JPH09207287A - Decorative paper - Google Patents
Decorative paperInfo
- Publication number
- JPH09207287A JPH09207287A JP1656596A JP1656596A JPH09207287A JP H09207287 A JPH09207287 A JP H09207287A JP 1656596 A JP1656596 A JP 1656596A JP 1656596 A JP1656596 A JP 1656596A JP H09207287 A JPH09207287 A JP H09207287A
- Authority
- JP
- Japan
- Prior art keywords
- resin layer
- paper
- layer
- decorative paper
- base material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Laminated Bodies (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、住宅用家具やキッ
チン、洗面、ドアー等の内装材の防汚染性化粧紙に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a stain-proofing decorative paper for interior materials such as residential furniture, kitchens, washbasins and doors.
【０００２】[0002]
【従来の技術】従来、住宅用家具やキッチン、洗面、ド
アー等の内装材の防汚染用化粧紙としては、ウレタン樹
脂にポリエチレンワックスやシリコンオイル等を添加し
た樹脂液でコートした化粧コート紙やフッ素樹脂コート
化粧紙等が有り使用されてきた。2. Description of the Related Art Conventionally, as a stain-proof decorative paper for interior materials such as furniture for homes, kitchens, washbasins, doors, etc., a decorative coated paper coated with a resin solution obtained by adding polyethylene wax or silicone oil to urethane resin or Fluororesin coated decorative paper and the like have been used.
【０００３】[0003]
【発明が解決しようとする課題】従来の防汚染用化粧紙
としてのウレタン樹脂にポリエチレンワックスやシリコ
ーンオイル等を添加した樹脂液でコートした化粧コート
紙やフッ素樹脂コート化粧紙等は、軽微な汚れにはハジ
ク効果を有しているものの、本質的に多孔質である紙の
表面に直接コート層を設けてあるために、紙表面の孔部
を完全に塞ぐには至らず、該コート層の表面に微細な凹
凸が残るので、マジックインキ等で書き込んだ場合、前
記微細な凹凸の凹部に入り込んだ汚れが落ち難く、防汚
性能上問題となっており、改良が求められていた。[Problems to be Solved by the Invention] The conventional urethane-coated decorative paper for antifouling is coated with a resin solution containing polyethylene wax, silicone oil, or the like. Although it has a cissing effect, since the coating layer is provided directly on the surface of the paper which is essentially porous, it does not completely close the pores on the surface of the paper, and Since fine irregularities remain on the surface, when writing with a magic ink or the like, it is difficult for dirt to enter into the concave portions of the fine irregularities to be removed, which is a problem in terms of antifouling performance, and improvement has been demanded.
【０００４】本発明は、上述の化粧コート紙やフッ素樹
脂コート化粧紙にかわる新しい化粧紙の改良要望に応え
るものである。The present invention meets the demand for improvement of a new decorative paper which replaces the above-mentioned decorative coated paper and fluororesin-coated decorative paper.
【０００５】本発明の第一は、紙基材の片面上に、印刷
層と２液反応硬化型樹脂層、そしてシリコーン樹脂層を
この順に重ね、形成した化粧紙である。The first aspect of the present invention is a decorative paper formed by laminating a printing layer, a two-component reaction curing type resin layer, and a silicone resin layer in this order on one side of a paper base material.
【０００６】また、本発明の第二は、紙基材の片面上
に、印刷層と熱可塑性樹脂層、そしてシリコーン樹脂層
をこの順に重ね、形成した化粧紙である。A second aspect of the present invention is a decorative paper sheet having a printing layer, a thermoplastic resin layer, and a silicone resin layer, which are laminated in this order on one side of a paper substrate.
【０００７】また、本発明の第三は、紙基材の片面上
に、印刷層と熱可塑性樹脂層と２液反応硬化型樹脂層、
そしてシリコーン樹脂層をこの順に重ね、形成した化粧
紙である。The third aspect of the present invention is to provide a printing layer, a thermoplastic resin layer, a two-component reaction-curable resin layer on one side of a paper base material,
The decorative paper is formed by stacking silicone resin layers in this order.
【０００８】本発明の化粧紙を、図１、図２、図３に示
す実施の形態に従って詳細に説明すれば、図１は、紙基
材１０の片面上に、印刷層１１と２液反応硬化型樹脂層
１２、そしてシリコーン樹脂層１３をこの順に重ね形成
したものである。図２は、紙基材１０の片面上に、印刷
層１１と熱可塑性樹脂層１４、そしてシリコーン樹脂層
１３をこの順に重ね、形成したものである。図３は、紙
基材１０の片面上に、印刷層１１と熱可塑性樹脂層１４
と２液反応硬化型樹脂層１２、そして、シリコーン樹脂
層１３をこの順に重ね、形成したものである。The decorative paper of the present invention will be described in detail with reference to the embodiments shown in FIGS. 1, 2 and 3. FIG. 1 shows that a printing layer 11 and a two-liquid reaction are formed on one side of a paper substrate 10. The curable resin layer 12 and the silicone resin layer 13 are laminated in this order. In FIG. 2, the printing layer 11, the thermoplastic resin layer 14, and the silicone resin layer 13 are formed in this order on one surface of the paper base material 10 in this order. FIG. 3 shows that the printing layer 11 and the thermoplastic resin layer 14 are provided on one side of the paper base material 10.
The two-component reaction-curable resin layer 12, and the silicone resin layer 13 are formed in this order by stacking.
【０００９】本発明の紙基材１０としては２０〜８０ｇ
／ｍ2 の薄葉紙、紙間強化紙、片艶クラフト、純白ロー
ル等が用いられる。The paper base material 10 of the present invention is 20 to 80 g.
/ M 2 thin paper, inter-paper reinforcing paper, single gloss craft, pure white roll, etc. are used.
【００１０】また、印刷インキ１１としてはニトロセル
ロース、セルロースアセテートプロピオネート、塩化ビ
ニルー酢酸ビニル共重合体、アクリル酸エステル、ポリ
ビニルブチラール等をバインダーとしたグラビアインキ
等が用いられる。Further, as the printing ink 11, gravure ink using nitrocellulose, cellulose acetate propionate, vinyl chloride-vinyl acetate copolymer, acrylic ester, polyvinyl butyral or the like as a binder is used.
【００１１】また、２液反応硬化型樹脂層１２として、
水酸基（−０Ｈ）を有するアルキッド樹脂、アクリル樹
脂、セルロース系誘導体樹脂、ポリビニルアルコール等
のポリオール樹脂乃至はアミノ基（−ＮＨ2 ）を有する
ポリアミン、カルボキシル基（−Ｃ００Ｈ）を有するポ
リカルボン酸等の活性水素を持つ樹脂と、イソシアネー
ト基（−ＮＣ０）を有するポリイソシアネート樹脂やト
リレンジイソシアネート、メチレンジイソシアネート、
ヘキサメチレンジイソシアネート等のイソシアネート化
合物とを混合、架橋硬化してなる樹脂層を用いられる。As the two-component reaction-curable resin layer 12,
Hydroxyl (-0H) alkyd resin with an acrylic resin, cellulose derivative resin, a polyamine having a polyol resin or an amino group such as polyvinyl alcohol (-NH 2), polycarboxylic acid having a carboxyl group (-C00H) Resin having active hydrogen, polyisocyanate resin having isocyanate group (-NC0), tolylene diisocyanate, methylene diisocyanate,
A resin layer obtained by mixing an isocyanate compound such as hexamethylene diisocyanate and crosslinking and curing is used.
【００１２】また、熱可塑性樹脂層１４として、ポリオ
レフィン系、ポリエチレンテレフタレート、ポリエステ
ル系、ポリアクリル系、スチレン、エチレン酢酸ビニル
共重合体、ナイロン、ポリカーボネート等のフィルムラ
ミネートやエキストルージョンコーティング及び同樹脂
液等のコーティングにより得られるものが用いられる。Further, as the thermoplastic resin layer 14, a film laminate such as a polyolefin type, polyethylene terephthalate, polyester type, polyacrylic type, styrene, ethylene vinyl acetate copolymer, nylon, polycarbonate or the like, extrusion coating and the same resin liquid are used. What is obtained by the coating of is used.
【００１３】また、図３に示す様に、熱可塑性樹脂層１
４上に２液反応硬化型樹脂層１２を積層した２層構成と
することも可能である。この様な構成とすると、熱可塑
性樹脂層１４とシリコーン樹脂層１３との間に十分な密
着性が得られない場合にも、間に２液反応硬化型樹脂層
１２を介在させることによって密着性を改善することが
できる他、仮に熱可塑性樹脂層１４の表面に微細な凹凸
が残存していても、２液反応硬化型樹脂層１２によって
これを埋め尽くし、シリコーン樹脂層１３の表面の平滑
性を向上することもできるので、さらに好適である。Further, as shown in FIG. 3, the thermoplastic resin layer 1
It is also possible to have a two-layer structure in which the two-component reaction-curable resin layer 12 is laminated on the four. With such a configuration, even when sufficient adhesion cannot be obtained between the thermoplastic resin layer 14 and the silicone resin layer 13, the adhesion can be improved by interposing the two-component reaction curable resin layer 12 therebetween. In addition, even if fine irregularities remain on the surface of the thermoplastic resin layer 14, the two-component reaction-curable resin layer 12 fills up the irregularities and smoothes the surface of the silicone resin layer 13. Can be improved, and thus is more preferable.
【００１４】また、シリコーン樹脂層１３としては、ス
トレートシリコーンワニスやアクリル樹脂、エポキシ樹
脂、アルキッド樹脂、ポリエステル樹脂等の変性シリコ
ーンワニス等を有機カルボン酸金属塩（Ｐｂ，Ｆｅ，Ｚ
ｎ）やアミン等を触媒として、熱硬化して用いられる。As the silicone resin layer 13, a straight silicone varnish, a modified silicone varnish such as an acrylic resin, an epoxy resin, an alkyd resin, a polyester resin or the like is used as an organic carboxylic acid metal salt (Pb, Fe, Z).
n) or amine is used as a catalyst to be heat-cured.
【００１５】[0015]
【実施例】次に、本発明の具体的実施例を以下に詳細に
説明する。Next, specific embodiments of the present invention will be described in detail below.
【００１６】＜実施例１＞基材となる紙間強化紙とし
て、名古屋パルプ（株）製、ＮＡＰ３０ｇ／ｍ2 の片面
に２液反応硬化型樹脂を含むインキとして、東洋インキ
製造（株）製、ラミスターインキ９５重量％、ＬＰＮＹ
Ｂ硬化剤５重量％を用いてグラビア印刷法により木目柄
印刷層を形成させ、次にその表面に２液反応硬化型樹脂
液として、東洋インキ製造（株）製、ウレタン樹脂；Ｕ
ＲＶ１５３ワニス９０重量％、硬化剤ＵＲ１００Ｂ５重
量％を用いてグラビアコートを行い、２液反応硬化型ウ
レタン樹脂層を形成させ、次に防汚層を形成するシリコ
ーン樹脂として、信越シリコーン（株）製、主剤ＫＳ７
７４と硬化剤ＣＡＴ−ＰＬ−４を用いて、グラビアコー
トし、熱硬化して形成して、化粧紙を作成した。[0016] <Example 1> inter-sheet reinforced paper as a base material, Nagoya Pulp Co., Ltd., as an ink comprising a two-liquid reaction curing type resin on one surface of NAP30g / m 2, manufactured by Toyo Ink Mfg Co., Ltd. , Lamister ink 95% by weight, LPNY
A wood grain pattern printing layer was formed by a gravure printing method using 5% by weight of B curing agent, and then a two-component reaction-curing resin liquid was produced on the surface thereof by Toyo Ink Mfg. Co., Ltd., urethane resin; U
RV153 varnish 90% by weight and curing agent UR100B 5% by weight are used for gravure coating to form a two-component reaction-curable urethane resin layer, and then as a silicone resin for forming an antifouling layer, manufactured by Shin-Etsu Silicone Co., Ltd. Main agent KS7
74 and a curing agent CAT-PL-4 were used for gravure coating and thermosetting to form a decorative paper.
【００１７】上記化粧紙を、従来のウレタン樹脂にシリ
コーンオイルを添加した樹脂液でコートした化粧コート
紙、及びフッ素樹脂コート化粧紙とともに、油性マジツ
クで１ｃｍ×３ｃｍの長方形を塗りつぶして６時間放置
後に乾いた布で拭き取る防汚性試験を行ったところ、本
発明の化粧紙は色残りなしに対して後者２点は色残り有
りと言う結果となり、本発明の化粧紙の方が防汚性が良
好であった。The above decorative paper was coated with a conventional urethane resin-coated resin solution containing silicone oil and a fluororesin-coated decorative paper, and a rectangle of 1 cm × 3 cm was painted with oily magic and left for 6 hours. When an antifouling property test was carried out by wiping with a dry cloth, the result was that the decorative paper of the present invention had no residual color, whereas the latter two points had residual color, indicating that the decorative paper of the present invention is more stain resistant. It was good.
【００１８】[0018]
【発明の効果】以上詳細に説明した様に、本発明の化粧
紙は、基材となる紙１０の片面上に、印刷層１１と、熱
可塑性樹脂層１４及び／又は２液反応硬化型樹脂層１
２、そしてシリコーン樹脂層１３をこの順に重ね、形成
したものであり、紙表面の微細な孔部が上記樹脂層１４
及び／又は１２で覆われ、表面が平滑なシリコーン樹脂
防汚層１３が得られるので、従来知られていた表面をウ
レタン樹脂にポリエチレンワックスやシリコーンオイル
等を添加した樹脂液でコートした化粧コート紙や、フッ
素樹脂コート化粧紙等の様に、表面の微細な凹凸の凹部
に汚染物が入り込み、取れ難くなることがなく、防汚性
が優れたものとなる。As described above in detail, the decorative paper of the present invention has the printing layer 11, the thermoplastic resin layer 14 and / or the two-component reaction curable resin on one side of the paper 10 as the base material. Layer 1
2 and a silicone resin layer 13 are laminated in this order to form fine holes on the surface of the paper.
And / or 12 to obtain a silicone resin antifouling layer 13 having a smooth surface, and thus the conventionally known surface is a coated paper coated with a resin solution obtained by adding polyethylene wax or silicone oil to urethane resin. In addition, unlike the fluororesin-coated decorative paper, contaminants do not easily get into the recesses of the fine irregularities on the surface, and the stain resistance is excellent.
【図１】本発明の化粧紙の側断面図である。FIG. 1 is a side sectional view of a decorative paper of the present invention.
【図２】本発明の化粧紙の側断面図である。FIG. 2 is a side sectional view of the decorative paper of the present invention.
【図３】本発明の化粧紙の側断面図である。FIG. 3 is a side sectional view of the decorative paper of the present invention.
１０……紙基材 １１……印刷層 １２……２液反応型樹脂層 １３……シリコーン樹脂層 １４……熱可塑性樹脂層 10 ... Paper base material 11 ... Printing layer 12 ... Two-liquid reactive resin layer 13 ... Silicone resin layer 14 ... Thermoplastic resin layer
Claims (3)
型樹脂層、そしてシリコーン樹脂層をこの順に積層して
なることを特徴とする化粧紙。1. A decorative paper characterized in that a printing layer, a two-component reaction-curable resin layer, and a silicone resin layer are laminated in this order on one side of a paper base material.
層、そしてシリコーン樹脂層をこの順に積層してなるこ
とを特徴とする化粧紙。2. A decorative paper characterized in that a printing layer, a thermoplastic resin layer, and a silicone resin layer are laminated in this order on one side of a paper base material.
層と２液反応硬化型樹脂層、そしてシリコーン樹脂層を
この順に積層してなることを特徴とする化粧紙。3. A decorative paper characterized in that a printing layer, a thermoplastic resin layer, a two-component reaction-curable resin layer, and a silicone resin layer are laminated in this order on one side of a paper base material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1656596A JPH09207287A (en) | 1996-02-01 | 1996-02-01 | Decorative paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1656596A JPH09207287A (en) | 1996-02-01 | 1996-02-01 | Decorative paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH09207287A true JPH09207287A (en) | 1997-08-12 |
Family
ID=11919820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1656596A Pending JPH09207287A (en) | 1996-02-01 | 1996-02-01 | Decorative paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH09207287A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11300905A (en) * | 1998-04-24 | 1999-11-02 | Toppan Printing Co Ltd | Decorative sheet having weather resistance, stain resistance and solvent resistance |
| JP2001248096A (en) * | 1999-12-28 | 2001-09-14 | Ibiden Co Ltd | Decorative laminate |
-
1996
- 1996-02-01 JP JP1656596A patent/JPH09207287A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11300905A (en) * | 1998-04-24 | 1999-11-02 | Toppan Printing Co Ltd | Decorative sheet having weather resistance, stain resistance and solvent resistance |
| JP2001248096A (en) * | 1999-12-28 | 2001-09-14 | Ibiden Co Ltd | Decorative laminate |
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