JPH0811435B2 - Cosmetic material - Google Patents

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is applied to various base materials for decorative materials to provide a new decorative material having a rich natural feel.

[0002]

2. Description of the Related Art Conventionally, various decorative materials have been used for the purposes of finishing the interior and exterior of buildings, finishing furniture, finishing ornaments and the like. Of these decorative materials, excluding actual wood and animal skins, stones such as marble, cloth, etc., many decorative materials are printed, painted, embossed, etc. on a substrate appropriately selected according to the application. To imitate the appearance of wood, leather, stone, cloth, etc., or to create an abstract pattern that is completely different from them, and in any case, artificially manufacture cosmetic materials and apply it to each application are doing.

In the case of artificially manufacturing a cosmetic material, it is sufficient to use the presently advanced photoengraving technology and printing technology in the case of simply imitating the appearance pattern, but a manufacturer using the cosmetic material With the increasing demand from consumers and the ultimate consumer, there have been several attempts to add elements other than patterns.

(A) For example, it has been attempted to provide a gloss adjusting layer for adjusting gloss after printing on a base material, and according to this, a predetermined gloss which cannot be obtained by simply printing is obtained. It is almost achievable, but the depth (depth) and the texture of the surface (texture such as fine irregularities) cannot be fully expressed, and the three-dimensional effect is poor, or the internal structure of natural products is expressed. I cannot deny the intangible feeling. (B) Alternatively, instead of simply printing the print in a flat manner, a part of the pattern is printed so that the transfer amount of the solid portion is increased, and a three-dimensional feeling which cannot be obtained in the above (a) is imparted. Attempts have also been made, and although this method produces a considerably three-dimensional effect,
After all, it is impossible to reproduce the depth and internal structure. (C) In addition to the method of (b), attempts have been made to use a glossy ink and a matte ink in combination to further emphasize the three-dimensional feeling, but the depth still cannot be reproduced. Moreover, when the surface is worn, the three-dimensional effect is reduced. (D) If printing is performed using a base material in which threads are arranged in one direction and attached, or printed on a base material that gives an equivalent appearance by stretching, a texture that cannot be expressed in (a) to (c) above. , It becomes possible to express the internal structure, but generally it is difficult to print on a substrate with unevenness,
On the contrary, it damages the pattern. (E) Alternatively, there is also a method of forming a transparent synthetic resin layer and embossing after printing on the substrate, but it is still lacking in depth and the gloss is determined by the embossing, making free adjustment difficult.

[0005]

Therefore, in the present invention, a part or all of the depth, texture and internal structure is improved as compared with the above-mentioned prior art, and the printing itself can be normally performed, and the appearance is excellent. To provide cosmetics.

[0006]

The decorative material of the present invention is applied to the surface of a substrate with an ink containing a non-brilliant color hiding pigment or a printing layer and an ink containing a bright pigment formed thereon. Alternatively, a colored layer composed of two layers of a printed layer is formed, a transparent synthetic resin layer is formed on the surface of the colored layer, and a pattern through which the lower layer can be seen through is provided on the surface of the transparent synthetic resin layer. And a surface gloss adjusting layer made of a transparent synthetic resin containing a matting agent is formed on the surface of the pattern,
The outermost surface is characterized by being embossed on the entire surface.

Next, a specific example of the present invention will be described with respect to a wood grain decorative paper having a wood grain pattern. As will be described later, the substrate of the present invention is not limited to paper, and the reason why the pattern is a wood grain pattern in the following examples is that the wood grain pattern is the most difficult to reproduce in the field of cosmetic materials, and the demand is also high. This is because there are a lot of them, and the expression method of the wood grain pattern can be applied to almost other patterns.

FIG. 1 is a schematic cross-sectional view showing the basic structure of a wood grain decorative paper. The wood grain decorative paper 1 has a solid (entirely uniform) coloring layer 3, a transparent synthetic resin layer 4, on a surface of a paper 2. The grain pattern layer 5 and the gloss adjusting layer 6 are sequentially laminated, and the surface has an emboss 7.

As the paper 2, ordinary paper such as thin paper, bleached or unbleached kraft paper, high-quality paper, so-called inter-paper reinforced paper (latex-impregnated paper), mixed paper mixed with synthetic resin, titanium paper, linter Paper, paperboard, gypsum board, etc. can be used.

The coloring layer 3 conceals the paper 2 and imparts the concealing property and the printing base color of the wood grain pattern layer 5 to the entire decorative paper, and
The colored layer 3 is for reproducing the luster of a natural wood grain board, and the colored layer 3 is applied or printed with an ink containing a non-brilliant color concealing pigment and a coating layer or an ink with a bright pigment formed thereon. It consists of two layers. As the non-brilliant color hiding pigment, an ink containing a large amount of a highly hiding pigment such as titanium dioxide is used in order to increase the hiding property. The colored layer 3 is usually solid printed with the brightest color (highlight) of the wood grain. Examples of the luster pigments include (i) pearl pigments, specifically, inner wall portions of shells, crushed powder of pearls, mica, and mica fine particles (about 1 to 100 μm in diameter) with Tio ₂ or Baked with iron oxide, (ii) metal powder, specifically copper, aluminum, brass, bronze, gold, silver, etc., preferably from 1 to 120 μm, (iii) evaporated plastic film Debris, for example, polyethylene terephthalate film with metal (usually aluminum) vapor-deposited and pulverized (silver powder), vapor-deposited with transparent yellow paint, and then pulverized (gold color) Powder) can be used. These luster pigments can be selected according to the gloss, luster, and brilliance of the object to be reproduced, and one or more of them can be used.

Since the bright pigment can be used in any place as long as it is an upper layer of the colored layer 3, it may be used in other layers as necessary.

The transparent synthetic resin layer 4 creates a space between the colored layer 3 and the wood grain pattern layer 5 to give the pattern a sense of depth and, in some cases, to the surface of the colored layer 3 by the shadow of the pattern layer 5. The layer 4 is made of transparent synthetic resin and can be formed by an appropriate coating method. Examples of the synthetic resin include polyolefin resins such as polyethylene, polypropylene, ethylene / vinyl acetate copolymer, and ionomer, thermoplastic resins other than polyolefin such as saturated polyester resin and polyvinyl chloride, unsaturated polyester resin and polyurethane. Thermosetting resins such as resins are suitable examples.

The lower part of the wood grain pattern layer 5 is transparent. In order to make the pattern visible through the lower layer, it is possible to use a transparent ink, or even an opaque ink can be used as a watermark pattern (cutout pattern). Since the pattern formed by the usual printing method is composed of halftone dots, the area between the halftone dots is always transparent, and the lower layer can be seen through regardless of whether the ink itself is transparent or opaque.

The gloss adjusting layer 6 is a transparent synthetic resin top coat layer that protects the surface of the decorative paper 1, prevents the disappearance of the wood grain pattern, and imparts a desirable gloss to the surface of the decorative paper 1. The gloss adjusting layer 6 is formed by applying a paint using an appropriate vehicle. Examples of the vehicle include the following; polyurethane resin, acrylic resin, amino resin,
Nitrocellulose resin, alkyd resin, polyester resin, polyvinyl butyral resin, melamine resin, cellulose acetate resin, polyvinyl chloride resin, polyvinyl acetate resin, polystyrene resin, polyvinyl alcohol resin.
The resins mentioned above as vehicles can be used alone or in combination.

The following matting agents are dispersed in the coating material for forming the gloss adjusting layer 6 to obtain the desired gloss. Examples of matting agents that can be used include: mica, silica, alumina, calcium carbonate, diatomaceous earth, silica sand,
An inorganic hollow body such as Shirasu balloon.

The embossing 7 gives the surface of the decorative paper 1 a pattern, for example, a wood fiber feeling and a material feeling, and the entire surface of the decorative paper 1 is preferably the fibers of the wood pattern layer 5. It is applied so as to have unevenness of hairline along the direction.

The hair line means a line pattern formed by arranging a number of fine lines such as fine hair arranged in parallel,
Normally, the flow of a line consists of straight lines (Japanese Patent Publication No. 54-23).
No. 024, column 2, lines 2 to 4, and the elementary radio editorial section, "Primary Stereo Manufacturing Technology," 5th edition, Seibundo Shinkosha Co., Ltd. (Showa 51-6-1), No. 121. Column in the page ○ Refer to the column for hair and line processing).

The embossing 7 may be another embossing, for example, one expressing a conduit groove of a wood grain suitable for the wood grain pattern layer 5, one reproducing a glossy state of a coated plate, or a combination of these. Good. In addition, when a woodgrain pattern is printed, it imitates the unevenness of the surface of the wooden board, especially the one that expresses the feeling of eddying, the one that is close to a mirror surface for glossing, the one that is satin to deluster etc. When a leather pattern is printed, the one that imitates the texture of the surface of the leather, the above-mentioned satin finish, and in some cases the one that is close to the mirror surface of is suitable, and the stone pattern In the case of printing, the condition of the surface of the stone, for example, imitating unevenness or cracks, or the above is applicable when expressing a polished stone, and in the case of a texture pattern, plain weave, twill The unevenness of the cloth made of a woven or satin weave or a combination thereof is suitable.

Since the wood grain decorative paper shown in FIG. 1 is provided with the transparent synthetic resin layer 4 under the pattern, it has a depth feeling, and the embossing 7 on the surface imparts a wood fiber feeling and a material feeling to the luster. The gloss is adjusted to a preferable gloss by the adjustment layer.

FIG. 2 shows a more preferable structure of the wood grain decorative paper, and in addition to that of FIG. 1, another gloss adjusting layer 8 is provided on the gloss adjusting layer 6. For example, the layer 6 is a matte layer, the layer 8 is a gloss layer, and when the gloss layer 8 is provided in a specific portion of the wood grain pattern, particularly in a portion corresponding to the autumn wood part of the wood grain, the grain texture is substantive. improves. The one shown in FIG. 2 is suitable for reproducing, for example, a cedar board that has been "worked" and is preferably used for a ceiling or the like.

Here, in addition to providing the gloss layer in a pattern on the matte layer, a method of providing the matte layer on the matte layer and a method of separating the matte layer from the matte layer are also provided. There may be a method of providing on the same surface, or either one of the matte layer and the gloss layer may be provided in a pattern. In short, if the gloss adjusting layer is provided in a pattern, It is adapted to increase the visual stereoscopic effect.

Since the wood grain decorative paper shown in FIG. 2 has a partial change in gloss as compared with the one shown in FIG. 1, in addition to the effect of the wood grain decorative paper of FIG. It is what is done.

In the present invention, it is better to add the following elements in addition to those shown in FIGS. That is, the printed pattern layer 5 shown in FIGS. 1 and 2 is provided on the transparent synthetic resin layer 4, but the printed pattern layer 5 is transparently combined with the colored layer 3 in addition to the positions shown in FIGS. If it is also provided between the resin layers 4, a further three-dimensional effect can be obtained. Similarly,
The printed pattern may be provided also on the gloss adjusting layer 6, but in this case, it is preferable that the printed pattern is also provided as the gloss adjusting layer 8 in FIG. 2, and it is preferable that the printed pattern is provided by a gloss-adjusted composition that is appropriately colored. .
In addition to the positions shown in FIGS. 1 and 2, the printed patterns may be provided at the above-mentioned two places, and the printed patterns may be provided at a total of three places.

The outline of the method for producing the decorative material of the present invention is as follows. First, a base material having a colored surface is prepared. As the base material 2, any material other than paper may be used as long as it can be used as a base material for a decorative material. Examples of substrates that can be used other than paper are as follows: polyethylene film, polypropylene film, polyvinyl chloride film, polyvinylidene chloride film, polyvinyl alcohol film, polyethylene terephthalate film, polycarbonate film, nylon film, polystyrene film,
Ethylene vinyl acetate copolymer film, ethylene vinyl alcohol copolymer film, plastic films such as ionomer, wood, plywood, wood base materials such as particle board, gypsum boats, gypsum base materials such as gypsum slag board, pulp cement board, Fiber cement board such as asbestos cement board, wood chip cement board, GRC and concrete,
Metal foils or sheets of iron, aluminum, copper, etc., and composites of the above respective base materials. Note that the decorative material may be temporarily manufactured using the first base material before being made into a composite, and may be further attached to the second base material.

The surface of the substrate is colored with a coloring ink or coating composition. As the ink or coating composition, a vehicle prepared by kneading a pigment or dye colorant, a plasticizer, a stabilizer, other additives, a solvent or a diluent into a vehicle is used, and examples of the vehicle include ethyl cellulose and ethyl. Hydroxyethyl cellulose, cellulose acetate propionate, cellulose derivatives such as cellulose acetate, polystyrene, styrene resins such as poly-α-methylstyrene and styrene copolymer resins, polymethylmethacrylate, polyethylmethacrylate, ethylpolyacrylate, polyacrylic acid. Acrylic or methacrylic resin homo- or copolymer resin such as butyl, rosin,
One or two of rosin-modified maleic acid resin, rosin-modified phenolic resin, rosin ester resin such as polymerized rosin, polyvinyl acetate resin, coumarone resin, vinyltoluene resin, vinyl chloride resin, polyester resin, polyurethane resin, butyral resin, etc. It is advisable to select and use the above and use the created one.

These compositions are coated by a suitable coating method, for example,
Gravure coat, roll coat, air knife coat,
The colored layer is formed by coating the base material by spray coating, flow coating, or the like, or by solid printing by an ordinary printing method.

Next, the transparent synthetic resin layer 4 is formed on the colored layer. The synthetic resin for forming the transparent synthetic resin layer 4 may be selected from the vehicles used for forming the colored layer other than those described in the explanation of FIG. 1 and used. These are applied by selecting an appropriate application means such as extrusion, T-die, roll coating or gravure coating according to the properties of the resin. The transparent synthetic resin layer 4 needs to have a thickness of 5 μm or more in order to achieve its purpose.
More preferably, it is 20 μm or more. The larger the thickness of the layer 4, the greater the effect, but if the thickness exceeds 5 mm, the effect cannot be expected to be improved, and the required amount of the material becomes excessive, which is not preferable.

When the transparent synthetic resin layer 4 is formed by extrusion coating a polyolefin resin which does not have particularly good adhesiveness, an anchoring agent such as alkyl titanate or polyethyleneimine is coated prior to the extrusion coating. It is good to do it.

Similarly, from the viewpoint of adhesiveness, the transparent synthetic resin layer may be subjected to a treatment for improving the adhesiveness. For example, when the transparent synthetic resin layer is formed of a polyolefin resin, the transparent synthetic resin layer is formed on the transparent synthetic resin layer. The wettability index of the surface of the transparent synthetic resin layer was 38 dyne / c by corona discharge treatment.
m ² or more is desirable, and 38 dyne / cm ²
By the above, the adhesiveness of the printing ink is improved.

It is considered that the decorative material of the present invention is generally manufactured by a method of sequentially laminating each layer on a base material. However, at least the surface of the base material is colored and an appropriate peeling is performed. The transparent substrate may be laminated together with the transparent synthetic resin layer, or the transparent synthetic resin layer may be laminated on one of the transparent synthetic resin layer and the gloss adjusting layer and the printed pattern formed on the flexible substrate. It is also possible to employ a method such as pressure bonding, and the embossing can be performed simultaneously with the laminating or after the laminating.

Generally, after forming the transparent synthetic resin layer, printing is performed on the surface thereof. As a printing method, when the base material 2 is a flexible sheet, it is usually a gravure printing method.
Other general printing methods can also be applied. Further, when the substrate 2 is a plate-shaped one, it is usual to apply the silk screen printing method or the gravure offset printing method, but a printing method other than these may be used. In the present invention, the printed pattern formed on the transparent synthetic resin layer should have a certain proportion of the lower layer visible. Therefore, when a non-hiding ink is used as well as a hiding ink. However, the ratio of the printed pattern to the total area is 80% or less, preferably 70% or less. After forming the print pattern layer, a gloss adjusting layer is formed next. The gloss adjusting layer is designated by reference numeral 6 in FIG.
As shown in FIG. 2, when it is formed uniformly on the printed pattern, the same coating or solid printing method as when forming the colored layer may be used.
8 and 8 or any other method, the same printing method as that for forming a print pattern is used.

After the gloss adjusting layer is formed, an emboss having, for example, hairline-shaped irregularities is formed on the surface. The embossing method is preferably performed by a flat plate press or a roll press, but a known embossing method performed by other physical and chemical means may be used. The roll press method is preferably used to continuously manufacture the decorative material in the form of a roll, and the embossed roe has the hardness of metal, etc., and can be applied to the surface of a roll material with heat resistance and abrasion resistance. Engraving, engraving with an automatic gravure printing plate engraving machine (made by Hell in West Germany, Heliocrisiograph, etc.), and using a product having a desired unevenness formed by corrosion or the like, usually 90 embossing targets and / or embossing rolls While heating to about 160 ° C., the pressure is applied between the rubber rolls facing each other, and then the pattern is formed.
Cool at about 0 to 60 ° C and wind. The maximum unevenness of the mold during embossing is about 1,500 μm.

[0033]

Since the decorative material of the present invention has the transparent synthetic resin layer between the colored surface of the base material and the printed pattern, the printed pattern appears to float when viewed from the surface and the shadow of the printed pattern. Can be seen. Therefore, when the pattern is a wood grain pattern, the depth (sense of depth) of the natural wood grain board can be reproduced.

In addition, the intense luster of the coloring layer containing the bright pigment itself is soft and natural due to the isotropic uniform diffusion of the light in the surface matting control layer (particularly in the cedar board as in Examples). It is converted into a gloss (close to the surface gloss), and the synergistic effect of this in combination with anisotropic light convergence and divergence due to embossing reproduces the natural wood grain and the appearance very close to the fine fiber bundle structure cross section. To be done.

Further, in the present invention, the coloring layer is a non-brilliant pigment layer (coating or printing layer of ink containing a non-brilliant coloring concealing pigment) and a layer having only the bright pigment formed thereon (brightness). Ink coated or printed layer)
By having a two-layer structure with

I. Improving the effectiveness of the effect of the luster pigment, lowering the necessary addition amount accordingly and decreasing the cost If the coloring layer has a single-layer structure in which the non-lustrous pigment and the luster pigment are mixed and added, The sunken bright pigment is wasted because the effect of its luster is blocked by the hiding power of the non-brilliant pigment. On the other hand, in the present invention, the non-brilliant pigment layer is first formed, and since the layer having only the bright pigment is formed thereon, the effectiveness of the action of the bright pigment is improved as a whole, As a result, the amount of expensive bright pigment required to be added decreases, leading to a gradual decrease in cost.

Ii. Improvement of printing suitability: The bright pigment is generally coarser than the ordinary pigment (usually commonly used is a particle size of about 10 μm to 100 μm, and objectively, if it is not so coarse, “glittering”). It does not give a brilliance.) Moreover, it is usually in the form of scales / foil pieces rather than spherical shapes. Therefore, when a bright pigment is contained (added) in the ink or paint, the dispersibility of the pigment and the suitability for printing / coating deteriorate. Specifically, during printing and coating, the bright pigment is dispersed and settled over time,
Since the degree of glitter changes and the dispersibility of the glitter pigment is poor, the glitter of the colored layer printed / applied may vary or vary depending on the location, and printing defects such as streaks and ink dropouts during printing may occur. Since it is necessary to match both the occurrence and the luster and the hue, color matching and color management during compounding of inks and paints or during printing and coating processes
It becomes very difficult.

There are problems such as Each of these problems (1) to (4) is exacerbated by the interaction between the bright pigment and the non-brilliant pigment.

On the other hand, in the case of the present invention, first (non-brightness)
Providing a composition coating or printing layer having only color pigments,
After that, since a coating or printing layer of a composition containing only a glittering pigment is provided thereon, when performing hue matching, it is sufficient to perform only hue matching, and when performing glitter matching. Does not cause the problem of brilliant color matching. That is, color matching / color correction (during ink formulation, printing, or coating process) of hue and glitter is easy. Therefore, it is also easy to manage and suppress fluctuations in glitter.

In addition, since no coloring pigment is added to the ink containing the glitter pigment, the problem that the addition of the coloring pigment does not further deteriorate the fluidity of the glitter ink having poor fluidity is also inherent in the glitter pigment. It can be kept to the minimum necessary. In addition, even when uneven density of the bright pigment occurs, the color pigment enters the portion where the density of the bright pigment becomes coarse, or the color pigment is excluded from the portion where the density of the bright pigment becomes dense. By doing so, the problem that the unevenness of the glitter and the unevenness of the hue are synergistically emphasized and become inconspicuous is reduced. That is, in summary, according to the present invention, the defects and defects are prevented from being amplified by the interaction and synergistic effect of the bright pigment and the non-brilliant pigment. Further, the glitter and the hue can be managed separately (measurement, correction, etc.), and the glitter and the color can be reproduced well.

[0041]

According to the present invention, it is possible to obtain a decorative board which is capable of avoiding various problems at the time of forming a colored layer, and in which the three-dimensional effect of the pattern, the soft and natural luster and the like are extremely well reproduced.

[0042]

Example 1 Thin paper (basis weight: 40 g / m ² ) was used as a substrate, firstly the following ink (A) was used, and then the following ink (B)
After solid printing using a gravure solid plate, polyethyleneimine was diluted to a concentration of 1% with a mixed solvent of 80% water and 20% methanol as an anchor agent for coating the polyethylene resin on the printed surface. Was applied by gravure roll coating (at the time of application) at 10 g / m ² and dried.

Ink (A) (for hiding the base)

Ink (B) (for forming pearly luster)

Next, using a high-density polyethylene resin (Mitsui Polychemical, Mirason 14), extrusion coating was applied to the surface of the thin paper to which the anchor agent was applied to form a polyethylene resin layer having a thickness of 50 μm.
The surface of the polyethylene resin layer was subjected to corona discharge treatment so that the wetting index was 38 dyne / cm ² or more.

The following ink (C) is applied to the corona discharge treated surface.
Using, to print a cedar pattern by a gravure printing method, after printing, use a matte overprint varnish (D) below to form a matte layer on the entire surface by gravure solid printing. Using (E), printing was also performed by the gravure printing method in synchronization with the portion corresponding to the autumn material portion in the cedar grain pattern.

Ink (C) (for pattern printing)

Matte overprint varnish (D) (Moroshi Ink, UM No. 50)

Glazing varnish (E)

The printing surface of the printing paper obtained above is heated to 120 ° C.
The polyethylene resin layer is softened by heating to a surface temperature of 2
Using an embossing machine equipped with a hairline embossing roll at 0 ° C, emboss by aligning the hairline direction with the fiber direction of the cedar grain pattern (the direction in which the tree grows) on the entire outermost surface of the printing paper. I got a decorative paper.

The resulting decorative paper has a depth (depth), and because of the hairline-like embossing on the surface, the fibrous nature of wood is simulated, and the matte layer on the surface has a wood grain autumn wood part. Since the glossiness is matched, the partial luster brought about by the cedar buffing process is expressed, and the gloss of the layer formed by the ink (B) can be seen from the surface through the printed pattern layer. Since the shining of natural wood was reproduced to be visible, it had an appearance very similar to that of natural cedar boards that were processed and made. The above decorative paper was adhered to a plywood of 440 mm × 1,820 mm by a conventional method and could be used as a ceiling board.

Example 2 Thin paper (basis weight: 40 g / m ² ) was used as a base material, firstly the following ink (F) was used, and then the following ink (G) was used.
After solid printing using a gravure solid plate, the following vinyl chloride resin paste (H) was applied to the printed surface.
Roll coating, heating to gel, thickness 70 μm
A transparent layer of polyvinyl chloride resin was formed.

Ink (F) (for hiding the base)

Ink (G) (for forming pearly luster)

Vinyl chloride resin paste (H) (for transparent layer formation)

Printing was performed in the same manner as in Example 1 using the following ink (I) on the surface of the transparent layer on the thin paper formed as described above,
After printing, printing was performed in the same manner as in Example 1 using the matte overprint varnish (D) and the gloss varnish (E) used in Example 1.

Ink (I) (for pattern printing)

Thereafter, embossing was applied in the same manner as in Example 1 to obtain a decorative paper sheet similar to that obtained in Example 1.

Since the transparent synthetic resin layer of the decorative paper obtained in Example 2 has a higher transparency than that of the decorative paper obtained in Example 1, the transparent synthetic resin layer has an excellent transparency, and the transparent synthetic resin layer is polychlorinated. Since it is made of vinyl resin, it has excellent heat resistance and fire resistance, and has the same effects as the decorative paper obtained in Example 1.

[Brief description of drawings]

FIG. 1 is a schematic sectional view showing an embodiment of the present invention.

FIG. 2 is a schematic sectional view showing an embodiment of the present invention.

[Explanation of symbols]

 1 Decorative paper 2 Paper (base material) 3 Coloring layer 4 Transparent synthetic resin layer 5 Pattern layer 6,8 Gloss adjusting layer 7 Embossing

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Claims (1)

[Claims] 1. A non-brilliant colored hiding pigment is added to the surface of a substrate.
Applied ink or printed layer and formed on it
Applying ink containing bright pigment or printing layer
Is formed on the surface of the colored layer.
A synthetic resin layer is formed on the surface of the transparent synthetic resin layer.
A pattern that allows the lower layer to be seen through is provided on the surface of the pattern.
Is a surface gloss adjusting layer made of a transparent synthetic resin containing a matting agent.
Is formed, and the entire surface is embossed on the outermost surface.
A cosmetic material characterized by being applied.