JPH06287609A - Production of stepped cemented carbide material - Google Patents

Production of stepped cemented carbide material

Info

Publication number
JPH06287609A
JPH06287609A JP5095189A JP9518993A JPH06287609A JP H06287609 A JPH06287609 A JP H06287609A JP 5095189 A JP5095189 A JP 5095189A JP 9518993 A JP9518993 A JP 9518993A JP H06287609 A JPH06287609 A JP H06287609A
Authority
JP
Japan
Prior art keywords
powder
density compression
compression molded
cemented carbide
stepped
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5095189A
Other languages
Japanese (ja)
Inventor
Yoshihiro Kawagishi
美裕 川岸
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokyo Rope Manufacturing Co Ltd
Tokyo Seiko Co Ltd
Original Assignee
Tokyo Rope Manufacturing Co Ltd
Tokyo Seiko Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokyo Rope Manufacturing Co Ltd, Tokyo Seiko Co Ltd filed Critical Tokyo Rope Manufacturing Co Ltd
Priority to JP5095189A priority Critical patent/JPH06287609A/en
Publication of JPH06287609A publication Critical patent/JPH06287609A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To provide the process for production of the stepped cemented carbide material which improves quality and reliability together with productivity and reduces a cost by a clearance formed between both high-density compression molded articles of a large diameter and a small diameter and shrinkage on sintering varying from each other. CONSTITUTION:The high-density compression molded article 3 of the small diameter formed by press forming of sintered hard alloy powder is inserted into a central hole 2 of the high-density compression molded article 1 of the large diameter formed by press forming of the cemented carbide powder and after both high-density compression molded articles 1 and 3 are set in a stepped state by forming the clearance alpha therebetween, these two high-density compression molded articles 1, 3 are sintered and the clearance alpha is eliminated by the shrinkage on sintering varying from each other to form a sintered compact 10 which is integrally joined and stepped. The powder P for sintered hard alloy, such as Co powder or Ni powder, is otherwise injected into the clearance alphaformed between both high-density compression molded articles 1 and 3 and thereafter the high-density compression molded articles 1, 3 are sintered.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、超硬合金製の金型の部
品やガイドブッシュ等の素材として好適な段付き超硬合
金材の製法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a stepped cemented carbide material which is suitable as a material for metal mold parts and guide bushes made of cemented carbide.

【0002】[0002]

【従来の技術】従来、耐摩耗性を必要とする部品には強
度、硬度ともに優れた超硬合金材が使用されている。例
えば、各種の金型の部品やガイドブッシュ等では、その
摩耗部分に超硬合金材、それ以外の部分にはスチール材
を用い、超硬合金にスチールをロー付けして接合した段
付き形状にする場合がある。しかし、前記のような段付
き形状の場合はそのロー付け部分の強度が弱いため、最
近、全体を超硬合金で一体に形成する要望が多くなり、
比較的に段差の小さい形状のものは、超硬合金粉末をプ
レス成形した高密度圧縮成形体を焼結して、焼結後に研
削して段付き焼結体に形成し、段差の大きい形状のもの
は、焼結前の高密度圧縮成形体を削つて段付き高密度圧
縮成形体とし、この段付き高密度圧縮成形体を焼結して
段付き焼結体に形成する段付き超硬合金材の製法が開発
されている。
2. Description of the Related Art Conventionally, cemented carbide materials having excellent strength and hardness have been used for parts requiring wear resistance. For example, in various mold parts and guide bushes, cemented carbide material is used for the worn parts and steel material for the other parts, and the stepped shape is obtained by brazing steel to the cemented carbide and joining it. There is a case. However, in the case of the stepped shape as described above, the strength of the brazed portion is weak, so recently, there is a growing demand for integrally forming the whole body with a cemented carbide,
For those with a relatively small step, a high-density compression-molded body obtained by press-molding cemented carbide powder is sintered, and after sintering, it is ground to form a stepped sintered body. The stepped cemented carbide is formed by scraping the high-density compression molded body before sintering into a stepped high-density compression molded body, and sintering the stepped high-density compression molded body to form a stepped sintered body. The manufacturing method of wood is being developed.

【0003】[0003]

【発明が解決しようとする課題】従来の段付き超硬合金
材は、前記のように高密度圧縮成形体の焼結後に研削し
て段付き焼結体に形成したり、又は焼結前に削つて段付
き高密度圧縮成形体に形成した後、焼結して段付き焼結
体に形成され、その高硬度の焼結体や焼結前の高密度圧
縮成形体の段付け削取加工に多くの時間、手数を要し、
削り粉が多く発生して不経済になるなど、生産性の低下
やコスト高などの課題がある。
The conventional step cemented carbide material is ground into a stepped sintered body by grinding after the sintering of the high-density compression molded article as described above, or before sintering. After cutting and forming into a stepped high-density compression molded body, it is sintered and formed into a stepped sintered body, and the high hardness sintered body and stepped cutting processing of the high-density compression molded body before sintering Takes a lot of time and effort,
There are problems such as a decrease in productivity and an increase in cost, such as a large amount of shavings and uneconomical.

【0004】本発明は、前記のような課題に対処するた
めに開発されたものであつて、その目的とする処は、太
径と細径の両高密度圧縮成形体の間に形成したクリアラ
ンスと両者の異なる焼結収縮により、生産性とともに品
質、信頼性を向上しコスト節減を可能にした段付き超硬
合金材の製法を提供するにある。
The present invention was developed in order to solve the above-mentioned problems, and the object of the present invention is to provide a clearance formed between high-density compression moldings of both large diameter and small diameter. The purpose of the present invention is to provide a method for manufacturing a stepped cemented carbide material, which improves the quality and reliability as well as the productivity by reducing the different sintering shrinkages and enables cost reduction.

【0005】[0005]

【課題を解決するための手段】本発明は、超硬合金粉末
をプレス成形した太径の高密度圧縮成形体の中穴に、超
硬合金粉末をプレス成形した細径の高密度圧縮成形体を
嵌挿し、両高密度圧縮成形体の間にクリアランスを形成
して段付き状態にセツトした後、両高密度圧縮成形体を
焼結して異なる焼結収縮によりクリアランスをなくし一
体に接合した段付き焼結体に形成することにより、太径
と細径の両高密度圧縮成形体を均質、一体に連設して接
合精度、信頼性を高め、段付け削取加工を殆んど不必要
とし生産性を高めている。
DISCLOSURE OF THE INVENTION The present invention provides a high-density compression molding of small diameter in which a cemented carbide powder is press-molded in the inner hole of a large-diameter high-density compression molding of press-molded cemented carbide powder. After inserting and inserting a clearance between the two high-density compression molded bodies to set them in a stepped state, the high-density compression molded bodies are sintered and the clearance is eliminated by different sintering shrinkage, and the steps are joined together. By forming a sintered body with a large diameter, high-density compression moldings of both large diameter and small diameter can be homogenously and integrally connected to improve the joining accuracy and reliability, and the step cutting process is almost unnecessary. And increase productivity.

【0006】また、前記の段付き超硬合金材の製法にお
いて、両高密度圧縮成形体の間に形成したクリアランス
にCo粉末あるいはまたNi粉末等の超硬合金用粉末を
注入した後、両高密度圧縮成形体を焼結することによ
り、両高密度圧縮成形体の接合精度、信頼性をさらに高
めている。
Further, in the above method for producing a stepped cemented carbide material, after the powder for cemented carbide such as Co powder or Ni powder is injected into the clearance formed between both high density compression molded bodies, By sintering the density compression molded product, the joining accuracy and reliability of both high density compression molded products are further enhanced.

【0007】[0007]

【作用】超硬合金粉末をプレス成形した太径の高密度圧
縮成形体の中穴に、超硬合金粉末をプレス成形した細径
の高密度圧縮成形体を嵌挿し、両高密度圧縮成形体の間
にクリアランスを形成して段付き状態にセツトした後、
両高密度圧縮成形体を焼結して異なる焼結収縮によりク
リアランスをなくし一体に接合した段付き焼結体に形成
し、太径と細径の両高密度圧縮成形体を均質、一体に連
設して接合精度、信頼性を効果的に高め、段付け削取加
工を殆んど不必要にしている。
[Function] Both of the high-density compression molded articles are obtained by inserting the small-diameter high-density compression molded article obtained by press-molding the cemented carbide alloy powder into the middle hole of the large-diameter high-density compression molded article obtained by press-molding the cemented carbide powder. After forming a clearance between and setting it in a stepped state,
Both high-density compression compacts are sintered to form a stepped sintered compact that eliminates clearance due to different sintering shrinkage and is joined together. By installing it, the joining accuracy and reliability are effectively improved, and the step cutting work is almost unnecessary.

【0008】また、両高密度圧縮成形体の間に形成した
クリアランスにCo粉末あるいはまたNi粉末等の超硬
合金用粉末を注入した後、両高密度圧縮成形体を焼結す
ることにより、両高密度圧縮成形体の一体接合の強度や
精度、信頼性をさらに高めている。
In addition, by injecting a powder for cemented carbide such as Co powder or Ni powder into the clearance formed between the two high-density compression molded bodies, and then sintering both high-density compression molded bodies, The strength, precision, and reliability of the high-density compression-molded body are integrally joined.

【0009】[0009]

【実施例】図1(A)(B)に本発明の一実施例を示
す。図中1は超硬合金粉末をプレス成形した比較的に太
径の高密度圧縮成形体、2は高密度圧縮成形体1に形成
した中穴、3は超硬合金粉末をプレス成形した比較的に
細径の高密度圧縮成形体、5は焼結用のカーボン板、α
は高密度圧縮成形体1と3の間に形成したクリアラン
ス、Pは中穴2に注入したCo粉末あるいはまたNi粉
末等の超硬合金用粉末、10は段付き焼結体であつて、
太径の高密度圧縮成形体1は、WC粉末、Co粉末、N
i粉末等あるいはまたTiC粉末、VC粉末、Cr3
2 粉末、ZrC粉末、NbC粉末、Mo2 C粉末、Hf
C粉末、TaC粉末等を所望の比率で混合して各種の組
成にした粉末冶金用の粉末、即ち超硬合金粉末を金型プ
レス等により均等にプレス成形したものであり、そのプ
レス成形時あるいはプレス成形後に中穴2を形成する。
また、細径の高密度圧縮成形体3は、前記のような粉末
を所望の比率で混合して各種の組成にした粉末冶金用の
粉末、即ち超硬合金粉末を金型プレス等により均等にプ
レス成形したものであり、その高密度圧縮成形体3の断
面外形状は円形、楕円形、多角形等に形成され、高密度
圧縮成形体1とその中穴2の断面形状は、高密度圧縮成
形体3の断面形状に対応した形状として所望のクリアラ
ンスαが確保されている。中穴2に注入される超硬合金
用粉末Pとしては、好ましくはCo粉末、Ni粉末ある
いはCo粉末とNi粉末の混合粉末が適用される。
1A and 1B show an embodiment of the present invention. In the figure, 1 is a relatively large-diameter high-density compression-molded body obtained by press-molding a cemented carbide powder, 2 is a middle hole formed in the high-density compression-molded body 1, 3 is a relatively-high-density compression-molded body obtained by press-molding a cemented carbide powder. A high-density compression molded product with a small diameter, 5 a carbon plate for sintering, α
Is a clearance formed between the high-density compression molded bodies 1 and 3, P is a powder for cemented carbide such as Co powder or Ni powder injected into the inner hole 2, and 10 is a stepped sintered body,
The large-diameter high-density compression molded body 1 is composed of WC powder, Co powder, N
i powder, etc. or TiC powder, VC powder, Cr 3 C
2 powder, ZrC powder, NbC powder, Mo 2 C powder, Hf
C powder, TaC powder, etc. are mixed in a desired ratio to form powders for powder metallurgy, that is, cemented carbide powder is uniformly press-molded by a die press or the like. After press forming, the inner hole 2 is formed.
Further, the small-diameter high-density compression molded body 3 is obtained by uniformly mixing powders for powder metallurgy having various compositions by mixing the above-mentioned powders in a desired ratio, that is, cemented carbide powder by a die press or the like. The high-density compression molded body 3 is formed by press molding, and the cross-sectional outer shape of the high-density compression molded body 3 is formed into a circle, an ellipse, a polygon, or the like. A desired clearance α is secured as a shape corresponding to the cross-sectional shape of the molded body 3. As the cemented carbide powder P injected into the inner hole 2, Co powder, Ni powder, or a mixed powder of Co powder and Ni powder is preferably applied.

【0010】図1に示す実施例は、図1(A)のように
超硬合金粉末を圧縮成形した太径の高密度圧縮成形体1
の中穴2に、超硬合金粉末を圧縮成形した細径の高密度
圧縮成形体3を嵌挿し、両高密度圧縮成形体1と3の間
に適度のクリアランスαを形成して段付き状態にセツト
した後、両高密度圧縮成形体1,3を焼結して異なる焼
結収縮によりクリアランスαをなくし一体に接合した段
付き焼結体10(図1B参照)に形成する粉末冶金法に
よる段付超硬合金材の製法とし、また、その粉末冶金法
による段付超硬合金材の製法において、両高密度圧縮成
形体1,3の間に形成したクリアランスαにCo粉末あ
るいはまたNi粉末等の超硬合金用粉末Pを注入した
後、両高密度圧縮成形体1,3を焼結することを特徴と
する粉末冶金法による段付き超硬合金材の製法になつて
いる。
The embodiment shown in FIG. 1 is a large-diameter high-density compression-molded body 1 obtained by compression-molding cemented carbide powder as shown in FIG. 1 (A).
A small-diameter high-density compression-molded body 3 obtained by compression-molding cemented carbide powder is fitted into the inner hole 2 of the hollow body, and an appropriate clearance α is formed between the high-density compression-molded bodies 1 and 3 to form a stepped state. After the above-mentioned steps, the two high-density compression-molded bodies 1 and 3 are sintered to form a stepped sintered body 10 (see FIG. 1B) integrally bonded by eliminating the clearance α due to different sintering shrinkages. In the method of manufacturing a stepped cemented carbide material, and in the method of manufacturing a stepped cemented carbide material by the powder metallurgy method, the clearance α formed between the both high-density compression molded bodies 1 and 3 is made of a cemented carbide such as Co powder or Ni powder. After the alloy powder P is injected, both the high-density compression-molded bodies 1 and 3 are sintered, which is a method for producing a stepped cemented carbide material by a powder metallurgy method.

【0011】さらに、前記段付き超硬合金材の製法にお
いて、高密度圧縮成形体1と3は、必要に応じて異なる
組成に形成される。例えば、太径の高密度圧縮成形体1
は、WC−20%Coのような比較的に靭性に富む組成
とし、細径の高密度圧縮成形体3は、WC−7%Coの
ような比較的に高硬度の組成として耐摩耗性を高めるな
ど、製品に対応した超硬合金の粉末組成として製品の汎
用性を高める。
Further, in the method for manufacturing the stepped cemented carbide material, the high-density compression molded bodies 1 and 3 are formed to have different compositions, if necessary. For example, a thick high-density compression molded body 1
Is a composition having a relatively high toughness such as WC-20% Co, and the thin high-density compression-molded body 3 has a composition having a relatively high hardness such as WC-7% Co and exhibits wear resistance. Increase the versatility of the product as a powder composition of cemented carbide corresponding to the product.

【0012】また、太径の高密度圧縮成形体1に形成し
た中穴2は、図1(A)に示すように細径の高密度圧縮
成形体3に対し程良く大径に形成して所望のクリアラン
スαを形成する。このクリアランスαは、細径の高密度
圧縮成形体3の直径の0.5〜5%範囲にするのが好ま
しく、一方、太径の高密度圧縮成形体1の焼結による収
縮率は細径の高密度圧縮成形体3よりも適度に大きくす
る。例えば、両高密度圧縮成形体1と3のプレス圧力を
変えて成形し(プレス圧力を小さくすると収縮率が大き
くなる)、具体的には細径の高密度圧縮成形体3に対し
太径の高密度圧縮成形体1の収縮率を1〜5.5%増加
することが肝要であり、両高密度圧縮成形体1,3を図
1(A)に示すように焼結用のカーボン板5上に段付き
状態にしてセツトし、焼結炉内で焼結条件(1300〜
1500℃、0.5〜2時間)に従って焼結処理する
と、図1(B)に示すような段付き焼結体10に焼結さ
れ、この焼結に際し、細径の高密度圧縮成形体3に対し
太径の高密度圧縮成形体1が適度に異なる大きい焼結収
縮によりクリアランスαが効果的になくなり、両高密度
圧縮成形体1,3が均質に一体接合される。即ち、前記
のクリアランスと焼結収縮差のバランスにより接合部の
粉体密度の過不足がなく適度に平均化されて、段付き高
密度圧縮成形体の焼結に際し生じる太径部分と細径部分
の密度差が解消され、太径部分10aと細径部分10b
及びその接合部分が全体に均質に一体接合されて優れた
精度、品質が得られる。
Further, as shown in FIG. 1 (A), the inner hole 2 formed in the large-diameter high-density compression molded body 1 is formed to have a large diameter reasonably large with respect to the small-diameter high-density compression molded body 3. Form the desired clearance α. This clearance α is preferably in the range of 0.5 to 5% of the diameter of the thin high-density compression molded body 3, while the shrinkage rate of the large-diameter high-density compression molded body 1 due to sintering is small. The density is appropriately larger than that of the high-density compression molded body 3. For example, the two high-density compression molded bodies 1 and 3 are molded by changing the pressing pressure (reducing the pressing pressure increases the shrinkage ratio). It is essential to increase the shrinkage rate of the high-density compression molded body 1 by 1 to 5.5%. As shown in FIG. 1 (A), both of the high-density compression molded bodies 1 and 3 have a carbon plate 5 for sintering. Set it in a stepped state on top and set it in the sintering furnace (1300-300).
When subjected to a sintering treatment at 1500 ° C. for 0.5 to 2 hours, it is sintered into a stepped sintered body 10 as shown in FIG. 1B, and at the time of this sintering, a small diameter high density compression molded body 3 On the other hand, the large-diameter high-density compression-molded body 1 has a moderately different large sintering shrinkage, so that the clearance α is effectively eliminated, and the high-density compression-molded bodies 1 and 3 are uniformly and integrally joined. That is, due to the balance between the clearance and the difference in sintering shrinkage, there is no excess or deficiency in the powder density of the joint portion and the particles are appropriately averaged, and the large diameter portion and the small diameter portion generated during the sintering of the stepped high density compression molded body are obtained. The density difference between the two is eliminated, and the large diameter portion 10a and the small diameter portion 10b
And the joint portion thereof is uniformly and integrally joined to the whole, so that excellent accuracy and quality can be obtained.

【0013】また、両高密度圧縮成形体1,3の間に形
成したクリアランスαにCo粉末あるいはまたNi粉末
等の超硬合金用粉末Pを注入する場合は、前記のクリア
ランスαがさらに+0.5%まで増加可能となり、その
超硬合金用粉末Pは、焼結により両高密度圧縮成形体
1,3の間で同様な組成となりさらに精度良く接合され
て信頼性がさらに高められる。
When the powder P for cemented carbide such as Co powder or Ni powder is injected into the clearance α formed between the two high-density compression molded bodies 1, 3, the clearance α is further +0. It is possible to increase up to 5%, and the cemented carbide powder P has a similar composition between the two high-density compression molded bodies 1 and 3 by sintering, and is joined more accurately to further improve reliability.

【0014】[0014]

【発明の効果】本発明は、前述のように超硬合金粉末を
プレス成形した太径の高密度圧縮成形体の中穴に、超硬
合金粉末をプレス成形した細径の高密度圧縮成形体を嵌
挿し、両高密度圧縮成形体の間にクリアランスを形成し
て段付き状態にセツトした後、両高密度圧縮成形体を焼
結して異なる焼結収縮によりクリアランスをなくし一体
に接合した段付き焼結体に容易に均質に精度良く形成さ
れ、段付け削取加工が殆んど不必要となり、生産性とと
もに両高密度圧縮成形体の強度や精度、品質、信頼性が
著しく向上されている。
Industrial Applicability The present invention has a small diameter high-density compression-molded product obtained by press-molding a cemented-metal alloy powder in the inner hole of a large-diameter high-density compression-molded product obtained by press-molding a cemented-metal alloy powder as described above. After inserting and inserting a clearance between the two high-density compression molded bodies to set them in a stepped state, the high-density compression molded bodies are sintered and the clearance is eliminated by different sintering shrinkage, and the steps are joined together. It can be easily and homogeneously formed on the attached sintered body with high accuracy, and the step cutting process is almost unnecessary, and the strength, precision, quality and reliability of both high density compression molded bodies are significantly improved along with the productivity. There is.

【0015】また、両高密度圧縮成形体の間に形成した
クリアランスに超硬合金用粉末を注入した後、両高密度
圧縮成形体を焼結することにより、両高密度圧縮成形体
の接合精度、信頼性がさらに高められ、従ってまた、大
幅なコスト節減が可能になつている。
Further, by injecting the cemented carbide powder into the clearance formed between the two high-density compression molded bodies, and then sintering the two high-density compression molded bodies, the joining accuracy of both high-density compression molded bodies is improved. However, the reliability is further increased, and therefore, significant cost savings are also possible.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例を示す焼結前の側面図(一部
断面)(A)と段付き焼結体の側面図(B)である。
FIG. 1 is a side view (partial cross section) (A) before sintering showing an embodiment of the present invention and a side view (B) of a stepped sintered body.

【符号の説明】[Explanation of symbols]

1 高密度圧縮成形体(太径) 2 中穴 3 高密度圧縮成形体(細径) 10 段付き焼結体 α クリアランス P 超硬合金用粉末(Co粉末,Ni粉末等) 1 High Density Compression Molded Body (Large Diameter) 2 Medium Hole 3 High Density Compression Molded Body (Small Diameter) 10 Stepped Sintered Body α Clearance P Cemented Carbide Powder (Co Powder, Ni Powder, etc.)

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 超硬合金粉末をプレス成形した太径の高
密度圧縮成形体の中穴に、超硬合金粉末をプレス成形し
た細径の高密度圧縮成形体を嵌挿し、両高密度圧縮成形
体の間にクリアランスを形成して段付き状態にセツトし
た後、両高密度圧縮成形体を焼結して異なる焼結収縮に
よりクリアランスをなくし一体に接合した段付き焼結体
に形成することを特徴とする段付き超硬合金材の製法。
1. A small-diameter high-density compression molded product obtained by press-molding a cemented carbide powder is inserted into a middle hole of a large-diameter high-density compression molded product obtained by press-molding a cemented carbide powder, and both high-density compressions are performed. After forming a clearance between the compacts and setting them in a stepped state, sinter both high-density compression compacts to eliminate the clearances due to different sintering shrinkage and form a stepped sintered compact that is integrally joined. A method of manufacturing a stepped cemented carbide material characterized by.
【請求項2】 請求項1記載の段付き超硬合金材の製法
において、前記の両高密度圧縮成形体の間に形成したク
リアランスにCo粉末あるいはまたNi粉末等の超硬合
金用粉末を注入した後、両高密度圧縮成形体を焼結する
ことを特徴とする段付き超硬合金材の製法。
2. The stepped cemented carbide material manufacturing method according to claim 1, wherein a powder for cemented carbide such as Co powder or Ni powder is injected into the clearance formed between the two high-density compression molded bodies. And then sintering both high-density compression-molded bodies, a method for producing a stepped cemented carbide material.
JP5095189A 1993-03-31 1993-03-31 Production of stepped cemented carbide material Pending JPH06287609A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5095189A JPH06287609A (en) 1993-03-31 1993-03-31 Production of stepped cemented carbide material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5095189A JPH06287609A (en) 1993-03-31 1993-03-31 Production of stepped cemented carbide material

Publications (1)

Publication Number Publication Date
JPH06287609A true JPH06287609A (en) 1994-10-11

Family

ID=14130812

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5095189A Pending JPH06287609A (en) 1993-03-31 1993-03-31 Production of stepped cemented carbide material

Country Status (1)

Country Link
JP (1) JPH06287609A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014131749A (en) * 2014-02-05 2014-07-17 Seiko Epson Corp Dental implant
CN104439254A (en) * 2014-10-31 2015-03-25 浙江恒成硬质合金有限公司 Large scale hard alloy butting joint process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014131749A (en) * 2014-02-05 2014-07-17 Seiko Epson Corp Dental implant
CN104439254A (en) * 2014-10-31 2015-03-25 浙江恒成硬质合金有限公司 Large scale hard alloy butting joint process

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