratio (c) / (b) ( Gravity ratio) = 0.01 ~ 10. 3. The liquid cleaner composition for hard surface according to item 2 of the patent application, which further contains (d) a surfactant or a polymer dispersant or a mixture thereof. 4_ The detergent composition according to any one of the items 1 to 3 of the scope of the patent application, wherein the surface energy of the constituent material of the spherical particles is 60 dyn / cm or less "5. According to the items 1 to 3 of the scope of the patent application The detergent composition of any one, wherein the true specific gravity of the spherical particles is 0.5 to 2.5. 6. The detergent composition according to any one of the claims 1 to 3, wherein the elastic modulus of the spherical particles is 10 to 1000 kg / mm2. 7. The detergent composition according to any one of claims 1 to 3 in the scope of the patent application, in which the constituent material of the spherical particles is a silicone resin 'or a silicone resin composed of constituent units represented by the following formulae and (Γ) Trialkoxysilane or its partially hydrolyzed 'condensate is hydrolyzed in an aqueous solution of ammonia or amine, and the resulting polycondensation (please read the precautions on the back before filling this page) V. The paper size is applicable to the national standard (CNS ) Α4 specification (21〇; 7 monographs-415964 I .. Patent application scope Silicone silsesquioxane: A8 B8 C8 D8 —S i-(Ϊ) (Please read the precautions on the back before filling in this page) Printed by the Central Laboratories of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives (where R !, R2, and R3 show the same or different iMOOi alkyl groups, alkoxy groups, hydroxyalkyl groups, hydroxyl groups, and siloxane groups , Carboxyl, carboxyalkyl, N_ (2-aminoalkyl) amine alkyl, amine alkyl, amino 'epoxy alkyl, epoxy, methyl polyoxyethylene alkyl, hydroxy polyoxyethylene Base, methyl, base polyoxyethylene. Polyoxypropylene, hydroxypolyoxyethylene. Polyoxypropylene , Alkyl polyoxyethylene, polyethylenyloxy, phenyl or fluoroalkyl.) 8. The cleaning agent composition according to any one of claims 1 to 3, wherein the liquid cleaning medium of the rhenium component is It is water or a mixture of water and an organic solvent. 9. The detergent composition according to any one of claims 2 to 3 of the scope of application for a patent, wherein the liquid lubricating component of the hafnium component is a liquid organic polymer in a liquid state. Silicone oil. 10. The cleaning agent composition according to any one of items 1 to 3 of the scope of patent application, wherein the hard surface is the car body. CNS) A4 specification (210X297 mm) 415004 Λ8 B8 C8 D8 VI. Patent application scope '-1L type of hard surface cleaning method, which is characterized by the use of the detergent composition on page [] of the patent application scope for the presence of solid particles Hard surface of dirt 'and cleaning the hard surface by wiping off dirt a 12 ·-A method for cleaning a car body, characterized in that a liquid cleaning composition is used for the presence of solid particles without prior cleaning Dirt car The liquid cleaning composition is a detergent composition according to item 2 of the scope of patent application, and the viscosity is 2 to 500 cps under a uniform stirring state. 13. According to the scope of patent application The cleaning method according to item U or 丨 2, wherein the detergent composition is used at a ratio of spherical particles relative to the hard surface of 0.05 to 5 g / m2. According to the cleaning of the patent application park No. 11 or 丨 2 A method in which the detergent composition is used for a hard surface in an amount in which the extended projected area of all spherical particles is 30 to 300% of the surface area of the hard surface. 15. The cleaning method according to the scope of application patent No. 丨 丨 or 12, wherein a small amount of a cleaning agent composition of 50 g or less is used for each hard surface. (Please read the notes on the back before filling in this page. • IP Order Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Printed by the Shellfish Consumer Cooperatives-Sizes on Paper, Standards for I Home Countries, National Standards for Fi, 7mm 2