JPH08183727A - Emulsified cosmetic - Google Patents
Emulsified cosmeticInfo
- Publication number
- JPH08183727A JPH08183727A JP33944994A JP33944994A JPH08183727A JP H08183727 A JPH08183727 A JP H08183727A JP 33944994 A JP33944994 A JP 33944994A JP 33944994 A JP33944994 A JP 33944994A JP H08183727 A JPH08183727 A JP H08183727A
- Authority
- JP
- Japan
- Prior art keywords
- emulsified cosmetic
- water
- hydrogenated
- lecithin
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Cosmetics (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、保湿効果に優れ、か
つ、使用性及び経時安定性の良好な乳化化粧料に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an emulsified cosmetic composition which has an excellent moisturizing effect and is excellent in usability and stability over time.
【0002】[0002]
【従来の技術】乾燥による皮膚のかさつきや肌荒れを防
止するために、保湿効果を目的とした各種の乳液、クリ
ーム等の化粧料や皮膚外用剤が市販されている。これら
は、皮膚に適度な水分を補給したり、または、水分を逃
がさず潤いを保持させることによって、肌の水分を適正
に保ち、健康な皮膚を維持させている。従来から、保湿
効果の向上のために種々の水性成分や油剤成分が研究、
応用されており、その中でも、水溶性多価アルコールは
保湿性に優れる特性を有していることから、化粧料用原
料として汎用されてきた。2. Description of the Related Art In order to prevent the skin from becoming dry and rough due to drying, various cosmetics such as emulsions and creams and external preparations for the skin for the purpose of moisturizing are commercially available. These supply proper amount of water to the skin or keep the moisture without letting the water escape so that the water in the skin is properly maintained and healthy skin is maintained. Traditionally, various aqueous components and oil components have been studied to improve the moisturizing effect,
The water-soluble polyhydric alcohol has been widely used as a raw material for cosmetics because it has excellent moisturizing properties.
【0003】[0003]
【発明が解決しようとする課題】しかしながら、水溶性
多価アルコールは保湿効果が良好で、皮膚のかさつきや
肌荒れの改善に優れるものの、反面、べたつき感が生
じ、特に多量に配合した場合、その傾向は顕著となって
化粧料としての官能特性上好ましいものではなかった。
一方、保湿能を有する界面活性剤としてレシチンが挙げ
られるが、これを配合した乳化化粧料は経時安定性が充
分ではなく、特に高温域では分離を生じる等の欠点を有
していた。従って、これらの持つ保湿効果を減ずること
なく、いかにしてべたつき感が抑制された良好な官能特
性及び安定性を有する化粧料を提供するかが課題とされ
ていた。However, although the water-soluble polyhydric alcohol has a good moisturizing effect and is excellent in improving the dryness and roughness of the skin, on the other hand, it causes a sticky feeling. Became remarkable and was not preferable in terms of sensory characteristics as a cosmetic.
On the other hand, lecithin can be mentioned as a surfactant having a moisturizing ability, but an emulsion cosmetic containing this is not sufficiently stable with time and has a drawback such as separation in a high temperature range. Therefore, it has been a subject to provide a cosmetic having good organoleptic properties and stability in which a sticky feeling is suppressed without reducing the moisturizing effect.
【0004】[0004]
【課題を解決するための手段】本発明者らは上記実情に
鑑み、鋭意研究の結果、水溶性多価アルコールと特定成
分を併用することにより、保湿効果に優れ、かつ、べた
つき感のない良好な使用感及び安定性を有する乳化化粧
料が得られることを見いだし本発明を完成するに至っ
た。すなわち本発明は、水溶性多価アルコールを5〜4
0重量%含有する乳化化粧料において、次の成分(A)
及び(B); (A)レシチン 0.3〜5重量% (B)ポリオキシアルキレンジグリセリルエーテル
0.3〜20重量% を含有し、かつ(A)と(B)の重量比が1:0.1〜
1:20であることを特徴とする乳化化粧料を提供する
ものである。以下、詳細に説明する。Means for Solving the Problems In view of the above circumstances, the present inventors have earnestly studied, and as a result, by using a water-soluble polyhydric alcohol and a specific component in combination, an excellent moisturizing effect and no sticky feeling were obtained. It was found that an emulsified cosmetic having a good feeling and stability of use can be obtained, and the present invention has been completed. That is, the present invention uses a water-soluble polyhydric alcohol in an amount of 5 to 4
In the emulsified cosmetic containing 0% by weight, the following component (A)
And (B); (A) lecithin 0.3 to 5% by weight (B) polyoxyalkylene diglyceryl ether
0.3 to 20% by weight, and the weight ratio of (A) and (B) is 1: 0.1.
The present invention provides an emulsified cosmetic characterized by being 1:20. The details will be described below.
【0005】本発明に用いられる水溶性多価アルコール
としては、グリセリン、1,3−ブチレングリコール、
プロピレングリコール、ジグリセリン、ジプロピレング
リコール、マルチトール、マンニトール、ソルビトー
ル、キシリトール等が挙げられる。これらの水溶性多価
アルコールは5〜40重量%(以下、単に「%」で示
す)配合される。5%以下では保湿効果が充分ではな
く、また、40%を超えて配合すると後述する特定成分
を併用してもべたつき感を低減することができなくな
る。The water-soluble polyhydric alcohol used in the present invention includes glycerin, 1,3-butylene glycol,
Propylene glycol, diglycerin, dipropylene glycol, maltitol, mannitol, sorbitol, xylitol and the like can be mentioned. These water-soluble polyhydric alcohols are blended in an amount of 5 to 40% by weight (hereinafter, simply indicated by "%"). If it is 5% or less, the moisturizing effect is not sufficient, and if it exceeds 40%, the sticky feeling cannot be reduced even if the specific components described later are used together.
【0006】本発明に用いられる(A)成分のレシチン
としては、例えば、ホスファチジルコリン、ホスファチ
ジルエタノールアミン、ホスファチジルイノシトール、
ホスファチジルセリン、ホスファチジン酸等のジアシル
エステル型グリセロリン脂質、リゾホスファチジルコリ
ン、リゾホスファチジルエタノールアミン、リゾホスフ
ァチジルイノシトール等のモノアシルエステル型グリセ
ロリン脂質、大豆や卵黄等の天然由来レシチン又はこれ
らの水素添加物等が挙げられ、これらの一種又は二種以
上を組み合わせて使用することができる。この中でも水
素添加大豆レシチン、水素添加卵黄レシチン、水素添加
ホスファチジルコリン、水素添加ホスファチジルセリン
から選ばれる一種又は二種以上が好ましい。Examples of the component (A) lecithin used in the present invention include phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol,
Examples include phosphatidylserine, diacylester type glycerophospholipids such as phosphatidic acid, lysophosphatidylcholine, lysophosphatidylethanolamine, monoacylester type glycerophospholipids such as lysophosphatidylinositol, naturally derived lecithin such as soybean and egg yolk, or hydrogenated products thereof. These can be used alone or in combination of two or more. Among these, one or more selected from hydrogenated soybean lecithin, hydrogenated egg yolk lecithin, hydrogenated phosphatidylcholine and hydrogenated phosphatidylserine are preferable.
【0007】(A)成分の配合量は0.3〜5%、より
好ましくは、0.5〜4%である。0.3%よりも少な
いと充分な乳化安定性を得ることができず、また、5%
を超えて配合するとレシチン自体の匂いや着色を生じて
しまう。The blending amount of the component (A) is 0.3 to 5%, more preferably 0.5 to 4%. If it is less than 0.3%, sufficient emulsion stability cannot be obtained, and it is 5%.
If added in excess of the above range, the odor and coloring of lecithin itself will occur.
【0008】(B)成分のポリオキシアルキレンジグリ
セリルエーテルは、ジグリセリンにエチレンオキサイド
やプロピレンオキサイドを付加重合したものである。こ
れらのうち、プロピレンオキサイドの付加モル数が5〜
30モルであるプロピレンオキサイドジグリセリルエー
テルがより好ましい。市販品としてはプリストールDG
P−09(ミヨシ油脂社製)、SavondolGP−
9(日本油脂社製)、SY−DP9、SY−DP14
(阪本薬品工業社製)等が挙げられる。The component (B), polyoxyalkylene diglyceryl ether, is obtained by addition-polymerizing ethylene oxide or propylene oxide to diglycerin. Of these, the number of added moles of propylene oxide is 5 to 5
More preferred is 30 moles of propylene oxide diglyceryl ether. As a commercial product, Pristol DG
P-09 (made by Miyoshi Yushi Co., Ltd.), Savondol GP-
9 (manufactured by NOF CORPORATION), SY-DP9, SY-DP14
(Made by Sakamoto Yakuhin Kogyo Co., Ltd.) and the like.
【0009】(B)成分の配合量は0.3〜20%、よ
り好ましくは0.5〜15%である。0.3%よりも少
ないと水溶性多価アルコールのべたつきを低減すること
ができず、また、20%を超えて配合すると(B)成分
自体のぬるつき感が生じ、使用感が悪化する。The blending amount of the component (B) is 0.3 to 20%, more preferably 0.5 to 15%. If it is less than 0.3%, the tackiness of the water-soluble polyhydric alcohol cannot be reduced, and if it is more than 20%, the component (B) itself feels slimy and the usability deteriorates.
【0010】本発明の乳化化粧料は、上述した特定量の
(A)、(B)成分を配合し、かつ、(A)と(B)の
重量比が1:0.1〜1:20であることを必須とす
る。上述した各々の特定量内において、(A)成分に対
する(B)成分の重量比が0.1未満であると、特に高
温域での充分な経時安定性が得られず、また、同重量比
が20を超えて配合すると、良好な乳化物を得ることが
できない。The emulsified cosmetic composition of the present invention contains the above-mentioned specific amounts of the components (A) and (B), and the weight ratio of (A) to (B) is 1: 0.1 to 1:20. Is mandatory. When the weight ratio of the component (B) to the component (A) is less than 0.1 in each of the specific amounts described above, sufficient stability over time, particularly in a high temperature range, cannot be obtained, and the weight ratio is the same. When it exceeds 20, a good emulsion cannot be obtained.
【0011】本発明の乳化化粧料には、上記必須成分に
加えて、通常、化粧料に配合される成分、例えば、油
剤、界面活性剤、粉体、水溶性高分子、紫外線吸収剤、
防腐剤、着色料、香料、美容成分等を本発明の効果を損
なわない範囲で配合することができる。In the emulsified cosmetic composition of the present invention, in addition to the above-mentioned essential components, components that are usually blended in the cosmetic composition, such as oils, surfactants, powders, water-soluble polymers, ultraviolet absorbers,
Preservatives, colorants, fragrances, cosmetic ingredients and the like can be added within a range that does not impair the effects of the present invention.
【0012】[0012]
【実施例】以下、実施例を挙げて本発明を更に詳細に説
明するが、本発明はこれらにより何等限定されるもので
はない。The present invention will be described in more detail below with reference to examples, but the present invention is not limited thereto.
【0013】実施例1〜5及び比較例1〜5 乳液 表1に示す成分の乳液を製造し、それらの保湿効果、べ
たつき感のなさ及び乳化安定性について評価した。Examples 1 to 5 and Comparative Examples 1 to 5 Emulsions Emulsions having the components shown in Table 1 were prepared and evaluated for their moisturizing effect, lack of stickiness and emulsion stability.
【0014】[0014]
【表1】 [Table 1]
【0015】(製造方法) A:成分1〜5を加熱溶解する。 B:成分6〜10、13を加熱溶解し、Aに添加して乳
化混合する。 C:Bを冷却後、成分11〜12を添加して均一に混合
し、乳液を得る。(Production Method) A: Components 1 to 5 are heated and dissolved. B: Components 6 to 10 and 13 are melted by heating, added to A and emulsified and mixed. After cooling C: B, components 11 to 12 were added and mixed uniformly to obtain an emulsion.
【0016】(評価方法) 1.保湿効果及びべたつき感のなさ 専門評価パネル10名を用いて、上記乳液の使用テスト
を行い5段階の官能評価を行った。さらに、その評価点
を平均して判定した。評価基準を以下に示す。 (判定) ◎:4.5点以上。 ○:3.5点以上4.5点未満。 △:2.5点以上3.5点未満。 ×:2.5点未満。(Evaluation method) 1. Moisturizing effect and lack of stickiness Using 10 professional evaluation panels, the use test of the above emulsion was carried out and a sensory evaluation of 5 levels was performed. Furthermore, the evaluation points were averaged and judged. The evaluation criteria are shown below. (Judgment) A: 4.5 points or more. Good: 3.5 points or more and less than 4.5 points. Δ: 2.5 points or more and less than 3.5 points. X: less than 2.5 points.
【0017】2.乳化安定性 上記各乳液を40℃の恒温槽に放置し、1ヶ月後の安定
性を目視にて評価した。評価基準を以下に示す。 (評価) ◎:非常に良好。 ○:良好。 △:やや分離傾向あり。 ×:明らかに分離。 各評価結果を表2に示す。2. Emulsion Stability Each of the above emulsions was left in a constant temperature bath at 40 ° C., and the stability after 1 month was visually evaluated. The evaluation criteria are shown below. (Evaluation) A: Very good. ◯: Good. Δ: There is a tendency for separation. X: Clearly separated. The evaluation results are shown in Table 2.
【0018】[0018]
【表2】 [Table 2]
【0019】上記評価結果から明らかなように、本発明
に係わる実施例1〜5は、保湿効果、べたつき感のな
さ、乳化安定性のいずれの評価項目をも満足するもので
あった。一方、比較例1〜5においては、全ての評価項
目を満足するものは得られなかった。As is clear from the above evaluation results, Examples 1 to 5 according to the present invention satisfied all the evaluation items of the moisturizing effect, lack of stickiness and emulsion stability. On the other hand, in Comparative Examples 1 to 5, none satisfying all the evaluation items was obtained.
【0020】 実施例6 白濁化粧水 (成分) (%) 1.モノオレイン酸ポリオキシエチレン 0.5 ソルビタン(20E.O.) 2.水素添加卵黄レシチン 0.5 3.精製オリーブ油 1.0 4.香料 適量 5.防腐剤 適量 6.グリセリン 5.0 7.エタノール 10.0 8.1,3−ブチレングリコール 5.0 9.ポリオキシプロピレンジグリセリル 3.0 エーテル(14P.O.) 10.クエン酸 0.02 11.クエン酸ナトリウム 0.1 12.精製水 残量Example 6 Whitening lotion (component) (%) 1. Polyoxyethylene monooleate 0.5 sorbitan (20 EO) 1. Hydrogenated egg yolk lecithin 0.5 3. Refined olive oil 1.0 4. Perfume proper amount 5. Preservative proper amount 6. Glycerin 5.0 7. Ethanol 10.0 8.1, 3-butylene glycol 5.0 9. Polyoxypropylene diglyceryl 3.0 ether (14 PO) 10. Citric acid 0.02 11. Sodium citrate 0.1 12. Purified water Remaining amount
【0021】(製造方法) A:成分1〜7を均一に混合溶解する。 B:成分8〜12を均一に混合溶解する。 C:BにAを添加して乳化混合し、化粧水を得る。 実施例6は、安定性が良好で、保湿効果に優れた化粧水
であった。(Production Method) A: Components 1 to 7 are uniformly mixed and dissolved. B: Components 8 to 12 are uniformly mixed and dissolved. C: A is added to B and emulsified and mixed to obtain a lotion. Example 6 was a lotion having good stability and an excellent moisturizing effect.
【0022】 実施例7 クリーム (成分) (%) 1.ステアリン酸 3.0 2.スクワラン 20.0 3.ワセリン 5.0 4.ミツロウ 1.0 5.セタノール 5.0 6.水素添加ホスファチジルコリン 1.5 7.モノオレイン酸ポリオキシエチレン 0.5 ソルビタン(20E.O.) 8.1,3−ブチレングリコール 15.0 9.グリセリン 5.0 10.ポリオキシプロピレンジグリセリル 1.5 エーテル(9P.O.) 11.カルボキシビニルポリマー 0.1 12.トリエタノールアミン 1.0 13.防腐剤 適量 14.香料 適量 15.精製水 残量Example 7 Cream (ingredient) (%) 1. Stearic acid 3.0 2. Squalane 20.0 3. Vaseline 5.0 4. Beeswax 1.0 5. Cetanol 5.0 6. Hydrogenated phosphatidylcholine 1.5 7. Polyoxyethylene monooleate 0.5 sorbitan (20 EO) 8.1,3-butylene glycol 15.0 9. Glycerin 5.0 10. Polyoxypropylene diglyceryl 1.5 ether (9 PO) 11. Carboxyvinyl polymer 0.1 12. Triethanolamine 1.0 13. Preservative appropriate amount 14. Perfume proper amount 15. Purified water Remaining amount
【0023】(製造方法) A:成分1〜7を加熱溶解し、70℃とする。 B:成分8〜13及び15を加熱溶解し、70℃とす
る。 C:AにBを添加して乳化混合後、冷却し、成分14を
添加混合してクリームを得る。 実施例7は、べたつきがなく、しっとり感に優れたクリ
ームであった。(Manufacturing Method) A: Components 1 to 7 are dissolved by heating to 70 ° C. B: Components 8 to 13 and 15 are dissolved by heating to 70 ° C. C: B is added to A, the mixture is emulsified and mixed, then cooled, and the component 14 is added and mixed to obtain a cream. Example 7 was a cream with no stickiness and an excellent moist feeling.
【0024】[0024]
【発明の効果】本発明の乳化化粧料は、水溶性多価アル
コールのべたつき感が抑制され、かつ、保湿効果に優
れ、良好な使用感及び安定性を有するものである。The emulsified cosmetic composition of the present invention suppresses the sticky feel of the water-soluble polyhydric alcohol, has an excellent moisturizing effect, and has good usability and stability.
Claims (3)
有する化粧料において、次の成分(A)及び(B); (A)レシチン 0.3〜5重量% (B)ポリオキシアルキレンジグリセリルエーテル
0.3〜20重量% を含有し、かつ(A)と(B)の重量比が1:0.1〜
1:20であることを特徴とする乳化化粧料。1. A cosmetic containing 5 to 40% by weight of a water-soluble polyhydric alcohol, which comprises the following components (A) and (B): (A) lecithin 0.3 to 5% by weight (B) polyoxyalkoxy. Range glyceryl ether
0.3 to 20% by weight, and the weight ratio of (A) and (B) is 1: 0.1.
An emulsified cosmetic characterized by being 1:20.
素添加大豆レシチン、水素添加ホスファチジルコリン、
水素添加ホスファチジルセリンから選ばれる一種又は二
種以上であることを特徴とする請求項1記載の乳化化粧
料。2. The component (A) comprises hydrogenated egg yolk lecithin, hydrogenated soybean lecithin, hydrogenated phosphatidylcholine,
The emulsified cosmetic composition according to claim 1, which is one kind or two or more kinds selected from hydrogenated phosphatidylserine.
加モル数が5〜30のポリオキシプロピレンジグリセリ
ルエーテルであることを特徴とする請求項1又は2のい
ずれかに記載の乳化化粧料。3. The emulsified cosmetic composition according to claim 1, wherein the component (B) is a polyoxypropylene diglyceryl ether having a propylene oxide addition mole number of 5 to 30.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP33944994A JP3453643B2 (en) | 1994-12-28 | 1994-12-28 | Emulsified cosmetic |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP33944994A JP3453643B2 (en) | 1994-12-28 | 1994-12-28 | Emulsified cosmetic |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH08183727A true JPH08183727A (en) | 1996-07-16 |
JP3453643B2 JP3453643B2 (en) | 2003-10-06 |
Family
ID=18327574
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP33944994A Expired - Lifetime JP3453643B2 (en) | 1994-12-28 | 1994-12-28 | Emulsified cosmetic |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3453643B2 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998013436A1 (en) * | 1995-03-23 | 1998-04-02 | The Nisshin Oil Mills, Ltd. | Humectant composition, base containing the same, and cosmetic material or external preparation containing said humectant composition |
US6416771B1 (en) | 1995-03-23 | 2002-07-09 | The Nisshin Oil Mills Ltd. | Moisturizing composition, base containing the same, and cosmetic or external preparation containing the moisturizing composition |
JP2005263793A (en) * | 2004-02-18 | 2005-09-29 | Rohto Pharmaceut Co Ltd | Skin lotion |
JP2013166709A (en) * | 2012-02-14 | 2013-08-29 | Asanuma Corporation | Aqueous cosmetic |
JP2017081882A (en) * | 2015-10-30 | 2017-05-18 | 花王株式会社 | Oil-in-water type emulsion composition |
-
1994
- 1994-12-28 JP JP33944994A patent/JP3453643B2/en not_active Expired - Lifetime
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998013436A1 (en) * | 1995-03-23 | 1998-04-02 | The Nisshin Oil Mills, Ltd. | Humectant composition, base containing the same, and cosmetic material or external preparation containing said humectant composition |
US6117434A (en) * | 1995-03-23 | 2000-09-12 | The Nisshin Oil Mills Ltd. | Humectant composition, base containing the same, and cosmetic material or external preparation containing said humectant composition |
US6416771B1 (en) | 1995-03-23 | 2002-07-09 | The Nisshin Oil Mills Ltd. | Moisturizing composition, base containing the same, and cosmetic or external preparation containing the moisturizing composition |
JP2005263793A (en) * | 2004-02-18 | 2005-09-29 | Rohto Pharmaceut Co Ltd | Skin lotion |
JP2013166709A (en) * | 2012-02-14 | 2013-08-29 | Asanuma Corporation | Aqueous cosmetic |
JP2017081882A (en) * | 2015-10-30 | 2017-05-18 | 花王株式会社 | Oil-in-water type emulsion composition |
Also Published As
Publication number | Publication date |
---|---|
JP3453643B2 (en) | 2003-10-06 |
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