JPH076709B2 - Absorption type water heater - Google Patents

Absorption type water heater

Info

Publication number
JPH076709B2
JPH076709B2 JP29455288A JP29455288A JPH076709B2 JP H076709 B2 JPH076709 B2 JP H076709B2 JP 29455288 A JP29455288 A JP 29455288A JP 29455288 A JP29455288 A JP 29455288A JP H076709 B2 JPH076709 B2 JP H076709B2
Authority
JP
Japan
Prior art keywords
temperature regenerator
absorber
evaporator
refrigerant
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP29455288A
Other languages
Japanese (ja)
Other versions
JPH02143063A (en
Inventor
聡 三宅
一雄 渡瀬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP29455288A priority Critical patent/JPH076709B2/en
Publication of JPH02143063A publication Critical patent/JPH02143063A/en
Publication of JPH076709B2 publication Critical patent/JPH076709B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Sorption Type Refrigeration Machines (AREA)

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は吸収式冷温水機に係り、暖房温水を蒸発器から
取出す構造の吸収式冷温水機に関する。
TECHNICAL FIELD The present invention relates to an absorption chiller-heater, and more particularly to an absorption chiller-heater having a structure for taking out heating hot water from an evaporator.

〔従来の技術〕[Conventional technology]

暖房温水を蒸発器から取出すようにした吸収式冷温水機
には例えば特開昭62−213663号に記載されるものが、こ
れを第5図に示す。図示のものは複数の再生器を備えた
パラレルフロー型の吸収式冷暖房機であつて、この暖房
運転は次のように行われる。まず、高温再生器9はガス
や油等による燃焼熱源11を備え、内部の溶液を加熱して
蒸気を発生させる。この蒸気は冷暖切替弁14を経由して
直接蒸発器1に導入されてスプレーされるようになつて
おり、蒸発器1内の伝熱管4の通流水を加熱し、蒸気は
凝縮液化する。加熱された通流水は温水として暖房など
に用いられる。蒸発器1にて凝縮液化した冷媒液2は冷
媒ポンプ3により冷媒切換弁17を経由して吸収器5と溶
液ポンプ7との間に送給され、吸収溶液を稀釈する。稀
釈された溶液は溶液ポンプ7により高温再生器9と熱源
のない低温再生器10に送給される。高温再生器9で濃縮
された濃溶液及び低温再生器10の溶液は、熱交換器8を
経由して吸収器5内にスプレーされサイクルを一巡す
る。
FIG. 5 shows an absorption type cold / hot water machine which takes out heating hot water from the evaporator, for example, as described in JP-A-62-213663. The illustrated one is a parallel flow type absorption cooling and heating machine provided with a plurality of regenerators, and this heating operation is performed as follows. First, the high temperature regenerator 9 is provided with a combustion heat source 11 of gas, oil or the like, and heats the internal solution to generate steam. This steam is directly introduced into the evaporator 1 via the cooling / heating switching valve 14 and is sprayed, heats the water flowing through the heat transfer pipe 4 in the evaporator 1, and the steam is condensed and liquefied. The heated flowing water is used as heating water for heating. The refrigerant liquid 2 condensed and liquefied in the evaporator 1 is fed by the refrigerant pump 3 between the absorber 5 and the solution pump 7 via the refrigerant switching valve 17 to dilute the absorbing solution. The diluted solution is fed by a solution pump 7 to a high temperature regenerator 9 and a low temperature regenerator 10 having no heat source. The concentrated solution concentrated in the high temperature regenerator 9 and the solution in the low temperature regenerator 10 are sprayed into the absorber 5 via the heat exchanger 8 and complete the cycle.

〔発明が解決しようとする課題〕[Problems to be Solved by the Invention]

蒸発器,吸収器内の圧力は温水温度によつて決定され、
吸収器内へのスプレーされる溶液の温度はこの吸収器内
の圧力及びスプレーされる溶液の濃度により決定る。溶
液の温度が高いと吸収器9に配設された伝熱管(図示せ
ず)が高温(例えば90℃)に晒され耐久性を低下させて
しまう問題があり、また冷房中には起り得ないような熱
応力の繰り返しが作用し、伝熱管の変形や管板との固着
部に過度の負担が加わつて経年寿命を低下させ、あるい
は損傷が生じる恐れがあつた。
The pressure in the evaporator and absorber is determined by the hot water temperature,
The temperature of the sprayed solution in the absorber is determined by the pressure in the absorber and the concentration of the sprayed solution. When the temperature of the solution is high, there is a problem that the heat transfer tube (not shown) arranged in the absorber 9 is exposed to a high temperature (for example, 90 ° C.) and durability is deteriorated, and it cannot occur during cooling. Such repeated thermal stress may cause deformation of the heat transfer tube or excessive load on the fixed portion with the tube plate, resulting in a decrease in aged life or damage.

本発明の目的は、吸収器内の伝熱管か暖房時にうける熱
応力を低減させて経年寿命を向上させ、また、伝熱管の
耐腐食性を向上させるうるように伝熱管にスプレーする
溶液の濃度を稀くして温度を低下させることが可能な吸
収式冷温水機を提供することを目的とする。
It is an object of the present invention to reduce the thermal stress in the heat transfer tube in the absorber during heating to improve the aging life, and also to improve the corrosion resistance of the heat transfer tube, the concentration of the solution sprayed on the heat transfer tube. It is an object of the present invention to provide an absorption chiller-heater capable of reducing the temperature by diluting water.

〔課題を解決するための手段〕[Means for Solving the Problems]

上記目的は蒸発器,吸収器,高温及び低温再生器,熱交
換器,溶液ポンプ,冷媒ポンプとこれらを作動的に結合
する配管系から成り、高温再生器の蒸気を開閉弁を介し
て蒸発器に導いて暖房用温水を加熱するとともに前記高
温再生器により得られた濃溶液を吸収器へ環流する吸収
式冷温水機において、冷媒ポンプの吐出側と前記濃溶液
を環流する管とを開閉弁を介して接続し、暖房時に蒸発
器内の冷媒液を冷媒ポンプによつて吸収器に環流する前
の再生器からの戻り濃溶液に供給して稀釈することによ
つて達成される。
The above object consists of an evaporator, an absorber, a high temperature and low temperature regenerator, a heat exchanger, a solution pump, a refrigerant pump and a piping system for operatively connecting them, and vapor of the high temperature regenerator is vaporized through an on-off valve. In the absorption chiller-heater that heats the warm water for heating while circulating the concentrated solution obtained by the high-temperature regenerator to the absorber, the discharge side of the refrigerant pump and the pipe circulating the concentrated solution are opened / closed. It is achieved by supplying the diluted refrigerant solution in the evaporator to the concentrated concentrated solution returned from the regenerator before circulating it to the absorber by the refrigerant pump during heating.

又、上記目的は蒸発器,吸収器,高温及び低温再生器,
熱交換器,溶液ポンプ,冷媒ポンプとこれらを作動的に
結合する配管系から成り、高温再生器の蒸気を開閉弁を
介して蒸発器に導いて暖房用温水を加熱するとともに前
記高温再生器により得られた濃溶液を吸収器へ環流する
吸収式冷温水機において、冷媒ポンプの吐出側と高温再
生器とを開閉弁を介して接続し、暖房時に蒸発器内の冷
媒液を冷媒ポンプによつて高温再生器へ供給して稀釈す
ることによつて、達成される。
In addition, the above-mentioned purpose is evaporator, absorber, high temperature and low temperature regenerator,
It consists of a heat exchanger, a solution pump, a refrigerant pump, and a piping system that operatively connects these, and guides the steam of the high-temperature regenerator to an evaporator through an on-off valve to heat the hot water for heating and by the high-temperature regenerator. In the absorption chiller-heater that recirculates the obtained concentrated solution to the absorber, the discharge side of the refrigerant pump and the high temperature regenerator are connected via an on-off valve, and the refrigerant liquid in the evaporator is heated by the refrigerant pump during heating. It is achieved by supplying it to a high temperature regenerator and diluting it.

更に上記目的は、蒸発器,吸収器,高温及び低温再生
器,熱交換器,溶液ポンプ,冷媒ポンプとこれらを作動
的に結合する配管系から成り、高温再生器とを開閉弁を
介して蒸発器に導いて暖房用温水を加熱するとともに前
記高温再生器により得られた濃溶液を吸収器へ環流する
吸収式冷温水機において、冷媒ポンプの吐出側と低温再
生器とを開閉弁を介して接続し、暖房時に蒸発器内の冷
媒液を冷媒ポンプによつて低温再生器へ供給して稀釈す
ることによつて、達成される。
Further, the above object is composed of an evaporator, an absorber, a high temperature and low temperature regenerator, a heat exchanger, a solution pump, a refrigerant pump and a piping system for operatively connecting them, and the high temperature regenerator is vaporized through an on-off valve. In the absorption chiller-heater that guides the heating water to the heater and heats the concentrated solution obtained by the high-temperature regenerator to the absorber, the discharge side of the refrigerant pump and the low-temperature regenerator are opened and closed via an on-off valve. This is achieved by connecting and supplying the refrigerant liquid in the evaporator to the low temperature regenerator by means of a refrigerant pump for dilution during heating.

〔作用〕[Action]

濃溶液は再生器あるいは吸収器に戻る過程において冷媒
液と混合し十分に稀釈されるため、吸収器にスプレーさ
れる溶液の濃度は稀く保たれる。吸収器内へスプレーさ
れる溶液の温度は、吸収器内の圧力(これは供給する通
流水温度により決定される。)とスプレーされる溶液の
濃度により決定されるものであるから、スプレーされる
溶液の温度も安全な低い温度に保たれる。
Since the concentrated solution mixes with the refrigerant liquid and is sufficiently diluted in the process of returning to the regenerator or absorber, the concentration of the solution sprayed on the absorber is kept rare. The temperature of the solution sprayed into the absorber is determined by the pressure in the absorber (which is determined by the temperature of the flowing water supplied) and the concentration of the solution sprayed, and thus is sprayed. The temperature of the solution is also kept at a safe low temperature.

〔実施例〕〔Example〕

以下本発明の一実施例を第1図,第2図により説明す
る。
An embodiment of the present invention will be described below with reference to FIGS.

まず吸収式冷温水機の冷房サイクルについて、第1図に
より説明する。
First, the cooling cycle of the absorption chiller-heater will be described with reference to FIG.

蒸発器1内は約百分の1気圧に保たれており、この中で
冷媒2(水)は冷媒ポンプ3により冷水が通る伝熱管4
上にスプレーされ、冷水の熱を奪い蒸発して冷却効果が
生ずる。蒸発した冷媒蒸気は、冷却水により低圧に保た
れ吸収器5へ流れ込み、ここで吸収器伝熱管6上にスプ
レーされる臭化リチウム水溶液により吸収され、臭化リ
チウム水溶液は稀くなる。この稀溶液は溶液ポンプ7に
より熱交換器8を経て、一部は高温再生器9へ残りは低
温再生器10へ送り込まれ、高温再生器9では直接熱源11
により加熱されて蒸気と濃溶液へ分離される。また低温
再生器10では稀溶液は高温再生器9で発生した蒸気によ
り加熱されて蒸気と濃溶液に分離される。この様にして
濃縮された溶液は再び熱交換器8を経て吸収器5内にス
プレーされる。低温再生器10で溶液を加熱し凝縮したド
レンは凝縮器12へ導かれる。
The inside of the evaporator 1 is maintained at about one-hundredth atmospheric pressure, in which the refrigerant 2 (water) is heated by a refrigerant pump 3 and a heat transfer tube 4 through which cold water passes.
It is sprayed on and takes the heat of cold water to evaporate, producing a cooling effect. The evaporated refrigerant vapor is kept at a low pressure by cooling water and flows into the absorber 5, where it is absorbed by the lithium bromide aqueous solution sprayed on the absorber heat transfer tube 6, and the lithium bromide aqueous solution becomes rare. This diluted solution is sent by the solution pump 7 through the heat exchanger 8, part of which is sent to the high temperature regenerator 9 and the rest of which is sent to the low temperature regenerator 10.
Is heated and separated into steam and a concentrated solution. In the low temperature regenerator 10, the dilute solution is heated by the steam generated in the high temperature regenerator 9 and separated into steam and concentrated solution. The solution thus concentrated is again sprayed into the absorber 5 via the heat exchanger 8. The drain that has heated and condensed the solution in the low temperature regenerator 10 is guided to the condenser 12.

また低温再生器10で発生した蒸気は凝縮器12で凝縮す
る。この様にしてできた凝縮冷媒は蒸発器1へ導かれス
プレーされてサイクルを一巡する。
Further, the vapor generated in the low temperature regenerator 10 is condensed in the condenser 12. The condensed refrigerant produced in this way is guided to the evaporator 1 and sprayed to complete the cycle.

次に、暖房サイクルについて第2図によつて説明する。
高温再生器9で発生した冷媒蒸気は冷媒切替弁14を経由
して直接蒸発器1に導入されスプレーされる様になつて
おり、蒸発器1内の伝熱管4の通流水を加熱して冷媒蒸
気は凝縮液化する。加熱された通流水は温水として例え
ば暖房に用いられる。蒸発器1にて凝縮液化した冷媒液
2は冷媒ポンプ3により冷媒切換弁15及び戻り配管20を
経由して吸収器5の溶液スプレー配管13に導かれ、吸収
器5へスプレーされる溶液を稀釈(約4%)する。稀釈
された吸収液は、吸収器5を経由して、溶液ポンプ7に
より熱交換器8を経て高温再生器9と低温再生器10とに
送り込まれる。そして、高温再生器9で濃縮された濃溶
液及び、低温再生器10の溶液は、再び熱交換器8を経由
して吸収器5のスプレー配管13内で稀釈され、サイクル
を一巡する。
Next, the heating cycle will be described with reference to FIG.
The refrigerant vapor generated in the high temperature regenerator 9 is directly introduced into the evaporator 1 via the refrigerant switching valve 14 and is sprayed. The refrigerant flowing through the heat transfer pipe 4 in the evaporator 1 is heated by the refrigerant. The vapor condenses and liquefies. The heated flowing water is used as warm water for heating, for example. The refrigerant liquid 2 condensed and liquefied in the evaporator 1 is guided by the refrigerant pump 3 to the solution spray pipe 13 of the absorber 5 via the refrigerant switching valve 15 and the return pipe 20, and the solution sprayed to the absorber 5 is diluted. (About 4%). The diluted absorption liquid is sent to the high temperature regenerator 9 and the low temperature regenerator 10 via the absorber 5, the solution pump 7 and the heat exchanger 8. Then, the concentrated solution concentrated in the high temperature regenerator 9 and the solution in the low temperature regenerator 10 are diluted again in the spray pipe 13 of the absorber 5 via the heat exchanger 8 to complete the cycle.

上述したように、再生器からの戻り濃溶液は、溶液スプ
レー配管13で十分に稀釈されるため、吸収器5内でスプ
レーされる溶液濃度は稀く保たれ、すなわち、吸収器5
内でスプレーされる溶液温度も低く保つことができる。
As described above, the concentrated solution returned from the regenerator is sufficiently diluted in the solution spray pipe 13, so that the solution concentration sprayed in the absorber 5 is kept rare, that is, the absorber 5
The temperature of the solution sprayed in can also be kept low.

第3図は他の実施例で、戻り配管20を高温再生器9に接
続したもので、戻り配管20の吐出口は濃溶液の表面に注
がれるように、濃溶液の表面上方に開口している。これ
は、注がれた冷媒液が濃溶液と混合することをできるだ
け回避し、スプレー配管13の溶液の稀釈効果を向上させ
るためである。
FIG. 3 shows another embodiment, in which the return pipe 20 is connected to the high temperature regenerator 9, and the discharge port of the return pipe 20 is opened above the surface of the concentrated solution so as to be poured onto the surface of the concentrated solution. ing. This is to prevent the poured refrigerant liquid from mixing with the concentrated solution as much as possible and improve the dilution effect of the solution in the spray pipe 13.

本実施例によれば、稀釈作用の他に配管の接続が容易と
なる効果がある。
According to this embodiment, in addition to the dilution effect, there is an effect that the connection of the pipe is easy.

第4図は更に他の実施例で戻り配管20を低温再生器10に
接続したもので、前記実施例と同様、戻り配管20の吐出
口は濃溶液の表面に注がれるように、濃溶液の表面上方
に開口し、注がれた冷媒液か濃溶液と混合するこをでき
るだけ回避し、スプレー配管13の溶液の稀釈効果を向上
させるためである。
FIG. 4 shows a still another embodiment in which the return pipe 20 is connected to the low temperature regenerator 10. As in the previous embodiment, the discharge port of the return pipe 20 is poured onto the surface of the concentrated solution so that the concentrated solution is poured. This is to prevent mixing with the poured refrigerant liquid or concentrated solution as much as possible and to improve the dilution effect of the solution in the spray pipe 13.

本実施例によれば、稀釈作用の他に配管の接続が容易と
なる効果がある。
According to this embodiment, in addition to the dilution effect, there is an effect that the connection of the pipe is easy.

〔発明の効果〕〔The invention's effect〕

本発明によれば高温再生器から蒸発器へ蒸気を導く切換
弁及び、冷媒ポンプの吐出側から再生器あるいは再生器
からの戻り溶液系に冷媒液を導く配管を設けることによ
つて、簡単なバルブ操作のみで冷暖房運転を行うことが
できる。
According to the present invention, by providing a switching valve for guiding steam from the high temperature regenerator to the evaporator and a pipe for guiding the refrigerant liquid from the discharge side of the refrigerant pump to the regenerator or the return solution system from the regenerator, a simple Air conditioning operation can be performed only by operating the valve.

【図面の簡単な説明】[Brief description of drawings]

第1図から第4図は本発明に係る吸収式冷温水機のシス
テム系統図で、第1図は一実施例の冷房時のシステム系
統図、第2図は暖房時のシステム系統図、第3図は他の
実施例の暖房時のシステム系統図、第4図は更に他の実
施例のシステム系統図、第5図は従来の吸収式冷温水機
の暖房時のシステム系統図である。 1…蒸発器、3…冷媒ポンプ、4…蒸発器伝熱管、5…
吸収器、6…吸収器伝熱管、7…溶液ポンプ、8…熱交
換器、9…高温再生器、10…低温再生器、11…熱源、12
…凝縮器、13…溶液スプレー配管、14,15,16…切換弁。
1 to 4 are system system diagrams of an absorption chiller-heater according to the present invention, FIG. 1 is a system system diagram during cooling of one embodiment, and FIG. 2 is a system system diagram during heating. FIG. 3 is a system diagram of another embodiment during heating, FIG. 4 is a system diagram of yet another embodiment, and FIG. 5 is a system diagram of a conventional absorption chiller-heater during heating. 1 ... Evaporator, 3 ... Refrigerant pump, 4 ... Evaporator heat transfer tube, 5 ...
Absorber, 6 ... Absorber heat transfer tube, 7 ... Solution pump, 8 ... Heat exchanger, 9 ... High temperature regenerator, 10 ... Low temperature regenerator, 11 ... Heat source, 12
… Condenser, 13… Solution spray piping, 14,15,16… Switching valve.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】蒸発器,吸収器,高温及び低温再生器,熱
交換器,溶液ポンプ,冷媒ポンプとこれらを作動的に結
合する配管系から成り、高温再生器の蒸気を開閉弁を介
して蒸発器に導いて暖房用温水を加熱するとともに前記
高温再生器により得られた濃溶液を吸収器へ環流する吸
収式冷温水機において、冷媒ポンプの吐出側と前記濃溶
液を環流する管とを開閉弁を介して接続し、暖房時に蒸
発器内の冷媒液を冷媒ポンプによつて吸収器に環流する
前の再生器からの戻り濃溶液に供給して稀釈することを
特徴とする吸収式冷温水機。
1. An evaporator, an absorber, a high-temperature and low-temperature regenerator, a heat exchanger, a solution pump, a refrigerant pump, and a piping system for operatively connecting them, and the vapor of the high-temperature regenerator through an on-off valve. In an absorption chiller-heater that guides an evaporator to heat hot water for heating and recirculates a concentrated solution obtained by the high-temperature regenerator to an absorber, a discharge side of a refrigerant pump and a pipe that recirculates the concentrated solution. An absorption-type cold temperature, which is connected via an on-off valve and is characterized in that during heating, the refrigerant liquid in the evaporator is diluted by supplying it to the concentrated concentrated solution returned from the regenerator before circulating to the absorber by a refrigerant pump. Water machine.
【請求項2】蒸発器,吸収器,高温及び低温再生器,熱
交換器,溶液ポンプ,冷媒ポンプとこれらを作動的に結
合する配管系から成り、高温再生器の蒸気を開閉弁を介
して蒸発器に導いて暖房用温水を加熱するとともに前記
高温再生器により得られた濃溶液を吸収器へ環流する吸
収式冷温水機において、冷媒ポンプの吐出側と高温再生
器とを開閉弁を介して接続し、暖房時に蒸発器内の冷媒
液を冷媒ポンプによつて高温再生器へ供給して稀釈する
ことを特徴とする吸収式冷温水機。
2. An evaporator, an absorber, a high-temperature and low-temperature regenerator, a heat exchanger, a solution pump, a refrigerant pump, and a piping system for operatively connecting these, and vapor of the high-temperature regenerator through an on-off valve. In an absorption chiller-heater that guides to an evaporator to heat hot water for heating and recirculates the concentrated solution obtained by the high-temperature regenerator to the absorber, the discharge side of the refrigerant pump and the high-temperature regenerator are connected via an on-off valve. The absorption chiller-heater is characterized in that the refrigerant liquid in the evaporator is supplied to the high-temperature regenerator by a refrigerant pump to be diluted during heating.
【請求項3】冷媒ポンプの吐出側と高温再生器の蒸気発
生部とを開閉弁を介して接続することを特徴とする請求
項2記載の吸収式冷温水機。
3. The absorption chiller-heater according to claim 2, wherein the discharge side of the refrigerant pump and the steam generator of the high temperature regenerator are connected via an on-off valve.
【請求項4】蒸発器,吸収器,高温及び低温再生器,熱
交換器,溶液ポンプ,冷媒ポンプとこれらを作動的に結
合する配管系から成り、高温再生器とを開閉弁を介して
蒸発器に導いて暖房用温水を加熱するとともに前記高温
再生器により得られた濃溶液を吸収器へ環流する吸収式
冷温水機において、冷媒ポンプの吐出側と低温再生器と
を開閉弁を介して接続し、暖房時に蒸発器内の冷媒液を
冷媒ポンプによつて低温再生器へ供給して稀釈すること
を特徴とする吸収式冷温水機。
4. An evaporator, an absorber, a high-temperature and low-temperature regenerator, a heat exchanger, a solution pump, a refrigerant pump and a piping system for operatively connecting them, and the high-temperature regenerator is vaporized through an on-off valve. In the absorption chiller-heater that guides the heating water to the heater and heats the concentrated solution obtained by the high-temperature regenerator to the absorber, the discharge side of the refrigerant pump and the low-temperature regenerator are opened and closed via an on-off valve. An absorption chiller-heater characterized by being connected and supplying the refrigerant liquid in an evaporator to a low-temperature regenerator by means of a refrigerant pump for dilution during heating.
JP29455288A 1988-11-24 1988-11-24 Absorption type water heater Expired - Fee Related JPH076709B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29455288A JPH076709B2 (en) 1988-11-24 1988-11-24 Absorption type water heater

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29455288A JPH076709B2 (en) 1988-11-24 1988-11-24 Absorption type water heater

Publications (2)

Publication Number Publication Date
JPH02143063A JPH02143063A (en) 1990-06-01
JPH076709B2 true JPH076709B2 (en) 1995-01-30

Family

ID=17809268

Family Applications (1)

Application Number Title Priority Date Filing Date
JP29455288A Expired - Fee Related JPH076709B2 (en) 1988-11-24 1988-11-24 Absorption type water heater

Country Status (1)

Country Link
JP (1) JPH076709B2 (en)

Also Published As

Publication number Publication date
JPH02143063A (en) 1990-06-01

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