JPH09507504A - ビススチリル化合物をベースとする増白剤混合物 - Google Patents
ビススチリル化合物をベースとする増白剤混合物Info
- Publication number
- JPH09507504A JPH09507504A JP7508943A JP50894395A JPH09507504A JP H09507504 A JPH09507504 A JP H09507504A JP 7508943 A JP7508943 A JP 7508943A JP 50894395 A JP50894395 A JP 50894395A JP H09507504 A JPH09507504 A JP H09507504A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- brightener
- bisstyryl
- mixture
- formulas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 55
- 150000001875 compounds Chemical class 0.000 title claims abstract description 21
- 238000009472 formulation Methods 0.000 claims abstract description 13
- 230000003287 optical effect Effects 0.000 claims abstract description 5
- 238000005282 brightening Methods 0.000 claims abstract description 4
- 239000000126 substance Substances 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 230000002087 whitening effect Effects 0.000 abstract description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- HVAMZGADVCBITI-UHFFFAOYSA-N pent-4-enoic acid Chemical compound OC(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-N 0.000 description 3
- SUBJHSREKVAVAR-UHFFFAOYSA-N sodium;methanol;methanolate Chemical compound [Na+].OC.[O-]C SUBJHSREKVAVAR-UHFFFAOYSA-N 0.000 description 3
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 3
- MFXWOYIWKNJHPC-UHFFFAOYSA-N 4-(diethoxyphosphorylmethyl)benzonitrile Chemical compound CCOP(=O)(OCC)CC1=CC=C(C#N)C=C1 MFXWOYIWKNJHPC-UHFFFAOYSA-N 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- HTSGKJQDMSTCGS-UHFFFAOYSA-N 1,4-bis(4-chlorophenyl)-2-(4-methylphenyl)sulfonylbutane-1,4-dione Chemical compound C1=CC(C)=CC=C1S(=O)(=O)C(C(=O)C=1C=CC(Cl)=CC=1)CC(=O)C1=CC=C(Cl)C=C1 HTSGKJQDMSTCGS-UHFFFAOYSA-N 0.000 description 1
- YDFXKRLGZYFXOE-UHFFFAOYSA-N 2-(diethoxyphosphorylmethyl)benzonitrile Chemical compound CCOP(=O)(OCC)CC1=CC=CC=C1C#N YDFXKRLGZYFXOE-UHFFFAOYSA-N 0.000 description 1
- ZPUYDPWWJCNLFT-UHFFFAOYSA-N 3-(diethoxyphosphorylmethyl)benzonitrile Chemical compound CCOP(=O)(OCC)CC1=CC=CC(C#N)=C1 ZPUYDPWWJCNLFT-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241000700159 Rattus Species 0.000 description 1
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- -1 alkyl cyanophosphonate Chemical compound 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- KVBGVZZKJNLNJU-UHFFFAOYSA-N naphthalene-2-sulfonic acid Chemical compound C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 KVBGVZZKJNLNJU-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/315—Compounds containing carbon-to-nitrogen triple bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C255/50—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings
- C07C255/51—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings containing at least two cyano groups bound to the carbon skeleton
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/614—Optical bleaching or brightening in aqueous solvents
- D06L4/636—Optical bleaching or brightening in aqueous solvents with disperse brighteners
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/65—Optical bleaching or brightening with mixtures of optical brighteners
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Detergent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Paper (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4330968A DE4330968A1 (de) | 1993-09-13 | 1993-09-13 | Aufhellermischungen auf Basis von Bisstyrylverbindungen |
| DE4330968.2 | 1993-09-13 | ||
| PCT/EP1994/002914 WO1995008017A1 (de) | 1993-09-13 | 1994-09-02 | Aufhellermischungen auf basis von bisstyrylverbindungen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH09507504A true JPH09507504A (ja) | 1997-07-29 |
Family
ID=6497547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7508943A Pending JPH09507504A (ja) | 1993-09-13 | 1994-09-02 | ビススチリル化合物をベースとする増白剤混合物 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5695686A (enExample) |
| EP (1) | EP0719356B1 (enExample) |
| JP (1) | JPH09507504A (enExample) |
| KR (1) | KR100317187B1 (enExample) |
| CN (1) | CN1119451C (enExample) |
| AU (1) | AU7693394A (enExample) |
| DE (2) | DE4330968A1 (enExample) |
| ES (1) | ES2114223T3 (enExample) |
| TW (1) | TW283155B (enExample) |
| WO (1) | WO1995008017A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003513111A (ja) * | 1999-10-25 | 2003-04-08 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | 蛍光増白剤混合物 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4426004A1 (de) * | 1994-07-22 | 1996-01-25 | Basf Ag | Verfahren zum optischen Aufhellen von Polyamiden |
| KR20010101802A (ko) * | 1999-02-11 | 2001-11-14 | 에프. 아. 프라저, 에른스트 알테르 (에. 알테르), 한스 페터 비틀린 (하. 페. 비틀린), 피. 랍 보프, 브이. 스펜글러, 페. 아에글러 | 비스-스티릴비페닐 화합물 |
| TWI255304B (en) * | 1999-09-06 | 2006-05-21 | Ciba Sc Holding Ag | Mixtures of fluorescent whitening agents |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1415977A (fr) * | 1963-10-31 | 1965-10-29 | Basf Ag | Procédé pour l'azurage optique de matériaux en polyesters et en polyamides synthétiques |
| DE2929599A1 (de) * | 1979-07-21 | 1981-02-05 | Hoechst Ag | Mischungen von optischen aufhellern, deren herstellung und verwendung |
| DE3070041D1 (en) * | 1979-12-13 | 1985-03-07 | Ciba Geigy Ag | Optical brighteners from bistyryl benzene, process for their preparation and their use |
| US4778622A (en) * | 1986-03-21 | 1988-10-18 | Ciba-Geigy Corporation | Mixtures of fluorescent whitening agents |
| CH671956A5 (enExample) * | 1987-01-29 | 1989-10-13 | Ciba Geigy Ag | |
| EP0321393B1 (de) * | 1987-11-27 | 1993-02-17 | Ciba-Geigy Ag | Aufhellerdispersion |
-
1993
- 1993-09-13 DE DE4330968A patent/DE4330968A1/de not_active Withdrawn
-
1994
- 1994-09-02 AU AU76933/94A patent/AU7693394A/en not_active Abandoned
- 1994-09-02 ES ES94927538T patent/ES2114223T3/es not_active Expired - Lifetime
- 1994-09-02 DE DE59405658T patent/DE59405658D1/de not_active Expired - Lifetime
- 1994-09-02 JP JP7508943A patent/JPH09507504A/ja active Pending
- 1994-09-02 US US08/605,076 patent/US5695686A/en not_active Expired - Fee Related
- 1994-09-02 WO PCT/EP1994/002914 patent/WO1995008017A1/de not_active Ceased
- 1994-09-02 EP EP94927538A patent/EP0719356B1/de not_active Expired - Lifetime
- 1994-09-02 KR KR1019960701262A patent/KR100317187B1/ko not_active Expired - Fee Related
- 1994-09-02 CN CN94193895A patent/CN1119451C/zh not_active Expired - Fee Related
- 1994-09-03 TW TW083108126A patent/TW283155B/zh not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003513111A (ja) * | 1999-10-25 | 2003-04-08 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | 蛍光増白剤混合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW283155B (enExample) | 1996-08-11 |
| WO1995008017A1 (de) | 1995-03-23 |
| AU7693394A (en) | 1995-04-03 |
| US5695686A (en) | 1997-12-09 |
| DE4330968A1 (de) | 1995-03-16 |
| KR960705101A (ko) | 1996-10-09 |
| EP0719356A1 (de) | 1996-07-03 |
| KR100317187B1 (ko) | 2002-02-19 |
| CN1150828A (zh) | 1997-05-28 |
| EP0719356B1 (de) | 1998-04-08 |
| CN1119451C (zh) | 2003-08-27 |
| DE59405658D1 (de) | 1998-05-14 |
| ES2114223T3 (es) | 1998-05-16 |
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