JPH0547077B2 - - Google Patents
Info
- Publication number
- JPH0547077B2 JPH0547077B2 JP61136328A JP13632886A JPH0547077B2 JP H0547077 B2 JPH0547077 B2 JP H0547077B2 JP 61136328 A JP61136328 A JP 61136328A JP 13632886 A JP13632886 A JP 13632886A JP H0547077 B2 JPH0547077 B2 JP H0547077B2
- Authority
- JP
- Japan
- Prior art keywords
- nuclear fuel
- fuel material
- diamine
- oxalate
- ceramic nuclear
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003758 nuclear fuel Substances 0.000 claims description 100
- 239000000463 material Substances 0.000 claims description 94
- 239000011230 binding agent Substances 0.000 claims description 85
- 239000000919 ceramic Substances 0.000 claims description 76
- 239000000203 mixture Substances 0.000 claims description 48
- -1 oxalate ions Chemical class 0.000 claims description 48
- OOAWCECZEHPMBX-UHFFFAOYSA-N oxygen(2-);uranium(4+) Chemical compound [O-2].[O-2].[U+4] OOAWCECZEHPMBX-UHFFFAOYSA-N 0.000 claims description 45
- FCTBKIHDJGHPPO-UHFFFAOYSA-N uranium dioxide Inorganic materials O=[U]=O FCTBKIHDJGHPPO-UHFFFAOYSA-N 0.000 claims description 45
- 238000000034 method Methods 0.000 claims description 37
- 150000004985 diamines Chemical class 0.000 claims description 35
- 238000000748 compression moulding Methods 0.000 claims description 24
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 23
- VBIXEXWLHSRNKB-UHFFFAOYSA-N ammonium oxalate Chemical compound [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 claims description 19
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 18
- 239000007864 aqueous solution Substances 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 15
- MUBZPKHOEPUJKR-UHFFFAOYSA-L Oxalate Chemical compound [O-]C(=O)C([O-])=O MUBZPKHOEPUJKR-UHFFFAOYSA-L 0.000 claims description 13
- 239000000243 solution Substances 0.000 claims description 13
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000000047 product Substances 0.000 claims description 11
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 10
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- 238000007906 compression Methods 0.000 claims description 8
- 230000006835 compression Effects 0.000 claims description 8
- 230000002459 sustained effect Effects 0.000 claims description 7
- 239000007795 chemical reaction product Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 claims description 5
- 235000006408 oxalic acid Nutrition 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 125000003916 ethylene diamine group Chemical group 0.000 claims 3
- 238000011065 in-situ storage Methods 0.000 claims 2
- 230000002085 persistent effect Effects 0.000 claims 2
- 239000008187 granular material Substances 0.000 claims 1
- 230000002045 lasting effect Effects 0.000 claims 1
- 239000011259 mixed solution Substances 0.000 claims 1
- 238000005245 sintering Methods 0.000 description 13
- 239000002245 particle Substances 0.000 description 9
- 239000008188 pellet Substances 0.000 description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 230000002411 adverse Effects 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- DSERHVOICOPXEJ-UHFFFAOYSA-L uranyl carbonate Chemical compound [U+2].[O-]C([O-])=O DSERHVOICOPXEJ-UHFFFAOYSA-L 0.000 description 3
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910052688 Gadolinium Inorganic materials 0.000 description 2
- 229910052778 Plutonium Inorganic materials 0.000 description 2
- 229910052776 Thorium Inorganic materials 0.000 description 2
- 229910052770 Uranium Inorganic materials 0.000 description 2
- WZECUPJJEIXUKY-UHFFFAOYSA-N [O-2].[O-2].[O-2].[U+6] Chemical compound [O-2].[O-2].[O-2].[U+6] WZECUPJJEIXUKY-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- BVCZEBOGSOYJJT-UHFFFAOYSA-N ammonium carbamate Chemical compound [NH4+].NC([O-])=O BVCZEBOGSOYJJT-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- SHZGCJCMOBCMKK-KGJVWPDLSA-N beta-L-fucose Chemical compound C[C@@H]1O[C@H](O)[C@@H](O)[C@H](O)[C@@H]1O SHZGCJCMOBCMKK-KGJVWPDLSA-N 0.000 description 2
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- OYEHPCDNVJXUIW-UHFFFAOYSA-N plutonium atom Chemical compound [Pu] OYEHPCDNVJXUIW-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 2
- 229910003452 thorium oxide Inorganic materials 0.000 description 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 2
- 229910000439 uranium oxide Inorganic materials 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- CSSWKUCQEKKMAV-UHFFFAOYSA-N carbamic acid;carbonic acid Chemical compound NC(O)=O.OC(O)=O CSSWKUCQEKKMAV-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000003361 porogen Substances 0.000 description 1
- 238000009700 powder processing Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002915 spent fuel radioactive waste Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000007847 structural defect Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
- G21C3/42—Selection of substances for use as reactor fuel
- G21C3/58—Solid reactor fuel Pellets made of fissile material
- G21C3/62—Ceramic fuel
- G21C3/623—Oxide fuels
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/51—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on compounds of actinides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- High Energy & Nuclear Physics (AREA)
- General Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Glanulating (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US744945 | 1985-06-17 | ||
| US06/744,945 US4670198A (en) | 1985-06-17 | 1985-06-17 | Binder system for the manufacture of nuclear fuel pellets, and the method and product thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6232387A JPS6232387A (ja) | 1987-02-12 |
| JPH0547077B2 true JPH0547077B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-07-15 |
Family
ID=24994576
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61136328A Granted JPS6232387A (ja) | 1985-06-17 | 1986-06-13 | 核燃料ペレツト製造用の結合剤並びにそれを用いた方法および製品 |
Country Status (6)
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2007108716A (ru) * | 2004-09-10 | 2008-10-20 | Вайет (Us) | Гуманизированные антитела к антигену 5т4 и конъюгаты гуманизированного антитела к антигену 5т4 с калихеамицином |
| US9466398B2 (en) * | 2010-09-27 | 2016-10-11 | Purdue Research Foundation | Ceramic-ceramic composites and process therefor, nuclear fuels formed thereby, and nuclear reactor systems and processes operated therewith |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1536677A (fr) * | 1966-09-14 | 1968-08-16 | Atomenergi Ab | Procédé de fabrication d'un corps poreux d'un oxyde combustible nucléaire |
| US3927154A (en) * | 1968-08-05 | 1975-12-16 | Gen Electric | Process for preparing sintered uranium dioxide nuclear fuel |
| US3923933A (en) * | 1968-10-29 | 1975-12-02 | Gen Electric | Process for preparing sintered uranium dioxide grains |
| US3803273A (en) * | 1971-08-27 | 1974-04-09 | Gen Electric | Ceramic fuel fabrication process providing controlled density and grain size |
| GB1461263A (en) * | 1973-01-12 | 1977-01-13 | British Nuclear Fuels Ltd | Ceramic nuclear fuel pellets |
| GB1461264A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1973-01-12 | 1977-01-13 | ||
| US4061700A (en) * | 1975-09-10 | 1977-12-06 | General Electric Company | Fugitive binder for nuclear fuel materials |
| US4383953A (en) * | 1980-01-21 | 1983-05-17 | General Electric Company | Method of improving the green strength of nuclear fuel pellets |
| US4389341A (en) * | 1981-06-15 | 1983-06-21 | General Electric Company | Fugitive binder-containing nuclear fuel material and method of production |
| US4427579A (en) * | 1981-12-17 | 1984-01-24 | General Electric Company | Method of producing fugitive binder-containing nuclear fuel material |
| US4432915A (en) * | 1982-03-22 | 1984-02-21 | General Electric Company | Method for producing nuclear fuel pellets, and product thereof |
| US4575436A (en) * | 1982-08-24 | 1986-03-11 | General Electric Company | Production of nuclear fuel products |
| US4522769A (en) * | 1982-08-24 | 1985-06-11 | General Electric Company | Method for the manufacture of nuclear fuel products |
| JPS6070393A (ja) * | 1983-07-27 | 1985-04-22 | ゼネラル・エレクトリツク・カンパニイ | 核燃料ペレツト製造用の改良された方法および結合剤並びにそれによつて得られる製品 |
| US4572810A (en) * | 1984-09-17 | 1986-02-25 | General Electric Company | Method for providing uranium hydroxide on UO2 particles prior to generation of fugitive binder for sintering |
-
1985
- 1985-06-17 US US06/744,945 patent/US4670198A/en not_active Expired - Lifetime
-
1986
- 1986-04-11 DE DE19863612163 patent/DE3612163A1/de not_active Withdrawn
- 1986-06-09 IT IT20724/86A patent/IT1190009B/it active
- 1986-06-12 ES ES555998A patent/ES8900182A1/es not_active Expired
- 1986-06-13 JP JP61136328A patent/JPS6232387A/ja active Granted
- 1986-06-13 CA CA000511598A patent/CA1263526A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IT8620724A1 (it) | 1987-12-09 |
| ES8900182A1 (es) | 1989-02-16 |
| ES555998A0 (es) | 1989-02-16 |
| IT8620724A0 (it) | 1986-06-09 |
| IT1190009B (it) | 1988-02-10 |
| CA1263526A (en) | 1989-12-05 |
| DE3612163A1 (de) | 1986-12-18 |
| US4670198A (en) | 1987-06-02 |
| JPS6232387A (ja) | 1987-02-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |