JPH11300905A - Decorative sheet having weather resistance, stain resistance and solvent resistance - Google Patents
Decorative sheet having weather resistance, stain resistance and solvent resistanceInfo
- Publication number
- JPH11300905A JPH11300905A JP10115667A JP11566798A JPH11300905A JP H11300905 A JPH11300905 A JP H11300905A JP 10115667 A JP10115667 A JP 10115667A JP 11566798 A JP11566798 A JP 11566798A JP H11300905 A JPH11300905 A JP H11300905A
- Authority
- JP
- Japan
- Prior art keywords
- resistance
- resin layer
- layer
- weather
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、建築内装、間仕
切、収納家具等の表面化粧材及び建築準外装すなわち玄
関ドアー、同枠材、窓枠及び出窓カウンターなどに使用
される耐候性、耐汚染性及び耐溶剤性を有する化粧シー
トに関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to weather resistance and contamination resistance used for surface decorative materials such as interior decoration, partitioning, and storage furniture and semi-exterior constructions, that is, entrance doors, frame materials, window frames and bay window counters. The present invention relates to a decorative sheet having water resistance and solvent resistance.
【０００２】[0002]
【従来の技術】従来、建築内装、間仕切、収納家具等の
表面化粧材及び建築準外装すなわち玄関ドアー、同枠
材、窓枠及び出窓カウンターなどに使用される化粧シー
トとしては塩化ビニル樹脂に耐候性の良いアクリル樹脂
を積層したものがほとんどであるが、該アクリル樹脂は
耐汚染性、耐油性及び耐溶剤性が低い為に、汚れが付着
し易く、また付着した汚れを溶剤で拭き取ることができ
ないという問題があった、また、この塩化ビニル樹脂に
アクリル樹脂を積層した化粧シートは廃棄の際の燃焼時
にダイオキシンを発生させる危険性が有るため燃焼処理
が困難という問題もある。2. Description of the Related Art Conventionally, vinyl chloride resin has been used as a decorative sheet used for surface decoration materials such as building interiors, partitions, and storage furniture and semi-exterior constructions such as entrance doors, frame materials, window frames and bay window counters. Most of them are laminated with good acrylic resin, but the acrylic resin is low in stain resistance, oil resistance and solvent resistance, so it is easy for dirt to adhere, and it can be wiped off with a solvent. In addition, there is a problem in that the decorative sheet obtained by laminating an acrylic resin on a vinyl chloride resin has a risk of generating dioxin when burning at the time of disposal, so that there is also a problem that the burning treatment is difficult.
【０００３】[0003]
【発明が解決しようとする課題】本発明は、上記従来技
術の問題点に鑑みなされたもので、建築準外装用に用い
られている塩化ビニル樹脂にアクリル樹脂を積層した化
粧シートの問題点である該アクリル樹脂が耐汚染性、耐
油性及び耐溶剤性が低い為に、汚れが付着し易く、また
付着した汚れを溶剤で拭き取ることができないというこ
と、また、この塩化ビニル樹脂を積層した該化粧シート
は廃棄の際の燃焼時にダイオキシンを発生させる危険性
が有るため、焼却処理が困難ということを解決できる耐
候性、耐汚染性及び耐溶剤性を有する化粧シートを提供
することを目的とするものである。SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned problems of the prior art, and has been made in view of the problem of a decorative sheet obtained by laminating an acrylic resin on a vinyl chloride resin used for a building exterior. Since the acrylic resin has low stain resistance, low oil resistance and low solvent resistance, dirt easily adheres thereto, and it is not possible to wipe off the adhered dirt with a solvent. An object of the present invention is to provide a decorative sheet having weather resistance, stain resistance, and solvent resistance that can solve the difficulty of incineration because the decorative sheet has a risk of generating dioxin when burned at the time of disposal. Things.
【０００４】[0004]
【課題を解決するための手段】本発明の耐候性、耐汚染
性及び耐溶剤性を有する化粧シートは、シート基材上
に、耐候性樹脂層を設け、更にフッ素樹脂層、シリコ−
ン樹脂層又はエチレンビニルアルコール共重合樹脂層の
いずれかからか選んだ樹脂層を積層してなることを特徴
とするものである。The decorative sheet having weather resistance, stain resistance and solvent resistance according to the present invention is provided with a weather resistant resin layer on a sheet substrate, a fluororesin layer and a silicone resin layer.
A resin layer selected from any of a resin layer and an ethylene vinyl alcohol copolymer resin layer.
【０００５】また、本発明の耐候性、耐汚染性及び耐溶
剤性を有する化粧シートは、前記耐候性樹脂層が紫外線
吸収剤を含有するアクリル樹脂層又はポリエステル樹脂
層であることを特徴とするものである。The decorative sheet having weather resistance, stain resistance and solvent resistance according to the present invention is characterized in that the weather resistant resin layer is an acrylic resin layer or a polyester resin layer containing an ultraviolet absorber. Things.
【０００６】また、本発明の耐候性、耐汚染性及び耐溶
剤性を有する化粧シートは、表裏にかかわらず、少なく
とも着色層と絵柄層が形成されてなることを特徴とする
ものである。The decorative sheet having weather resistance, stain resistance and solvent resistance of the present invention is characterized in that at least a colored layer and a picture layer are formed irrespective of the front and back.
【０００７】また、本発明のの耐候性、耐汚染性及び耐
溶剤性を有する化粧シートは、前記シート基材には少な
くとも紫外線吸収剤及び難燃剤が含有されてなることを
特徴とするものである。The decorative sheet having weather resistance, stain resistance and solvent resistance according to the present invention is characterized in that the sheet base material contains at least an ultraviolet absorber and a flame retardant. is there.
【０００８】また、本発明のの耐候性、耐汚染性及び耐
溶剤性を有する化粧シートは、前記耐候性樹脂層に凹凸
模様を有することを特徴とするものである。Further, the decorative sheet having weather resistance, stain resistance and solvent resistance of the present invention is characterized in that the weather resistant resin layer has an uneven pattern.
【０００９】[0009]
【発明の実施の形態】本発明を実施の形態に基づき説明
する。本発明の化粧シート（図１）は表裏に係わらず少
なくとも全面を被覆する着色層（２）と絵柄層（３）が
形成されてなるシート基材（１）上に、耐候性樹脂層
（４）を設け、更にフッ素樹脂層、シリコ−ン樹脂層又
はエチレンビニルアルコール共重合樹脂層のいずれかか
らか選んだ耐汚染樹脂層（５）を積層してなるものであ
る。DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described based on embodiments. The decorative sheet (FIG. 1) of the present invention has a weather resistant resin layer (4) on a sheet substrate (1) on which a colored layer (2) and a picture layer (3) covering at least the entire surface regardless of the front and back are formed. ), And a layer of a stain-resistant resin (5) selected from the group consisting of a fluororesin layer, a silicone resin layer and an ethylene-vinyl alcohol copolymer resin layer.
【００１０】本発明の化粧シートに用いるシート基材
（１）としては塩化ビニルや塩化ビニリデン樹脂以外の
熱可塑性樹脂を用いることができる、すなわち、ポリエ
チレンビニルアルコール共重合体、ポリエチレン酢酸ビ
ニル共重合体、ポリエステル系、ポリエチレン、ポリプ
ロピレンなどオレフィン系、オレフイン系エラストマ
ー、アイオノマー系、アミド系、そしてアクリル系樹脂
等が使用できるが、板や金属など基材への接着性や折り
曲げなどの加工性の点で優れるオレフィン系、オレフィ
ン系エラストマー、アイオノマー系樹脂が好ましく使用
できる。また前記シート基材に着色剤、難燃剤や紫外線
吸収剤等を混入して、隠蔽性、難燃性または防褪色性を
保持させることもできる、すなわち、着色剤としては有
機、無機顔料（酸化チタンを含む）が使用できる、また
紫外線吸収剤としてはベンゾフェノン系、ベンゾトリア
ゾール系、サリシラート系、シアノアクリレート系、ホ
ルムアミジン系オキザニリド系及びヒンダードアミン系
が使用できるが、特にベンゾトリアゾール系、オキザニ
リド系やヒンダードアミン系及びこれらの混合物が紫外
線吸収性に優れ、またオレフィン樹脂などとの相溶性に
も優れるため好ましく使用できる。難燃剤としては、無
機系（水酸化アルミニウム、水酸化マグネシウム、三酸
化アンチモン等）、リン系（有機系：リン酸エステル、
リン酸アンモニウム等、無機系：赤リン系）、反応型
（ビニル付加重合させるビニル化合物、カルボン酸基、
水酸基、エポキシ基などの官能基を有し、高分子の一部
原料：共重合モノマー：として使用されるもの）などが
使用できるが、樹脂への相溶性、難燃効果及び環境面の
安全性等の点において優れる水酸化アルミニウム、水酸
化マグネシウムが好ましく使用できる。As the sheet substrate (1) used in the decorative sheet of the present invention, thermoplastic resins other than vinyl chloride and vinylidene chloride resin can be used, that is, polyethylene vinyl alcohol copolymer, polyethylene vinyl acetate copolymer Polyester, polyethylene, polypropylene, and other olefins, olefin elastomers, ionomers, amides, and acrylic resins can be used, but in terms of adhesion to substrates such as plates and metals and workability such as bending. Excellent olefin-based, olefin-based elastomer, and ionomer-based resins can be preferably used. Further, a colorant, a flame retardant, an ultraviolet absorber, or the like may be mixed into the sheet base to maintain the concealing property, the flame retardancy, or the anti-fading property. That is, as the colorant, an organic or inorganic pigment (oxidized Benzophenone-based, benzotriazole-based, salicylate-based, cyanoacrylate-based, formamidine-based oxanilide-based and hindered amine-based UV absorbers, and particularly benzotriazole-based, oxanilide-based and hindered amine-based UV absorbers. The system and the mixture thereof are preferably used because they have excellent ultraviolet absorbing properties and also have excellent compatibility with olefin resins and the like. As the flame retardant, inorganic (aluminum hydroxide, magnesium hydroxide, antimony trioxide, etc.), phosphorus (organic: phosphate ester,
Inorganic: red phosphorus based such as ammonium phosphate, reactive type (vinyl compound to be subjected to vinyl addition polymerization, carboxylic acid group,
It has a functional group such as a hydroxyl group or an epoxy group and can be used as a raw material of some polymers: used as a copolymer monomer), etc., but it has compatibility with resin, flame retardant effect and environmental safety. Aluminum hydroxide and magnesium hydroxide which are excellent in such points can be preferably used.
【００１１】また、本発明の化粧シートに用いるシート
基材（１）には表裏に係わらず少なくとも着色層（２）
及び絵柄層（３）を設けることができる、シート基材の
裏面、すなわち、被貼材（板や金属板など）に接する面
に絵柄層（３）を先に印刷し、その後該絵柄層（３）上
に着色層（２）を設ける場合、また、シート基材の表
面、すなわち、被貼材（板や金属板など）に接しない面
に先に着色層（２）を設け、その後、該着色層（２）上
に絵柄層（３）を印刷して設ける場合、また、シート基
材の裏面には着色層（２）を設け、シート基材の表面に
は絵柄層（３）を設ける場合等の構成をとることがで
き、意匠効果に応じて使い分けが可能である。The sheet substrate (1) used in the decorative sheet of the present invention has at least a colored layer (2)
And a pattern layer (3) on which a pattern layer (3) can be provided, that is, a pattern layer (3) is first printed on the back surface of the sheet substrate, that is, a surface in contact with a material to be pasted (a plate, a metal plate, or the like). 3) When the colored layer (2) is provided on the surface, the colored layer (2) is provided first on the surface of the sheet substrate, that is, on the surface that is not in contact with the material to be pasted (a plate, a metal plate, or the like). When the picture layer (3) is provided by printing on the coloring layer (2), the coloring layer (2) is provided on the back surface of the sheet base, and the picture layer (3) is provided on the surface of the sheet base. It is possible to adopt a configuration such as the case of providing, and it is possible to use properly according to the design effect.
【００１２】前記着色層（２）及び絵柄層（３）として
は、着色剤と樹脂を主体とするものであり、着色剤とし
ては耐光性、耐候性の良い有機顔料、無機顔料が使用可
能であるが、分散される樹脂との組み合わせで耐光性、
耐候性が異なる場合が多いため、適宜紫外線吸収剤等を
併用し補うこともできる、特に、フタロシアニンブル
ー、フタロシアニングリーン、ペリレンマルーン、キナ
クリドンレッド、アンソラキノンレツド、ペリレンレッ
ド、ペリノンオレンジ、フラバースロンエロー、ハンザ
エローなどが樹脂との相互影響の少ない耐光性、耐候性
の良い顔料として好ましく使用できる。また前記樹脂と
しては、光の影響や無機顔料の影響を受け劣化し易い、
また燃焼時に有害な塩化水素ガスを発生する塩化ビニル
樹脂、塩化ビニリデンや塩素化ポリプロピレン樹脂の使
用は避けて、エチレン酢酸ビニル共重合体、エチレンビ
ニルアルコール共重合体、エチレンビニルブチラール共
重合体、セルロース系樹脂、ポリエステル系樹脂、アク
リル系樹脂、水酸基（−ＯＨ）を有するアルキッド樹
脂、アクリル樹脂、セルロース系誘導体樹脂、ポリビニ
ルアルコール樹脂などのポリオール樹脂、アミノ基（−
ＮＨ2 ）を有するアミノ樹脂、あるいはカルボキシル基
（−ＣＯＯＨ）を有するカルボン酸等の活性水素を有す
る樹脂と、イソシアネート基（−ＮＣＯ）を有するポリ
イソシアネート樹脂との２液混合樹脂が使用できるが、
上層、下層との接着性や層としての柔軟性の点で優れる
エチレン酢酸ビニル共重合や上記２液混合樹脂（ウレタ
ンインキ）が好ましく使用できる。The coloring layer (2) and the picture layer (3) are mainly composed of a coloring agent and a resin. As the coloring agent, organic pigments and inorganic pigments having good light resistance and weather resistance can be used. There is light resistance in combination with the resin to be dispersed,
Since the weather resistance often differs, it can be supplemented by appropriately using an ultraviolet absorber or the like as appropriate.In particular, phthalocyanine blue, phthalocyanine green, perylene maroon, quinacridone red, anthoraquinone red, perylene red, perinone orange, and flavour Slon Yellow, Hansa Yellow and the like can be preferably used as a pigment having little light interaction and good weather resistance with little interaction with the resin. Further, as the resin, easily deteriorated under the influence of light and inorganic pigments,
Avoid the use of vinyl chloride resin, vinylidene chloride or chlorinated polypropylene resin, which generates harmful hydrogen chloride gas during combustion.Ethylene vinyl acetate copolymer, ethylene vinyl alcohol copolymer, ethylene vinyl butyral copolymer, cellulose Resin, polyester resin, acrylic resin, alkyd resin having hydroxyl group (-OH), acrylic resin, cellulose derivative resin, polyol resin such as polyvinyl alcohol resin, amino group (-
An amino resin having an NH 2 ) or a two-liquid mixed resin of a resin having an active hydrogen such as a carboxylic acid having a carboxyl group (—COOH) and a polyisocyanate resin having an isocyanate group (—NCO) can be used.
Ethylene vinyl acetate copolymer or the above two-component mixed resin (urethane ink), which is excellent in the adhesiveness to the upper layer and the lower layer and the flexibility as a layer, can be preferably used.
【００１３】また、本発明の化粧シートに設ける耐候性
樹脂層（４）としては，オレフイン系樹脂、スチレン系
樹脂、エチレン酢酸ビニル共重合体、エチレンビニルア
ルコール共重合体、アクリル樹脂（アクリル酸、メタク
リル酸及びこれらの誘導体たとえばアクリルアミド、ア
クリロニトリルなどの重合体を含む、すなわちアクリル
酸エステル樹脂、メタクリル酸エステル樹脂及びアクリ
ロニトリルとアクリル酸エステルの共重合体等）、ポリ
アミド系及びポリエステル系等の熱可塑性樹脂と熱可塑
性エラストマー樹脂等が使用できるが、特に耐光性、耐
候性及び透明性の点で優れるアクリル樹脂やポリエステ
ル系樹脂が好ましく使用できる、更に紫外線吸収剤を併
用して耐光性、耐候性を向上させることができる（但し
樹脂に色が着くほどの添加は望ましくない）、また該樹
脂厚みとしては１０〜２００μｍの範囲で用いることが
でき、エンボスなどの凹凸をこの樹脂層に設けることで
意匠感を向上させることができる。The weather-resistant resin layer (4) provided on the decorative sheet of the present invention includes olefin resin, styrene resin, ethylene vinyl acetate copolymer, ethylene vinyl alcohol copolymer, acrylic resin (acrylic acid, Methacrylic acid and derivatives thereof including polymers such as acrylamide and acrylonitrile, that is, acrylate resins, methacrylate resins and copolymers of acrylonitrile and acrylate, etc.), and thermoplastic resins such as polyamides and polyesters And thermoplastic elastomer resin can be used, but acrylic resin and polyester resin, which are particularly excellent in light resistance, weather resistance and transparency, can be preferably used.Furthermore, light resistance and weather resistance are improved by using an ultraviolet absorber in combination. (However, if the color The addition of undesirable), also examples of the resin thickness can be used in the range of 10 to 200 [mu] m, it is possible to improve the design sense by providing irregularities such as embossing the resin layer.
【００１４】また、本発明の化粧シートに用いる耐候性
樹脂層（４）上に設ける耐汚染樹脂層（５）としてはフ
ッ素樹脂層、シリコ−ン樹脂層又はエチレンビニルアル
コール樹脂層のいずれかからか選んだ樹脂層であって、
フッ素樹脂層としてはコーティングで設けても良いが、
ポリフッ化ビニル樹脂（ＰＶＦ）、エチレン−テトラフ
ロロエチレン共重合体（ＥＴＦＥ）、ポリフッ化ビニリ
デン（ＰＶＤＦ）、テトラフルオロエチレン−ヘキサフ
ロロプロピレン共重合体（ＦＥＰ）、テトラフロロエチ
レン−パーフロロアルキルビニルエーテル共重合体（Ｐ
ＦＡ）等のフッ素系樹脂フイルムを用いて貼り合わせて
も良いが、特に溶融成形性、耐汚染性の点で優れるエチ
レン−テトラフロロエチレン共重合体（ＥＴＦＥ）、テ
トラフロロエチレン−パーフロロアルキルビニルエーテ
ル共重合体（ＰＦＡ）が好ましく使用できる、更に紫外
線吸収剤を併用して耐光性、耐候性を向上させることが
できる（但し樹脂に色が着くほどの添加は望ましくな
い）、またフッ素系樹脂フイルムを用いる場合のエンボ
スなどの凹凸加工は、耐候性樹脂層（４）上に貼り合わ
せた後に行うことが望ましい。The stain-resistant resin layer (5) provided on the weather-resistant resin layer (4) used in the decorative sheet of the present invention may be any one of a fluororesin layer, a silicone resin layer and an ethylene vinyl alcohol resin layer. Or the chosen resin layer,
The fluororesin layer may be provided by coating,
Polyvinyl fluoride resin (PVF), ethylene-tetrafluoroethylene copolymer (ETFE), polyvinylidene fluoride (PVDF), tetrafluoroethylene-hexafluoropropylene copolymer (FEP), tetrafluoroethylene-perfluoroalkyl vinyl ether Polymer (P
FA) or other fluororesin films, but ethylene-tetrafluoroethylene copolymer (ETFE) and tetrafluoroethylene-perfluoroalkyl vinyl ether, which are particularly excellent in melt moldability and stain resistance, A copolymer (PFA) can be preferably used, and furthermore, a light resistance and a weather resistance can be improved by using an ultraviolet absorber together (however, it is not desirable to add the resin to a color), and a fluororesin film In the case of using, it is desirable to perform the embossing and other irregularities after laminating on the weather resistant resin layer (4).
【００１５】また、前記シリコ−ン樹脂層としてはスト
レートシリコンでは柔軟性、光沢、密着性にかけるの
で、変性シリコーン樹脂が用いられる、変性樹脂として
はアクリル樹脂、エポキシ樹脂、アルキッド樹脂、ポリ
エステル樹脂などが使用可能であるが、相溶性、柔軟
性、密着性の点で優れるアクリル樹脂、ポリエステル樹
脂との変性物が好ましく使用できる。As the silicone resin layer, straight silicone is used because flexibility, gloss and adhesiveness are imparted to the silicone resin layer, so that a modified silicone resin is used. As the modified resin, an acrylic resin, an epoxy resin, an alkyd resin, a polyester resin or the like is used. Can be used, but a modified product of an acrylic resin or a polyester resin, which is excellent in compatibility, flexibility and adhesion, can be preferably used.
【００１６】また、前記エチレンビニルアルコール共重
合樹脂（ＥＶＯＨ）層としてはエチレン含有率８２〜９
０モル％と２５〜５０モル％の２タイプのＥＶＯＨが知
られているが、耐溶剤性、耐油性、耐汚染性、透明性の
点で優れるエチレン含有率２５〜５０モル％タイプのＥ
ＶＯＨが好ましく使用できる、更に紫外線吸収剤を併用
して耐光性、耐候性を向上させることができる（但し樹
脂に色が着くほどの添加は望ましくない）、またエンボ
スなどの凹凸加工は、耐候性樹脂層（４）上に貼り合わ
せた後に行なっても、該ＥＶＯＨを熱溶融ルーダーコー
テング時にエンボス加工を行なっても良い（耐候性樹脂
層（４）と該ＥＶＯＨ樹脂を共押し出しエクストルーダ
ーラミネート時にエンボス加工を行うことを含む）。The ethylene-vinyl alcohol copolymer resin (EVOH) layer has an ethylene content of 82-9.
Although two types of EVOH, 0 mol% and 25 to 50 mol%, are known, ethylene having a ethylene content of 25 to 50 mol% is excellent in solvent resistance, oil resistance, stain resistance and transparency.
VOH can be preferably used. Further, light resistance and weather resistance can be improved by using an ultraviolet absorber in combination (however, it is not desirable to add the resin so that the color is obtained). The EVOH may be embossed at the time of hot-melting ruder coating, or may be embossed at the time of laminating the resin layer (4) (co-extrusion of the weatherproof resin layer (4) and the EVOH resin at the time of extruder lamination). Processing).
【００１７】[0017]
【実施例】〈実施例１〉 図１に基づき、本件発明にな
る耐候性、耐汚染性及び耐溶剤性を有する化粧シートの
実施例を説明する。シート基材（１）：厚さ６０μｍの
着色ポリプロピレンフイルム（理研ビニル（株）製、紫
外線吸収剤含有、難燃剤含有）の片面に２液混合樹脂ウ
レタンインキ（東洋インキ製造（株）製、ラミスター）
（紫外線吸収剤添加）を用いて、全面ベタ着色層（２）
と絵柄層（３）を設けた、更に接着ニス（（アクリル）
東洋インキ製造（株）製、ＯＰＳ）を塗布して後、アク
リル樹脂（紫外線吸収剤添加）とエチレン−ビニルアル
コール共重合樹脂（紫外線吸収剤添加）を共押出エクス
トルーダーラミネートし、エンボスロールにて凹凸を付
与して耐候性、耐汚染性及び耐溶剤性を有する化粧シー
トを作成した。EXAMPLES Example 1 An example of a decorative sheet having weather resistance, stain resistance and solvent resistance according to the present invention will be described with reference to FIG. Sheet base material (1): Two-component resin urethane ink (manufactured by Toyo Ink Manufacturing Co., Ltd., Lamister) on one side of a colored polypropylene film (manufactured by Riken Vinyl Co., Ltd., containing an ultraviolet absorber and a flame retardant) having a thickness of 60 μm )
(Addition of UV absorber), solid colored layer (2)
And a pattern layer (3), and an adhesive varnish ((acrylic))
After applying Toyo Ink Mfg. Co., Ltd., OPS), an acrylic resin (with an ultraviolet absorber) and an ethylene-vinyl alcohol copolymer resin (with an ultraviolet absorber) are co-extruded and extruded with an emboss roll. A decorative sheet having weather resistance, stain resistance and solvent resistance was prepared by providing irregularities.
【００１８】〈実施例２〉 図１に基づき、本件発明に
なる耐候性、耐汚染性及び耐溶剤性を有する化粧シート
のもうひとつの実施例を説明する。シート基材（１）：
厚さ６０μｍの着色ポリプロピレンフイルム（理研ビニ
ル（株）製、紫外線吸収剤含有、難燃剤含有）の片面に
２液混合樹脂ウレタンインキ（東洋インキ製造（株）
製、ラミスター）（紫外線吸収剤添加）を用いて、全面
ベタ着色層（２）と絵柄層（３）を設けた、更に接着ニ
ス（（アクリル）東洋インキ製造（株）製、ＯＰＳ）を
塗布して後、アクリル樹脂（紫外線吸収剤添加）をラミ
ネートし、次にエンボスロールにて凹凸を付与して、そ
の上に変性シリコーン樹脂（信越シリコン（株）製ＫＲ
２１２／大日本インキ（株）製バーノツクＤ１５０−７
０＝５０／５０の混合比によるポリエステル変性シリコ
ーン樹脂）を固形分１０ｇ／ｍ2 塗布を行ない、耐汚染
性及び耐溶剤性を有する化粧シートを作成した。Example 2 Another example of a decorative sheet having weather resistance, stain resistance and solvent resistance according to the present invention will be described with reference to FIG. Sheet substrate (1):
A two-component resin urethane ink (Toyo Ink Manufacturing Co., Ltd.) on one side of a colored polypropylene film (manufactured by Riken Vinyl Co., Ltd., containing an ultraviolet absorber and a flame retardant) having a thickness of 60 μm.
Coating, Lamister) (added with ultraviolet absorber), provided with solid color layer (2) and picture layer (3) on the entire surface, and further applied with adhesive varnish ((Acrylic) Toyo Ink Mfg. Co., Ltd., OPS) After that, an acrylic resin (with an ultraviolet absorber added) is laminated, and then irregularities are imparted with an embossing roll, and a modified silicone resin (KR, manufactured by Shin-Etsu Silicon Co., Ltd.) is placed thereon.
212 / Bannot D150-7 manufactured by Dainippon Ink and Chemicals, Inc.
A polyester-modified silicone resin having a mixing ratio of 0 = 50/50) was applied at a solid content of 10 g / m 2 to prepare a decorative sheet having stain resistance and solvent resistance.
【００１９】[0019]
【発明の効果】本発明の化粧シートは、建築内装、間仕
切、収納家具等の表面化粧材及び建築準外装すなわち玄
関ドアー、同枠材、窓枠及び出窓カウンターなどに使用
されるものであるが、前記シート基材上に、前記耐候性
樹脂層を設け、更に前記耐汚染性層を積層することによ
って、耐候性、耐汚染性及び耐溶剤性を有する化粧シー
トとなり、従来、塩化ビニル樹脂にアクリル樹脂を積層
したものなどで耐汚染性、耐油性及び耐溶剤性が低い為
に、汚れが付着し易く、また付着した汚れを溶剤で拭き
取ることができないという問題や、この塩化ビニル樹脂
が積層されてある為した化粧シートは廃棄の際の燃焼時
にダイオキシンを発生させる危険性が有るため燃焼処理
が困難という問題を解決できるという効果を奏するもの
である。The decorative sheet of the present invention is used for surface decorative materials such as architectural interiors, partitions, and storage furniture, and architectural semi-exteriors, that is, entrance doors, frame materials, window frames and bay window counters. By providing the weather resistant resin layer on the sheet substrate and further laminating the stain resistant layer, a decorative sheet having weather resistance, stain resistance and solvent resistance can be obtained. Because of the low stain resistance, oil resistance and solvent resistance of acrylic resin laminates, dirt tends to adhere, and the adhered dirt cannot be wiped off with a solvent. Such a decorative sheet has the effect of solving the problem that the burning treatment is difficult because of the danger of generating dioxin when burning at the time of disposal.
【００２０】[0020]
【図１】本発明の耐候性、耐汚染性及び耐溶剤性を有す
る化粧シートの断面図である。FIG. 1 is a cross-sectional view of a decorative sheet having weather resistance, stain resistance, and solvent resistance of the present invention.
１…基材シート ２…着色層 ３…絵柄層 ４…耐候性樹脂層 ５…耐汚染性及び耐溶剤性樹脂層 DESCRIPTION OF SYMBOLS 1 ... Base sheet 2 ... Colored layer 3 ... Picture layer 4 ... Weather-resistant resin layer 5 ... Stain-resistant and solvent-resistant resin layer
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 ＦＩ Ｂ３２Ｂ 27/18 Ｂ３２Ｂ 27/18 Ａ Ｂ 27/28 １０２ 27/28 １０２ 27/36 27/36 33/00 33/00 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification code FI B32B 27/18 B32B 27/18 AB 27/28 102 27/28 102 27/36 27/36 33/00 33/00
Claims (5)
にフッ素樹脂層、シリコ−ン樹脂層又はエチレンビニル
アルコール共重合樹脂層のいずれかからか選んだ樹脂層
を積層してなることを特徴とする耐候性、耐汚染性及び
耐溶剤性を有する化粧シート。A weather resistant resin layer is provided on a sheet base material, and a resin layer selected from a fluororesin layer, a silicone resin layer and an ethylene vinyl alcohol copolymer resin layer is further laminated. A decorative sheet having weather resistance, stain resistance and solvent resistance, characterized in that:
るアクリル樹脂層又はポリエステル樹脂層であることを
特徴とする請求項１に記載の耐候性、耐汚染性及び耐溶
剤性を有する化粧シート。2. The weather resistant, stain resistant and solvent resistant cosmetic according to claim 1, wherein said weather resistant resin layer is an acrylic resin layer or a polyester resin layer containing an ultraviolet absorbent. Sheet.
なくとも着色層と絵柄層が形成されてなることを特徴と
する請求項１〜２に記載の耐候性、耐汚染性及び耐溶剤
性を有する化粧シート。3. The weather resistance, stain resistance and solvent resistance according to claim 1, wherein at least the coloring layer and the picture layer are formed on the decorative sheet regardless of whether it is on the front or the back. Having a decorative sheet.
剤及び難燃剤が含有されてなることを特徴とする請求項
１〜３に記載の耐候性、耐汚染性及び耐溶剤性を有する
化粧シート。4. A decorative sheet having weather resistance, stain resistance and solvent resistance according to claim 1, wherein said sheet base material contains at least an ultraviolet absorber and a flame retardant. .
を特徴とする請求項１〜４に記載の耐候性、耐汚染性及
び耐溶剤性を有する化粧シート。5. The decorative sheet having weather resistance, stain resistance and solvent resistance according to claim 1, wherein the weather resistant resin layer has an uneven pattern.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10115667A JPH11300905A (en) | 1998-04-24 | 1998-04-24 | Decorative sheet having weather resistance, stain resistance and solvent resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10115667A JPH11300905A (en) | 1998-04-24 | 1998-04-24 | Decorative sheet having weather resistance, stain resistance and solvent resistance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11300905A true JPH11300905A (en) | 1999-11-02 |
Family
ID=14668326
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10115667A Pending JPH11300905A (en) | 1998-04-24 | 1998-04-24 | Decorative sheet having weather resistance, stain resistance and solvent resistance |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11300905A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014201024A (en) * | 2013-04-08 | 2014-10-27 | クラレプラスチックス株式会社 | Natural lighting nonflammable sheet |
| WO2016120912A1 (en) * | 2015-01-27 | 2016-08-04 | 凸版印刷株式会社 | Non-combustible decorative sheet, metal decorative member and method for producing metal decorative member |
| JP2016137614A (en) * | 2015-01-27 | 2016-08-04 | 株式会社トッパン・コスモ | Aluminum decorative laminate, aluminum decorative member and method of manufacturing the same |
| JP2016147388A (en) * | 2015-02-10 | 2016-08-18 | 凸版印刷株式会社 | Decorative sheet and metal decorative member |
| JP2016165866A (en) * | 2015-03-10 | 2016-09-15 | 凸版印刷株式会社 | Decorative sheet and decorative material |
| CN107107593A (en) * | 2015-01-27 | 2017-08-29 | 凸版印刷株式会社 | The manufacture method of noninflammability decoration sheet, metal finishing part and metal finishing part |
| WO2022019310A1 (en) * | 2020-07-22 | 2022-01-27 | 株式会社クラレ | Laminate having functions that vary between two surfaces |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5456828U (en) * | 1977-09-28 | 1979-04-19 | ||
| JPH04299141A (en) * | 1991-03-28 | 1992-10-22 | Toppan Printing Co Ltd | Decorative sheet |
| JPH0531937U (en) * | 1991-10-09 | 1993-04-27 | 大日本印刷株式会社 | Decorative glass |
| JPH05229066A (en) * | 1991-04-02 | 1993-09-07 | Dainippon Printing Co Ltd | Decorative sheet |
| JPH06115003A (en) * | 1992-10-08 | 1994-04-26 | Nippon Steel Corp | Polyolefin-coated steel material with design |
| JPH0985925A (en) * | 1995-09-20 | 1997-03-31 | Dainippon Printing Co Ltd | Decorative sheet and decorative plate |
| JPH09141813A (en) * | 1995-11-22 | 1997-06-03 | Toppan Printing Co Ltd | Weather-resistant decorative sheet |
| JPH09207287A (en) * | 1996-02-01 | 1997-08-12 | Toppan Printing Co Ltd | Decorative paper |
| JPH09272186A (en) * | 1996-04-04 | 1997-10-21 | Dainippon Printing Co Ltd | Wall decorative material sheet |
| JPH1095077A (en) * | 1996-09-20 | 1998-04-14 | Dainippon Printing Co Ltd | Decorative sheet |
-
1998
- 1998-04-24 JP JP10115667A patent/JPH11300905A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5456828U (en) * | 1977-09-28 | 1979-04-19 | ||
| JPH04299141A (en) * | 1991-03-28 | 1992-10-22 | Toppan Printing Co Ltd | Decorative sheet |
| JPH05229066A (en) * | 1991-04-02 | 1993-09-07 | Dainippon Printing Co Ltd | Decorative sheet |
| JPH0531937U (en) * | 1991-10-09 | 1993-04-27 | 大日本印刷株式会社 | Decorative glass |
| JPH06115003A (en) * | 1992-10-08 | 1994-04-26 | Nippon Steel Corp | Polyolefin-coated steel material with design |
| JPH0985925A (en) * | 1995-09-20 | 1997-03-31 | Dainippon Printing Co Ltd | Decorative sheet and decorative plate |
| JPH09141813A (en) * | 1995-11-22 | 1997-06-03 | Toppan Printing Co Ltd | Weather-resistant decorative sheet |
| JPH09207287A (en) * | 1996-02-01 | 1997-08-12 | Toppan Printing Co Ltd | Decorative paper |
| JPH09272186A (en) * | 1996-04-04 | 1997-10-21 | Dainippon Printing Co Ltd | Wall decorative material sheet |
| JPH1095077A (en) * | 1996-09-20 | 1998-04-14 | Dainippon Printing Co Ltd | Decorative sheet |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014201024A (en) * | 2013-04-08 | 2014-10-27 | クラレプラスチックス株式会社 | Natural lighting nonflammable sheet |
| WO2016120912A1 (en) * | 2015-01-27 | 2016-08-04 | 凸版印刷株式会社 | Non-combustible decorative sheet, metal decorative member and method for producing metal decorative member |
| JP2016137614A (en) * | 2015-01-27 | 2016-08-04 | 株式会社トッパン・コスモ | Aluminum decorative laminate, aluminum decorative member and method of manufacturing the same |
| CN107107593A (en) * | 2015-01-27 | 2017-08-29 | 凸版印刷株式会社 | The manufacture method of noninflammability decoration sheet, metal finishing part and metal finishing part |
| KR20170107968A (en) * | 2015-01-27 | 2017-09-26 | 도판 인사츠 가부시키가이샤 | Non-combustible decorative sheet, metal decorative member and method for producing metal decorative member |
| EP3251842A4 (en) * | 2015-01-27 | 2018-09-26 | Toppan Printing Co., Ltd. | Non-combustible decorative sheet, metal decorative member and method for producing metal decorative member |
| US10399301B2 (en) | 2015-01-27 | 2019-09-03 | Toppan Printing Co., Ltd. | Incombustible decorative sheet, metal decorative member and method for fabricating a metal decorative member |
| CN107107593B (en) * | 2015-01-27 | 2019-11-19 | 凸版印刷株式会社 | The manufacturing method of noninflammability decoration sheet, metal finishing component and metal finishing component |
| JP2016147388A (en) * | 2015-02-10 | 2016-08-18 | 凸版印刷株式会社 | Decorative sheet and metal decorative member |
| JP2016165866A (en) * | 2015-03-10 | 2016-09-15 | 凸版印刷株式会社 | Decorative sheet and decorative material |
| WO2022019310A1 (en) * | 2020-07-22 | 2022-01-27 | 株式会社クラレ | Laminate having functions that vary between two surfaces |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100566995C (en) | Decorating material for flooring | |
| JP2000094602A (en) | Plastic composite sheet for thermoformable furniture of multilayer, furniture member manufactured by using the plastic composite sheet for the furniture, and manufacture of the plastic compotsite sheet for the furniture | |
| CN107107593A (en) | The manufacture method of noninflammability decoration sheet, metal finishing part and metal finishing part | |
| WO2016120912A1 (en) | Non-combustible decorative sheet, metal decorative member and method for producing metal decorative member | |
| JP2017042975A (en) | Decorative sheet and metal decorative member | |
| JPH11300905A (en) | Decorative sheet having weather resistance, stain resistance and solvent resistance | |
| JP2000326458A (en) | Decorative sheet | |
| JP2010082826A (en) | Decorative sheet | |
| JP2008101453A (en) | Decorative sheet for flooring material | |
| JP4522538B2 (en) | Decorative sheet and method for producing the same | |
| JP3633367B2 (en) | Decorative sheet | |
| JP4433896B2 (en) | Steel sheet with decorative sheet | |
| JP4670119B2 (en) | Manufacturing method of decorative sheet | |
| JP2000343649A (en) | Decorative sheet | |
| JP2002338706A (en) | Vinylidene fluoride based resin film | |
| JP4816833B2 (en) | Decorative sheet and base material with decorative sheet | |
| JP6511843B2 (en) | Decorative sheet and metal decorative member | |
| JP2788756B2 (en) | Fluororesin-based colored film and method for producing the same | |
| JP4428191B2 (en) | Manufacturing method of decorative sheet | |
| JP2004223823A (en) | Decorative material | |
| JP4470527B2 (en) | Decorative sheet | |
| JP2000108265A (en) | Decorative sheet | |
| JP2002127345A (en) | Laminated sheet and its manufacturing method | |
| JPH02167956A (en) | Exterior facing material | |
| JP4372878B2 (en) | Polyolefin decorative sheet |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20040407 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20040413 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20040524 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20041026 |