JP2007325693A - Deodorant, and deodorizing product containing this deodorant - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a useful deodorant which is effective to bad odors over a wide range, is safe to the human body, has good solubility and is easy to handle, and has less problems for discoloring or the like. <P>SOLUTION: This deodorant consists of the extract of a mixture of Angelica acutiloba Kitagawa, Cnidium officinale Makino, Peony and Rehmannia root. This deodorizing product contains the deodorant. The brewed substance of the above-mentioned galenical by a specified ratio is the same composition as so-called "Shimotsutou" in the Chinese medicine. The extract of the mixture of the galenical is safe to the human body, is easy to handle while having good solubility, and is a useful deodorant having less problems for discoloring or the like. From the extract of the mixture of the galenical, an excellent deodorant composition, a cosmetic composition for deodorization, a bathing agent composition, and a detergent composition or the like can be obtained. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to a deodorant. More specifically, the present invention relates to a safe deodorant that is effective for ammonia, amines, hydrogen sulfide, and mercaptans and does not cause skin irritation.

  Deodorant products remove unpleasant odors and keep people's living space comfortable, and can be said to be a daily necessity for Japanese who prefer cleanliness. In recent years, many deodorizing products have been developed that can be instantly and locally deodorized by spraying them in the form of a spray. Along with this, many materials have been developed for deodorizers, but so many general-purpose deodorants have not been proposed. The types of deodorants are as follows: (1) Preventing the generation of malodors caused by microorganisms due to antibacterial action. (2) The odor substance is physically adsorbed and deodorized. (3) Neutralize alkaline malodor with acid. (4) Chemically decompose malodorous substances with oxidizing agents. (5) Deodorize sensuously with aroma substances. However, the method (1) is a preventive measure and cannot eliminate the actually bad odor. The methods (3) to (5) are effective for specific malodorous substances but have not been widely used. (For example, in the method (3), an alkaline malodorous substance and an acidic malodorous substance are mixed at the same time. It is difficult to reconcile). The adsorption method (2) is effective for many malodorous substances, but most of the adsorbents represented by activated carbon are colored and often powdery, which has problems in handling. . In particular, in the spray product, since there are many opportunities for the deodorant to come into contact with the human body, a deodorant that is safe for humans and friendly to the environment has been demanded. As a general-purpose deodorant, for example, a deodorant in which a vinyl monomer having a carboxylic acid group is 90% by weight or more of polymer fine particles and a part of the carboxylic acid group is at least one salt of copper, nickel and cobalt. Agent (Patent Document 1), deodorant (Patent Document 2) containing zinc 2-ethylhexanoate as an active ingredient, and a compound having a specific amino acid skeleton having an acid dissociation index of 6 to 9 Deodorants (Patent Document 3) and the like have been proposed to be effective for both amine-based and mercaptan-based malodors, but both have the potential for the above problems. As a natural and versatile deodorant, a deodorant (Patent Document 4) characterized by blending Amiris oil as an active ingredient is effective for both amine-based and mercaptan-based malodors. Although it has been proposed, since the amylis oil itself has a fragrance, it is presumed that its deodorizing effect has a limit.

  On the other hand, it is known that various plant extracts also have a deodorizing action (for example, Non-Patent Document 1). However, there has been no known example in which a specific combination of plant extracts has been studied together with safety to humans and a deodorizing effect. As a mixed plant extract without skin irritation, for example, a mixed plant extract having the same composition as Kampo (Patent Document 5) is known, but no deodorizing effect is described.

JP-A-6-261931 JP-A-9-276381 JP 2004-33436 A Japanese Patent Laid-Open No. 11-178907 JP 2005-89402 A Gazette of the Japan Patent Office. Collection of well-known and commonly used techniques (fragrance) Part I. Fragrance in general 230 pages

  The problem to be solved is that there is no deodorant that has both human safety and a wide range of deodorizing effects.

  The present invention solves such a problem, and is effective against a wide range of bad odors such as amine odor and mercaptan odor, is safe for the human body, has good solubility and is easy to handle, and has few problems such as coloring. It provides a useful deodorant.

  In order to solve the above problems, the present inventors searched various plant extracts and mixtures thereof, and as a result, extracts of herbal medicines having the same composition as the Kampo prescription called Shimototo have a synergistically excellent deodorizing effect. It was found that the present invention was completed. That is, the present invention is a deodorant comprising an extract of a mixture of Toki, Senkyu, Peonies, and Ziou, and more specifically, Toki 0.4-10.0 parts (parts by weight, hereinafter the same), Senkyu 0.4- It is a deodorant consisting of an extract of a mixture of 10.0 parts, peony 0.4-10.0 parts and diau 0.4-10.0 parts, and more specifically, 1.6-8.0 parts of Toki. , A deodorant composed of an extract of a mixture of 1.6 to 8.0 parts of Senkyu, 1.6 to 8.0 parts of peony, and 1.6 to 8.0 parts of Diou. A deodorant comprising an extract of a mixture of 8 to 6.0 parts, Senku 2.8 to 6.0 parts, Peonies 2.8 to 6.0 parts and Diou 2.8 to 6.0 parts; Specifically, the deodorant is an extract of water or alcohols or a mixture thereof. There also is a deodorant product characterized by containing the deodorant.

  The deodorant of the present invention is effective against a wide range of bad odors such as amine odor and mercaptan odor, provides a useful deodorant that is safe for the human body, has good solubility and is easy to handle, and has few problems such as coloring. can do.

The plants used in the present invention are shown below, and any of them can use leaves, stems, roots, flowers, seeds or whole plants. Moreover, you may utilize the crude drug based on the following plant.
(1) Touki Angelica acutiloba Kitagawa (Apiaceae)
（２） Cendium officinale Makino (Apiaceae)
(3) Peonies Paeonia lactiflora Pallas (button department)
(4) Giant Rehmannia glutinosa Liboschitz var. Purpurea Makino or Rehmannia glutinosa Liboschitz
The type of each herbal medicine is not limited to this, and variants, congeners, and other related species can also be used.

  Shimotsuke is a combination of four species of Toki, Senkyu, Peonies, and Giant, and has the following symptoms in people with dry skin, poor body color and no gastrointestinal disorders: postpartum or postpartum fatigue recovery, irregular menstruation, coldness It is said that it is effective for frostbite, blotches, and bloody thrombosis. [Natural product pharmacology (Shuji Itokawa, Taichi Omoto, Masahiro Nagai, Riki Furuya, published by Asakura Shoten, April 10, 1987)].

  Shimotsuke is used for those with relatively weak physical strength, tending to be anemic, with dry skin, poor color, soft belly and palpation on the navel. It is said to be a holy medicine for various diseases of women and obstetrics and gynecology. It is said to be effective for anemia, uterine bleeding, irregular menstruation, menstrual pain, coldness, autonomic dysfunction, climacteric disorder, and postpartum. [Natural drug encyclopedia (Takuo Okuda, published by Yodogawa Shoten, March 3, 1986)].

  The active ingredient is extracted from the mixture of these plants using a suitable solvent. Examples of the solvent include water, alcohols (for example, lower alcohols such as methanol, absolute ethanol, and ethanol, or polyhydric alcohols such as 1,3-butylene glycol, propylene glycol, and dipropylene glycol). Any mixture can be used. Moreover, after extraction, the extract can be diluted or concentrated and dried as necessary.

  The extraction method is not particularly limited, and may be in the range up to the boiling point of the solvent at normal temperature or normal pressure, and a microwave extraction method or a supercritical extraction method may be used. After extraction, filtration or an ion exchange resin may be used for adsorption purification to form a solution, paste, gel, or powder. In many cases, it can be used as it is, but if necessary, further purification treatment such as deodorization and decolorization may be added as long as the effect is not affected. An activated carbon column or the like may be used, and usual means generally applied depending on the extracted substance may be arbitrarily selected.

  The herbal medicine used in the present invention provides a highly effective extract from what is extracted after blending four kinds. Therefore, it is more effective than those extracted individually from each other, arbitrarily extracted by combining up to three kinds of plants, and mixed with each extract or extract. Since the persistence of the deodorizing effect is further improved by extracting after blending four kinds of plants, it is considered that it is sufficiently meaningful to use a product extracted after blending four kinds of plants.

  The compounding amount of each herbal medicine used in the present invention is as follows. The amount described in the 4th edition, 12th edition, April 30, 1992 is preferred. The blending ratio can be adjusted according to the purpose. For example, in the general Chinese medicine prescription, as the prescription of Shimotou, the weight ratio of Toki: Senkyu: Peonies: Diou is 4: 4: 4: Examples such as 4 are described. Accordingly, in the present invention, as a normal blending amount, 0.4 to 10.0 parts of Toki (parts by weight, the same shall apply hereinafter), 0.4 to 10.0 parts of Senkyu, 0.4 to 10.0 parts of Peonies, and 0 .4 to 10.0 parts, more preferably 1.6 to 8.0 parts of Toki, 1.6 to 8.0 parts of Senkyu, 1.6 to 8.0 parts of Peonies and 1.6 to 1.6 parts of Geo The most preferred amount is from 2.8 to 6.0 parts of Toki, 2.8 to 6.0 parts of Senkyu, 2.8 to 6.0 parts of Peonies and 2.8 to 6. 0 parts.

  In addition to the essential deodorant of the present invention, the deodorant product according to the present invention is manufactured using, for example, a base or additive commonly used in cosmetics as shown below. Can do.

  (1) Various fats and oils: avocado oil, almond oil, fennel oil, sesame oil, olive oil, orange oil, orange luffy oil, sesame oil, cocoa butter, chamomile oil, carrot oil, cucumber oil, beef fat fatty acid, cucumber nut oil, safflower Oil, shea fat, liquid shea fat, soybean oil, camellia oil, corn oil, rapeseed oil, persic oil, castor oil, cottonseed oil, peanut oil, turtle oil, mink oil, egg yolk oil, palm oil, palm kernel oil, palm oil , Beef tallow, pork tallow or hydrogenated products (hardened oil etc.) of these fats and oils.

  (2) Waxes: beeswax, owl, carnauba wax, whale wax, lanolin, liquid lanolin, reduced lanolin, hard lanolin, candelilla wax, montan wax, shellac wax, rice wax, squalene, squalane, pristane, etc.

  (3) Mineral oil: liquid paraffin, petrolatum, paraffin, ozokelide, ceresin, microcrystalline wax and the like.

  (4) Fatty acids: natural fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, 12-hydroxystearic acid, undecylenic acid, tall oil fatty acid, lanolin fatty acid, isononanoic acid, caproic acid, Synthetic fatty acids such as 2-ethylbutanoic acid, isopentanoic acid, 2-methylpentanoic acid, 2-ethylhexanoic acid and isopentanoic acid.

  (5) Alcohols: natural alcohols such as ethanol, isopropanol, lauryl alcohol, cetanol, stearyl alcohol, oleyl alcohol, lanolin alcohol, cholesterol and phytosterol, and synthetic alcohols such as 2-hexyldecanol, isostearyl alcohol and 2-octyldodecanol.

  (6) Polyhydric alcohols: ethylene glycol, diethylene glycol, triethylene glycol, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, 1,3-butylene glycol, 1,2-pentanediol, glycerin, diglycerin, pentaerythritol, sorbitol, mannitol and the like.

  (7) Esters: isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, oleyl oleate, decyl oleate, octyldodecyl myristate, hexyl decyl dimethyloctanoate, cetyl lactate, myristyl lactate , Diethyl phthalate, dibutyl phthalate, lanolin acetate, ethylene glycol monostearate, propylene glycol monostearate, propylene glycol dioleate, and the like.

  (8) Metal soaps: aluminum stearate, magnesium stearate, zinc stearate, calcium stearate, zinc palmitate, magnesium myristate, zinc laurate, zinc undecylenate and the like.

  (9) Gum, sugars or water-soluble polymer compounds: gum arabic, benzoin rubber, dammar gum, guaiac oil, Irish moss, karaya gum, tragacanth gum, carob gum, quinseed, agar, casein, lactose, fructose, sucrose or esters thereof , Trehalose or derivatives thereof, dextrin, gelatin, pectin, starch, carrageenan, carboxymethyl chitin or chitosan, hydroxyalkyl (C2-C4) chitin or chitosan to which alkylene (C2-C4) oxide such as ethylene oxide is added, low molecule Chitin or chitosan, chitosan salt, sulfated chitin or chitosan, phosphorylated chitin or chitosan, alginic acid or salt thereof, hyaluronic acid or salt thereof, chondroitin sulfate or salt thereof, heparin, ethylcellulose, methylcellulose , Carboxymethyl cellulose, carboxyethyl cellulose, sodium carboxyethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, nitrocellulose, crystalline cellulose, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, polyvinyl methacrylate, polyacrylate, polyethylene oxide, polypropylene oxide, etc. Polyalkylene oxide or a crosslinked polymer thereof, carboxyvinyl polymer, polyethyleneimine and the like.

  (10) Surfactant: Anionic surfactant (alkyl carboxylate, alkyl sulfonate, alkyl sulfate ester salt, alkyl phosphate ester salt), cationic surfactant (alkyl amine salt, alkyl quaternary ammonium salt), Amphoteric surfactant [carboxylic acid type amphoteric surfactant (amino type, betaine type), sulfate ester type amphoteric surfactant, sulfonic acid type amphoteric surfactant, phosphate ester type amphoteric surfactant], nonionic surfactant Agents (ether type nonionic surfactants, ether ester type nonionic surfactants, ester type nonionic surfactants, block polymer type nonionic surfactants, nitrogen-containing type nonionic surfactants), other surfactants Agents (natural surfactants, derivatives of protein hydrolysates, polymer surfactants, surfactants containing titanium and silicon, Carbon-based surface active agent), such as.

  (11) Various vitamins Vitamin A group: retinol, retinal (vitamin A1), dehydroretinal (vitamin A2), carotene, lycopene (provitamin A), vitamin B group: thiamine hydrochloride, thiamine sulfate (vitamin B1), Riboflavin (vitamin B2), pyridoxine (vitamin B6), cyanocobalamin (vitamin B12), folic acid, nicotinic acids, pantothenic acids, biotins, choline, inositols, vitamin C group: vitamin C acid or derivatives thereof, vitamin D group: Ergocalciferol (vitamin D2), cholecalciferol (vitamin D3), dihydrotaxosterol, vitamin E group: vitamin E or derivatives thereof, ubiquinones, vitamin K group: phytonadione (vitamin K1), menaquinone (vitamin K2), Menadione (vitamin K3), menadiol (vitamin K4), other essential fatty acids (vitamin F), carnitine, ferulic acid, γ-oryzanol, orotic acid, vitamin Ps (rutin, eliocitrin, hesperidin), vitamin U and the like.

  (12) Various amino acids: valine, leucine, isoleucine, threonine, methionine, phenylalanine, tryptophan, lysine, glycine, alanine, asparagine, glutamine, serine, cysteine, cystine, tyrosine, proline, hydroxyproline, aspartic acid, glutamic acid, hydroxy Amino acid derivatives such as lysine, arginine, ornithine, histidine, and their sulfates, phosphates, nitrates, citrates, or pyrrolidone carboxylic acids.

  (13) Various additives derived from plant or animal materials: These are processed in a conventional manner according to the type and form of the product to be added (for example, pulverization, milling, washing, hydrolysis, fermentation, Purify, squeeze, extract, fractionate, filter, dry, pulverize, granulate, dissolve, sterilize, adjust pH, deodorize, decolorize, etc.) And serve.

  The solvent used for the extraction of the plant or animal material may be selected in consideration of the purpose and type of the product to be provided, or the processing performed later. It is desirable to use one or a mixture of two or more selected from organic organic solvents (for example, ethanol, propylene glycol, 1,3-butylene glycol, etc.). However, when it is not preferable to contain an organic solvent depending on the application, it is sufficient to use only water or ethanol that can be easily removed after extraction, and it may be used alone or in any mixture with water. The thing extracted and extracted may be sufficient.

  In addition, when the additive derived from the plant or animal material is used for systemic or topical external preparations, cosmetics, including the protection of skin and hair, moisturizing, improvement of touch / feel, imparting flexibility, Relaxation of stimulation, stress reduction by fragrance, cell activation (prevention of cell aging), suppression of inflammation, improvement of skin / hair quality, prevention of rough skin and its improvement, hair growth, hair growth, prevention of hair loss, imparting luster, cleaning effect In addition to cosmetic effects such as fatigue relief, blood flow promotion, and warm bath effects, effects such as flavoring, deodorizing, thickening, preserving, and buffering can also be expected.

  (14) Fragrance: Natural animal fragrance such as musk, civet, castorium, ambergris, anise essential oil, angelica essential oil, ylang ylang essential oil, iris essential oil, fennel essential oil, orange essential oil, cananga essential oil, caraway essential oil, cardamom essential oil, guayakwood essential oil , Cumin essential oil, black letter essential oil, cinnamon essential oil, cinnamon essential oil, geranium essential oil, copaiba balsam essential oil, coriander essential oil, perilla essential oil, cedarwood essential oil, citronella essential oil, jasmine essential oil, gingergrass essential oil, cedar essential oil, spearmint essential oil, western peppermint essential oil, Otsuka perfume essential oil, tuberose essential oil, clove essential oil, orange flower essential oil, winter green essential oil, trout balsam essential oil, patchouli essential oil, rose essential oil, palmarosa essential oil, persimmon essential oil, hiba essential oil, sandalwood essential oil, petit gren essential oil, bay essential oil, vetiver essential oil, berga Plant essential oils such as coconut essential oil, peru balsam essential oil, boad rose essential oil, melamine essential oil, mandarin essential oil, eucalyptus essential oil, lime essential oil, lavender essential oil, linaloe essential oil, lemongrass essential oil, lemon essential oil, rosemary essential oil, Japanese mint mint essential oil Such. Synthetic perfume ingredients include aliphatic hydrocarbons, terpene hydrocarbons, aromatic hydrocarbons and other hydrocarbons, aliphatic alcohols, terpene alcohols, aromatic alcohols and other alcohols, aliphatic ethers, aromatic ethers and other ethers Oxides, aliphatic oxides, terpene oxides, aliphatic aldehydes, terpene aldehydes, hydrogenated aromatic aldehydes, aldehydes such as thioaldehydes, aromatic aldehydes, aliphatic ketones, terpene ketones, hydrogenated aromatics Ketones such as aromatic ketones, aliphatic cyclic ketones, non-benzene aromatic ketones, aromatic ketones, acetals, ketals, phenols, phenol ethers, fatty acids, terpene carboxylic acids, hydrogenated aromatic carboxylic acids, Acids such as aromatic carboxylic acids, acid amides, aliphatic lactones Lactates such as macrocyclic lactones, terpene lactones, hydrogenated aromatic lactones, aromatic lactones, esters such as aliphatic esters, furan carboxylic acid esters, aliphatic cyclic carboxylic acid esters, aromatic carboxylic acid esters , Nitrogen-containing compounds such as nitromusks, nitriles, amines, pyridines, quinolines, pyrrole and indole. More specific examples of synthetic fragrances include, for example, 1996 published by Chemical Industry Daily, Motoichi Into (Synthetic fragrance chemistry and product knowledge), 1969, by Stefan Arcamder (Perfume and Flavor Chemicals <Perfume and) Flavors described in Flavor Chemicals>) and the like can be suitably used. The main fragrances are shown below. Aldehyde C6-C12, anisaldehyde, acetal R, acetophenone, acetyl cedrene, adoxal, allyl amyl glycolate, allyl cyclohexane propionate, alpha damascon, beta damascon, delta damascon, ambrette lid, ambroxan, amyl Cinnamic aldehyde, amyl cinnamic aldehyde dimethyl acetal, amyl valericate, amyl salicylate, isoamyl acetate, isoamyl salicylate, auranthiol, acetyl eugenol, bacdanol, benzyl acetate, benzyl alcohol, benzyl salicylate, bergamyl acetate, bornyl acetate , Butyl butyrate, para tertiary butyl cyclohexanol, para tertiary butyl Rohexyl acetate, ortho-tertiary butyl cyclohexanol, benzaldehyde, benzyl formate, potassium olefin, cashomeran, carvone, cedro amber, cedryl acetate, cedrol, cerythlid, cinnamic alcohol, cinnamaldehyde, cis jasmon, citral, citral Dimethyl acetal, citrusal, citronellol, citronellyl acetate, citronellyl formate, citronellyl nitrile, cyclaset, cyclamenaldehyde, cyclaprop, caron, coumarin, cinnamyl acetate, delta C6-C13 lactone, dimethylbenzyl carbinol, dihydrojasmon , Dihydrolinalool, dihydromyrcenol, dimethol, dimyrcetol, diph Nyl oxide, ethyl vanillin, eugenol, fluitate, fenkyl alcohol, phenyl ethyl phenyl acetate, galaki solid, gamma C6-C13 lactone, geraniol, geranyl acetate, geranyl formate, geranyl nitrile, hedion, helional, heliotropin, cis-3-hexenol Cis-3-hexenyl acetate, cis-3-hexenyl rusalicylate, hexylcinnamic aldehyde, hexyl salicylate, hyacinth dimethyl acetal, hydrotropic alcohol, hydroxycitronellal, indole, isobornyl acetate, isocyclocitral, isoE Super, isoyugenol, isononyl acetate, isobutyl quinoline, jasmar, jasmolact , Jasmofilan, coabon, ligustral, lyial, lime oxide, limonene, linalool, linalool oxide, linalyl acetate and the like.

  In addition, other raw materials known so far, such as α-hydroxy acids, inorganic pigments, ultraviolet absorbers, whitening agents, tyrosinase activity inhibitors, melanin degrading substances, cell activators, astringents , Active oxygen scavenger, antioxidant, lipid peroxide production inhibitor, anti-inflammatory agent, antibacterial agent, moisturizer, elastase activity inhibitor, antiandrogen agent, warming agent, cooling sensation agent, pigment, hormones, metal Ion sequestering agent, pH adjuster, chelating agent, antiseptic and antibacterial agent, cooling agent, stabilizer, emulsifier, animal / plant protein or its degradation product, animal / plant polysaccharide or its degradation product, animal / plant Glycoprotein or its degradation products, anti-inflammatory agents / antiallergic agents, wound treatment agents, foams / foaming agents, thickeners, oral preparations, deodorizing / deodorizing agents, enzymes and the like.

  The deodorant product in which the deodorant of the present invention is used is not particularly limited as long as a deodorant effect is required as well as a deodorant composition (for indoor use, for toilets, for automobiles, etc.). For example, a deodorant cosmetic composition, a bath preparation composition, a detergent composition, etc. are exemplified, and liquid, emulsion, paste, gel, powder (powder), granule, pellet, You may provide as any form, such as stick form and solid form.

  Cosmetic compositions include lotion, milky lotion, cream, oil, ointment, pack, lip, lipstick, foundation, eyeliner, blusher, mascara, eye shadow, nail polish / pedicure, nail coating, nail coating removal Agent, shaving agent, shampoo, rinse, hair treatment, hair tonic, hair spray, hair cream, hair lotion, hair conditioner, hair restorer, permanent liquid, hair dye, hand soap / body soap, toothpaste, mouthwash And facial cleansers and soaps.

  The bath agent composition is used by bathing in bath water at the time of bathing, and may have any properties such as liquid, powder, granule, solid and the like. In the case of a powder, granule or solid, the moisturizing plant extract of the present invention can be produced by spraying and drying in a liquid state without drying.

  Examples of the detergent composition include daily detergents for kitchens, bathrooms, washbasins or toilets, glass cleaners, glasses / contact lens cleaners, car cleaners, and building material cleaners.

  In addition, it can be impregnated in sanitary goods, wet type tissue paper, non-woven fabric, paper towel, cotton and the like.

  In the deodorant composition in which the deodorant of the present invention is used, the deodorant contains about 0.0001 to 5% by mass, preferably about 0.001 to 1% by mass as a dry extract. Good usability and good results. In the deodorant cosmetic composition and the detergent composition, the deodorant contains about 0.001 to 5% by mass, preferably about 0.01 to 1% by mass as a dry extract, and the usability is improved. Good and good effects can be obtained. Moreover, in a bath agent composition, it can be used at 0.001-99 mass%, Preferably when it contains 0.1-30 mass%, usability is good and a favorable result is obtained.

  Although a manufacture example, a test example, and a formulation example are given and demonstrated below, this invention is not limited to these.

[Example 1]
500 mL of water was added to each of the mixed herbal medicines, i.e., 4 g of touki, 4 g of peony, 4 g of senkyu, and 4 g of dianthus, and refluxed for 1 hour. Next, this was filtered to obtain an extract, and further concentrated and dried to obtain 7 g of a tan powder extract.

[Example 2]
500 L of ethanol was added to each constituent herb of Shimototou, ie 4 kg of Toki, 3 kg of peony, 3 kg of Senkyu, 4 kg of Dieu, and extracted by immersion overnight. Next, this was filtered to obtain an extract, and further dried to obtain 2.0 kg of a light brown powdery extract.

[Example 3]
A mixture of 4 g of ginger, 4 g of peonies, 4 g of peony, 4 g of nematode, and 4 g of dianthus was added to 500 mL of a 30% aqueous ethanol solution, followed by reflux extraction for 1 hour. Next, this was filtered to obtain 450 mL of an extract.

Safety test Evaluation of skin irritation In order to evaluate the skin irritation of the deodorant of the present invention, a patch test was conducted by monitoring 42 healthy persons (men and women aged 24 to 58 years).
(Sample) The deodorant obtained in Examples 1 and 2 was swollen with purified water.
(Method) For each sample, the skin sensitization test tape “Fin Chamber” (manufactured by Taisho Pharmaceutical Co., Ltd.) was used to make a determination by applying occlusion for 24 hours on the subject's flexor side and the inner side of the forehead. That is, the sample was removed at the time when 24 hours passed after the application, and after 1 hour, the skin condition was observed to make a judgment.
(Criteria) Judgment was performed according to the following criteria.
(+) Positive: Those with erythema.
(±) false positive: Minor erythema or suspected erythema.
(-) Negative: No reaction is observed.
Table 1 shows the results.

  From Table 1, the skin irritant was not recognized by the deodorizer by this invention.

[Test Example 1]
The deodorizing effect of the deodorizer of the present invention against amine-based and mercaptan-based malodor was measured. Measurement conditions were as follows: 1 mL of the deodorant of Production Example 3 was allowed to stand in a 5 L container, and after filling each malodorous component with a predetermined concentration (ppm), the concentration of the malodorous component was measured over time. The results are shown in Table 2.

  The deodorant of the present invention was effective in amine and mercaptan systems.

[Example 4]
A room deodorant a (liquid type) was prepared according to the following formulation.
Deodorant of Example 2 1.0%
Amphoteric surfactant 0.5%
Green tea extract 0.5%
Tannic acid 0.2%
Preservative 0.1%
The remainder is 100% with purified water.

[Example 5]
A room deodorant b (liquid type) was prepared according to the following formulation.
Deodorant of Example 2 1.0%
Amphoteric surfactant 0.5%
Allantoin 0.1%
Preservative 0.1%
The remainder is 100% with purified water.

[Example 6]
A room deodorant c (liquid type) was prepared according to the following formulation.
Deodorant of Example 2 1.0%
Amphoteric surfactant 1.0%
Ethanol 2.0%
Tea extract 0.2%
Preservative 0.1%
The remainder is 100% with purified water.

[Example 7]
An automotive deodorant (liquid type) was prepared according to the following formulation.
Deodorant of Example 2 1.0%
Nonionic surfactant 5.0%
Ethanol 10.0%
The remainder is 100% with purified water.

[Example 8]
A toilet deodorant (liquid type) was prepared according to the following formulation.
Deodorant of Example 2 1.0%
Nonionic surfactant 2.0%
Ethanol 5.0%
The remainder is 100% with purified water.

[Example 9]
A bath preparation a (liquid type) was prepared according to the following formulation.
Deodorant of Example 2 1.0%
Nonionic surfactant 3.0%
Glycerin 10.0%
Ethanol 5.0%
Preservative 0.1%
The remainder is 100% with purified water.

[Example 10]
Bath preparation b (powder type) was prepared according to the following formulation.
Deodorant of Example 2 1.0%
Sodium sulfate 50.0%
Sodium bicarbonate 49.0%

[Example 11]
An antiperspirant (deodorant spray) was prepared according to the following formulation.
(Stock solution formulation)
Deodorant of Example 2 1.0%
Zinc paraphenol sulfonate 2.0%
1,3-butylene glycol 2.0%
Isopropyl myristate 2.0%
The remainder is 100% with ethanol.
(Filling prescription)
Stock solution 50%
LPG 50%

[Example 12]
A body soap was prepared according to the following formulation.
Deodorant of Example 2 1.0%
Polyoxyethylene (2) sodium lauryl ether sulfate 15.0%
Lauryl sulfate triethanolamine 5.0%
Palm oil fatty acid amidopropyl betaine 5.0%
Ethylene glycol distearate 2.0%
Glycerol monopalmitate 1.0%
Adsorption refined lanolin 2.0%
Glycerin 2.0%
Propylene glycol 3.0%
Preservative 0.1%
The remainder is 100% with purified water.

[Comparative Examples 1-6]
In Examples 4, 7, 8, 9, 11, and 12, instead of the deodorant of the present invention, those in which the blending amount was replaced with purified water (Comparative Examples 1 to 6) were prepared.

[Test Example 2]
The deodorizing effect of the deodorizing products of Examples 4, 7, 8, 9, 11, 12 and Comparative Examples 1 to 6 was evaluated in the following manner.
(1) Implementation Guidelines The indoor deodorant a, bathing agent a, antiperspirant, body soap, indoor / automobile / toilet deodorant (liquid type) manufactured in each example were used as test products (A), A use test was conducted by male and female panelists (17 in total). Let Comparative Examples 1-6 be a comparative product (B), use the test product (A) for one month after the start of the test, and then use the comparative product (B) for the next one month under the following conditions. Asked.
(2) Usage conditions Room deodorant a of Example 4: 100 ml of each was filled in an open container and allowed to stand between 6 tatami mats in Japan.
Deodorant for automobiles of Example 7: 100 ml of each was filled in an open container and fixed under the car seat.
Deodorant for toilet of Example 8: 100 ml of each was filled in an open container and left in the toilet.
Bath agent a of Example 9: 30 g of bath water was poured into about 200 L of bath water (once / day).
Antiperspirant of Example 11: Immediately after face washing in the morning and immediately after bathing at night, 3 g each (once / day) was applied to buds.
Body soap of Example 12: 10ml, (once / day) used during bathing.
(3) Evaluation criteria It evaluated in three steps.
I do not feel bad smell 3
Somewhat bad odor 2
No change 1

  From the above results, all the deodorizing products using the deodorant of the present invention showed an excellent deodorizing effect.

  The deodorant of the present invention is effective against a wide range of bad odors such as amine odor and mercaptan odor, provides a useful deodorant that is safe for the human body, has good solubility and is easy to handle, and has few problems such as coloring. can do

Claims (7)

  A deodorant comprising an extract of a mixture of Toki, Senkyu, Peonies, and Giant.   A deodorant comprising an extract of a mixture of 0.4 to 10.0 parts of Toki, 0.4 to 10.0 parts of Senkyu, 0.4 to 10.0 parts of peony, and 0.4 to 10.0 parts of Ziou.   A deodorant comprising an extract of a mixture of 1.6 to 8.0 parts of Toki, 1.6 to 8.0 parts of Senkyu, 1.6 to 8.0 parts of peony, and 1.6 to 8.0 parts of Diou.   A deodorant comprising an extract of a mixture of 2.8 to 6.0 parts of Toki, 2.8 to 6.0 parts of Senkyu, 2.8 to 6.0 parts of peony, and 2.8 to 6.0 parts of Diou.   The deodorizer according to any one of claims 1 to 4, wherein the deodorizer is an extract of water, alcohols or a mixture thereof.   The amount of the extraction solvent is 10 to 100 times the amount to be extracted, The deodorant according to any one of claims 1 to 4.   A deodorant product comprising the deodorizer according to any one of claims 1 to 6.