JPH055169A - Production of hot-dip coated wire - Google Patents

Production of hot-dip coated wire

Info

Publication number
JPH055169A
JPH055169A JP26830391A JP26830391A JPH055169A JP H055169 A JPH055169 A JP H055169A JP 26830391 A JP26830391 A JP 26830391A JP 26830391 A JP26830391 A JP 26830391A JP H055169 A JPH055169 A JP H055169A
Authority
JP
Japan
Prior art keywords
wire
plated
hot
dip
plating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP26830391A
Other languages
Japanese (ja)
Inventor
Setsu Kubota
節 久保田
Yoshitada Hanai
嘉忠 花井
Koichi Otani
浩一 大谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Totoku Electric Co Ltd
Original Assignee
Totoku Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Totoku Electric Co Ltd filed Critical Totoku Electric Co Ltd
Priority to JP26830391A priority Critical patent/JPH055169A/en
Publication of JPH055169A publication Critical patent/JPH055169A/en
Pending legal-status Critical Current

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Landscapes

  • Coating With Molten Metal (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

PURPOSE:To apply hot-dip coating on a wire to be coated having clean surface and to manufacture high quality of the hot-dip coated wire without exposing wire surface by making hot-dip coating pre-treating process from wire drawing process for the wire to be coated into the constitution having no stickness of particularly, iron content, on surface of the wire to be coated. CONSTITUTION:The wire drawing is executed to the base-wire A to be coated by using a wire drawing machine 10 consisted of wear resistant material developing no iron rust on surface in the wire drawing process in a water soluble lubricant. The obtd. wire 1 to be coated is wound to a winding frame 2 composed of material having no iron rust on the surface and stored. The stored wire 1 to be coated is introduced into a steam atmospheric heating furnace 3 to execute steam cleaning on the wire surface and annealing. Successively, this is introduced into an ultrasonic cleaning bath 5 and after cleaning, this is dried with an air wiper 6a. Successively, this is introduced into a reducing gas atmospheric heating furnace 7 and at the same time of removing oxide layer on the surface of wire 1 to be coated, this is directly introduced into the hot dipping bath 8 under pre-heated condition to apply the hot-dip coating.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は電子部品のリード線や電
子配線材の導体として用いられる溶融めっき線、例えば
溶融錫めっき線、溶融はんだめっき線等の製造方法に関
する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a hot-dip galvanized wire used as a lead wire of an electronic component or a conductor of an electronic wiring material, for example, a hot-dip tinned wire or a hot-soldered wire.

【0002】[0002]

【従来の技術】従来の溶融めっき線の製造方法について
図5を用いて説明する。被めっき母線Aは、段ロール,
滑車,キャプスタン等の伸線加工経路表面の大部分を鉄
材から構成した伸線機(図示せず)を用いて、通常、水
溶性潤滑剤又は油性潤滑剤中にて伸線加工が施され所要
サイズの被めっき線1’として鉄材からなる巻枠2’に
巻き取られている。一旦、巻枠2’に貯留された被めっ
き線1’は、次の工程で巻枠2’から導出されて蒸気焼
鈍炉3’内を走行しながら焼鈍され、続いて水洗浴5’
中を走行させ線材の冷却を行なった後、乾燥器6で線表
面に付着した水分が乾燥され、次に酸フラックス浴11中
を通過し被めっき線1’の表面が酸洗いされ、続いて、
この被めっき線1’はその表面に酸フラックスの付着さ
れたまま溶融金属めっき浴8へ導入され、この溶融めっ
き浴8の溶融金属に触れることにより被めっき線1’の
表面洗浄が行なわれると同時に被めっき線1’にめっき
が施され、続いて絞りダイスdを通過させ、所要めっき
厚さに調整して溶融めっき線1’aを得る製造方法であ
る。
2. Description of the Related Art A conventional method for producing a hot-dip wire will be described with reference to FIG. The bus bar A to be plated is a corrugated roll,
A wire drawing machine (not shown), which is made of iron for the majority of the surface of the wire drawing path of pulleys, capstans, etc., is usually used to draw wires in a water-soluble lubricant or oil-based lubricant. The wire to be plated 1'having a required size is wound around a winding frame 2'made of an iron material. The wire to be plated 1 ′ once stored in the winding frame 2 ′ is derived from the winding frame 2 ′ in the next step and annealed while traveling in the steam annealing furnace 3 ′, and subsequently, a washing bath 5 ′.
After traveling through the inside to cool the wire, the water adhering to the wire surface is dried by the dryer 6, then passed through the acid flux bath 11 and the surface of the wire 1'to be plated is pickled. ,
The wire 1 ′ to be plated is introduced into the molten metal plating bath 8 with an acid flux adhered to the surface thereof, and the surface of the wire 1 ′ to be plated is washed by touching the molten metal in the molten plating bath 8. At the same time, the wire to be plated 1'is plated, and then passed through a drawing die d to adjust the required plating thickness to obtain a hot-dipped wire 1'a.

【0003】[0003]

【発明が解決しようとする課題】従来から一般に、伸線
機の伸線加工経路にあたる段ロール,滑車,キャプスタ
ン等には鉄材が多用されている。このため、伸線加工工
程でこれらの鉄材の一部鉄粉が微量ながら被めっき線
1’の表面に付着してきて、鉄粉が付着されたまま巻枠
2’に巻き取られていた。また更に、被めっき線1’が
巻き取られ、貯留される前記巻枠2’には鉄材の巻枠が
用いられていた。このように、被めっき線1’は伸線加
工工程、更に被めっき線を長時間貯留する巻枠で鉄材と
接触する状態にあった。特に、被めっき線1’は鉄製巻
枠2’に貯留中、常に鉄製巻枠2’の胴部表面及び内つ
ば表面で鉄材と接触している状態にあるので、この接触
面から鉄さび等の鉄酸化物が被めっき線1’の表面に付
着してくることは避けられなかった。しかも、このよう
にして被めっき線1’の表面に付着してきた鉄酸化物は
その後の溶融めっき工程でめっき線の品質に極めて悪影
響を及ぼすものであった。即ち、被めっき線1’の表面
に付着した鉄酸化物は、めっき前処理工程の蒸気焼鈍炉
3’内を走行中に水酸化鉄に変質し、この被めっき線
1’の表面の水酸化鉄は被めっき線1’が溶融金属めっ
き浴8中に導入されたとき、めっき浴の熱により分解し
て水分を生じ、この水分が直ちに気化して被めっき線
1’の表面から発散する結果、水酸化鉄が付着していた
被めっき線1’の表面部分には溶融めっきが施されない
まま残り、所謂、芯線肌露出の不具合を発生させる原因
となっていた。
In general, iron materials have been widely used for corrugated rolls, pulleys, capstans, etc., which correspond to the wire drawing path of a wire drawing machine. Therefore, some iron powder of these iron materials adhered to the surface of the wire 1'to be plated in the drawing process, and was wound around the reel 2'with the iron powder adhered. Still further, an iron reel is used for the reel 2'for winding and storing the plated wire 1 '. As described above, the wire to be plated 1 ′ was in a state of being in contact with the iron material in the wire drawing step and further in the winding frame which stores the wire to be plated for a long time. In particular, since the wire to be plated 1'is always in contact with the iron material on the body surface and the inner brim surface of the iron reel 2'during storage in the iron reel 2 ', from this contact surface, iron rust or the like is removed. It was unavoidable that iron oxide adhered to the surface of the plated wire 1 '. Moreover, the iron oxide thus attached to the surface of the wire to be plated 1'has a very bad influence on the quality of the plated wire in the subsequent hot dipping process. That is, the iron oxide adhered to the surface of the wire 1'to be plated is transformed into iron hydroxide while running in the steam annealing furnace 3'in the pretreatment process of plating, and the hydroxide of the surface of the wire 1'to be plated is hydroxylated. When the wire to be plated 1'is introduced into the molten metal plating bath 8, iron is decomposed by the heat of the plating bath to generate water, and this water is immediately vaporized and diffused from the surface of the wire to be plated 1 '. The surface of the plated wire 1'on which the iron hydroxide had been adhered remained as it was without hot-dip plating, which caused a so-called core wire exposure problem.

【0004】また、めっき前処理工程として酸フラック
ス浴11が用いられているため、浴中の酸が飛散したり、
被めっき線1’に付着した酸フラックスが高温の溶融金
属めっき浴8で気化したりして、周囲設備を汚損,劣化
させ、また作業環境を汚染するという問題があった。更
に、酸フラックスは高温の溶融めっき金属と反応して金
属塩を生成するため、溶融めっき浴が不純化されめっき
品質を低下させるという問題もあった。
Further, since the acid flux bath 11 is used as a pretreatment process for plating, the acid in the bath is scattered,
There is a problem that the acid flux adhering to the wire to be plated 1'evaporates in the hot metal plating bath 8 to pollute and deteriorate the surrounding equipment and contaminate the working environment. Further, since the acid flux reacts with the hot-dip galvanized metal to generate a metal salt, there is a problem that the hot-dip galvanizing bath is impure and the plating quality is deteriorated.

【0005】本発明は従来の溶融めっき線の製造方法が
有する上記問題点を解決するために為されたものであ
り、被めっき線の芯線肌露出のない高品質な溶融めっき
線を得ることのできる溶融めっき線の製造方法を提供す
ることを目的とする。
The present invention has been made to solve the above problems of the conventional method for producing a hot-dip galvanized wire, and it is possible to obtain a high-quality hot-dip galvanized wire without exposing the core wire skin of the wire to be plated. An object of the present invention is to provide a method for producing a hot-dip galvanized wire.

【0006】[0006]

【課題を解決するための手段】上記目的を達成するため
に本発明は、伸線材の接触通過する伸線加工経路表面を
鉄錆の発生しない耐磨耗性材料から構成した伸線機10を
用い水溶性潤滑剤中にて被めっき母線Aに伸線加工を施
す伸線加工工程;と伸線加工された被めっき線1を少な
くとも該被めっき線1と接触する表面が鉄錆の発生しな
い材料からなる巻枠2に巻取り貯留する巻取り貯留工
程;と、前記巻枠2に巻取り貯留された被めっき線1を
蒸気雰囲気の加熱炉3内を走行させ、前記伸線加工工程
で被めっき線1の表面に付着した水溶性潤滑剤を分離し
やすい状態にする蒸気洗浄と被めっき線1の焼鈍とを同
時に行なう蒸気加熱工程と、この蒸気加熱工程後の被め
っき線1を洗浄液4を用いた超音波洗浄浴5中を通過さ
せ線表面を洗浄する洗浄工程と、この被めっき線1の表
面の水分をエアワイパー6a等を用い強制的に除去,乾
燥する乾燥工程と、この乾燥工程後の被めっき線1を還
元性ガス雰囲気の加熱炉7(以下ガス還元炉7と略記す
る)内を走行させ、被めっき線1の表面の酸化層の除去
と同時に被めっき線1を予備加熱し溶融めっき金属との
反応を促進するための還元性ガス加熱工程とからなるめ
っき前処理工程;と、この還元性ガス加熱工程と直結し
て被めっき線1に溶融金属めっきを施す溶融めっき工
程;とを備えた溶融めっき線の製造方法にある。
In order to achieve the above object, the present invention provides a wire drawing machine 10 made of an abrasion resistant material that does not cause iron rust on the surface of a wire drawing path through which a wire drawing material comes into contact. A wire drawing step of drawing a bus bar A to be plated in a water-soluble lubricant; and at least the surface of the drawn wire 1 in contact with the plated wire 1 is free from iron rust A winding and storing step of winding and storing on a winding frame 2 made of a material; and, the wire to be plated 1 wound and stored on the winding frame 2 is run in a heating furnace 3 in a steam atmosphere, and in the wire drawing step. A steam heating step of simultaneously performing steam cleaning for making the water-soluble lubricant adhering to the surface of the wire to be plated 1 easy to separate and annealing of the wire to be plated 1, and a cleaning liquid for the wire to be plated 1 after the steam heating step. Ultrasonic wave cleaning bath 5 is used to clean the wire surface. A cleaning step, a drying step of forcibly removing water on the surface of the wire to be plated 1 using an air wiper 6a, etc. and a drying step, and the wire to be plated 1 after the drying step is heated in a reducing gas atmosphere heating furnace 7 ( (Hereinafter abbreviated as gas reduction furnace 7), and heating with a reducing gas for preheating the wire 1 to be plated at the same time as removing the oxide layer on the surface of the wire 1 to be plated and accelerating the reaction with the hot-dip metal. And a hot dipping process for directly performing hot dip metal plating on the wire to be plated 1 in direct contact with the reducing gas heating step.

【0007】また本発明は、伸線材の接触通過する伸線
加工経路表面を鉄錆の発生しない耐磨耗性材料から構成
した伸線機10を用い水溶性潤滑剤中にて被めっき母線A
に伸線加工を施す伸線加工工程;と、前記伸線加工され
た被めっき線1を蒸気雰囲気の加熱炉3内を走行させ、
前記伸線加工工程において被めっき線1の表面に付着し
た水溶性潤滑剤を分離しやすい状態にする蒸気洗浄と被
めっき線1の焼鈍とを同時に行なう蒸気加熱工程と、こ
の蒸気加熱工程後の被めっき線1を洗浄液4を用いた超
音波洗浄浴5中を通過させ線表面を洗浄する洗浄工程
と、この被めっき線1の表面の水分をエアワイパー6a
等を用い強制的に除去,乾燥する乾燥工程と、この乾燥
工程後の被めっき線1をガス還元炉7内を走行させ、前
記被めっき線1の表面の酸化層の除去と同時に被めっき
線1を予備加熱し溶融めっき金属との反応を促進するた
めの還元性ガス加熱工程とからなるめっき前処理工程;
と、この還元性ガス加熱工程と直結して被めっき線1に
溶融金属めっきを施す溶融めっき工程;とを備え、前記
伸線加工工程,めっき前処理工程および溶融めっき工程
を連続して行なう溶融めっき線の製造方法にある。
Further, according to the present invention, the wire drawing machine 10 in which the surface of the wire drawing path through which the wire drawing material comes into contact is made of a wear-resistant material that does not generate iron rust is used.
A wire drawing step of applying wire drawing to the wire; and the wire to be plated 1 that has been wire drawn is run in a heating furnace 3 in a steam atmosphere,
In the wire drawing step, a steam heating step of simultaneously performing steam cleaning for making the water-soluble lubricant adhering to the surface of the wire to be plated 1 easy to separate and annealing of the wire 1 to be plated, and a step after the steam heating step A cleaning step in which the wire to be plated 1 is passed through an ultrasonic cleaning bath 5 using a cleaning liquid 4 to clean the surface of the wire, and moisture on the surface of the wire to be plated 1 is removed by an air wiper 6a.
And the like, and the wire to be plated 1 after the drying step is run in the gas reduction furnace 7 to remove the oxide layer on the surface of the wire to be plated 1 and the wire to be plated at the same time. A pretreatment process comprising a preheating step 1 and a reducing gas heating step for promoting a reaction with the hot-dip plated metal;
And a hot dip galvanizing step for directly performing hot dip metal plating on the wire to be plated 1 in direct connection with the reducing gas heating step, and performing the wire drawing step, the pre-plating step, and the hot dip step continuously. It is in the method of manufacturing the plated wire.

【0008】また本発明は、前記めっき前処理工程で被
めっき線1が接触して通過する経路表面を鉄錆の発生し
ない材料から構成した溶融めっき線の製造方法にある。
更に前記溶融めっき工程における被めっき線1外周の溶
融金属めっき厚さの調整が、絞りダイスdにより行なわ
れるか、又は前記被めっき線1の導出される前記溶融金
属めっき浴8面に接して非酸化性ガス又は還元性ガス雰
囲気のガス室9を設け、前記被めっき線1を前記溶融金
属めっき浴8面から前記非酸化性ガス又は還元性ガス雰
囲気のガス室9内へ垂直方向へ導出通過させることによ
り行なわれる溶融めっき線の製造方法にある。
The present invention is also a method for producing a hot-dip galvanized wire, which is made of a material that does not cause iron rust on the surface of the path through which the wire 1 to be plated comes into contact in the pre-plating treatment step.
Further, the thickness of the molten metal plating on the outer periphery of the wire to be plated 1 in the hot dip plating step is adjusted by a drawing die d, or the surface of the molten metal plating bath 8 from which the wire to be plated 1 is drawn is not contacted. A gas chamber 9 having an oxidizing gas or reducing gas atmosphere is provided, and the wire 1 to be plated is vertically led out from the surface of the molten metal plating bath 8 into the gas chamber 9 having the non-oxidizing gas or reducing gas atmosphere. The method for producing a hot-dip wire is carried out by

【0009】[0009]

【作用】被めっき母線Aは被めっき母線Aの接触通過す
る伸線加工経路表面を鉄錆の発生しない耐磨耗性材料か
ら構成した伸線機10を用いて伸線されるので、伸線加工
工程で被めっき線1の表面に鉄粉が付着してくることが
ない。更にまた、巻取り貯留工程に於いて、被めっき線
1は少なくとも該被めっき線1と接触する表面が鉄錆の
発生しない材料からなる巻枠2に巻取られ貯留されるの
で、巻枠に長期間貯留された状態にあっても、巻枠から
の鉄さび等の鉄酸化物の影響を受けることがない。
Function: The bus bar A to be plated is drawn on the surface of the wire drawing path through which the bus bar A to be plated comes into contact by using the wire drawing machine 10 made of a wear resistant material that does not generate iron rust. Iron powder does not adhere to the surface of the plated wire 1 in the processing step. Furthermore, in the winding and storing step, at least the surface of the wire to be plated 1 in contact with the wire to be plated 1 is wound up and stored in the winding frame 2 made of a material that does not cause iron rust. Even when it is stored for a long period of time, it is not affected by iron oxide such as iron rust from the reel.

【0010】従って、伸線加工工程,めっき前処理工程
及び溶融めっき工程とを連続して行う連続工程方式とし
た場合は勿論、伸線加工工程,巻取り貯留工程とそれ以
降のめっき前処理工程,溶融めっき工程とを分割した分
割工程方式とした場合であっても、被めっき線1はその
表面に鉄粉及び鉄酸化物の付着されない状態でめっき前
処理工程の蒸気加熱工程に導入されるので、蒸気雰囲気
の加熱炉3内を走行中にも該線表面に水酸化鉄の発生を
みることがなくなり、被めっき線1が溶融金属めっき浴
8に導入されたときにも、従来のように被めっき線1の
表面に付着した水酸化鉄の分解によって生じていた水分
の生成及びこの水分の気化によるガス発生もなくなるの
で、めっき線の芯線肌露出の不具合発生がなくなる。
Therefore, not only when the wire drawing step, the plating pretreatment step and the hot dip plating step are continuously carried out, the wire drawing step, the winding storage step and the plating pretreatment steps after that , Even when the hot dip plating process is divided into separate processes, the wire to be plated 1 is introduced to the steam heating process of the pretreatment process for plating without iron powder and iron oxide adhered to the surface thereof. Therefore, generation of iron hydroxide on the surface of the wire is not observed even while traveling in the heating furnace 3 in a steam atmosphere, and even when the wire to be plated 1 is introduced into the molten metal plating bath 8, the conventional method is used. In addition, since the generation of water generated by the decomposition of the iron hydroxide attached to the surface of the wire to be plated 1 and the generation of gas due to the evaporation of this water are also eliminated, the problem of the exposed core wire skin of the plated wire is eliminated.

【0011】また、蒸気加熱工程に於いては、被めっき
線1は蒸気雰囲気の加熱炉3内を走行することにより焼
鈍され、同時に伸線加工工程で被めっき線1の表面に極
く微量に付着してくる水溶性の潤滑剤が加熱蒸気による
蒸気洗浄により除去し易い状態となり、次工程の洗浄工
程に於いて、洗浄液4の超音波洗浄浴5中を通過するこ
とにより、被めっき線1の表面に付着した水溶性潤滑剤
は勿論、その他の付着不純物も完全に洗浄される。また
乾燥工程に於いては、洗浄工程で被めっき線表面に付着
した水分がエアワイパー等により強制的に除去,乾燥さ
れる。また還元性ガス加熱工程に於いては、被めっき線
1はガス還元炉7内を走行することにより、線表面酸化
層が還元除去されるので線表面は清浄化されるととも
に、このガス還元炉7で被めっき線1に付与される熱に
より、被めっき線1と溶融めっき金属との反応が促進さ
れ、良好なめっき層を有する溶融めっき線1aが得られ
る。
Further, in the steam heating step, the wire to be plated 1 is annealed by running in the heating furnace 3 in a steam atmosphere, and at the same time, a very small amount on the surface of the wire to be plated 1 in the wire drawing step. The adhering water-soluble lubricant becomes easy to remove by steam cleaning with heating steam, and in the next cleaning step, the cleaning liquid 4 passes through the ultrasonic cleaning bath 5, whereby the plated wire 1 Not only the water-soluble lubricant adhering to the surface of, but also other adhering impurities are completely cleaned. Further, in the drying step, the water adhering to the surface of the plated wire in the washing step is forcibly removed and dried by an air wiper or the like. Further, in the reducing gas heating step, the wire 1 to be plated runs in the gas reducing furnace 7 to reduce and remove the oxide layer on the wire surface, so that the wire surface is cleaned and the gas reducing furnace The heat applied to the wire to be plated 1 at 7 promotes the reaction between the wire to be plated 1 and the hot-dip metal, and the hot-dip wire 1a having a good plating layer is obtained.

【0012】また、溶融めっき工程で被めっき線1の外
周に付着してくる溶融金属を所要のめっき厚さに調整す
る絞り手段としては、通常用いられている絞りダイスd
を用いる手段と、絞りダイスdのような固体絞り具を用
いずに、溶融金属めっき浴8の表面を非酸化性ガス又は
還元性ガス雰囲気に保持し、溶融めっき線1aを溶融金
属めっき浴8の表面から前記非酸化性ガス又は還元性ガ
ス雰囲気中へ垂直方向に導出し、溶融めっき厚さの調整
を行なう手段とがある。後者の絞り手段を用いた場合、
前者の場合の絞りダイスのダイス孔径の選択の如何によ
って生ずるめっき厚の変動や偏肉のおそれがないので、
本発明の効果は一層向上される。
Further, as a drawing means for adjusting the molten metal adhering to the outer periphery of the wire 1 to be plated in the hot dipping process to a required plating thickness, a drawing die d which is usually used is used.
And a solid drawing tool such as a drawing die d are used, the surface of the molten metal plating bath 8 is maintained in a non-oxidizing gas or reducing gas atmosphere, and the molten plating wire 1a is held in the molten metal plating bath 8 There is a means for adjusting the thickness of the hot-dip galvanized film by drawing it out from the surface to the non-oxidizing gas or reducing gas atmosphere in the vertical direction. When using the latter diaphragm means,
In the former case, there is no fear of variation in plating thickness or uneven thickness caused by how to select the die hole diameter of the drawing die.
The effect of the present invention is further improved.

【0013】[0013]

【実施例】本発明の溶融めっき線の製造方法の実施例に
ついて図を用いて説明する。図1は本発明の溶融めっき
線の製造方法の工程ブロック図で、図1の(a)の矢印
線は本発明の第1実施例の製造工程を示し、被めっき母
線の伸線加工工程;と、被めっき線の巻取り貯留工程;
と、蒸気洗浄と焼鈍とを同時に行なう蒸気加熱工程,洗
浄工程,乾燥工程,及び酸化物除去と予備加熱を同時に
行なう還元性ガス加熱工程からなるめっき前処理工程;
と、溶融めっき工程からなる。
EXAMPLE An example of a method for manufacturing a hot-dip wire according to the present invention will be described with reference to the drawings. FIG. 1 is a process block diagram of a method for manufacturing a hot-dip galvanized wire according to the present invention. The arrow line in FIG. 1 (a) shows the manufacturing process of the first embodiment of the present invention, in which a bus bar to be plated is drawn. And a winding and storing step of the plated wire;
And a plating pretreatment step comprising a steam heating step of simultaneously performing steam cleaning and annealing, a cleaning step, a drying step, and a reducing gas heating step of simultaneously performing oxide removal and preheating;
And a hot dip plating process.

【0014】また図1の(b)の矢印線は本発明の第2
及び第3実施例の製造工程を示し、被めっき線の巻取り
貯留工程が除かれたもので、伸線加工工程後の被めっき
線は直ちに蒸気加熱工程へと導入され、以降は第1実施
例と同一工程を経る。即ち、第2及び第3実施例は伸線
加工工程,めっき前処理工程及び溶融めっき工程をタン
デム方式化した溶融めっき線の製造方法である。以下そ
れぞれの実施例につき詳細に説明する。
The arrow line in FIG. 1 (b) is the second line of the present invention.
And showing the manufacturing process of the third embodiment, the winding and storing step of the wire to be plated is omitted, the wire to be plated after the wire drawing step is immediately introduced into the steam heating step, and thereafter the first embodiment Go through the same steps as the example. That is, the second and third embodiments are methods of manufacturing a hot-dip wire in which the wire drawing step, the plating pretreatment step, and the hot-dip plating step are made into a tandem system. Each embodiment will be described in detail below.

【0015】第1実施例 第1実施例を図2に沿って説明する。同図(a)に示す
伸線機10は伸線材の接触通過する段ロール,キャプスタ
ン及び滑車等には例えばセラミック製或は鉄材の外周に
セラミック材を嵌め込む、又は鉄材の表面にセラミック
を熔射する、或は鉄材の表面に硬質クロムめっきを施す
等の鉄錆の発生しない耐磨耗性材料で表面処理したもの
が用いられる。被めっき母線Aはかかる伸線機10を用い
水溶性潤滑剤中にて、例えば2.6mmφの銅母線Aから0.3
mmφの被めっき銅線1に伸線加工される。伸線加工され
た被めっき銅線1が巻き取り貯留される巻枠2は、プラ
スチック製或は鉄製の巻枠の表面にエポキシ樹脂等の合
成樹脂をコーテイングしたもの、或は鉄製の巻枠の表面
にセラミックを被覆したもの、或は鉄製の巻枠の表面に
ニッケルやクロムめっきを施したもの等、巻枠の表面に
鉄錆の発生しない表面処理を行なったものが採用され
る。かようにして、被めっき銅線1はその表面に鉄粉及
び鉄酸化物の付着されない状態で貯留される。
First Embodiment A first embodiment will be described with reference to FIG. The wire drawing machine 10 shown in FIG. 1 (a) is made of, for example, ceramic or iron material fitted with ceramic material on the outer periphery of a corrugated roll, capstan, pulley, or the like through which the drawn material comes into contact, or ceramic is applied to the surface of the iron material. What is surface-treated with a wear-resistant material that does not generate iron rust, such as by melting, or by plating the surface of an iron material with hard chrome, is used. The bus bar A to be plated is, for example, from the copper bus bar A of 2.6 mmφ to 0.3 in a water-soluble lubricant using the wire drawing machine 10.
A copper wire 1 having a diameter of mmφ is drawn. The reel 2 in which the drawn copper wire 1 subjected to the wire drawing is wound and stored is a plastic or iron reel whose surface is coated with a synthetic resin such as epoxy resin, or an iron reel. The surface of the reel is coated with ceramics, or the surface of an iron reel is plated with nickel or chrome. Thus, the copper wire 1 to be plated is stored in a state where iron powder and iron oxide are not attached to the surface thereof.

【0016】以降の工程について図2(b)を用いて説
明する。巻枠2に巻取り貯留された被めっき銅線1は線
速70m/minで巻枠2から導出され、設定温度650℃の蒸
気雰囲気のトンネル式加熱炉3内を走行し、この加熱炉
3内で、被めっき銅線1の表面に付着した水溶性潤滑剤
が分離し易い状態に蒸気洗浄されると一緒に焼鈍され
る。次に、被めっき銅線1は外気に触れることなく直接
洗浄液4の超音波洗浄浴5に導かれ、被めっき銅線1の
表面の水溶性潤滑剤及びその他の付着不純物が完全に洗
浄される。なお、洗浄液4としては、例えば不純物の混
在のない上水を用いたが、純水を用いれば更に好まし
い。続いて圧搾空気kの送り込まれたエアワイパー6a
により超音波洗浄浴5で被めっき銅線1の表面に付着し
た水分が除去,乾燥される。次に被めっき銅線1は設定
温度500℃の一酸化炭素ガス雰囲気のガス還元炉7内に
導入され、線表面の酸化層が還元されCO2ガスとして除
去されると同時に被めっき銅線1は予熱された状態で直
接設定温度260℃の溶融錫めっき浴8に導入され、溶融
錫が付着され、続いて被めっき銅線1は、該溶融めっき
浴8直上に設けた絞りダイスdを通過し、被めっき銅線
1に付着してくる過剰の溶融錫を絞り、線外周に約5μ
m厚の溶融錫めっきを施し、しかる後大気中に導出し被
めっき銅線1外周のめっき層を冷却固化して溶融錫めっ
き線1aを製造した。また溶融めっき線の製造工程中の
伸線加工工程以降、溶融めっき工程までの間、被めっき
銅線1の通過する経路表面は鉄錆の発生しない材料で構
成した。この結果、被めっき銅線1は付着不純物及び酸
化層が完全に除去された状態で溶融めっきが施され、芯
線肌露出のない品質良好な溶融錫めっき線1aが得られ
た。
The subsequent steps will be described with reference to FIG. The to-be-plated copper wire 1 wound up and stored on the winding frame 2 is led out from the winding frame 2 at a linear velocity of 70 m / min, runs in a tunnel type heating furnace 3 in a steam atmosphere at a set temperature of 650 ° C., and the heating furnace 3 In the inside, the water-soluble lubricant adhering to the surface of the copper wire 1 to be plated is annealed together with being vapor-cleaned so as to be easily separated. Next, the copper wire 1 to be plated is directly introduced into the ultrasonic cleaning bath 5 of the cleaning liquid 4 without being exposed to the outside air, and the water-soluble lubricant and other adhered impurities on the surface of the copper wire 1 to be plated are completely cleaned. .. As the cleaning liquid 4, for example, clean water containing no impurities was used, but pure water is more preferable. Subsequently, the air wiper 6a into which the compressed air k has been sent
Thus, the ultrasonic cleaning bath 5 removes the moisture adhering to the surface of the copper wire 1 to be plated and dries it. Next, the copper wire 1 to be plated is introduced into the gas reduction furnace 7 in a carbon monoxide gas atmosphere at a set temperature of 500 ° C., and the oxide layer on the wire surface is reduced and removed as CO 2 gas, and at the same time the copper wire 1 to be plated 1 Is introduced into the molten tin plating bath 8 having a preset temperature of 260 ° C. in a preheated state, and the molten tin is adhered thereto, and subsequently the copper wire 1 to be plated passes through the drawing die d provided directly above the molten plating bath 8. Then, squeeze the excess molten tin adhering to the copper wire 1 to be plated, and apply about 5μ to the outer circumference of the wire.
A molten tin-plated wire 1a was produced by performing a hot-dip tin plating with a thickness of m and then introducing it into the atmosphere to cool and solidify the plating layer around the copper wire 1 to be plated. Further, after the wire drawing step in the manufacturing process of the hot dip plated wire and before the hot dip plating step, the surface of the route through which the plated copper wire 1 passes is made of a material that does not cause iron rust. As a result, the copper wire 1 to be plated was subjected to hot dip plating in a state where the attached impurities and the oxide layer were completely removed, and a good quality hot-dip tinned wire 1a with no exposed core wire skin was obtained.

【0017】第2実施例 第2実施例につき図3を用いて説明する。この第2実施
例は伸線加工工程,めっき前処理工程及び溶融めっき工
程を連続工程方式とし、タンデム化したものである。
Second Embodiment A second embodiment will be described with reference to FIG. In the second embodiment, the wire drawing process, the plating pretreatment process and the hot dip plating process are continuous processes and are tandemized.

【0018】被めっき母線Aの2.6mmφ銅線は、第1実
施例に示すと同一の伸線機10と伸線加工工程により0.3m
mφの被めっき銅線1に伸線加工され、この伸線加工さ
れた被めっき銅線1は伸線巻枠に貯留されることなく連
続して蒸気加熱工程の蒸気雰囲気のトンネル式加熱炉3
に導入され、以降の工程は第1実施例の工程と全く同一
の工程及び製造条件を経て溶融錫めっき線1aを製造し
た。なお、第2実施例の場合の線速も70m/minであっ
た。また、第2実施例の溶融めっき線の製造工程中の伸
線加工工程以降、溶融めっき工程までの間、被めっき銅
線1の通過する経路表面は第1実施例と同様鉄錆の発生
しない材料で構成した。第2実施例によって得られた溶
融錫めっき線1aも芯線肌見えのない極めて外観良好な
ものであった。
The 2.6 mmφ copper wire of the bus bar A to be plated is 0.3 m by the same wire drawing machine 10 and wire drawing process as shown in the first embodiment.
The mφ coated copper wire 1 is drawn, and the drawn copper wire 1 is continuously stored in the wire drawing reel without being stored in the drawing reel.
In the subsequent steps, the molten tin-plated wire 1a was manufactured through the same steps and manufacturing conditions as those of the first embodiment. The linear velocity in the case of the second embodiment was also 70 m / min. Further, from the wire drawing step in the hot-dip wire manufacturing process of the second embodiment to the hot-dip plating step, the route surface through which the copper wire 1 to be plated passes does not generate iron rust as in the first embodiment. Composed of materials. The molten tin-plated wire 1a obtained in the second example also had a very good appearance with no visible appearance of the core wire.

【0019】第3実施例 第3実施例につき図3及び図4を用いて説明する。第3
実施例も第2実施例と同様、伸線加工工程,めっき前処
理工程及び溶融めっき工程を連続工程方式とし、タンデ
ム化したものである。なお、溶融めっき工程における溶
融めっきの絞りは特に絞りダイス等の固体絞り具を用い
ずに行なった。
Third Embodiment A third embodiment will be described with reference to FIGS. 3 and 4. Third
Similar to the second embodiment, the embodiment is a tandem process in which the wire drawing process, the plating pretreatment process and the hot dip plating process are continuous processes. In the hot-dip plating process, the hot-dip plating was performed without using a solid drawing tool such as a drawing die.

【0020】被めっき母線Aとして2.6mmφの無酸素銅
(OFHC)線を用い、この被めっき母線A を、第1実施例
に示すと同一の伸線機10と伸線加工工程により0.46mmφ
の被めっきOFHC線1に伸線加工を施し、続いてこの被め
っきOFHC線1を第2実施例と同様の製造工程,即ち伸線
加工を施した被めっきOFHC線1は伸線巻枠に貯留される
ことなく連続して設定温度650℃の蒸気雰囲気のトンネ
ル式加熱炉3内を走行し、次に被めっきOFHC線1は外気
に触れることなく直接洗浄液4の超音波洗浄浴5に導か
れ、被めっきOFHC線1の表面の水溶性潤滑剤及びその他
の付着不純物が完全に洗浄される。なお、洗浄液4は上
水を用いたが、純水を用いてもよい。続いて圧搾空気k
の送り込まれたエアワイパー6aにより超音波洗浄浴5
で被めっきOFHC線1の表面に付着した水分が除去,乾燥
される。次に被めっき0FHC線1は設定温度500℃の水素
ガスを10VOL%含有した窒素ガス雰囲気のガス還元炉7内
を走行し、線表面の酸化層が還元除去されると同時に被
めっきOFHC線1は予熱された状態で直接図4に示す設定
温度260℃の溶融錫めっき浴8に導入される。この溶融
めっき浴8に浸漬された被めっきOFHC線1は、該めっき
浴8から垂直方向へ導出されることにより、絞り具を用
いることなく線外周に溶融錫めっきが施される。この
際、被めっきOFHC線1が導出される溶融めっき浴面に接
して非酸化性或は還元性ガス雰囲気の室9を設ける。被
めっきOFHC線1は、前記溶融めっき浴8面から垂直方向
に非酸化性或は還元性ガス室9中へ導出され、非酸化性
或は還元性ガス室9を通過した後大気中に導出され、め
っき層を冷却固化し、めっき厚12μmの溶融錫めっき線
1aを製造した。第3実施例の場合の線速は30m/minで
あった。固体絞り具を用いない第3実施例の場合のめっ
き厚さの調整は線速及び非酸化性或は還元性ガス室9の
ガス温度をコントロールすることによって可能である。
即ち線速を速くすればめっき厚を厚くでき、また線速を
遅くすればめっき厚を薄くでき、またガス室の温度を高
温にすることによりめっき厚を薄くすることができる。
また、第3実施例の溶融めっき線の製造工程中の伸線加
工工程以降、溶融めっき工程までの間、被めっきOFHC線
1の通過する経路表面は第1実施例と同様鉄錆の発生し
ない材料で構成した。第3実施例によって得られた溶融
錫めっき線1aは芯線肌見えのない均一なめっき厚さを
有する極めて外観良好なものであった。
A 2.6 mmφ oxygen-free copper (OFHC) wire was used as the busbar A to be plated, and this busbar A was 0.46 mmφ by the same wire drawing machine 10 and wire drawing process as shown in the first embodiment.
The plated OFHC wire 1 is subjected to wire drawing, and then the plated OFHC wire 1 is subjected to the same manufacturing process as in the second embodiment, that is, the plated OFHC wire 1 subjected to wire drawing is formed into a wire drawing reel. It runs continuously in a tunnel-type heating furnace 3 in a steam atmosphere with a set temperature of 650 ° C without being stored, and then the plated OFHC wire 1 is directly introduced into an ultrasonic cleaning bath 5 of a cleaning liquid 4 without touching the outside air. Then, the surface of the plated OFHC wire 1 is completely cleaned of water-soluble lubricant and other attached impurities. Although clean water was used as the cleaning liquid 4, pure water may be used. Then compressed air k
Ultrasonic cleaning bath 5 by air wiper 6a
The water adhering to the surface of the plated OFHC wire 1 is removed and dried. Next, the 0FHC wire to be plated 1 runs in a gas reduction furnace 7 in a nitrogen gas atmosphere containing 10 vol% of hydrogen gas at a set temperature of 500 ° C, and the oxide layer on the wire surface is reduced and removed, and at the same time, the OFHC wire to be plated 1 Is directly introduced into the molten tin plating bath 8 shown in FIG. The to-be-plated OFHC wire 1 immersed in the hot dip plating bath 8 is drawn out from the hot plating bath 8 in the vertical direction, so that the outer circumference of the wire is hot-dip plated without using a wringer. At this time, a chamber 9 of a non-oxidizing or reducing gas atmosphere is provided in contact with the surface of the hot dip bath from which the OFHC wire 1 to be plated is led out. The to-be-plated OFHC wire 1 is led out vertically into the non-oxidizing or reducing gas chamber 9 from the surface of the hot dip plating bath 8 and, after passing through the non-oxidizing or reducing gas chamber 9, is led out to the atmosphere. Then, the plated layer was cooled and solidified to produce a molten tin-plated wire 1a having a plating thickness of 12 μm. The linear velocity in the case of the third embodiment was 30 m / min. In the case of the third embodiment which does not use a solid wringer, the plating thickness can be adjusted by controlling the linear velocity and the gas temperature of the non-oxidizing or reducing gas chamber 9.
That is, the plating thickness can be increased by increasing the linear velocity, the plating thickness can be reduced by decreasing the linear velocity, and the plating thickness can be reduced by increasing the temperature of the gas chamber.
Further, from the wire drawing step in the manufacturing process of the hot-dip wire of the third embodiment to the hot-dip plating step, the route surface through which the plated OFHC wire 1 passes does not generate iron rust as in the first embodiment. Composed of materials. The hot-dip tinned wire 1a obtained in the third example had an extremely good appearance with a uniform plating thickness with no visible appearance of the core wire.

【0021】[0021]

【発明の効果】本発明の溶融めっき線の製造方法によれ
ば、被めっき線の伸線加工工程及び被めっき線の貯留工
程で被めっき線表面に鉄粉及び鉄酸化物が付着する恐れ
が全くなくなったので、従来被めっき線表面に前記鉄酸
化物等が付着し、これらが変質した水酸化鉄の反応に起
因して発生していためっき線の芯線肌露出の不具合がな
くなり、また被めっき線の表面に付着してくる伸線加工
工程中の水溶性潤滑剤,その他の付着不純物及び被めっ
き線表面の酸化層等溶融めっきを阻害する汚れが、蒸気
雰囲気加熱炉,超音波洗浄浴,ガス還元炉を通過するこ
とにより被めっき線の表面から除去される。この結果、
外観の極めて優れた品質良好な溶融めっき線を安定して
製造することができる。更に、酸フラックス浴を用いる
必要がないのでめっき装置や周辺物の汚染,損耗もな
く、作業環境が改善される。
EFFECTS OF THE INVENTION According to the method for producing a hot-dip coated wire of the present invention, there is a possibility that iron powder and iron oxide may adhere to the surface of the wire to be plated during the wire drawing process of the wire to be plated and the step of storing the wire to be plated. Since it is completely eliminated, the iron oxides and the like adhere to the surface of the wire to be plated, and the problem of exposing the core wire skin of the plated wire, which has occurred due to the reaction of the altered iron hydroxide, is eliminated. Water-soluble lubricants, other adhering impurities that adhere to the surface of the plated wire during the drawing process, and dirt that interferes with hot-dip plating such as the oxide layer on the surface of the plated wire, steam atmosphere heating furnace, ultrasonic cleaning bath , It is removed from the surface of the wire to be plated by passing through the gas reduction furnace. As a result,
It is possible to stably manufacture a hot-dip wire having a very good appearance and good quality. Further, since it is not necessary to use an acid flux bath, there is no contamination or wear of the plating equipment and surroundings, and the working environment is improved.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の溶融めっき線の製造方法の工程ブロッ
ク図である。
FIG. 1 is a process block diagram of a method for manufacturing a hot-dip wire according to the present invention.

【図2】本発明の溶融めっき線の製造方法の第1実施例
を示す概略図であり、同図(a)は伸線加工工程及び巻
取り貯留工程を示し、また同図(b)は巻枠に貯留され
た被めっき線のめっき前処理工程及び溶融めっき工程を
示す。
FIG. 2 is a schematic view showing a first embodiment of the method for producing a hot-dip wire according to the present invention, wherein FIG. 2 (a) shows a wire drawing process and a winding / storing process, and FIG. The pre-plating process and the hot-dip plating process of the wire to be plated stored in the reel are shown.

【図3】本発明の溶融めっき線の製造方法の第2及び第
3実施例を示す概略図である。
FIG. 3 is a schematic view showing second and third embodiments of the method for manufacturing a hot-dip wire according to the present invention.

【図4】第3実施例の溶融めっき工程を示す概略図であ
る。
FIG. 4 is a schematic view showing a hot dip plating process of a third embodiment.

【図5】従来の溶融めっき線の製造方法を示す概略図で
ある。
FIG. 5 is a schematic view showing a conventional hot-dip wire manufacturing method.

【符号の説明】[Explanation of symbols]

1 被めっき線 1a 溶融めっき線 2 巻枠 3 蒸気雰囲気加熱炉 4 洗浄液 5 超音波洗浄浴 6a エアワイパー 7 還元性ガス雰囲気加熱炉 8 溶融金属めっき浴 9 非酸化性或は還元性ガス室 10 伸線機 A 被めっき母線 d 絞りダイス k 圧搾空気 1 Wire to be plated 1a Hot-dip wire 2 Reel 3 Steam atmosphere heating furnace 4 Cleaning liquid 5 Ultrasonic cleaning bath 6a Air wiper 7 Reducing gas atmosphere heating furnace 8 Molten metal plating bath 9 Non-oxidizing or reducing gas chamber 10 Stretching Wire machine A Plated bus bar d Drawing die k Compressed air

Claims (1)

【特許請求の範囲】 【請求項1】 伸線材の接触通過する伸線加工経路表面
を鉄錆の発生しない耐磨耗性材料から構成した伸線機10
を用い水溶性潤滑剤中にて被めっき母線Aに伸線加工を
施す伸線加工工程;と、伸線加工された被めっき線1を
少なくとも該被めっき線1と接触する表面が鉄錆の発生
しない材料からなる巻枠2に巻取り貯留する巻取り貯留
工程;と、前記巻枠2に巻取り貯留された被めっき線1
を蒸気雰囲気の加熱炉3内を走行させ、前記伸線加工工
程で被めっき線1の表面に付着した水溶性潤滑剤を分離
しやすい状態にする蒸気洗浄と被めっき線1の焼鈍とを
同時に行なう蒸気加熱工程と、この蒸気加熱工程後の被
めっき線1を洗浄液4を用いた超音波洗浄浴5中を通過
させ線表面を洗浄する洗浄工程と、この被めっき線1の
表面の水分を除去,乾燥する乾燥工程と、この乾燥工程
後の被めっき線1を還元性ガス雰囲気の加熱炉7内を走
行させ、被めっき線1の表面の酸化層の除去と同時に被
めっき線1を予備加熱し溶融めっき金属との反応を促進
するための還元性ガス加熱工程とからなるめっき前処理
工程;と、この還元性ガス加熱工程と直結して被めっき
線1に溶融金属めっきを施す溶融めっき工程;とを備え
たことを特徴とする溶融めっき線の製造方法。 【請求項2】 伸線材の接触通過する伸線加工経路表面
を鉄錆の発生しない耐磨耗性材料から構成した伸線機10
を用い水溶性潤滑剤中にて被めっき母線Aに伸線加工を
施す伸線加工工程;と、前記伸線加工された被めっき線
1を蒸気雰囲気の加熱炉3内を走行させ、前記伸線加工
工程において被めっき線1の表面に付着した水溶性潤滑
剤を分離しやすい状態にする蒸気洗浄と被めっき線1の
焼鈍とを同時に行なう蒸気加熱工程と、この蒸気加熱工
程後の被めっき線1を洗浄液4を用いた超音波洗浄浴5
中を通過させ線表面を洗浄する洗浄工程と、この被めっ
き線1の表面の水分を除去,乾燥する乾燥工程と、この
乾燥工程後の被めっき線1を還元性ガス雰囲気の加熱炉
7内を走行させ、前記被めっき線1の表面の酸化層の除
去と同時に被めっき線1を予備加熱し溶融めっき金属と
の反応を促進するための還元性ガス加熱工程とからなる
めっき前処理工程;と、この還元性ガス加熱工程と直結
して被めっき線1に溶融金属めっきを施す溶融めっき工
程;とを備え、前記伸線加工工程,めっき前処理工程お
よび溶融めっき工程を連続して行なうことを特徴とする
溶融めっき線の製造方法。 【請求項3】 前記めっき前処理工程で被めっき線1が
接触通過する経路表面を鉄錆の発生しない材料から構成
したことを特徴とする請求項1または2記載の溶融めっ
き線の製造方法。 【請求項4】 前記溶融めっき工程における被めっき線
1外周の溶融金属めっき厚さの調整が絞りダイスdによ
り行なわれることを特徴とする請求項1,2または3記
載の溶融めっき線の製造方法。 【請求項5】 前記溶融めっき工程における被めっき線
1外周の溶融金属めっき厚さの調整が、前記被めっき線
1の導出される前記溶融金属めっき浴8面に接して非酸
化性ガス又は還元性ガス雰囲気のガス室9を設け、前記
被めっき線1を前記溶融金属めっき浴8面から前記非酸
化性ガス又は還元性ガス雰囲気のガス室9内へ垂直方向
へ導出通過させることにより行なわれることを特徴とす
る請求項1,2または3記載の溶融めっき線の製造方
法。
Claims: 1. A wire drawing machine in which the surface of a wire drawing path through which a wire drawing material comes in contact is made of a wear-resistant material that does not generate iron rust.
A wire drawing step for drawing a bus bar A to be plated in a water-soluble lubricant by using; and at least the surface of the wire to be plated 1 that has been drawn is in contact with the wire to be plated 1 of iron rust. A winding and storing step of winding and storing on a winding frame 2 made of a material that does not occur; and a plated wire 1 wound and stored on the winding frame 2.
Is run in the heating furnace 3 in a steam atmosphere to simultaneously separate the water-soluble lubricant adhering to the surface of the wire 1 to be separated in the wire drawing step and the annealing of the wire 1 at the same time. A steam heating step to be performed, a cleaning step of passing the wire to be plated 1 after the steam heating step through an ultrasonic cleaning bath 5 using a cleaning liquid 4 to clean the wire surface, and moisture on the surface of the wire to be plated 1 After the drying step of removing and drying, and the plated wire 1 after this drying step is run in the heating furnace 7 in a reducing gas atmosphere, the oxidized wire on the surface of the plated wire 1 is removed and the plated wire 1 is preliminarily prepared at the same time. A plating pretreatment step comprising a heating step for heating and a reducing gas heating step for promoting a reaction with the hot-dip metal; and hot-dip plating for directly applying hot-dip metal plating to the wire 1 to be plated, which is directly connected to the reducing gas heating step Process; and are provided. Method for producing a melt-plated wire. 2. A wire drawing machine 10 in which the surface of a wire drawing path through which a wire drawing material comes into contact is made of a wear resistant material that does not generate iron rust.
And a wire drawing step of performing wire drawing on the bus bar A to be plated in a water-soluble lubricant; and running the wire 1 to be plated in the heating furnace 3 in a steam atmosphere, In the wire processing step, a steam heating step of simultaneously performing steam cleaning for making the water-soluble lubricant adhering to the surface of the plated wire 1 easy to separate and annealing of the plated wire 1 and plating after the steam heating step Ultrasonic cleaning bath 5 using cleaning liquid 4
A cleaning step of passing the inside of the wire to clean the surface of the wire, a drying step of removing water on the surface of the wire to be plated 1 and drying, and the wire 1 to be plated after the drying step in a heating furnace 7 in a reducing gas atmosphere. And a reducing gas heating step for preheating the wire to be plated 1 at the same time as removing the oxide layer on the surface of the wire to be plated 1 and promoting a reaction with the hot-dip plated metal; And a hot dip plating step for directly performing hot metal plating on the wire to be plated 1 by directly connecting to the reducing gas heating step; and continuously performing the wire drawing step, plating pretreatment step and hot dip coating step. A method for producing a hot-dip galvanized wire. 3. The method of manufacturing a hot-dip galvanized wire according to claim 1, wherein the surface of the path through which the wire to be plated 1 comes into contact in the pre-plating treatment step is made of a material that does not generate iron rust. 4. The method for producing a hot-dip wire according to claim 1, wherein the thickness of the hot-dip metal plating on the outer periphery of the wire to be plated 1 in the hot-dip plating step is adjusted by a drawing die d. .. 5. The adjustment of the thickness of the molten metal plating on the outer periphery of the wire to be plated 1 in the hot dip plating step is performed by contacting the surface of the molten metal plating bath 8 from which the wire to be plated 1 is drawn out with a non-oxidizing gas or reduction. A gas chamber 9 having an atmosphere of a reactive gas is provided, and the wire 1 to be plated is vertically led out from the surface of the molten metal plating bath 8 into the gas chamber 9 having a non-oxidizing gas or reducing gas atmosphere. The method for manufacturing a hot-dip wire according to claim 1, 2 or 3, characterized in that.
JP26830391A 1990-09-20 1991-09-19 Production of hot-dip coated wire Pending JPH055169A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP26830391A JPH055169A (en) 1990-09-20 1991-09-19 Production of hot-dip coated wire

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP25285390 1990-09-20
JP2-252853 1990-09-20
JP26830391A JPH055169A (en) 1990-09-20 1991-09-19 Production of hot-dip coated wire

Publications (1)

Publication Number Publication Date
JPH055169A true JPH055169A (en) 1993-01-14

Family

ID=26540914

Family Applications (1)

Application Number Title Priority Date Filing Date
JP26830391A Pending JPH055169A (en) 1990-09-20 1991-09-19 Production of hot-dip coated wire

Country Status (1)

Country Link
JP (1) JPH055169A (en)

Cited By (7)

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Publication number Priority date Publication date Assignee Title
EP1758175A1 (en) 2004-05-21 2007-02-28 Neomax Materials Co., Ltd. Electrode wire for solar battery
WO2011155477A1 (en) * 2010-06-11 2011-12-15 古河電気工業株式会社 Process and apparatus for producing solder-plated wire
WO2012063396A1 (en) * 2010-11-08 2012-05-18 三菱電線工業株式会社 Plated wire material, production method for same, and production device
JP2012101242A (en) * 2010-11-09 2012-05-31 Hitachi Metals Ltd Apparatus for forming deformed wire rod
WO2012111185A1 (en) * 2011-02-15 2012-08-23 三菱電線工業株式会社 Solder-plated copper wire and method for producing same
KR20160103884A (en) * 2015-02-25 2016-09-02 동명대학교산학협력단 A multifunctional compass with functions of Angle and length measurement
CN114015958A (en) * 2021-11-18 2022-02-08 杭州远鸿科技有限公司 Vertical copper wire tinning machine and production process thereof

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JPS5331529A (en) * 1976-09-06 1978-03-24 Showa Electric Wire & Cable Co Surface treatment method of core rod in dippforming process
JPS54114439A (en) * 1978-02-25 1979-09-06 Nippon Steel Corp High temperature atomosphere roll
JPS54159338A (en) * 1978-06-07 1979-12-17 Sakura Tokushiyukou Shinen Kk Production of plated copper wire
JPS59123751A (en) * 1982-12-27 1984-07-17 Sumitomo Electric Ind Ltd Production of electrode wire for electric spark machining for cutting wire
JPS62236618A (en) * 1986-04-03 1987-10-16 Fujikura Ltd Manufacture for coated steel wire
JPH02185958A (en) * 1989-01-13 1990-07-20 Furukawa Electric Co Ltd:The Production of wire plated with metal by hot dipping

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* Cited by examiner, † Cited by third party
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JPS5329248A (en) * 1976-08-31 1978-03-18 Tatsuta Densen Kk Solder plating wire pale packing method
JPS5331529A (en) * 1976-09-06 1978-03-24 Showa Electric Wire & Cable Co Surface treatment method of core rod in dippforming process
JPS54114439A (en) * 1978-02-25 1979-09-06 Nippon Steel Corp High temperature atomosphere roll
JPS54159338A (en) * 1978-06-07 1979-12-17 Sakura Tokushiyukou Shinen Kk Production of plated copper wire
JPS59123751A (en) * 1982-12-27 1984-07-17 Sumitomo Electric Ind Ltd Production of electrode wire for electric spark machining for cutting wire
JPS62236618A (en) * 1986-04-03 1987-10-16 Fujikura Ltd Manufacture for coated steel wire
JPH02185958A (en) * 1989-01-13 1990-07-20 Furukawa Electric Co Ltd:The Production of wire plated with metal by hot dipping

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1758175A1 (en) 2004-05-21 2007-02-28 Neomax Materials Co., Ltd. Electrode wire for solar battery
EP3012872B1 (en) 2004-05-21 2017-07-12 Hitachi Metals, Ltd. Solar cell
JP2011258963A (en) * 2004-05-21 2011-12-22 Neomax Materials Co Ltd Electrode wire for solar cell
EP1758175B1 (en) 2004-05-21 2016-05-04 Hitachi Metals, Ltd. Electrode wire for solar battery
JP2012017516A (en) * 2010-06-11 2012-01-26 Furukawa Electric Co Ltd:The Method and apparatus for manufacturing solder plated wire
JP2012017518A (en) * 2010-06-11 2012-01-26 Furukawa Electric Co Ltd:The Method and apparatus for manufacturing solder plated wire
JP2012017515A (en) * 2010-06-11 2012-01-26 Furukawa Electric Co Ltd:The Method and apparatus for manufacturing solder plated wire
JP2012017517A (en) * 2010-06-11 2012-01-26 Furukawa Electric Co Ltd:The Method and apparatus for manufacturing solder plated wire
JP2012017523A (en) * 2010-06-11 2012-01-26 Furukawa Electric Co Ltd:The Method and apparatus for manufacturing solder plated wire
WO2011155477A1 (en) * 2010-06-11 2011-12-15 古河電気工業株式会社 Process and apparatus for producing solder-plated wire
WO2012063396A1 (en) * 2010-11-08 2012-05-18 三菱電線工業株式会社 Plated wire material, production method for same, and production device
JP2012101242A (en) * 2010-11-09 2012-05-31 Hitachi Metals Ltd Apparatus for forming deformed wire rod
WO2012111185A1 (en) * 2011-02-15 2012-08-23 三菱電線工業株式会社 Solder-plated copper wire and method for producing same
JPWO2012111185A1 (en) * 2011-02-15 2014-07-03 三菱電線工業株式会社 Solder-plated copper wire and manufacturing method thereof
KR20160103884A (en) * 2015-02-25 2016-09-02 동명대학교산학협력단 A multifunctional compass with functions of Angle and length measurement
CN114015958A (en) * 2021-11-18 2022-02-08 杭州远鸿科技有限公司 Vertical copper wire tinning machine and production process thereof
CN114015958B (en) * 2021-11-18 2023-10-10 杭州远鸿科技有限公司 Vertical copper wire tinning machine and production process thereof

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