JPH10140353A - Cutting, tool made of surface coated cemented carbide in which hard coating layer has excellent wear resistance - Google Patents

Cutting, tool made of surface coated cemented carbide in which hard coating layer has excellent wear resistance

Info

Publication number
JPH10140353A
JPH10140353A JP30273696A JP30273696A JPH10140353A JP H10140353 A JPH10140353 A JP H10140353A JP 30273696 A JP30273696 A JP 30273696A JP 30273696 A JP30273696 A JP 30273696A JP H10140353 A JPH10140353 A JP H10140353A
Authority
JP
Japan
Prior art keywords
layer
hard coating
crystal structure
cemented carbide
coating layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP30273696A
Other languages
Japanese (ja)
Inventor
Akira Osada
晃 長田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP30273696A priority Critical patent/JPH10140353A/en
Publication of JPH10140353A publication Critical patent/JPH10140353A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide a cutting tool made of surface coated cemented carbide in which a hard coating layer has excellent wear resistance. SOLUTION: This cutting tool made of cemented carbide is the one in which the surface of a WC base cemented carbide substrate is applied with a hard coating layer contg. an Al2 O3 layer with a κ type crystal structure, e.g. composed of one or >=two kinds of Ti compound layers among a TiC layer, a TiN layer, a TiCN layer, a TiCO layer, a TiNO layer and a TiCNO layer and an Al2 O3 layer with a κ type crystal structure at 2 to 20μm average layer thickness by chemical vapor deposition and/or physical vapor deposition. In this case, the crystal structure in the cutting edge ridgeline part of the Al2 O2 layer with κ type crystal structure composing the hard coating layer is regulated to an α type by laser irradiation heating transformation or electron beam irradiation heating transformation.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】この発明は、硬質被覆層がす
ぐれた耐磨耗性を有し、したがって例えば鋼や鋳鉄の高
速切削にも長期に亘ってすぐれた切削性能を発揮する表
面被覆超硬合金製切削工具(以下、被覆超硬工具と云
う)に関するものである。
BACKGROUND OF THE INVENTION The present invention relates to a surface-coated cemented carbide in which a hard coating layer has excellent abrasion resistance, and therefore exhibits excellent cutting performance over a long period of time even for high-speed cutting of steel or cast iron, for example. The present invention relates to an alloy cutting tool (hereinafter, referred to as a coated carbide tool).

【0002】[0002]

【従来の技術】従来、一般に、例えば特公昭61−15
149号公報や特開平6−316758号公報などに記
載されるように、炭化タングステン基超硬合金基体(以
下、超硬基体という)の表面に、酸化アルミニウム(以
下、Al23 で示す)層を含む硬質被覆層、例えばT
iの炭化物(以下、TiCで示す)層、窒化物(以下、
同じくTiNで示す)層、炭窒化物(以下、TiCNで
示す)層、炭酸化物(以下、TiCOで示す)層、窒酸
化物(以下、TiNOで示す)層、および炭窒酸化物
(以下、TiCNOで示す)層からなるTi化合物層の
うちの1種または2種以上と、結晶構造がカッパー
(κ)型のAl23 層とで構成された硬質被覆層を2
〜20μmの平均層厚で化学蒸着および/または物理蒸
着してなる被覆超硬工具が知られており、またこの被覆
超硬工具が鋼や鋳鉄などの連続切削や断続切削に用いら
れていることも知られている。
2. Description of the Related Art Conventionally, generally, for example, Japanese Patent Publication No. 61-15 / 1986
As described in Japanese Patent Application Laid-Open No. 149 or JP-A-6-316758, a surface of a tungsten carbide-based cemented carbide substrate (hereinafter, referred to as a cemented carbide substrate) is coated with aluminum oxide (hereinafter, referred to as Al 2 O 3 ). Hard coating layer comprising a layer, for example T
i (hereinafter referred to as TiC) layer, nitride (hereinafter referred to as TiC)
Similarly, a layer represented by TiN), a carbonitride (hereinafter, represented by TiCN) layer, a carbonate (hereinafter, represented by TiCO) layer, a nitrided oxide (hereinafter, represented by TiNO) layer, and a carbonitride (hereinafter, represented by TiNO) A hard coating layer composed of one or two or more Ti compound layers (indicated by TiCNO) and an Al 2 O 3 layer having a kappa (κ) crystal structure.
Coated carbide tools made by chemical vapor deposition and / or physical vapor deposition with an average layer thickness of up to 20 μm are known, and the coated carbide tools are used for continuous or interrupted cutting of steel, cast iron, etc. Is also known.

【0003】[0003]

【発明が解決しようとする課題】一方、近年の切削装置
の高性能化はめざましく、かつ省力化に対する要求も強
く、これに伴い、切削加工は高速化の傾向にあるが、上
記の従来被覆超硬工具においては、これを構成する硬質
被覆層のうち、特に結晶構造がκ型のAl23層は耐
摩耗性が不十分であるために、例えば鋼や鋳鉄の高速切
削に用いた場合に摩耗進行が速く、比較的短時間で使用
寿命に至るのが現状である。
On the other hand, in recent years, the performance of cutting equipment has been remarkably improved, and there is a strong demand for labor saving. Accordingly, cutting work tends to be performed at a higher speed. In a hard tool, among the hard coating layers constituting the hard tool, the Al 2 O 3 layer having a κ-type crystal structure has insufficient wear resistance, and is used, for example, for high-speed cutting of steel or cast iron. At present, wear progresses quickly, and the service life is reached in a relatively short time.

【0004】[0004]

【課題を解決するための手段】そこで、本発明者等は、
上述のような観点から、被覆超硬工具の硬質被覆層に着
目し、これの耐摩耗性向上を図るべく研究を行った結
果、上記の従来被覆超硬工具における切刃のすくい面と
逃げ面の交わる切刃稜線部(以下、単に切刃稜線部と云
う)に、レーザーまたは電子ビームを照射して加熱し、
この部分の硬質被覆層を構成するAl23 層の結晶構
造をκ型からアルファ(α)型に変態させると、この結
果の被覆超硬工具は、特に切刃稜線部が一段とすぐれた
耐摩耗性を有するようになり、通常の条件での切削は勿
論のこと、連続切削および断続切削を高速条件で行って
も長期に亘ってすぐれた切削性能を発揮するようになる
という研究結果を得たのである。
Means for Solving the Problems Accordingly, the present inventors have
From the above viewpoint, we focused on the hard coating layer of the coated carbide tool and conducted research to improve the wear resistance of the hard coating layer. As a result, the rake face and flank face of the cutting edge in the conventional coated carbide tool described above Irradiating a laser or an electron beam to a cutting edge ridge portion (hereinafter, simply referred to as a cutting edge ridge portion) where the
When the crystal structure of the Al 2 O 3 layer constituting the hard coating layer in this portion is transformed from κ type to alpha (α) type, the resulting coated cemented carbide tool has a particularly improved cutting edge ridge line portion, which is more resistant. Research results show that it has abrasion properties and exhibits excellent cutting performance over a long period of time even when performing continuous cutting and intermittent cutting under high-speed conditions as well as cutting under normal conditions. It was.

【0005】この発明は、上記の研究結果に基づいてな
されたものであって、超硬基体の表面に、結晶構造がκ
型のAl23 層を含む硬質被覆層、例えばTiC層、
TiN層、TiCN層、TiCO層、TiNO層、およ
びTiCNO層からなるTi化合物層のうちの1種また
は2種以上と、結晶構造がκ型のAl2 3 層とで構成
された硬質被覆層を2〜20μmの平均層厚で形成して
なる被覆超硬工具において、前記硬質被覆層を構成する
結晶構造がκ型のAl23 層の切刃稜線部の結晶構造
を、レーザー照射加熱変態または電子ビーム照射加熱変
態のα型としてなる、硬質被覆層がすぐれた耐摩耗性を
有する被覆超硬工具に特徴を有するものである。
The present invention has been made on the basis of the above research results, and has a crystal structure of κ on the surface of a cemented carbide substrate.
A hard coating layer comprising an Al 2 O 3 layer of the type, for example a TiC layer,
Hard coating layer composed of one or more of Ti compound layers including TiN layer, TiCN layer, TiCO layer, TiNO layer, and TiCNO layer, and an Al 2 O 3 layer having a κ-type crystal structure Is formed with an average layer thickness of 2 to 20 μm, the crystal structure constituting the hard coating layer is the κ-type Al 2 O 3 layer, and the crystal structure of the cutting edge ridge portion is heated by laser irradiation. The present invention is characterized by a coated carbide tool having a hard coating layer having excellent abrasion resistance, which is an α-form of transformation or electron beam irradiation heating transformation.

【0006】なお、この発明の被覆超硬工具において、
硬質被覆層の平均層厚を2〜20μmとしたのは、その
層厚が2μm未満では所望のすぐれた耐摩耗性を確保す
ることができず、一方その層厚が20μmを越えると、
耐欠損性が低下するようになるという理由からである。
また、レーザー照射加熱または電子ビーム照射加熱によ
るAl23 層のκ型結晶構造からα型結晶構造への変
態は、これらの加熱手段によって切刃稜線部を1000
〜1400℃、望ましくは1100〜1300℃に加熱
することによって行われるものである。
[0006] In the coated carbide tool of the present invention,
When the average layer thickness of the hard coating layer is 2 to 20 μm, if the layer thickness is less than 2 μm, it is not possible to secure desired excellent wear resistance, while if the layer thickness exceeds 20 μm,
This is because the fracture resistance is reduced.
In addition, the transformation of the Al 2 O 3 layer from the κ-type crystal structure to the α-type crystal structure by laser irradiation heating or electron beam irradiation heating is performed by cutting the cutting edge ridge portion by 1000 by these heating means.
This is carried out by heating to 11400 ° C., preferably 1100 to 1300 ° C.

【0007】[0007]

【発明の実施の形態】つぎに、この発明の被覆超硬工具
を実施例により具体的に説明する。原料粉末として、平
均粒径:1.5μmの細粒WC粉末、同3μmの中粒W
C粉末、同1.2μmの(Ti,W)CN(重量比で、
以下同じ、TiC/TiN/WC=24/20/56)
粉末、同1.3μmの(Ta,Nb)C(TaC/Nb
C=90/10)粉末、同1μmのCr粉末、および同
1.2μmのCo粉末を用意し、これら原料粉末を表1
に示される配合組成に配合し、ボールミルで72時間湿
式混合し、乾燥した後、ISO・CNMG120408
に定める形状の圧粉体にプレス成形し、この圧粉体を同
じく表1に示される条件で真空焼結することにより超硬
基体A〜Eをそれぞれ製造した。なお、表1には、上記
超硬基体A〜Eの内部硬さ(ロックウエル硬さAスケー
ル)をそれぞれ示した。ついで、これらの超硬基体A〜
Eの表面に、ホーニングを施した状態で、通常の化学蒸
着装置を用い、表2に示される条件にて、表3に示され
る組成および平均層厚のTi化合物層およびκ型Al2
3 層を形成することにより従来被覆超硬工具1〜12
をそれぞれ製造した。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, the coated carbide tool of the present invention will be specifically described with reference to examples. As the raw material powder, fine-grained WC powder having an average particle diameter of 1.5 μm;
C powder, 1.2 μm (Ti, W) CN (by weight ratio,
Hereinafter, the same, TiC / TiN / WC = 24/20/56)
Powder, 1.3 μm of (Ta, Nb) C (TaC / Nb)
C = 90/10) powder, 1 μm Cr powder and 1.2 μm Co powder were prepared.
And wet-mixed with a ball mill for 72 hours, dried, and then subjected to ISO • CNMG120408.
Each of the compacts was press-formed into a green compact having the shape specified in Table 1, and the green compact was vacuum-sintered under the same conditions as shown in Table 1 to produce carbide substrates A to E, respectively. Table 1 shows the internal hardness (Rockwell hardness A scale) of each of the carbide substrates A to E. Next, these super-hard substrates A to
With the honing applied to the surface of E, a Ti compound layer and a κ-type Al 2 having a composition and an average thickness shown in Table 3 were obtained under the conditions shown in Table 2 using a conventional chemical vapor deposition apparatus.
By forming an O 3 layer, conventionally coated carbide tools 1 to 12
Was manufactured respectively.

【0008】さらに、上記従来被覆超硬工具1〜12の
それぞれの切刃稜線部に、以下の条件、すなわち、 種別:CO2 レーザー、 出力:20W、 送り速度:0.24m/min、 スポット径:0.3mm、 照射態様:すくい面および逃げ面の延長線上に配置した
2本の銃による照射、 の条件でのレーザー照射加熱、または、 加速電圧:40kV、 電流:100mA、 照射時間:1sec、 照射態様:切刃稜線に沿うビームパターンをすくい面側
および逃げ面側の2方向から高速偏向で照射、 の条件での電子ビーム照射加熱を行い、切刃稜線部のA
23 層の結晶構造をκ型からα型へ変態(X線回析
で確認)させることにより本発明被覆超硬工具1〜12
をそれぞれ製造した。
Further, the following conditions are applied to the cutting edge ridges of the conventional coated carbide tools 1 to 12, ie, type: CO 2 laser, output: 20 W, feed speed: 0.24 m / min, spot diameter. : 0.3 mm, Irradiation mode: Irradiation by two guns arranged on the extension of the rake face and flank, laser irradiation heating under the following conditions, or acceleration voltage: 40 kV, current: 100 mA, irradiation time: 1 sec, Irradiation mode: irradiates the beam pattern along the cutting edge ridge with high-speed deflection from two directions, the rake face side and the flank side, under the conditions of
By transforming the crystal structure of the l 2 O 3 layer from κ type to α type (confirmed by X-ray diffraction), the coated carbide tools 1 to 12 of the present invention can be obtained.
Was manufactured respectively.

【0009】つぎに、上記本発明被覆超硬工具1〜12
および従来被覆超硬工具1〜12について、 被削材:FC300(硬さ:HB 180)の丸棒、 切削速度:450m/min.、 切込み:1.5mm、 送り:0.45mm/rev、 の条件での鋳鉄の乾式連続高速高送り切削試験、並び
に、 被削材:JIS・SCM440(硬さ:HB 220)の
丸棒、 切削速度:400m/min.、 切込み:1.5mm.、 送り:0.4mm/rev、 の条件での合金鋼の乾式連続高速高送り切削試験を行
い、いずれの切削試験でも切刃の逃げ面摩耗幅が0.3
mmに至るまでの切削時間を測定した。これらの測定結
果を表4に示した。
Next, the coated carbide tools 1 to 12 according to the present invention will be described.
Work material: FC300 (hardness: HB180) round bar, Cutting speed: 450 m / min. , Depth of cut: 1.5 mm, feed: 0.45 mm / rev, dry continuous high-speed high-feed cutting test of cast iron, and work material: JIS SCM440 (hardness: HB220) round bar, cutting Speed: 400 m / min. Infeed: 1.5 mm. , Feed: 0.4mm / rev, A dry continuous high-speed high-feed cutting test of alloy steel was performed under the following conditions, and the flank wear width of the cutting edge was 0.3 in all cutting tests.
The cutting time to mm was measured. Table 4 shows the results of these measurements.

【0010】[0010]

【表1】 [Table 1]

【0011】[0011]

【表2】 [Table 2]

【0012】[0012]

【表3】 [Table 3]

【0013】[0013]

【表4】 [Table 4]

【0014】[0014]

【発明の効果】表4に示される結果から、硬質被覆層に
おけるAl2 3 層の切刃稜線部の結晶構造をκ型から
α型へ部分変態させてなる本発明被覆超硬工具1〜12
は、Al2 3 層の全体がκ型結晶構造を有する従来被
覆超硬工具1〜12に比して、苛酷な切削条件となる鋳
鉄および鋼の高速高送り切削ですぐれた耐摩耗性を示
し、長期に亘ってすぐれた切削性能を発揮することが明
らかである。上述のように、この発明の被覆超硬工具
は、これを構成する硬質被覆層がすぐれた耐摩耗性を示
すので、鋼や鋳鉄などの通常の条件での連続切削や断続
切削は勿論のこと、高速切削などの苛酷な条件での切削
に用いた場合にも、長期に亘ってすぐれた切削性能を発
揮するものであり、したがって切削装置の高性能化に十
分に対応でき、かつ省力化にも寄与するものである。
From the results shown in Table 4, it can be seen that the coated carbide tools of the present invention obtained by partially transforming the crystal structure of the cutting edge ridge of the Al 2 O 3 layer in the hard coating layer from κ-type to α-type. 12
Is superior to conventional coated carbide tools 1 to 12 in which the entire Al 2 O 3 layer has a κ-type crystal structure, and has excellent wear resistance in high-speed high-feed cutting of cast iron and steel, which is a severe cutting condition. It is evident that it exhibits excellent cutting performance over a long period of time. As described above, in the coated cemented carbide tool of the present invention, the hard coating layer constituting the coated carbide tool exhibits excellent wear resistance, so that not only continuous cutting and interrupted cutting under ordinary conditions such as steel or cast iron, but also Even when used in severe conditions such as high-speed cutting, it exhibits excellent cutting performance over a long period of time, and therefore can sufficiently cope with the high performance of cutting equipment and save labor. Also contribute.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 炭化タングステン基超硬合金基体の表面
に、結晶構造がカッパー型の酸化アルミニウム層を含む
硬質被覆層を2〜20μmの平均層厚で化学蒸着および
/または物理蒸着してなる表面被覆超硬合金製切削工具
において、 前記硬質被覆層を構成する結晶構造がカッパー型の酸化
アルミニウム層のうちの切刃のすくい面と逃げ面の交わ
る切刃稜線部の結晶構造を、レーザー照射加熱変態また
は電子ビーム照射加熱変態のアルファ型としたことを特
徴とする硬質被覆層がすぐれた耐摩耗性を有する表面被
覆超硬合金製切削工具。
1. A surface formed by chemical vapor deposition and / or physical vapor deposition of a hard coating layer including a copper-type aluminum oxide layer having a crystal structure with an average thickness of 2 to 20 μm on the surface of a tungsten carbide-based cemented carbide substrate. In the coated cemented carbide cutting tool, the crystal structure constituting the hard coating layer is formed by laser irradiation heating of the crystal structure at the cutting edge ridge portion where the rake face and flank of the cutting edge of the copper type aluminum oxide layer intersect. A cutting tool made of a surface-coated cemented carbide having a hard coating layer having excellent wear resistance, wherein the cutting tool is of an alpha type of transformation or electron beam irradiation heating transformation.
【請求項2】 炭化タングステン基超硬合金基体の表面
に、Tiの炭化物層、窒化物層、炭窒化物層、炭酸化物
層、窒酸化物層、および炭窒酸化物層からなるTi化合
物層のうちの1種または2種以上と、結晶構造がカッパ
ー型の酸化アルミニウム層とで構成された硬質被覆層を
2〜20μmの平均層厚で化学蒸着および/または物理
蒸着してなる表面被覆超硬合金製切削工具において、 前記硬質被覆層を構成する結晶構造がカッパー型の酸化
アルミニウム層のうちの切刃のすくい面と逃げ面の交わ
る切刃稜線部の結晶構造を、レーザー照射加熱変態また
は電子ビーム照射加熱変態のアルファ型としたことを特
徴とする硬質被覆層がすぐれた耐摩耗性を有する表面被
覆超硬合金製切削工具。
2. A Ti compound layer comprising a Ti carbide layer, a nitride layer, a carbonitride layer, a carbonate layer, a carbonitride layer, and a carbonitride layer on a surface of a tungsten carbide-based cemented carbide substrate. Surface coating obtained by chemical vapor deposition and / or physical vapor deposition of a hard coating layer composed of one or more of the above and a copper-type aluminum oxide layer with an average layer thickness of 2 to 20 μm. In a hard alloy cutting tool, the crystal structure constituting the hard coating layer is the crystal structure of the cutting edge ridge portion where the rake face and flank of the cutting edge of the copper-type aluminum oxide layer intersect, laser irradiation heating transformation or A cutting tool made of a surface-coated cemented carbide having excellent wear resistance, characterized in that the hard coating layer is of an alpha type of electron beam irradiation heating transformation.
JP30273696A 1996-11-14 1996-11-14 Cutting, tool made of surface coated cemented carbide in which hard coating layer has excellent wear resistance Pending JPH10140353A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP30273696A JPH10140353A (en) 1996-11-14 1996-11-14 Cutting, tool made of surface coated cemented carbide in which hard coating layer has excellent wear resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP30273696A JPH10140353A (en) 1996-11-14 1996-11-14 Cutting, tool made of surface coated cemented carbide in which hard coating layer has excellent wear resistance

Publications (1)

Publication Number Publication Date
JPH10140353A true JPH10140353A (en) 1998-05-26

Family

ID=17912543

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Country Link
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