JPH0770145A - 固体有機アルミノキシ組成物の製造方法 - Google Patents

固体有機アルミノキシ組成物の製造方法

Info

Publication number
JPH0770145A
JPH0770145A JP6125473A JP12547394A JPH0770145A JP H0770145 A JPH0770145 A JP H0770145A JP 6125473 A JP6125473 A JP 6125473A JP 12547394 A JP12547394 A JP 12547394A JP H0770145 A JPH0770145 A JP H0770145A
Authority
JP
Japan
Prior art keywords
solid
aluminoxane
solution
catalyst system
borane compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6125473A
Other languages
English (en)
Japanese (ja)
Inventor
Rolf L Geerts
エル.ギアーツ ロルフ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of JPH0770145A publication Critical patent/JPH0770145A/ja
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/603Component covered by group C08F4/60 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06Aluminium compounds
    • C07F5/061Aluminium compounds with C-aluminium linkage
    • C07F5/066Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C07F5/068Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602Component covered by group C08F4/60 with an organo-aluminium compound
    • C08F4/6028Component covered by group C08F4/60 with an organo-aluminium compound with an alumoxane, i.e. a compound containing an -Al-O-Al-group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP6125473A 1993-06-22 1994-06-07 固体有機アルミノキシ組成物の製造方法 Pending JPH0770145A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US080899 1993-06-22
US08/080,899 US5354721A (en) 1993-06-22 1993-06-22 Organo-aluminoxy product and use

Publications (1)

Publication Number Publication Date
JPH0770145A true JPH0770145A (ja) 1995-03-14

Family

ID=22160353

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6125473A Pending JPH0770145A (ja) 1993-06-22 1994-06-07 固体有機アルミノキシ組成物の製造方法

Country Status (8)

Country Link
US (2) US5354721A (enExample)
EP (1) EP0630900A1 (enExample)
JP (1) JPH0770145A (enExample)
KR (1) KR950000712A (enExample)
BR (1) BR9402351A (enExample)
CA (1) CA2119952A1 (enExample)
FI (1) FI942993A7 (enExample)
NO (1) NO942369L (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019533750A (ja) * 2016-11-07 2019-11-21 エスシージー ケミカルズ カンパニー,リミテッド 重合ポリエチレンワックスの調製のための方法

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5411925A (en) * 1993-02-12 1995-05-02 Phillips Petroleum Company Organo-aluminoxy product and use
DE4203753A1 (de) * 1992-02-10 1993-08-12 Basf Ag Katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)-bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
US5449650A (en) * 1992-12-08 1995-09-12 Mitsubishi Petrochemical Company Limited Catalyst components for polymerization of olefins and use thereof
US5354721A (en) * 1993-06-22 1994-10-11 Phillips Petroleum Company Organo-aluminoxy product and use
US5436212A (en) * 1994-04-15 1995-07-25 Phillips Petroleum Company Organoaluminoxy product, preparation, and use
US5496781A (en) * 1994-05-16 1996-03-05 Phillips Petroleum Company Metallocene catalyst systems, preparation, and use
US5622906A (en) * 1994-09-16 1997-04-22 Phillips Petroleum Company Compositions useful for olefin polymerization and processes therefor and therewith
EP0728773B1 (en) * 1995-02-21 1998-11-04 Mitsubishi Chemical Corporation Catalysts for olefin polymerization and a process for preparing olefin polymers therewith
WO1996028480A1 (en) * 1995-03-10 1996-09-19 The Dow Chemical Company Supported catalyst component, supported catalyst, preparation process, polymerization process, complex compounds, and their preparation
US5700748A (en) * 1995-09-29 1997-12-23 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers comprising a bridging allyl-cyclodienyl ligand on a metal atom
US5777143A (en) * 1995-12-22 1998-07-07 Akzo Nobel Nv Hydrocarbon soluble alkylaluminoxane compositions formed by use of non-hydrolytic means
US5767034A (en) * 1996-05-31 1998-06-16 Intevep, S.A. Olefin polymerization catalyst with additive comprising aluminum-silicon composition, calixarene derivatives or cyclodextrin derivatives
SG84505A1 (en) * 1996-06-12 2001-11-20 Phillips Petroleum Co Process for producing an organo-aluminoxane composition for olefin polymerization
CA2277294A1 (en) 1997-01-08 1998-07-16 Hercules Incorporated Metal halide solid acids and supported metal halides as catalysts for the preparation of hydrocarbon resins
DE19709866A1 (de) * 1997-03-11 1998-09-17 Basf Ag Geträgertes Katalysatorsystem zur Polymerisation von Alk-1-enen
CN1247619C (zh) 1998-05-18 2006-03-29 菲利浦石油公司 聚合单体用的催化剂组合物
US6812182B2 (en) * 1998-10-23 2004-11-02 Albemarle Corporation Compositions formed from hydroxyaluminoxane and their use as catalyst components
US6465385B1 (en) 1999-02-12 2002-10-15 Sunoco, Inc. (R&M) Zwitterionic polymerization catalyst
WO2001044308A2 (en) 1999-12-16 2001-06-21 Phillips Petroleum Company Organometal compound catalyst
US7550528B2 (en) * 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7541402B2 (en) * 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7223822B2 (en) * 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
ES2394304T3 (es) * 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
US7897539B2 (en) * 2007-05-16 2011-03-01 Chevron Phillips Chemical Company Lp Methods of preparing a polymerization catalyst
US8058200B2 (en) * 2007-05-17 2011-11-15 Chevron Phillips Chemical Company, L.P. Catalysts for olefin polymerization
US9708418B2 (en) 2011-03-08 2017-07-18 Dow Global Technologies Llc Process for recycling solvent used in an ethylene-based polymerization reaction and system therefor
US8440772B2 (en) 2011-04-28 2013-05-14 Chevron Phillips Chemical Company Lp Methods for terminating olefin polymerizations
US8487053B2 (en) 2011-11-30 2013-07-16 Chevron Phillips Chemical Company Lp Methods for removing polymer skins from reactor walls
US8501882B2 (en) 2011-12-19 2013-08-06 Chevron Phillips Chemical Company Lp Use of hydrogen and an organozinc compound for polymerization and polymer property control
US8703883B2 (en) 2012-02-20 2014-04-22 Chevron Phillips Chemical Company Lp Systems and methods for real-time catalyst particle size control in a polymerization reactor
US10273315B2 (en) 2012-06-20 2019-04-30 Chevron Phillips Chemical Company Lp Methods for terminating olefin polymerizations
US8916494B2 (en) 2012-08-27 2014-12-23 Chevron Phillips Chemical Company Lp Vapor phase preparation of fluorided solid oxides
US8940842B2 (en) 2012-09-24 2015-01-27 Chevron Phillips Chemical Company Lp Methods for controlling dual catalyst olefin polymerizations
EP2955187B1 (en) * 2013-02-08 2018-01-31 Mitsui Chemicals, Inc. Solid polyaluminoxane composition, catalyst for olefin polymerization and method for producing olefin polymer
CA2985611C (en) 2015-05-11 2021-06-01 W.R. Grace & Co.-Conn. Process to produce modified clay, supported metallocene polymerization catalyst, catalyst produced and use thereof
US10940460B2 (en) 2015-05-11 2021-03-09 W. R. Grace & Co.-Conn. Process to produce modified clay, modified clay produced and use thereof
US9708426B2 (en) 2015-06-01 2017-07-18 Chevron Phillips Chemical Company Lp Liquid-solid sampling system for a loop slurry reactor
US10005861B2 (en) 2016-06-09 2018-06-26 Chevron Phillips Chemical Company Lp Methods for increasing polymer production rates with halogenated hydrocarbon compounds
US10774161B2 (en) 2019-01-31 2020-09-15 Chevron Phillips Chemical Company Lp Systems and methods for polyethylene recovery with low volatile content
US11339229B2 (en) 2020-01-27 2022-05-24 Formosa Plastics Corporation, U.S.A. Process for preparing catalysts and catalyst compositions
CN115023446B (zh) 2020-01-27 2024-08-30 台塑工业美国公司 制备催化剂的工艺和催化剂组合物
US12077616B2 (en) 2021-12-15 2024-09-03 Chevron Phillips Chemical Company Lp Production of polyethylene and ethylene oligomers from ethanol and the use of biomass and waste streams as feedstocks to produce the ethanol
US11845814B2 (en) 2022-02-01 2023-12-19 Chevron Phillips Chemical Company Lp Ethylene polymerization processes and reactor systems for the production of multimodal polymers using combinations of a loop reactor and a fluidized bed reactor
US12466900B2 (en) 2022-04-19 2025-11-11 Chevron Phillips Chemical Company Lp Loop slurry periodogram control to prevent reactor fouling and reactor shutdowns
WO2023239560A1 (en) 2022-06-09 2023-12-14 Formosa Plastics Corporaton, U.S.A. Clay composite support-activators and catalyst compositions
WO2025042807A1 (en) 2023-08-22 2025-02-27 Chevron Phillips Chemical Company Lp Integrated processes utilizing water electrolysis and oxidative dehydrogenation of ethane

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4496699A (en) * 1981-03-13 1985-01-29 National Distillers And Chemical Corporation Process for polymerizing high melt index olefins and polymerization catalysts used therefore
CA1327366C (en) * 1988-06-22 1994-03-01 Howard Curtis Welborn, Jr. Non-aqueous process for the preparation of alumoxanes
US4952714A (en) * 1988-06-22 1990-08-28 Exxon Chemical Patents Inc. Non-aqueous process for the preparation of alumoxanes
US5091352A (en) * 1988-09-14 1992-02-25 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins
DE4203753A1 (de) * 1992-02-10 1993-08-12 Basf Ag Katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)-bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
US5354721A (en) * 1993-06-22 1994-10-11 Phillips Petroleum Company Organo-aluminoxy product and use

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019533750A (ja) * 2016-11-07 2019-11-21 エスシージー ケミカルズ カンパニー,リミテッド 重合ポリエチレンワックスの調製のための方法

Also Published As

Publication number Publication date
US5354721A (en) 1994-10-11
NO942369L (no) 1994-12-23
CA2119952A1 (en) 1994-12-23
FI942993A0 (fi) 1994-06-21
BR9402351A (pt) 1995-01-17
EP0630900A1 (en) 1994-12-28
FI942993L (fi) 1994-12-23
FI942993A7 (fi) 1994-12-23
US5480848A (en) 1996-01-02
NO942369D0 (enExample) 1994-06-21
KR950000712A (ko) 1995-01-03

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