JPH0578582B2 - - Google Patents
Info
- Publication number
- JPH0578582B2 JPH0578582B2 JP60187425A JP18742585A JPH0578582B2 JP H0578582 B2 JPH0578582 B2 JP H0578582B2 JP 60187425 A JP60187425 A JP 60187425A JP 18742585 A JP18742585 A JP 18742585A JP H0578582 B2 JPH0578582 B2 JP H0578582B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- block copolymer
- component
- hydrogenated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 vinyl aromatic compounds Chemical class 0.000 claims description 55
- 239000000203 mixture Substances 0.000 claims description 54
- 229920001400 block copolymer Polymers 0.000 claims description 45
- 229920001971 elastomer Polymers 0.000 claims description 32
- 239000005060 rubber Substances 0.000 claims description 29
- 229920000642 polymer Polymers 0.000 claims description 26
- 229920002554 vinyl polymer Polymers 0.000 claims description 18
- 229920001955 polyphenylene ether Polymers 0.000 claims description 17
- 229920001577 copolymer Polymers 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 11
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 150000002430 hydrocarbons Chemical group 0.000 claims description 6
- 239000004215 Carbon black (E152) Chemical group 0.000 claims description 5
- 229930195733 hydrocarbon Chemical group 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229920005672 polyolefin resin Polymers 0.000 claims description 5
- 229920005990 polystyrene resin Polymers 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical group 0.000 claims description 4
- 229920001519 homopolymer Polymers 0.000 claims description 4
- 150000002431 hydrogen Chemical group 0.000 claims description 4
- 239000004902 Softening Agent Substances 0.000 claims 1
- 230000006835 compression Effects 0.000 description 27
- 238000007906 compression Methods 0.000 description 27
- 238000005984 hydrogenation reaction Methods 0.000 description 21
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 19
- 238000000034 method Methods 0.000 description 10
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 238000002347 injection Methods 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 7
- 239000005062 Polybutadiene Substances 0.000 description 7
- 238000009826 distribution Methods 0.000 description 7
- 229920002857 polybutadiene Polymers 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 239000011256 inorganic filler Substances 0.000 description 6
- 229910003475 inorganic filler Inorganic materials 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- 229920002725 thermoplastic elastomer Polymers 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 235000010446 mineral oil Nutrition 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- 239000011342 resin composition Substances 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000010734 process oil Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- 239000004606 Fillers/Extenders Substances 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical group C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000006232 furnace black Substances 0.000 description 2
- 239000012442 inert solvent Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000012778 molding material Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 1
- XRUGBBIQLIVCSI-UHFFFAOYSA-N 2,3,4-trimethylphenol Chemical compound CC1=CC=C(O)C(C)=C1C XRUGBBIQLIVCSI-UHFFFAOYSA-N 0.000 description 1
- KUNNUNBSGQSGDY-UHFFFAOYSA-N 2-butyl-6-methylphenol Chemical compound CCCCC1=CC=CC(C)=C1O KUNNUNBSGQSGDY-UHFFFAOYSA-N 0.000 description 1
- QQOMQLYQAXGHSU-UHFFFAOYSA-N 236TMPh Natural products CC1=CC=C(C)C(O)=C1C QQOMQLYQAXGHSU-UHFFFAOYSA-N 0.000 description 1
- GRXOKDOOUFYKLX-UHFFFAOYSA-N 3,5-dichloro-7-oxabicyclo[2.2.1]hepta-1(6),2,4-triene Chemical compound ClC1=C(O2)C(Cl)=CC2=C1 GRXOKDOOUFYKLX-UHFFFAOYSA-N 0.000 description 1
- GVLZQVREHWQBJN-UHFFFAOYSA-N 3,5-dimethyl-7-oxabicyclo[2.2.1]hepta-1,3,5-triene Chemical compound CC1=C(O2)C(C)=CC2=C1 GVLZQVREHWQBJN-UHFFFAOYSA-N 0.000 description 1
- KXRLIZRDCCQKDZ-UHFFFAOYSA-N 3-ethyl-5-methyl-7-oxabicyclo[2.2.1]hepta-1,3,5-triene Chemical compound CC1=C(O2)C(CC)=CC2=C1 KXRLIZRDCCQKDZ-UHFFFAOYSA-N 0.000 description 1
- NGNBLQAYJAKWKR-UHFFFAOYSA-N 5-methyl-3-phenyl-7-oxabicyclo[2.2.1]hepta-1,3,5-triene Chemical compound O1C=2C(C)=CC1=CC=2C1=CC=CC=C1 NGNBLQAYJAKWKR-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 101100208721 Mus musculus Usp5 gene Proteins 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000006231 channel black Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000012690 ionic polymerization Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18742585A JPS6248758A (ja) | 1985-08-28 | 1985-08-28 | 高弾性水添ブロツク共重合体組成物 |
| EP86109956A EP0209874B2 (en) | 1985-07-19 | 1986-07-18 | Hydrogenated block copolymer compositions |
| ES8600373A ES2001020A6 (es) | 1985-07-19 | 1986-07-18 | Compuestos de copolimeros bloque hidrogenados |
| DE8686109956T DE3675095D1 (de) | 1985-07-19 | 1986-07-18 | Hydrierte blockcopolymerzusammensetzungen. |
| US06/886,601 US4772657A (en) | 1985-07-19 | 1986-07-18 | Hydrogenated block copolymer compositions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18742585A JPS6248758A (ja) | 1985-08-28 | 1985-08-28 | 高弾性水添ブロツク共重合体組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6248758A JPS6248758A (ja) | 1987-03-03 |
| JPH0578582B2 true JPH0578582B2 (zh) | 1993-10-29 |
Family
ID=16205824
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18742585A Granted JPS6248758A (ja) | 1985-07-19 | 1985-08-28 | 高弾性水添ブロツク共重合体組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6248758A (zh) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63251457A (ja) * | 1987-04-06 | 1988-10-18 | Asahi Chem Ind Co Ltd | ポリフエニレンエ−テル樹脂組成物 |
| JP4901106B2 (ja) * | 2005-01-27 | 2012-03-21 | 東レ・ダウコーニング株式会社 | 車両モールディング用熱可塑性エラストマー組成物および車両用モールディング付きガラス板 |
| JP2008063365A (ja) * | 2006-09-05 | 2008-03-21 | Aron Kasei Co Ltd | スチレン系エラストマー組成物 |
| US20080113138A1 (en) * | 2006-11-13 | 2008-05-15 | William Eugene Pecak | Poly(arylene ether)/polyolefin composition, method, and article |
| WO2015159912A1 (ja) * | 2014-04-16 | 2015-10-22 | 旭化成ケミカルズ株式会社 | 熱可塑性エラストマー組成物、医療容器用栓体及び医療容器 |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5071742A (zh) * | 1973-08-13 | 1975-06-13 | ||
| JPS51129450A (en) * | 1975-04-01 | 1976-11-11 | Gen Electric | Polyphenylene ether composition |
| JPS5371158A (en) * | 1976-12-03 | 1978-06-24 | Gen Electric | Polyphenylene ether and styrene resin preblended polymer composition and composition of block copolymer of vinyl aromatic compound and olefinntype elastomer |
| JPS5488960A (en) * | 1977-10-03 | 1979-07-14 | Gen Electric | Highhimpact thermoplastic composition |
| JPS55131051A (en) * | 1979-03-30 | 1980-10-11 | Mitsubishi Gas Chem Co Inc | High-molecular resin composition |
| JPS5679151A (en) * | 1979-10-15 | 1981-06-29 | Gen Electric | Polyphenylene ether composition |
| JPS57188111A (en) * | 1981-05-14 | 1982-11-19 | Toshiba Corp | Synchronizing detection circuit |
| JPS5883054A (ja) * | 1981-10-28 | 1983-05-18 | ゼネラル・エレクトリツク・カンパニイ | ポリフエニレンエ−テル樹脂、低分子量ポリスチレンおよびブロツク共重合体の組成物 |
-
1985
- 1985-08-28 JP JP18742585A patent/JPS6248758A/ja active Granted
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5071742A (zh) * | 1973-08-13 | 1975-06-13 | ||
| JPS51129450A (en) * | 1975-04-01 | 1976-11-11 | Gen Electric | Polyphenylene ether composition |
| JPS5371158A (en) * | 1976-12-03 | 1978-06-24 | Gen Electric | Polyphenylene ether and styrene resin preblended polymer composition and composition of block copolymer of vinyl aromatic compound and olefinntype elastomer |
| JPS5488960A (en) * | 1977-10-03 | 1979-07-14 | Gen Electric | Highhimpact thermoplastic composition |
| JPS55131051A (en) * | 1979-03-30 | 1980-10-11 | Mitsubishi Gas Chem Co Inc | High-molecular resin composition |
| JPS5679151A (en) * | 1979-10-15 | 1981-06-29 | Gen Electric | Polyphenylene ether composition |
| JPS57188111A (en) * | 1981-05-14 | 1982-11-19 | Toshiba Corp | Synchronizing detection circuit |
| JPS5883054A (ja) * | 1981-10-28 | 1983-05-18 | ゼネラル・エレクトリツク・カンパニイ | ポリフエニレンエ−テル樹脂、低分子量ポリスチレンおよびブロツク共重合体の組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6248758A (ja) | 1987-03-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |