JPH05139953A - Body shampoo composition - Google Patents

Body shampoo composition

Info

Publication number
JPH05139953A
JPH05139953A JP3326414A JP32641491A JPH05139953A JP H05139953 A JPH05139953 A JP H05139953A JP 3326414 A JP3326414 A JP 3326414A JP 32641491 A JP32641491 A JP 32641491A JP H05139953 A JPH05139953 A JP H05139953A
Authority
JP
Japan
Prior art keywords
saponin
effect
solution
water
clean cotton
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP3326414A
Other languages
Japanese (ja)
Other versions
JP3226225B2 (en
Inventor
Junji Nakamura
潤二 中村
Masayuki Suzuki
雅之 鈴木
Takashi Kurokawa
隆史 黒川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dowa Holdings Co Ltd
Original Assignee
Dowa Mining Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dowa Mining Co Ltd filed Critical Dowa Mining Co Ltd
Priority to JP32641491A priority Critical patent/JP3226225B2/en
Publication of JPH05139953A publication Critical patent/JPH05139953A/en
Application granted granted Critical
Publication of JP3226225B2 publication Critical patent/JP3226225B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PURPOSE:To provide the title composition having high washing power, high in safety and leaving no uncomfortableness after washing, containing, as active ingredient, saponin. CONSTITUTION:The objective composition containing, as active ingredient, at least one kind of plant-derived saponin as a natural surfactant (e.g. soybean saponin). Saponin is a general term describing a glycoside with polycyclic compounds as aglycone, being low toxic in terms of oral use, having surface-active effect, hemolytic effect, fish-poisonous effect, insecticidal effect, foaming effect, bactericidal effect, being readily soluble in water; its solution free from greasines or sliminess. Also, wet wipers or cotton for such purposes with no need for washing out with water can be provided by impregnation of a saponin- contg. solution.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、1種類以上のサポニン
を含有することを特徴とする身体用洗浄剤組成物、ウエ
ットワイパー類および清浄綿に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a personal cleansing composition, wet wipes and clean cotton, which contains one or more kinds of saponins.

【0002】[0002]

【従来の技術】近年、髪や身体を清潔に保つことが若い
女性の間のみならず広く重要視されるようになり、それ
に伴いさまざまな洗浄剤や衛生用品などが出回るように
なった。
2. Description of the Related Art In recent years, keeping the hair and body clean has become more important not only for young women, but along with it, various cleaning agents and hygiene products have come into circulation.

【0003】従来の洗浄剤においては、一般に陰イオン
活性剤(アルキルベンゼンスルホン酸塩、アルキル硫酸
塩、イゲポンTなど)や、アルキルフェノール系やプル
ロニック系の非イオン活性剤などが洗浄成分として添加
されていた。また、近年ではこのような洗浄成分に加え
てさらに脱臭作用を有する成分等を添加することによ
り、洗浄効果に優れるだけでなく、脱臭作用、起泡作
用、殺菌作用または防臭作用など様々な効果を兼ね備え
た洗浄剤が数多く製造・販売されている。しかしなが
ら、これら従来の洗浄剤には刺激性があったり、べたつ
き感やぬるつき感などがあったため、使用後に水で十二
分に洗い流さなければ皮膚が荒れたり不快感が残るなど
の問題点があった。
In conventional cleaning agents, anionic activators (alkylbenzene sulfonates, alkyl sulfates, Igepon T, etc.) and alkylphenol-based or Pluronic-based nonionic activators have generally been added as cleaning ingredients. .. In addition, in recent years, in addition to such a cleaning component, by adding a component having a deodorizing effect, etc., not only the cleaning effect is excellent, but also various effects such as deodorizing effect, foaming effect, bactericidal effect or deodorant effect can be obtained. A large number of combined cleaning agents are manufactured and sold. However, since these conventional cleaning agents have irritating, sticky feeling, and slimy feeling, there is a problem that the skin becomes rough and uncomfortable remains unless it is thoroughly washed off with water after use. there were.

【0004】一方、衛生用品においても上記のように様
々な効果を有するものが多く、例えば、防腐剤の配合さ
れているウエットティッシュや、殺菌剤の配合されてい
る清浄綿またはおしぼりなどが製造・販売されている。
しかしながら、従来のウエットワイパー類や清浄綿は、
洗浄効果が低いという問題点があった。これは、使用後
に水で十二分に洗い流さなければ皮膚が荒れたり不快感
が残るなどの問題点を未解決のまま残している上記洗浄
剤を使用後に水で洗い流すことをしないウエットワイパ
ー類や清浄綿に、多量に含有させることはできないため
である。
On the other hand, many hygiene products have various effects as described above, for example, wet tissues containing a preservative, clean cotton or a hand towel containing a bactericide are produced and manufactured. It is sold.
However, conventional wet wipes and clean cotton are
There is a problem that the cleaning effect is low. This is a wet wiper that does not wash away with water after using the above cleaning agent, which leaves problems such as rough skin and discomfort remaining if it is not washed off with water after use. This is because a large amount cannot be contained in clean cotton.

【0005】[0005]

【発明が解決しようとする課題】本発明は、上述従来の
技術の問題点を解決し、高い洗浄力を有し、かつ安全性
が高く不快感が残らない身体用洗浄剤組成物、ウエット
ワイパー類および清浄綿を提供することを目的とする。
DISCLOSURE OF THE INVENTION The present invention solves the above-mentioned problems of the prior art, has a high detergency, is highly safe and does not leave uncomfortable feeling, a personal cleansing composition and a wet wiper. And to provide clean cotton.

【0006】[0006]

【課題を解決するための手段】本発明者等は、上記目的
を達成するために鋭意研究の結果、身体用洗浄剤組成物
に天然界面活性物質である大豆サポニン等の植物性サポ
ニンを含有させることにより、上記課題が解決されるこ
とを見い出し、本発明に到達した。
Means for Solving the Problems The inventors of the present invention have conducted earnest research to achieve the above object, and as a result, have added a vegetable saponin such as soybean saponin, which is a natural surfactant, to a personal cleansing composition. As a result, they have found that the above problems can be solved, and have reached the present invention.

【0007】すなわち、本発明は、1種類以上のサポニ
ンを含有することを特徴とする身体用洗浄剤組成物;1
種類以上のサポニンを含有する溶液を含浸させたことを
特徴とするウエットワイパー類;および1種類以上のサ
ポニンを含有する溶液を含浸させたことを特徴とする清
浄綿を提供するものである。
That is, the present invention provides a personal cleansing composition characterized by containing one or more kinds of saponins; 1
Wet wipes characterized by being impregnated with a solution containing at least one type of saponin; and clean cotton characterized by being impregnated with a solution containing at least one type of saponin.

【0008】[0008]

【作用】サポニンとは、多環式化合物をアグリコンとす
る配糖体の総称であり、アスパラガス、大豆、小豆、薬
用人参、へちま等に含まれる植物性のものと、ひとでや
なまこ等に含まれる動物性のものとが知られている。ま
た、サポニンは一般に経口的にも毒性が弱く、界面活性
作用、溶血作用、魚毒性作用、殺虫作用、起泡作用およ
び殺菌作用等があることが知られている。さらに、サポ
ニンは容易に水に溶け、その溶液にはぬるつき感やべた
つき感がない。
[Action] Saponin is a general term for glycosides that use polycyclic compounds as aglycones, and includes plant-derived substances such as asparagus, soybeans, adzuki beans, ginseng, and hechima, and humans and yamamako. It is known that it is of animal origin. Further, saponin is generally less toxic even orally, and it is known that it has a surface active action, a hemolytic action, a fish toxic action, an insecticidal action, a foaming action and a bactericidal action. In addition, saponin is easily soluble in water and the solution has no slimy or sticky feeling.

【0009】すなわち、本発明者等は、上記のような性
質を有するサポニンを洗浄剤組成物に配合することによ
り、洗浄作用、殺菌作用および発泡性に優れ、安全性が
高く不快感の無い洗浄剤が得られることを見い出したの
である。
That is, the present inventors have added a saponin having the above-mentioned properties to a detergent composition to provide excellent cleaning action, bactericidal action and foaming property, high safety and no discomfort. They found that a drug could be obtained.

【0010】上記のようにサポニンを含有する洗浄剤
は、ぬるつき感やべたつき感などの不快感がなく、人体
に対する毒性が極めて低いため、使用後に水で洗い流さ
ないウエットワイパー類や清浄綿などに含ませることが
できる。また、このようにウエットワイパー類や清浄綿
にサポニンを含ませることにより、高い洗浄効果を得る
ことができる。さらに、サポニンは、紙類、不織布、綿
および布などを劣化させることがないため、多種多様の
衛生用品に含有させることが可能である。
As described above, the saponin-containing detergent has no discomfort such as sliminess or stickiness, and has extremely low toxicity to the human body. Therefore, it is suitable for use in wet wipes and clean cotton that are not washed off with water after use. Can be included. In addition, by including the saponin in the wet wipers and the clean cotton as described above, a high cleaning effect can be obtained. Furthermore, since saponin does not deteriorate papers, non-woven fabrics, cotton, cloth and the like, it can be contained in a wide variety of hygiene products.

【0011】以下、実施例により本発明をさらに詳細に
説明する。しかし本発明の範囲は以下の実施例により制
限されるものではない。
Hereinafter, the present invention will be described in more detail with reference to examples. However, the scope of the present invention is not limited by the following examples.

【0012】[0012]

【実施例1】本実施例では、大豆サポニンおよびアスパ
ラガスサポニンの洗浄力の測定(洗浄試験)を行った。
なお、洗浄力の測定は、JIS k-3362「合成洗剤試験方
法、台所用合成洗剤の洗浄力評価方法」を一部変更して
行った。
Example 1 In this example, the detergency of soybean saponins and asparagus saponins (washing test) was measured.
The cleaning power was measured by partially changing JIS k-3362 “Test method for synthetic detergent, Evaluation method for cleaning power of synthetic detergent for kitchen”.

【0013】まず、1サンプルにつき3枚のガラスプレ
ート4を用意し、各ガラスプレート4の重量を測定し
た。一方、トリオレイン20g、スクアレン10g、コレス
テロール10gおよびパルミチン酸10gをコニカルビーカ
ーに取り、そこにクロロフォルムを50ml入れ、45℃に加
温して溶解させ、得られた溶液をモデル汚れ溶液とし
た。なお、このモデル汚れ溶液は人間の皮膚の油分を模
擬して作製したものである。したがって、モデル汚れ溶
液の組成は上記組成に特に限定されるものではなく、他
の成分を加えたり、上記の成分を削ったりしても問題は
ない。
First, three glass plates 4 were prepared for each sample, and the weight of each glass plate 4 was measured. On the other hand, 20 g of triolein, 10 g of squalene, 10 g of cholesterol and 10 g of palmitic acid were placed in a conical beaker, 50 ml of chloroform was put therein and heated at 45 ° C. to be dissolved, and the obtained solution was used as a model soil solution. The model stain solution was prepared by simulating the oil content of human skin. Therefore, the composition of the model soil solution is not particularly limited to the above composition, and there is no problem even if other components are added or the above components are removed.

【0014】次に、上記重量を測定したガラスプレート
4を上記コニカルビーカーに入れて約1分間放置し、ガ
ラスプレート4に汚れを付着させた。汚れの付着後、ガ
ラスプレート4を静かに引き上げて約1時間風乾し、ガ
ラスプレート4の重量を測定して付着した汚れの重量を
算出した。
Next, the glass plate 4 whose weight was measured was placed in the conical beaker and allowed to stand for about 1 minute to stain the glass plate 4. After the dirt was attached, the glass plate 4 was gently pulled up and air-dried for about 1 hour, and the weight of the glass plate 4 was measured to calculate the weight of the adhered dirt.

【0015】一方、炭酸ナトリウムでpHを9に合わせた
0.01、0.05、 0.1および 0.5% (w/v)の大豆サポニン水
溶液、 0.005、0.01、0.1 および 0.5%(w/v) のアスパ
ラガスサポニン水溶液、および比較洗浄水溶液(サポニ
ンを含有しない従来の洗浄剤、および従来より広く用い
られている天然界面活性剤を含有する水溶液)をそれぞ
れ 900ml作製し、サンプル溶液7とした。なお、上記大
豆サポニンおよびアスパラガスサポニンは、各サポニン
を含有する原料を粉砕し、n−ヘキサン等の無極性溶媒
で脱脂した後、含水低級アルコールで抽出、濾過および
濃縮をおこなった後、n−ブタノールと水とで分配して
脱糖し、n−ブタノールを濃縮および乾固し、乾燥する
といった方法で抽出・精製を行った(本出願人による特
開平2-129198号「アスパラガス廃棄物からのサポニン回
収方法」、特開平2-247196号「アスパラガスから精製サ
ポニンを回収する方法」、または特願平2-412328号「大
豆胚軸よりのサポニンの製造法」に開示)。また、サポ
ニン含有水溶液(サンプル溶液7)の濃度を 0.005〜1.
0 % (w/v)としたが、これらの数値は本発明の範囲を制
限するものではない。
On the other hand, the pH was adjusted to 9 with sodium carbonate.
0.01, 0.05, 0.1 and 0.5% (w / v) Soy Saponin Aqueous Solution, 0.005, 0.01, 0.1 and 0.5% (w / v) Asparagus Saponin Aqueous Solution, and Comparative Cleaning Solution (traditional detergent without saponin) , And an aqueous solution containing a natural surfactant, which has been widely used from the past, were prepared as 900 ml, and used as a sample solution 7. The soybean saponins and asparagus saponins are pulverized raw materials containing each saponin, degreased with a non-polar solvent such as n-hexane, extracted with a hydrous lower alcohol, filtered and concentrated, and then n- Extraction and purification were carried out by a method such as partitioning with butanol and water to desugar, concentrating and drying n-butanol, and then drying (from Japanese Patent Application Laid-Open No. 2-129198 “Asparagus waste). Disclosed in JP-A-2-247196, "Method for recovering purified saponin from asparagus", or Japanese Patent Application No. 2-412328, "Method for producing saponin from soybean hypocotyl". In addition, the concentration of the saponin-containing aqueous solution (sample solution 7) should be 0.005-1.
Although set to 0% (w / v), these numerical values do not limit the scope of the present invention.

【0016】上記作製したサンプル溶液7とマグネチッ
クスターラー5とをビーカー6に入れ、このビーカー6
をマグミキサー2の上に載置したインキュベーター3に
入れ、円柱状保持具1に固定した上記汚れを付着させた
3枚のガラスプレート4をサンプル溶液7に浸漬し、該
溶液7を40℃、350rpmで30分間攪拌した(図1)。
The sample solution 7 prepared above and the magnetic stirrer 5 were placed in a beaker 6, and the beaker 6
Is placed in an incubator 3 placed on a mag mixer 2, and three glass plates 4 fixed to the cylindrical holder 1 to which the above-mentioned stains are attached are immersed in a sample solution 7, and the solution 7 is placed at 40 ° C. The mixture was stirred at 350 rpm for 30 minutes (Fig. 1).

【0017】攪拌後、約 500mlのイオン交換水で3枚の
ガラスプレート4(1サンプル)をすすぎ、デシケータ
ー中で一晩放置して乾燥させた。乾燥後、ガラスプレー
ト4の重量を測定して残留した汚れの重量を算出し、洗
浄力の評価を行い(化1に示す式を用いて汚れの除去率
を算出)、その結果を表1に示した。
After stirring, three glass plates 4 (1 sample) were rinsed with about 500 ml of ion-exchanged water and left overnight in a desiccator to dry. After drying, the weight of the glass plate 4 was measured to calculate the weight of the remaining stains, and the detergency was evaluated (the stain removal rate was calculated using the formula shown in Chemical formula 1). The results are shown in Table 1. Indicated.

【化1】 [Chemical 1]

【0018】[0018]

【表1】 [Table 1]

【0019】表1からも分かるように、大豆サポニンお
よびアスパラガスサポニン水溶液は、従来の洗浄剤およ
び天然界面活性剤と同等以上の洗浄力を示した。
As can be seen from Table 1, the aqueous solutions of soybean saponin and asparagus saponin showed detergency equal to or higher than that of conventional detergents and natural surfactants.

【0020】[0020]

【実施例2】炭酸ナトリウムでpHを7に合わせた 0.1%
(w/v) のアスパラガスサポニン水溶液、大豆サポニン水
溶液、およびアスパラガスサポニンと大豆サポニンとの
混合水溶液(アスパラガスサポニン0.01%、大豆サポニ
ン 0.9%)をそれぞれ 900ml作製し、サンプル溶液とし
たこと以外は実施例1と同様にして洗浄試験およびその
評価を行い、結果を表2に示した。
Example 2 0.1% adjusted to pH 7 with sodium carbonate
(w / v) asparagus saponin aqueous solution, soybean saponin aqueous solution, and mixed solution of asparagus saponin and soybean saponin (0.01% of asparagus saponin, 0.9% of soybean saponin) were prepared in 900 ml, respectively Was subjected to a cleaning test and its evaluation in the same manner as in Example 1, and the results are shown in Table 2.

【0021】[0021]

【表2】 [Table 2]

【0022】表2からもわかるように、アスパラガスサ
ポニンと大豆サポニンとを混合した溶液は、それぞれ単
独の溶液よりも高い洗浄力を示した。すなわち、2種類
以上のサポニンを適量混合することによって、単独で用
いるよりも高い洗浄力が得られる場合が有るのである。
As can be seen from Table 2, the solutions in which asparagus saponin and soybean saponin were mixed showed higher detergency than the solutions alone. That is, when two or more kinds of saponins are mixed in an appropriate amount, a higher detergency than that used alone may be obtained.

【0023】[0023]

【実施例3】本発明の清浄綿の一例を以下に示す。Example 3 An example of the clean cotton of the present invention is shown below.

【0024】まず、アスパラガスサポニン0.1 %(w/
v)、グルコン酸クロルヘキシジン0.02%(w/v)、および
精製水10mlを混合した。次いで、該混合溶液を約 1.6g
の脱脂綿にしみこませ、これを密封した後、高圧蒸気滅
菌処理を施し、清浄綿を作製した。
First, asparagus saponin 0.1% (w /
v), chlorhexidine gluconate 0.02% (w / v), and purified water 10 ml were mixed. Then, about 1.6 g of the mixed solution
The absorbent cotton was soaked in the absorbent cotton, sealed, and then subjected to high-pressure steam sterilization treatment to produce clean cotton.

【0025】上記のようにして作製した清浄綿は、高い
洗浄効果を示し、なおかつ使用後にべたつき感やぬるつ
き感などがなかった。なお、上記成分以外に安息香酸な
どの防腐剤、保湿剤、洗浄補助剤、防臭剤、香料、エタ
ノールなどの低級アルコール、バッファー剤、キレート
剤、消炎剤、表記サポニン以外の界面活性剤などを配合
することもできる。
The clean cotton produced as described above showed a high cleaning effect and had no sticky feeling or slimy feeling after use. In addition to the above components, preservatives such as benzoic acid, moisturizers, cleaning aids, deodorants, fragrances, lower alcohols such as ethanol, buffer agents, chelating agents, anti-inflammatory agents, surfactants other than the indicated saponin, etc. are compounded. You can also do it.

【0026】[0026]

【実施例4】実施例3で作製した清浄綿(清浄綿1とす
る)と、アスパラガスサポニンの代わりに大豆サポニン
0.1%(w/v) を配合したこと以外は実施例3と同様にし
て作製した清浄綿(清浄綿2とする)とを用い、最低3
時間は洗顔を行っていない15名の披験者に対して洗浄力
試験を行った。洗浄力試験は、試験部位とした頬部を上
記清浄綿で3回拭いた後、皮脂の除去能力を判定し、結
果を表3に示した。なお、上記の清浄綿からサポニンだ
けを除いた清浄綿をも作製し、その清浄綿を対照とし
た。
[Example 4] The clean cotton (clean cotton 1) prepared in Example 3 and soybean saponin instead of asparagus saponin
Clean cotton produced in the same manner as in Example 3 except that 0.1% (w / v) was blended (clean cotton 2), and a minimum of 3
For 15 hours, a detergency test was conducted on 15 testers who did not wash their faces. In the detergency test, the cheeks as test sites were wiped three times with the above-mentioned clean cotton, and then the ability to remove sebum was determined, and the results are shown in Table 3. In addition, a clean cotton obtained by removing only saponin from the above clean cotton was also prepared, and the clean cotton was used as a control.

【0027】[0027]

【表3】 [Table 3]

【0028】表3からも分かるように、本発明の清浄綿
は皮脂を除去する能力に優れていた。
As can be seen from Table 3, the clean cotton of the present invention was excellent in the ability to remove sebum.

【0029】[0029]

【実施例5】本発明のウエットワイパー類(ウエットテ
ィッシュ)の一例を以下に示す。
[Embodiment 5] An example of the wet wipes (wet tissue) of the present invention is shown below.

【0030】大豆サポニン 0.1%(w/v) 、パラベン 0.2
%(w/v) 、および精製水を混合し、4Cクロス(商品
名)の乾式不織布にしみこませ、洗浄剤含有のウエット
ティッシュを作製した。このようにして作製したウエッ
トティッシュは、高い洗浄効果を示し、なおかつ使用後
にべたつき感やぬるつき感がなかった。
Soybean saponin 0.1% (w / v), paraben 0.2
% (W / v) and purified water were mixed and soaked in a 4C cloth (trade name) dry non-woven fabric to prepare a wet tissue containing a detergent. The wet tissue thus produced exhibited a high cleaning effect and had no sticky feeling or slimy feeling after use.

【0031】[0031]

【発明の効果】本発明の身体用洗浄剤は、従来の洗浄剤
特有のぬるつき感やべたつき感および刺激性がなくなっ
た。また、本発明の身体用洗浄剤は低濃度で高い洗浄力
を示し、しかも安全性が高いため、水で洗い流さないウ
エットワイパー類や清浄綿などに含浸させることができ
るようになった。そのため、ウエットワイパー類や清浄
綿の洗浄効果が著しく向上した。
EFFECTS OF THE INVENTION The body cleaning agent of the present invention eliminates the slimy feeling, sticky feeling and irritation characteristic of conventional cleaning agents. Further, since the personal cleansing agent of the present invention shows a high detergency at a low concentration and has high safety, it has become possible to impregnate wet wipes and clean cotton which are not washed with water. Therefore, the cleaning effect of wet wipes and clean cotton was remarkably improved.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の実施例で用いた洗浄力測定装置を示す
模式図である。
FIG. 1 is a schematic view showing a detergency measuring device used in an example of the present invention.

【符号の説明】[Explanation of symbols]

1‥‥‥円柱状保持具 2‥‥‥マグミキサー 3‥‥‥インキュベーター 4‥‥‥ガラスプレート 5‥‥‥マグネチックスターラー 6‥‥‥ビーカー 7‥‥‥サンプル水溶液 1 ······························ Mug mixer 3 ······· Incubator 4 ····· Glass plate 5 ····· Magnetic stirrer 6 ···· Beaker 7 ···· Sample water solution

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 1種類以上のサポニンを含有することを
特徴とする身体用洗浄剤組成物。
1. A personal cleansing composition comprising one or more saponins.
【請求項2】 1種類以上のサポニンを含有する溶液を
含浸させたことを特徴とするウエットワイパー類。
2. A wet wiper characterized by being impregnated with a solution containing at least one saponin.
【請求項3】 1種類以上のサポニンを含有する溶液を
含浸させたことを特徴とする清浄綿。
3. Clean cotton characterized by being impregnated with a solution containing one or more saponins.
JP32641491A 1991-11-14 1991-11-14 Body wash composition Expired - Fee Related JP3226225B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP32641491A JP3226225B2 (en) 1991-11-14 1991-11-14 Body wash composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP32641491A JP3226225B2 (en) 1991-11-14 1991-11-14 Body wash composition

Publications (2)

Publication Number Publication Date
JPH05139953A true JPH05139953A (en) 1993-06-08
JP3226225B2 JP3226225B2 (en) 2001-11-05

Family

ID=18187526

Family Applications (1)

Application Number Title Priority Date Filing Date
JP32641491A Expired - Fee Related JP3226225B2 (en) 1991-11-14 1991-11-14 Body wash composition

Country Status (1)

Country Link
JP (1) JP3226225B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5760280B1 (en) * 2014-05-12 2015-08-05 株式会社東洋新薬 Effervescent skin external preparation

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5760280B1 (en) * 2014-05-12 2015-08-05 株式会社東洋新薬 Effervescent skin external preparation

Also Published As

Publication number Publication date
JP3226225B2 (en) 2001-11-05

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