JPH0588203B2 - - Google Patents
Info
- Publication number
- JPH0588203B2 JPH0588203B2 JP60064206A JP6420685A JPH0588203B2 JP H0588203 B2 JPH0588203 B2 JP H0588203B2 JP 60064206 A JP60064206 A JP 60064206A JP 6420685 A JP6420685 A JP 6420685A JP H0588203 B2 JPH0588203 B2 JP H0588203B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- residue
- present
- amphoteric surfactants
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002280 amphoteric surfactant Substances 0.000 claims description 15
- -1 hydroquinone glycosides Chemical class 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 238000011282 treatment Methods 0.000 claims description 8
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N 1,4-Benzenediol Natural products OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 7
- 229930182470 glycoside Natural products 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- 125000003712 glycosamine group Chemical group 0.000 claims 1
- 125000000625 hexosyl group Chemical group 0.000 claims 1
- 125000001805 pentosyl group Chemical group 0.000 claims 1
- 239000002453 shampoo Substances 0.000 claims 1
- BJRNKVDFDLYUGJ-RMPHRYRLSA-N hydroquinone O-beta-D-glucopyranoside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1=CC=C(O)C=C1 BJRNKVDFDLYUGJ-RMPHRYRLSA-N 0.000 description 15
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 13
- 230000000694 effects Effects 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 229960000271 arbutin Drugs 0.000 description 7
- 229960003237 betaine Drugs 0.000 description 7
- BJRNKVDFDLYUGJ-UHFFFAOYSA-N p-hydroxyphenyl beta-D-alloside Natural products OC1C(O)C(O)C(CO)OC1OC1=CC=C(O)C=C1 BJRNKVDFDLYUGJ-UHFFFAOYSA-N 0.000 description 7
- 239000008213 purified water Substances 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- 230000003020 moisturizing effect Effects 0.000 description 6
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 239000003676 hair preparation Substances 0.000 description 3
- 235000000346 sugar Nutrition 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- WQZGKKKJIJFFOK-SVZMEOIVSA-N (+)-Galactose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-SVZMEOIVSA-N 0.000 description 2
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 2
- LNCJHVLXANMHHD-UHFFFAOYSA-N 2-[2-heptadecyl-1-(2-hydroxyethyl)-4,5-dihydroimidazol-1-ium-1-yl]acetate Chemical compound CCCCCCCCCCCCCCCCCC1=NCC[N+]1(CCO)CC([O-])=O LNCJHVLXANMHHD-UHFFFAOYSA-N 0.000 description 2
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- PYMYPHUHKUWMLA-LMVFSUKVSA-N aldehydo-D-ribose Chemical group OC[C@@H](O)[C@@H](O)[C@@H](O)C=O PYMYPHUHKUWMLA-LMVFSUKVSA-N 0.000 description 2
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Chemical group OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 2
- MSWZFWKMSRAUBD-UHFFFAOYSA-N beta-D-galactosamine Natural products NC1C(O)OC(CO)C(O)C1O MSWZFWKMSRAUBD-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 150000002337 glycosamines Chemical group 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- GOHZKUSWWGUUNR-UHFFFAOYSA-N 2-(4,5-dihydroimidazol-1-yl)ethanol Chemical compound OCCN1CCN=C1 GOHZKUSWWGUUNR-UHFFFAOYSA-N 0.000 description 1
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 1
- MSWZFWKMSRAUBD-GASJEMHNSA-N 2-amino-2-deoxy-D-galactopyranose Chemical compound N[C@H]1C(O)O[C@H](CO)[C@H](O)[C@@H]1O MSWZFWKMSRAUBD-GASJEMHNSA-N 0.000 description 1
- MSFSPUZXLOGKHJ-PGYHGBPZSA-N 2-amino-3-O-[(R)-1-carboxyethyl]-2-deoxy-D-glucopyranose Chemical compound OC(=O)[C@@H](C)O[C@@H]1[C@@H](N)C(O)O[C@H](CO)[C@H]1O MSFSPUZXLOGKHJ-PGYHGBPZSA-N 0.000 description 1
- BKTMEKOLXCZRFW-UHFFFAOYSA-N 3-(octadecylamino)propanoic acid Chemical compound CCCCCCCCCCCCCCCCCCNCCC(O)=O BKTMEKOLXCZRFW-UHFFFAOYSA-N 0.000 description 1
- RFSUNEUAIZKAJO-VRPWFDPXSA-N D-Fructose Natural products OC[C@H]1OC(O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-VRPWFDPXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- BJHIKXHVCXFQLS-PUFIMZNGSA-N D-psicose Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)C(=O)CO BJHIKXHVCXFQLS-PUFIMZNGSA-N 0.000 description 1
- ZAQJHHRNXZUBTE-NQXXGFSBSA-N D-ribulose Chemical compound OC[C@@H](O)[C@@H](O)C(=O)CO ZAQJHHRNXZUBTE-NQXXGFSBSA-N 0.000 description 1
- LKDRXBCSQODPBY-OEXCPVAWSA-N D-tagatose Chemical compound OCC1(O)OC[C@@H](O)[C@H](O)[C@@H]1O LKDRXBCSQODPBY-OEXCPVAWSA-N 0.000 description 1
- ZAQJHHRNXZUBTE-UHFFFAOYSA-N D-threo-2-Pentulose Natural products OCC(O)C(O)C(=O)CO ZAQJHHRNXZUBTE-UHFFFAOYSA-N 0.000 description 1
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical group O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 1
- ZAQJHHRNXZUBTE-WUJLRWPWSA-N D-xylulose Chemical compound OC[C@@H](O)[C@H](O)C(=O)CO ZAQJHHRNXZUBTE-WUJLRWPWSA-N 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- LKDRXBCSQODPBY-AMVSKUEXSA-N L-(-)-Sorbose Chemical compound OCC1(O)OC[C@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-AMVSKUEXSA-N 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- 125000003599 L-arabinosyl group Chemical group C1([C@H](O)[C@@H](O)[C@@H](O)CO1)* 0.000 description 1
- WQZGKKKJIJFFOK-DHVFOXMCSA-N L-galactose Chemical compound OC[C@@H]1OC(O)[C@@H](O)[C@H](O)[C@@H]1O WQZGKKKJIJFFOK-DHVFOXMCSA-N 0.000 description 1
- IAJILQKETJEXLJ-SQOUGZDYSA-N L-guluronic acid Chemical compound O=C[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O IAJILQKETJEXLJ-SQOUGZDYSA-N 0.000 description 1
- SRBFZHDQGSBBOR-OWMBCFKOSA-N L-ribopyranose Chemical group O[C@H]1COC(O)[C@@H](O)[C@H]1O SRBFZHDQGSBBOR-OWMBCFKOSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- MSFSPUZXLOGKHJ-UHFFFAOYSA-N Muraminsaeure Natural products OC(=O)C(C)OC1C(N)C(O)OC(CO)C1O MSFSPUZXLOGKHJ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- IAJILQKETJEXLJ-RSJOWCBRSA-N aldehydo-D-galacturonic acid Chemical compound O=C[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)C(O)=O IAJILQKETJEXLJ-RSJOWCBRSA-N 0.000 description 1
- GZCGUPFRVQAUEE-KAZBKCHUSA-N aldehydo-D-talose Chemical compound OC[C@@H](O)[C@H](O)[C@H](O)[C@H](O)C=O GZCGUPFRVQAUEE-KAZBKCHUSA-N 0.000 description 1
- PYMYPHUHKUWMLA-YUPRTTJUSA-N aldehydo-L-lyxose Chemical compound OC[C@H](O)[C@@H](O)[C@@H](O)C=O PYMYPHUHKUWMLA-YUPRTTJUSA-N 0.000 description 1
- 150000001345 alkine derivatives Chemical class 0.000 description 1
- HMFHBZSHGGEWLO-UHFFFAOYSA-N alpha-D-Furanose-Ribose Natural products OCC1OC(O)C(O)C1O HMFHBZSHGGEWLO-UHFFFAOYSA-N 0.000 description 1
- AEMOLEFTQBMNLQ-WAXACMCWSA-N alpha-D-glucuronic acid Chemical compound O[C@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-WAXACMCWSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- AEMOLEFTQBMNLQ-UHFFFAOYSA-N beta-D-galactopyranuronic acid Natural products OC1OC(C(O)=O)C(O)C(O)C1O AEMOLEFTQBMNLQ-UHFFFAOYSA-N 0.000 description 1
- MSWZFWKMSRAUBD-QZABAPFNSA-N beta-D-glucosamine Chemical compound N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O MSWZFWKMSRAUBD-QZABAPFNSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- SQVRNKJHWKZAKO-UHFFFAOYSA-N beta-N-Acetyl-D-neuraminic acid Natural products CC(=O)NC1C(O)CC(O)(C(O)=O)OC1C(O)C(O)CO SQVRNKJHWKZAKO-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- AEMOLEFTQBMNLQ-YBSDWZGDSA-N d-mannuronic acid Chemical compound O[C@@H]1O[C@@H](C(O)=O)[C@H](O)[C@@H](O)[C@H]1O AEMOLEFTQBMNLQ-YBSDWZGDSA-N 0.000 description 1
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229960001617 ethyl hydroxybenzoate Drugs 0.000 description 1
- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004403 ethyl p-hydroxybenzoate Substances 0.000 description 1
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002402 hexoses Chemical group 0.000 description 1
- 125000000687 hydroquinonyl group Chemical group C1(O)=C(C=C(O)C=C1)* 0.000 description 1
- AEMOLEFTQBMNLQ-CLQWQSTFSA-N l-iduronic acid Chemical compound O[C@H]1O[C@H](C(O)=O)[C@H](O)[C@@H](O)[C@@H]1O AEMOLEFTQBMNLQ-CLQWQSTFSA-N 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002972 pentoses Chemical group 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- SQVRNKJHWKZAKO-OQPLDHBCSA-N sialic acid Chemical compound CC(=O)N[C@@H]1[C@@H](O)C[C@@](O)(C(O)=O)OC1[C@H](O)[C@H](O)CO SQVRNKJHWKZAKO-OQPLDHBCSA-N 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/602—Glycosides, e.g. rutin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Description
［産業上の利用分野］
本発明は頭髪に潤いを与え、しなやかにする毛
髪処理剤に関する。
［従来の技術］
リンスやリンス効果を有する毛髪処理剤にはカ
チオン界面活性剤が配合されることが多い。しか
し、カチオン界面活性剤は皮膚や、とくに眼に対
する刺激性が強いために、最近では、カチオン界
面活性剤に替えて皮膚や眼に対する安全性が高い
両性界面活性剤が検討されはじめている。
しかしながら、両性界面活性剤は安全性が高い
一方、リンス効果、とくに毛髪にうるおいを与
え、しなやかにする効果に劣るという欠点があ
る。
このために、要望が強いにもかかわらず、これ
まで両性界面活性剤を主たる界面活性剤としてな
る毛髪処理剤は数が少なかつた。
［発明が解決しようとする問題点］
そこで、本発明者らは、両性界面活性剤を主た
る界面活性剤とする毛髪化粧料において、毛髪に
うるおいを与え、しなやかにする効果を改善する
ことを目的に鋭意研究を行つた結果、驚くべきこ
とに、両性界面活性剤とともに特定のハイドロキ
ノンの配糖体を配合したならば、毛髪化粧料の安
全性は損なわれず、両性界面活性剤のリンス効果
が補われることを見いだし、本発明を完成するに
至つた。
［問題点を解決するための手段］
すなわち、本発明は両性界面活性剤の一種又は
二種以上と下記一般式（）で表されるハイドロ
キノンの配糖体から選ばれる一種又は二種以上と
を含有することを特徴とする毛髪処理剤である。
[Industrial Field of Application] The present invention relates to a hair treatment agent that moisturizes and makes hair supple. [Prior Art] A cationic surfactant is often blended into a rinse or a hair treatment agent having a rinse effect. However, since cationic surfactants are highly irritating to the skin and especially to the eyes, recently, amphoteric surfactants, which are highly safe for the skin and eyes, have begun to be considered in place of cationic surfactants. However, although amphoteric surfactants are highly safe, they have the disadvantage that they are inferior in rinsing effect, especially in the effect of moisturizing and making hair supple. For this reason, despite strong demand, until now there have been only a few hair treatment agents containing amphoteric surfactants as the main surfactant. [Problems to be Solved by the Invention] Therefore, the present inventors aimed to improve the effect of moisturizing and making hair supple in hair cosmetics containing an amphoteric surfactant as the main surfactant. As a result of extensive research, we surprisingly found that if a specific hydroquinone glycoside is blended with an amphoteric surfactant, the safety of hair cosmetics will not be compromised, and the rinsing effect of the amphoteric surfactant will be compensated for. The present invention was completed based on the discovery that the present invention is possible. [Means for Solving the Problems] That is, the present invention uses one or more amphoteric surfactants and one or more hydroquinone glycosides represented by the following general formula (). A hair treatment agent characterized by containing:
【式】
｛式（）中、Ｒは五炭糖残基、六炭糖残基、
アミノ糖残基、ウロン糖残基またはそれらのメチ
ル化物を示す。｝
以下、本発明について詳述する。
本発明で用いられる両性界面活性剤はこれまで
毛髪化粧料において一般的に用いられてきた両性
界面活性剤を全て包含する。具体例をあげるなら
ば、２−ウンデシル−Ｎ，Ｎ，Ｎ−（ヒドロキシ
エチルカルボキシメチル）−２−イミダゾリンナ
トリウム、２−ココイル−２−イミダゾリニウム
ヒドロキサド−１−カルボキシエチルオキシ−２
−ナトリウムなどのイミダゾリン系両性界面活性
剤、２−ヘプタデシル−Ｎ−カルボキシメチル−
Ｎ−ヒドロキシエチルイミダゾリニウムベタイ
ン、ラウリルジメチルアミノ酢酸ベタインなどの
ベタイン系両性界面活性剤、Ｎ−ラウリル−β−
アラニン、Ｎ−ステアリル−β−アラニンなどの
アラキルアミノ酸塩あるいはアルキンベタイン、
アミドベタイン、スルホベタインなどが例示され
る。
本発明においては、これら両性界面活性剤のう
ちの任意の一種又は二種以上が選ばれて用いられ
る。配合量はとくに限定されないが、一般的に
は、0.1〜20重量％である。
本発明で用いられるハイドロキノンの配糖体
は、上記一般式（）で表される。その具体例を
あげるならば、Ｒが、Ｌ−アラビノース、Ｄ−ア
ラビノース、Ｄ−キシロース、Ｄ−リボース、Ｌ
−キシルロース、Ｌ−リキソース、Ｄ−リブロー
スなどの五炭糖の残基、Ｄ−グルコース、Ｄ−ガ
ラクトース、Ｌ−ガラクトース、Ｄ−マンノー
ス、Ｄ−タロース、Ｄ−フルクトース、Ｌ−ソル
ボース、Ｄ−タガトース、Ｄ−プシコースなどの
六炭糖の残基、Ｄ−グルコサミン、Ｄ−ガラクト
サミン、シアル酸、アミノウロン酸、ムラミン酸
などのアミノ糖の残基、Ｄ−グルクロン酸、Ｄ−
ガラクツロン酸、Ｄ−マンヌロン酸、Ｌ−イズロ
ン酸、Ｌ−グルロン酸などのウロン酸の残基また
はそれらのメチル化合物のものなどが例示され
る。
なかでも、ＲがＤ−グルコースの残基、とくに
ハイドロキノンにＤ−グルコースがβ結合した、
すなわち、ハイドロキノン−β−Ｄ−グルコシド
（一般名；アルブチン）が、もつとも好ましい。
本発明においては上記ハイドロキノンの配糖体
の一種又は二種以上が任意に選ばれて用いられ、
その配合量は毛髪処理剤全量中の0.1〜30重量％、
好ましくは６〜20重量％である。
本発明の毛髪処理剤は、リンス、ヘアトリート
メント、ヘアクリームなど毛髪に使用する化粧料
あるいは医薬部外品など広い範囲の化粧料を表
す。本発明の毛髪化粧料には必要に応じて、本発
明の効果を損なわない範囲で、保湿剤、増粘剤、
油分、防腐剤、他の界面活性剤、酸化防止剤、金
属イオン封鎖剤、紫外線吸収剤、粉末、薬剤、色
剤、香料などを配合できる。
［発明の効果］
以下に、本発明に係るハイドロキノンの配糖体
が両性界面活性剤のリンス効果を補強する効果を
示す。
実験は、下記のリンス基本処方に対してアルブ
チン０重量％、１重量％、10重量％を加えた（水
と置換）試料を用意し、それぞれを19才〜27才の
女性パネル20名にシヤンプーの後に実際に使用さ
せ、その使用感触（タオルドライ後のしつとり
さ）を官能的に判定してもらい、その結果を下記
の基準に基づいて評価した。
−リンス基本処方−
スクワラン 5.0重量％
POE（３）※セチルエーテル 2.0
２−ヘプタデシル−Ｎ−カルボキシメチル−Ｎ
−ヒドロキシエチルイミダゾリニウムベタイン
10.0
精製水 残余
※ POE…ポリオキシエチレンを示す。以下も
同じ。
−評価基準−
20名中、17名以上がよいと答えたもの ◎
20名中、13〜16名がよいと答えたもの ○
20名中、９〜12名がよいと答えたもの △
20名中、４〜８名がよいと答えたもの ×
20名中、４名以下がよいと答えたもの ××
−結果−試料No.
アルブチン量 評価
１ 0重量％ ××
２ 1 ○
３ 10 ◎
以上の結果より、アルブチンが両性界面活性剤
に不足している髪にうるおいを与え、しつとりさ
せる効果を補うことは明らかである。
［実施例］
つぎに、本発明の実施例を示す。本発明はこれ
によつて限定されるものではない。
実施例１ リンス
セタノール 2.0重量％
流動パラフイン 0.6
精製ラノリン 0.2
POE（５）ステアリルエーテル 1.0
ラウリルジメチルアミノ酢酸ベタイン 7.0
アルブチン 10.0
精製水 残余
（製法）
常法に従い、上記成分を混合してリンスを得
た。
実施例２ リンス
イソプロパノール 12.0重量％
クエン酸 1.0
塩化ステアリルトリメチルアンモニウム 0.5
アルブチン 10.0
ラウリルジメチルアミノ酢酸ベタイン 7.0
精製水 残余
（製法）
実施例１に準じる。
実施例３ ヘアパツク
２−ヘプタデシル−Ｎ−カルボキシメチル−Ｎ
−ヒドロキシエチルイミダゾリニウムベタイン
25.0
ポリビニルピロリドン 1.0
グリセリン 3.0
エチルパラベン 0.1
アルブチン 6.0
精製水 残余
（製法）
実施例１に準じる。
実施例４ ヘアクリーム
ミツロウ 3.0重量％
ワセリン 10.0
ステアリルアルコール 5.0
流動パラフイン 15.0
POE（５）ステアリン酸エステル 1.0
POE（６）セチルエーテル 1.0
ココイルベタイン 3.0
プロピルパラベン 0.1
香料 0.1
ハイドロキノン−β−Ｄ−アラビノシド 1.0
精製水 残余
（製法）
精製水およびハイドロキノン−β−Ｄ−アラビ
ノシドと、精製水以外の原料とを別々に加熱攪拌
溶解した後、混合、乳化、冷却してヘアクリーム
を得た。
実施例１〜４は、髪にうるおいを与え、しつと
りさせる効果に優れ、安全性および安定性も良好
であつた。[Formula] {In the formula (), R is a pentose residue, a hexose residue,
Indicates an amino sugar residue, a urone sugar residue, or a methylated product thereof. } Hereinafter, the present invention will be explained in detail. The amphoteric surfactants used in the present invention include all amphoteric surfactants that have been commonly used in hair cosmetics. Specific examples include 2-undecyl-N,N,N-(hydroxyethylcarboxymethyl)-2-imidazoline sodium, 2-cocoyl-2-imidazoliniumhydroxado-1-carboxyethyloxy-2
-Imidazoline amphoteric surfactants such as sodium, 2-heptadecyl-N-carboxymethyl-
Betaine-based amphoteric surfactants such as N-hydroxyethylimidazolinium betaine and lauryldimethylaminoacetic acid betaine, N-lauryl-β-
Arachilamino acid salts such as alanine, N-stearyl-β-alanine or alkyne betaine,
Examples include amidobetaine and sulfobetaine. In the present invention, any one or more of these amphoteric surfactants may be selected and used. Although the amount is not particularly limited, it is generally 0.1 to 20% by weight. The hydroquinone glycoside used in the present invention is represented by the above general formula (). To give specific examples, R is L-arabinose, D-arabinose, D-xylose, D-ribose, L
- Residues of pentose sugars such as xylulose, L-lyxose, D-ribulose, D-glucose, D-galactose, L-galactose, D-mannose, D-talose, D-fructose, L-sorbose, D-tagatose , residues of hexose sugars such as D-psicose, residues of amino sugars such as D-glucosamine, D-galactosamine, sialic acid, aminouronic acid, muramic acid, D-glucuronic acid, D-
Examples include residues of uronic acids such as galacturonic acid, D-mannuronic acid, L-iduronic acid, and L-guluronic acid, or methyl compounds thereof. Among them, R is a residue of D-glucose, in particular, D-glucose is β-bonded to hydroquinone,
That is, hydroquinone-β-D-glucoside (common name: arbutin) is particularly preferred. In the present invention, one or more of the above hydroquinone glycosides are arbitrarily selected and used,
Its blending amount is 0.1 to 30% by weight of the total amount of hair treatment agent.
Preferably it is 6 to 20% by weight. The hair treatment agent of the present invention represents a wide range of cosmetics such as conditioners, hair treatments, hair creams, and other cosmetics used for hair, or quasi-drugs. The hair cosmetic of the present invention may contain moisturizing agents, thickeners,
Oils, preservatives, other surfactants, antioxidants, sequestrants, ultraviolet absorbers, powders, chemicals, colorants, fragrances, etc. can be added. [Effects of the Invention] The effect of the hydroquinone glycoside according to the present invention in reinforcing the rinsing effect of an amphoteric surfactant will be shown below. In the experiment, samples were prepared in which 0%, 1%, and 10% by weight of arbutin were added to the following basic rinse formula (replaced with water), and each sample was given to a panel of 20 women aged 19 to 27. After that, they were actually used, and the feeling of use (moistness after towel drying) was sensually judged, and the results were evaluated based on the following criteria. - Basic Rinse Formula - Squalane 5.0% by weight POE (3) * Cetyl ether 2.0 2-heptadecyl-N-carboxymethyl-N
-Hydroxyethylimidazolinium betaine
10.0 Purified water Residual* POE…Indicates polyoxyethylene. The same applies below. - Evaluation criteria - 17 or more out of 20 people answered that it was good ◎ 13 to 16 out of 20 people answered that it was good ○ 9 to 12 out of 20 people answered that it was good △ 20 people Medium, 4 to 8 people answered that it was good × Out of 20 people, 4 or less people answered that it was good ×× -Results- Sample No. Arbutin amount evaluation 1 0% by weight ×× 2 1 ○ 3 10 ◎ or more From the results, it is clear that arbutin supplements the hair moisturizing effect that is lacking in amphoteric surfactants. [Example] Next, an example of the present invention will be shown. The present invention is not limited thereby. Example 1 Rinse Setanol 2.0% by weight Liquid paraffin 0.6 Purified lanolin 0.2 POE (5) Stearyl ether 1.0 Betaine lauryldimethylaminoacetate 7.0 Arbutin 10.0 Purified water Remaining (manufacturing method) A rinse was obtained by mixing the above components according to a conventional method. Example 2 Rinse Isopropanol 12.0% by weight Citric acid 1.0 Stearyltrimethylammonium chloride 0.5 Arbutin 10.0 Betaine lauryldimethylaminoacetate 7.0 Purified water Remaining (manufacturing method) Same as Example 1. Example 3 Hair pack 2-heptadecyl-N-carboxymethyl-N
-Hydroxyethylimidazolinium betaine
25.0 Polyvinylpyrrolidone 1.0 Glycerin 3.0 Ethylparaben 0.1 Arbutin 6.0 Purified water Residue (manufacturing method) Same as Example 1. Example 4 Hair cream Beeswax 3.0% by weight Vaseline 10.0 Stearyl alcohol 5.0 Liquid paraffin 15.0 POE (5) Stearic acid ester 1.0 POE (6) Cetyl ether 1.0 Cocoyl betaine 3.0 Propyl paraben 0.1 Fragrance 0.1 Hydroquinone-β-D-arabinoside 1.0 Purified water Residue (manufacturing method) Purified water, hydroquinone-β-D-arabinoside, and raw materials other than purified water were separately heated and stirred, and then mixed, emulsified, and cooled to obtain a hair cream. Examples 1 to 4 were excellent in moisturizing and moisturizing effects on hair, and had good safety and stability.
Claims (1)
般式（）で表されるハイドロキノンの配糖体か
ら選ばれる一種又は二種以上とを含有することを
特徴とするシヤンプーを除く毛髪処理剤。 【化】 〔式（）中、Ｒは五炭糖残基、六炭糖残基、
アミノ糖残基、ウロン酸残基またはそれらのメチ
ル化物を示す。[Scope of Claims] 1. A shampoo characterized by containing one or more amphoteric surfactants and one or more hydroquinone glycosides represented by the following general formula (). Hair treatment agents excluding. [In the formula (), R is a pentose residue, a hexose residue,
Indicates an amino sugar residue, a uronic acid residue, or a methylated product thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6420685A JPS61225112A (en) | 1985-03-28 | 1985-03-28 | Hair cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6420685A JPS61225112A (en) | 1985-03-28 | 1985-03-28 | Hair cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61225112A JPS61225112A (en) | 1986-10-06 |
| JPH0588203B2 true JPH0588203B2 (en) | 1993-12-21 |
Family
ID=13251367
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6420685A Granted JPS61225112A (en) | 1985-03-28 | 1985-03-28 | Hair cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61225112A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61197508A (en) * | 1985-02-27 | 1986-09-01 | Shiseido Co Ltd | Hair cosmetic for preventing dandruff |
-
1985
- 1985-03-28 JP JP6420685A patent/JPS61225112A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61197508A (en) * | 1985-02-27 | 1986-09-01 | Shiseido Co Ltd | Hair cosmetic for preventing dandruff |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61225112A (en) | 1986-10-06 |
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