JPH07292373A - Fuel additive and fuel composition containing the same - Google Patents
Fuel additive and fuel composition containing the sameInfo
- Publication number
- JPH07292373A JPH07292373A JP10908394A JP10908394A JPH07292373A JP H07292373 A JPH07292373 A JP H07292373A JP 10908394 A JP10908394 A JP 10908394A JP 10908394 A JP10908394 A JP 10908394A JP H07292373 A JPH07292373 A JP H07292373A
- Authority
- JP
- Japan
- Prior art keywords
- fuel
- oil
- fuel additive
- fine particles
- organic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は燃料、特に重油、アスフ
ァルト、アスファルト／水エマルション燃料等に対し、
安価で、分散性が良く、腐食性が少なく、かつ媒塵の低
減効果を有する燃料添加剤（助燃剤）及びそれを含む燃
料組成物に関する。The present invention relates to fuels, particularly heavy oil, asphalt, asphalt / water emulsion fuels, etc.
The present invention relates to a fuel additive (combustor) which is inexpensive, has good dispersibility, has little corrosiveness, and has an effect of reducing dust particles, and a fuel composition containing the same.
【０００２】[0002]
【従来技術】重油、アスファルト等の重質燃料は残炭分
が多く、バーナー、ボイラー等の外燃機関や、舶用ディ
ーゼル機関等の内燃機関等で燃焼させた場合、未燃焼炭
化水素（媒塵）が多く発生しやすいという傾向がある。
燃焼機器を改善することなく簡便に媒塵を抑制するため
方法として、過剰空気量を増やして燃焼させるなどの方
法が取られるがこの方法では燃焼効率が低下し、有害な
窒素酸化物も増加してしまう。そこで、空気量を増やす
ことなく媒塵を低減する方法として燃料に添加剤を添加
するという方法が採られている。2. Description of the Related Art Heavy fuels such as heavy oil and asphalt have a large amount of residual carbon content, and when they are burned by an external combustion engine such as a burner or a boiler or an internal combustion engine such as a marine diesel engine, unburned hydrocarbons (dust ) Tends to occur easily.
As a method to easily control the dust particles without improving the combustion equipment, there is a method such as increasing the amount of excess air to burn, but this method lowers the combustion efficiency and increases harmful nitrogen oxides. Will end up. Therefore, a method of adding an additive to the fuel has been adopted as a method for reducing the amount of dust without increasing the amount of air.
【０００３】この種の試みとして従来より、Ｂａ、Ｃ
ａ、Ｆｅ、Ｍｎ、Ｃｅ等の様々な元素を含む添加剤につ
いて研究がなされている。無機微粒子の形態を有する添
加剤としてはＦｅ、カーボンブラック、Ｃａなど微粉状
粒子に鉄系材料を加えた添加剤（特開平５−９４７９）
等があるが、無機微粒子の固形物のみでは粒径を小さく
しても表面積に限度があるため添加元素の効力を発揮さ
せるには限度があり、また、使用中に無機微粒子が沈降
する恐れもある。また、油溶性化合物を含む添加剤とし
ては、例えばＣｅを含む油溶性石鹸（特開昭５３−１２
９０７）からなる添加剤等があるが、添加量を多くしな
いと十分な効果が得られず、高価である。さらに還元雰
囲気での使用も可能なものとして様々な金属を含む化合
物（特開平０３−２４４６９２）からなる添加剤もある
が、このような構造式が限られている化合物はいずれも
合成するのにコストがかかる。As an attempt of this kind, conventionally, Ba, C
Studies have been conducted on additives containing various elements such as a, Fe, Mn, and Ce. As an additive having the form of inorganic fine particles, an additive obtained by adding an iron-based material to fine powder particles such as Fe, carbon black, and Ca (Japanese Patent Laid-Open No. 5-9479).
However, there is a limit to the effectiveness of the added element because the surface area is limited even if the particle size is reduced with only solid particles of inorganic fine particles, and there is a possibility that the inorganic fine particles may settle during use. is there. As an additive containing an oil-soluble compound, for example, an oil-soluble soap containing Ce (Japanese Patent Laid-Open No. 53-12).
907), there is an additive and the like, but unless the addition amount is increased, a sufficient effect cannot be obtained and it is expensive. Further, there is an additive made of a compound containing various metals (Japanese Patent Laid-Open No. 03-244692) that can be used in a reducing atmosphere, but any compound having such a limited structural formula can be synthesized. There will be a cost.
【０００４】これらの問題点を解決するために、少量で
媒塵低減効果を上げる添加剤としてＣｅ、Ｎｄ、Ｌａ等
を含む添加剤（特開平１−２５６５９３）も挙げられ
る。しかし希土類元素は助燃効果は大きいが、Ｆｅなど
の遷移金属、アルカリ金属及びアルカリ土類金属に比べ
ると高価であるという欠点がある。また、Ｎａ、Ｋのよ
うなアルカリ金属系の添加剤は助燃効果が高いが、重油
中に含まれるバナジウムと低融点化合物を生成し、排気
系等で高温腐食を起こすことが知られている。またアル
カリ土類金属のうち比較的効果が大きく、安価なＣａは
堆積物の付着力が強く、剥がれ難いという欠点を有す
る。In order to solve these problems, an additive containing Ce, Nd, La and the like (Japanese Patent Laid-Open No. 1-256593) can be mentioned as an additive which can improve the effect of reducing the amount of dust with a small amount. However, although the rare earth element has a large auxiliary combustion effect, it has a drawback that it is expensive as compared with transition metals such as Fe, alkali metals and alkaline earth metals. Although alkali metal additives such as Na and K have a high combustion supporting effect, they are known to generate vanadium and low melting point compounds contained in heavy oil, and cause high temperature corrosion in exhaust systems and the like. In addition, among the alkaline earth metals, Ca, which has a relatively large effect and is inexpensive, has the drawback that the deposit has a strong adhesive force and is difficult to peel off.
【０００５】[0005]
【発明が解決しようとする課題】本発明は前記問題点を
解決し、安価で、分散性が良く、装置の腐食が少なく、
さらに媒塵の低減効果を有する燃料添加剤及びそれを含
む燃料組成物を提供することを目的とする。DISCLOSURE OF THE INVENTION The present invention solves the above problems, is inexpensive, has good dispersibility, and has little corrosion of equipment,
Another object of the present invention is to provide a fuel additive having a dust reduction effect and a fuel composition containing the same.
【０００６】[0006]
【課題を解決するための手段】本発明者らは上記目的を
解決するために鋭意研究した結果、ＣｅとＦｅを特定の
形態で組合せた燃料添加剤を燃料に配合することによ
り、上記目的を達成できることを見い出し本発明を完成
した。Means for Solving the Problems As a result of intensive studies for solving the above-mentioned object, the present inventors have achieved the above-mentioned object by blending a fuel additive containing Ce and Fe in a specific form in a fuel. The inventors have found what can be achieved and completed the present invention.
【０００７】すなわち、本発明はＣｅを含む無機物の微
細粒子とＦｅ含む油溶性有機酸塩又はＦｅを含む無機物
の微細粒子とＣｅを含む油溶性有機酸塩を含むことを特
徴とする燃料添加剤に関する。That is, the present invention includes a fuel additive characterized by containing fine particles of an inorganic substance containing Ce and an oil-soluble organic acid salt containing Fe, or fine particles of an inorganic substance containing Fe and an oil-soluble organic acid salt containing Ce. Regarding
【０００８】また、本発明は、燃料に、Ｃｅを含む無機
物の微細粒子とＦｅを含む油溶性有機酸塩又はＦｅを含
む無機物の微細粒子とＣｅを含む油溶性有機酸塩を含む
燃料添加剤が配合されていることを特徴とする燃料組成
物に関する。以下本発明を具体的に説明する。Further, the present invention provides a fuel additive containing, as a fuel, an inorganic fine particle containing Ce and an oil-soluble organic acid salt containing Fe or an inorganic fine particle containing Fe and an oil-soluble organic acid salt containing Ce. The present invention relates to a fuel composition comprising: The present invention will be specifically described below.
【０００９】本発明で対象とする燃料は、主として重
油、アスファルト、アスファルト／水エマルション燃料
等の重質燃料であるが、特にこれらに限定されるもので
はない。The fuel targeted by the present invention is mainly heavy fuel such as heavy oil, asphalt, asphalt / water emulsion fuel, but is not particularly limited thereto.
【００１０】本発明で使用するＣｅを含む無機物とは、
非油溶性のＣｅを含む無機物であり、具体的には、例え
ばＣｅ金属、ＣｅＯ2、Ｃｅ2Ｏ3、Ｃｅ（ＯＨ）3、Ｃｅ
Ｃｌ3、Ｃｅ2（ＳＯ4）3、Ｃｅ2（ＣＯ3）3、及びこれ
らを含む鉱物等が挙げられる。The Ce-containing inorganic material used in the present invention is
An inorganic substance containing non-oil-soluble Ce, and specifically, for example, Ce metal, CeO 2 , Ce 2 O 3 , Ce (OH) 3 , Ce.
Examples thereof include Cl 3 , Ce 2 (SO 4 ) 3 , Ce 2 (CO 3 ) 3 , and minerals containing these.
【００１１】本発明で使用するＦｅを含む無機物とは、
非油溶性のＦｅを含む無機物であり、具体的には、例え
ばＦｅ金属、ＦｅＯ、Ｆｅ2Ｏ3、ＦｅＯ（ＯＨ）、Ｆｅ
（ＯＨ）2、ＦｅＣＯ3、ＦｅＳＯ4、ＦｅＣｌ2、ＦｅＣ
ｌ3、Ｆｅ（ＮＯ3）2等が挙げられる。The inorganic substance containing Fe used in the present invention is
An inorganic substance containing non-oil-soluble Fe, specifically, for example, Fe metal, FeO, Fe 2 O 3 , FeO (OH), Fe
(OH) 2 , FeCO 3 , FeSO 4 , FeCl 2 , FeC
l 3 , Fe (NO 3 ) 2 and the like.
【００１２】Ｃｅ及びＦｅを含む無機物の微細粒子の粒
径はできるだけ微細な方が良い。例えば、１μｍ以下が
好ましく、さらに０．１μｍ以下が好ましい。しかしな
がら、このように微粉砕するのにコストがかかるようで
あれば燃料油の粘度にあわせて燃料中で安定に分散でき
る範囲の大きさでもよい。It is preferable that the particle size of the inorganic fine particles containing Ce and Fe be as small as possible. For example, it is preferably 1 μm or less, more preferably 0.1 μm or less. However, if it is costly to pulverize in this way, it may be of a size that can be stably dispersed in the fuel according to the viscosity of the fuel oil.
【００１３】本発明で使用するＣｅを含む油溶性有機酸
塩とは、Ｃｅとナフテン酸、オクチル酸、スルホン酸、
ステアリン酸、パルミチン酸等の有機酸とを反応させた
ものである。具体的には、例えばＣｅナフテン酸、Ｃｅ
オクチル酸、Ｃｅスルホン酸、Ｃｅステアリン酸、Ｃｅ
パルミチン酸等が挙げられる。The oil-soluble organic acid salt containing Ce used in the present invention includes Ce and naphthenic acid, octylic acid, sulfonic acid,
It is obtained by reacting with an organic acid such as stearic acid or palmitic acid. Specifically, for example, Ce naphthenic acid, Ce
Octyl acid, Ce sulfonic acid, Ce stearic acid, Ce
Palmitic acid and the like can be mentioned.
【００１４】本発明で使用するＦｅを含む油溶性有機酸
塩とはＦｅとナフテン酸、オクチル酸、スルホン酸、ス
テアリン酸、パルミチン酸等の有機酸とを反応させたも
のである。具体的には、例えばＦｅナフテン酸、Ｆｅオ
クチル酸、Ｆｅスルホン酸、Ｆｅステアリン酸、Ｆｅス
テアリン酸、Ｆｅパルミチン酸等が挙げられる。The oil-soluble organic acid salt containing Fe used in the present invention is obtained by reacting Fe with an organic acid such as naphthenic acid, octylic acid, sulfonic acid, stearic acid and palmitic acid. Specific examples include Fe naphthenic acid, Fe octylic acid, Fe sulfonic acid, Fe stearic acid, Fe stearic acid, and Fe palmitic acid.
【００１５】本発明の燃料添加剤において、ＦｅとＣｅ
両元素合計量に対するＣｅ含有量は１０〜９０重量％で
あり、好ましくは３０〜８０重量％であり、更に好まし
くは４０〜７０重量％である。Ｃｅ含有量が１０重量％
未満であるとＣｅとＦｅの両元素が接する効率が悪くな
り、助燃効果がＦｅのみの場合とほとんど変わらない。
Ｃｅ含有量が９０重量％を超えるとＣｅとＦｅの両元素
が接する効率が悪くなり、助燃効果がＣｅのみの場合と
ほとんど変わらない。In the fuel additive of the present invention, Fe and Ce
The Ce content based on the total amount of both elements is 10 to 90% by weight, preferably 30 to 80% by weight, and more preferably 40 to 70% by weight. Ce content is 10% by weight
If the amount is less than the above, the efficiency with which both Ce and Fe elements come into contact with each other deteriorates, and the combustion-inhibiting effect is almost the same as when only Fe is used.
When the Ce content exceeds 90% by weight, the efficiency with which both Ce and Fe elements come into contact with each other deteriorates, and the combustion supporting effect is almost the same as when only Ce is used.
【００１６】本発明の燃料添加剤はＣｅを含む無機物の
微細粒子等Ｆｅを含む油溶性有機酸塩、又はＦｅを含む
無機物の微細粒子とＣｅを含む油溶性有機酸塩を溶剤に
溶解したものである。本発明で使用される溶剤は特に限
定されないが、例えば灯油、軽油、重油等の石油系溶
剤、あるいはベンゼン、トルエン、キシレン等の芳香族
系溶剤等が挙げられる。The fuel additive of the present invention comprises Fe-containing oil-soluble organic acid salts such as Ce-containing inorganic fine particles, or Fe-containing inorganic fine particles and Ce-containing oil-soluble organic acid salt dissolved in a solvent. Is. The solvent used in the present invention is not particularly limited, and examples thereof include petroleum-based solvents such as kerosene, light oil and heavy oil, and aromatic-based solvents such as benzene, toluene and xylene.
【００１７】本発明の燃料組成物は上記本発明の燃料添
加剤を燃料に配合したものであるが、燃料に対する燃料
添加剤の含有量は金属量で１重量ｐｐｍ〜１０００重量
ｐｐｍであり、さらに好ましくは５重量ｐｐｍ〜１００
重量ｐｐｍである。１重量ｐｐｍ未満であると量が少な
すぎて媒塵低減効果も小さい。１０００重量ｐｐｍを超
えると逆に添加量の割には媒塵低減効果が上がらない。The fuel composition of the present invention is prepared by blending the fuel additive of the present invention with a fuel. The content of the fuel additive with respect to the fuel is 1 wtppm to 1000 wtppm in terms of metal amount, and Preferably 5 wtppm-100
It is ppm by weight. If it is less than 1 ppm by weight, the amount is too small and the effect of reducing dust is also small. On the other hand, if it exceeds 1000 ppm by weight, the effect of reducing the amount of dust cannot be improved relative to the amount added.
【００１８】[0018]
【作用】本発明の燃料添加剤で媒塵低減効果が大きい理
由としては、Ｃｅ酸化物には酸素を出し入れする酸素ポ
ンプ機能があり、その機能により残炭分の完全燃焼が促
進されていると考えられるが、Ｆｅ酸化物が介在するこ
とでその反応速度がさらに促進されている可能性があ
る。さらにＦｅの添加で生成カーボンの結晶化が低くお
さえられるので燃焼しやすい残留炭素が形成される。こ
れらの効果によりＣｅ、Ｆｅを合わせることで燃焼促進
効果が増大するものと思われる。また、Ｃｅは重油中の
バナジウムと化合し高融点化合物を生成するので、燃焼
生成物による高温腐食を抑制するという利点も合わせて
有している。The reason why the fuel additive of the present invention has a great effect of reducing dust particles is that Ce oxide has an oxygen pumping function for taking in and out oxygen, and that function promotes complete combustion of residual carbon. It is conceivable that the reaction rate may be further accelerated by the presence of Fe oxide. Further, the addition of Fe suppresses the crystallization of the produced carbon to a low level, so that residual carbon that is easily burned is formed. Due to these effects, it is considered that the combustion promoting effect is increased by combining Ce and Fe. Moreover, since Ce combines with vanadium in heavy oil to form a high-melting point compound, it also has an advantage of suppressing high-temperature corrosion due to combustion products.
【００１９】また、ＣｅとＦｅとを組合わせれば大きな
相乗効果が期待できるが両方とも微細粒子では分散性が
悪く、沈降の恐れがある。またＣｅとＦｅが近傍に存在
する確立も低く、大きな相乗効果が期待できない。一方
本発明では微粒子と油溶性化合物では油溶性化合物が界
面活性剤のようなはたらきで微粒子表面に吸着している
と思われるので、ＣｅとＦｅが近傍に存在しつつしかも
分散性が良く、微粒子添加剤の欠点である沈降がほとん
どない。Further, if Ce and Fe are combined, a great synergistic effect can be expected, but in both cases fine particles have poor dispersibility and there is a risk of sedimentation. Further, the probability that Ce and Fe exist in the vicinity is low, and a large synergistic effect cannot be expected. On the other hand, in the present invention, it is considered that the fine particles and the oil-soluble compound are adsorbed on the surface of the fine particles by the action of a surfactant like that of the fine particles and the fine particles and the oil-soluble compounds. There is almost no sedimentation, which is a drawback of the additive.
【００２０】[0020]
【実施例】本発明を実施例及び比較例により、さらに具
体的に以下に説明する。燃焼速度の測定、算出方法、媒
塵量の測定方法及び燃焼炉の条件は以下の通りである。 〔燃焼速度の測定及び算出方法〕燃料添加剤を添加した
燃料油１０ｍｇを示差熱天秤（理学電機製ＴＧ８１１
０）を用い昇温速度１００℃／分で５００℃まで加熱し
燃焼させ５００℃で保持した時の生成残炭の質量減少曲
線から燃焼速度を算出した。空気流量は１００ｍｌ／分
とした。（本測定装置では１００ｍｌ／分以下にすると
空気の拡散律速となり測定値が変動しやすいため）算出
方法は次式を利用した（注（１）、（２））。燃焼速度
定数ｋｓは次式で求められる。EXAMPLES The present invention will be described more specifically below with reference to Examples and Comparative Examples. The measurement and calculation method of the burning rate, the measurement method of the amount of dust and the conditions of the combustion furnace are as follows. [Measurement and Calculation Method of Burning Speed] 10 mg of fuel oil containing a fuel additive was used as a differential thermal balance (TG811 manufactured by Rigaku Denki KK).
0) was used to calculate the burning rate from the mass reduction curve of the produced residual coal when heated to 500 ° C. at a heating rate of 100 ° C./min and burned and held at 500 ° C. The air flow rate was 100 ml / min. (In this measuring device, if the flow rate is 100 ml / min or less, the diffusion rate of air becomes the rate-determining factor, and the measured value tends to fluctuate.) The combustion rate constant ks is calculated by the following equation.
【００２１】[0021]
【数１】 Ａ1：定数、Ｔ：温度、ｍ1、ｍ2：各測定点での質量 σ：表面積、τ：測定点間の時間間隔[Equation 1] A 1 : constant, T: temperature, m 1 , m 2 : mass at each measurement point σ: surface area, τ: time interval between measurement points
【００２２】実際の測定では、Ｔ＝５００℃（一定）、
ｍ1／ｍ2＝２．６（一定）にし、またσ＝一定とみなせ
ば、上式はIn actual measurement, T = 500 ° C. (constant),
Assuming m 1 / m 2 = 2.6 (constant) and σ = constant, the above equation becomes
【００２３】[0023]
【数２】 となるので、１／τで燃焼速度定数の比較ができる。 注（１）柴山ら、日本機械学会論文集、３４（２６
０）、７６９（１９６８） （２）候ら、日本機械学会論文集、５４（５０７）３３
０１（１９８８）[Equation 2] Therefore, the combustion rate constants can be compared by 1 / τ. Note (1) Shibayama et al., Transactions of the Japan Society of Mechanical Engineers, 34 (26
0), 769 (1968) (2) Shi et al., Transactions of the Japan Society of Mechanical Engineers, 54 (507) 33.
01 (1988)
【００２４】〔媒塵量の測定方法〕媒塵量は、排ガス中
のダスト濃度の測定方法（ＪＩＳ Ｚ ８８０８）によ
り測定した。[Measurement Method of Amount of Dust] The amount of dust was measured by a measurement method of dust concentration in exhaust gas (JIS Z 8808).
【００２５】〔燃焼炉の条件〕 燃焼炉 ：ボイラー 油量 ：１００Ｌ／ｈ 排ガスＯ2 ：１％ 蒸気量 ：３０ｋｇ／ｃｍ3 [Conditions of Combustion Furnace] Combustion furnace: Boiler Oil amount: 100 L / h Exhaust gas O 2 : 1% Steam amount: 30 kg / cm 3
【００２６】実施例１〜４ ＣｅＯ2微細粒子をトルエン溶剤にコロイド状に分散さ
せたものにＦｅナフテン酸塩を混合し、表１の金属組成
比で燃料添加剤を調製した。得られた燃料添加剤をＣ重
油（比重０．９４２２、残炭分５．１７ｗｔ％、硫黄分
１．９４ｗｔ％）に金属濃度が０．０３ｗｔ％となるよ
うに添加して得られた燃料組成物について、燃焼速度を
測定した。その結果を表１に示した。Examples 1 to 4 Fe naphthenate was mixed in a colloidal dispersion of fine particles of CeO 2 in a toluene solvent to prepare a fuel additive with the metal composition ratio shown in Table 1. Fuel composition obtained by adding the obtained fuel additive to C heavy oil (specific gravity 0.9422, residual carbon content 5.17 wt%, sulfur content 1.94 wt%) so that the metal concentration becomes 0.03 wt%. The burning rate of the product was measured. The results are shown in Table 1.
【００２７】実施例５〜６ ＦｅＯ2微細粒子をトルエン溶剤にコロイド状に分散さ
せたものに、Ｃｅナフテン酸塩を混合し、表１の金属組
成比で燃料添加剤を調製した以外は実施例１と同様に燃
料組成物を調製して燃焼速度を測定した。その結果を表
１に示したExamples 5 to 6 Examples except that CeO naphthenate was mixed with a dispersion of FeO 2 fine particles in a toluene solvent in a colloidal form to prepare a fuel additive at the metal composition ratio shown in Table 1. A fuel composition was prepared in the same manner as in No. 1, and the burning rate was measured. The results are shown in Table 1.
【００２８】比較例１ ＣｅＯ2微細粒子をトルエン溶剤にコロイド状に分散さ
せた燃料添加剤を調製した以外は実施例１と同様に燃料
組成物を調製して燃焼速度を測定した。その結果を表１
に示した。Comparative Example 1 A fuel composition was prepared and the burning rate was measured in the same manner as in Example 1 except that a fuel additive was prepared by dispersing CeO 2 fine particles in a toluene solvent in a colloidal form. The results are shown in Table 1.
It was shown to.
【００２９】比較例２ ＦｅＯ2微細粒子とトルエン溶剤にコロイド状に分散さ
せた燃料添加剤を調製した以外は実施例１と同様に燃料
組成物を調製して燃焼速度を測定した。その結果を表１
に示した。Comparative Example 2 A fuel composition was prepared in the same manner as in Example 1 except that a fuel additive prepared by colloidally dispersing FeO 2 fine particles and a toluene solvent was prepared, and the burning rate was measured. The results are shown in Table 1.
It was shown to.
【００３０】比較例３ 燃料添加剤を用いないで、実施例１の上記Ｃ重油につい
て燃焼速度を測定し、その結果を表１に示した。Comparative Example 3 The burning rate of the above C heavy oil of Example 1 was measured without using the fuel additive, and the results are shown in Table 1.
【００３１】実施例７ 実施例３で得られた燃料添加剤を実施例１の上記Ｃ重油
について金属量が３０ｐｐｍとなるように添加し燃料組
成物を調製した。燃焼炉で燃焼実験を行い燃焼炉での媒
塵量を測定した。その結果を表２に示した。Example 7 A fuel composition was prepared by adding the fuel additive obtained in Example 3 to the above C heavy oil of Example 1 so that the metal content was 30 ppm. Combustion experiments were conducted in a combustion furnace to measure the amount of dust particles in the combustion furnace. The results are shown in Table 2.
【００３２】実施例８ 実施例６で得られた燃料添加剤を用いて、実施例７と同
様に燃料組成物を調製し、同様に媒塵量を測定した。そ
の結果を表２に示した。Example 8 A fuel composition was prepared in the same manner as in Example 7 using the fuel additive obtained in Example 6, and the amount of dust was measured in the same manner. The results are shown in Table 2.
【００３３】比較例４ 比較例１で得られた燃料添加剤を用いて、実施例７と同
様に燃料組成物を調製し、同様に媒塵量を測定した。そ
の結果を表２に示した。Comparative Example 4 A fuel composition was prepared in the same manner as in Example 7 using the fuel additive obtained in Comparative Example 1, and the amount of dust was measured in the same manner. The results are shown in Table 2.
【００３４】比較例５ 燃料添加剤を用いないで、実施例１の上記Ｃ重油につい
て実施例７と同様に媒塵量を測定した。その結果を表２
に示した。Comparative Example 5 The amount of dust was measured in the same manner as in Example 7 with respect to the above C heavy oil of Example 1 without using the fuel additive. The results are shown in Table 2.
It was shown to.
【００３５】[0035]
【表１】 [Table 1]
【００３６】[0036]
【表２】 [Table 2]
【００３７】実施例１〜８及び比較例１〜５から次のこ
とが言える。 本発明の燃料添加剤を用いる実施例１〜６では燃焼速
度が大きい。 比較例１のＣｅＯ2微細粒子のみを用いた燃料添加剤
ケース、比較例２のＦｅＯ2微細粒子のみを用いた燃料
添加剤ケース及び比較例３の燃料添加剤を用いないケー
スは、いずれも燃焼速度が大きい。 本発明の燃料添加剤を用いる実施例５〜６では媒塵の
抑制効果が顕著で、また、使用に際して燃料添加剤の沈
降は見られなかった。 比較例４のＣｅＯ2微細粒子のみを用いた燃料添加剤
ケース及び比較例５の燃料添加剤を用いないケースは媒
塵量が多い。The following can be said from Examples 1 to 8 and Comparative Examples 1 to 5. The burning rate is high in Examples 1 to 6 using the fuel additive of the present invention. The fuel additive case using only CeO 2 fine particles of Comparative Example 1, the fuel additive case using only FeO 2 fine particles of Comparative Example 2, and the case not using the fuel additive of Comparative Example 3 are both burned. The speed is high. In Examples 5 to 6 in which the fuel additive of the present invention was used, the effect of suppressing dust was remarkable, and no precipitation of the fuel additive was observed during use. The fuel additive case using only CeO 2 fine particles of Comparative Example 4 and the case not using the fuel additive of Comparative Example 5 have a large amount of dust.
【００３８】[0038]
【発明の効果】本発明の燃料添加剤は、比較的安価で、
燃料への分散性が良く、装置の腐食が少なく、さらに、
燃焼促進効果が大きいため煤煙抑制効果が高いという利
点を有する。The fuel additive of the present invention is relatively inexpensive and
Good dispersibility in fuel, less corrosion of equipment,
Since it has a large effect of promoting combustion, it has an advantage that the effect of suppressing soot is high.
Claims (4)
む油溶性有機酸塩又はＦｅを含む無機物の微細粒子とＣ
ｅを含む油溶性有機酸塩を含むことを特徴とする燃料添
加剤。1. Fine particles of an inorganic substance containing Ce and an oil-soluble organic acid salt containing Fe or fine particles of an inorganic substance containing Fe and C
A fuel additive comprising an oil-soluble organic acid salt containing e.
有量が１０〜９０重量％であることを特徴とする請求項
１記載の燃料添加剤。2. The fuel additive according to claim 1, wherein the Ce content is 10 to 90% by weight based on the total amount of both Fe and Ce elements.
Ｆｅを含む油溶性有機酸塩又はＦｅを含む無機物の微細
粒子とＣｅを含む油溶性有機酸塩を含む燃料添加剤が配
合されていることを特徴とする燃料組成物。3. The fuel is blended with an inorganic fine particle containing Ce and an oil-soluble organic acid salt containing Fe or a fuel additive containing an inorganic fine particle containing Fe and an oil-soluble organic acid salt containing Ce. A fuel composition comprising:
量で１重量ｐｐｍ〜１０００重量ｐｐｍであることを特
徴とする請求項３記載の燃料組成物。4. The fuel composition according to claim 3, wherein the content of the fuel additive with respect to the fuel is 1 wtppm to 1000 wtppm in terms of metal amount.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10908394A JP3609119B2 (en) | 1994-04-25 | 1994-04-25 | Fuel additive and fuel composition containing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10908394A JP3609119B2 (en) | 1994-04-25 | 1994-04-25 | Fuel additive and fuel composition containing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07292373A true JPH07292373A (en) | 1995-11-07 |
| JP3609119B2 JP3609119B2 (en) | 2005-01-12 |
Family
ID=14501174
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10908394A Expired - Fee Related JP3609119B2 (en) | 1994-04-25 | 1994-04-25 | Fuel additive and fuel composition containing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3609119B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08120286A (en) * | 1994-10-25 | 1996-05-14 | Yoichi Nishimura | Substance for purifying fuel, etc., method for purifying fuel, etc., by using same, and fuel combustion apparatus using same |
| WO2001096502A1 (en) * | 2000-06-14 | 2001-12-20 | I.B.E. Co., Ltd. | Fuel modifier |
| JP2005126653A (en) * | 2003-10-20 | 2005-05-19 | Unylec:Kk | Oil modifier and modified oil composition |
-
1994
- 1994-04-25 JP JP10908394A patent/JP3609119B2/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08120286A (en) * | 1994-10-25 | 1996-05-14 | Yoichi Nishimura | Substance for purifying fuel, etc., method for purifying fuel, etc., by using same, and fuel combustion apparatus using same |
| WO2001096502A1 (en) * | 2000-06-14 | 2001-12-20 | I.B.E. Co., Ltd. | Fuel modifier |
| JP2001354979A (en) * | 2000-06-14 | 2001-12-25 | Ibe:Kk | Fuel modifier |
| JP2005126653A (en) * | 2003-10-20 | 2005-05-19 | Unylec:Kk | Oil modifier and modified oil composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3609119B2 (en) | 2005-01-12 |
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