JPH0477402A - Acaricidal composition - Google Patents

Acaricidal composition

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Publication number
JPH0477402A
JPH0477402A JP2192261A JP19226190A JPH0477402A JP H0477402 A JPH0477402 A JP H0477402A JP 2192261 A JP2192261 A JP 2192261A JP 19226190 A JP19226190 A JP 19226190A JP H0477402 A JPH0477402 A JP H0477402A
Authority
JP
Japan
Prior art keywords
acaricidal
compound
effects
parts
compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2192261A
Other languages
Japanese (ja)
Other versions
JP2976234B2 (en
Inventor
Masayuki Kimura
雅行 木村
Takamichi Konno
今埜 隆道
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nihon Nohyaku Co Ltd
Original Assignee
Nihon Nohyaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nihon Nohyaku Co Ltd filed Critical Nihon Nohyaku Co Ltd
Priority to JP2192261A priority Critical patent/JP2976234B2/en
Publication of JPH0477402A publication Critical patent/JPH0477402A/en
Application granted granted Critical
Publication of JP2976234B2 publication Critical patent/JP2976234B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE:To obtain the title composition for agriculture showing stable acaricidal effects without causing variability of effects caused by species of crops and with a smaller amount than an amount of single agent by synergistic effects, comprising a specific compound having acaricidal effects and another acaricidal compound as active components. CONSTITUTION:An acaricidal composition comprising well-known tertiarybutyl 4-[(1,3-dimethyl-5-phenoxypyrazol-4-yl)methyleneiminooxymethyl]benzoate shown by the formula having acaricidal effects and another acaricidal compound such as one or more compounds selected from 2,2,2-trichloro-1,1-bis(4-chlorophenyl) ethanol, ethyl 4,4'-dichlorobenzilate, etc., as active ingredients. The blending ratio of the active ingredients is 0.1-100 pts.wt. of the other acaricidal compound based on 1 pt.wt. of the compound shown by the formula. The composition has excellent effects on various kinds of acarides harmful to vegetables, fruits and horticultural crops.

Description

【発明の詳細な説明】 本発明はターツヤリーブチル 4〔(13−ジメチル−
5−フェノキシピラゾール−4イル)メチレンイミノオ
キシメチル〕ヘンシェード(以下、化合物Aという、)
と他の殺ダニ化合物から選択される1種又は2種以上の
化合物を含有することを特徴とする殺ダニ組成物に関す
るものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention provides tertiary butyl 4[(13-dimethyl-
5-phenoxypyrazol-4yl)methyleneiminooxymethyl] Henshade (hereinafter referred to as compound A)
The present invention relates to an acaricidal composition containing one or more compounds selected from the group consisting of acaricidal compounds and other acaricidal compounds.

ソ菜、果樹、園芸作物の害虫であるハダニ類等に対して
は、近年新規な殺ダニ剤が創出されているが、一方では
作物種の違いによる効果の不安定性、又単一の薬剤の重
複使用により効果を示さない薬剤抵抗性ハダニ類の出現
が頻繁に問題となってきている。
New acaricides have been created in recent years for spider mites, which are pests of vegetable crops, fruit trees, and horticultural crops. The emergence of drug-resistant spider mites that are ineffective due to repeated use has become a frequent problem.

本発明者等は作物種による効果の変動がなく、安定した
殺ダニ効果を発揮し、且つ低薬量化を図ることができる
新規殺ダニ組成物の創出に鋭意研究を重ねた結果、化合
物Aと他の殺ダニ活性を有する化合物から選択される1
種又は2種以上の化合物を混合して使用することにより
、それぞれ単独で使用した場合に比して、想到し得ない
程の相乗効果が得られることを見出し、本発明を完成さ
せたものである。
As a result of extensive research into the creation of a new acaricidal composition that does not vary in effectiveness depending on crop species, exhibits a stable acaricidal effect, and is capable of reducing the dosage, the present inventors found that Compound A and 1 selected from other compounds with acaricidal activity
The present invention was completed based on the discovery that by using a species or a mixture of two or more compounds, an unimaginable synergistic effect can be obtained compared to when each is used alone. be.

本発明の一方の有効成分である化合物Aは特開昭63−
183564号公報に記載された、殺ダニ効果を有する
下記構造式で表される公知の化合物である。
Compound A, which is one of the active ingredients of the present invention, is
This is a known compound represented by the following structural formula that has an acaricidal effect and is described in Japanese Patent No. 183564.

本発明の化合物AはE体及び2体の立体異性体を有する
ものであり、本発明はこれらの立体異性体及びこの混合
物をも包含するものであるが、好ましくはE〜異性体が
良い。
Compound A of the present invention has an E-isomer and two stereoisomers, and the present invention includes these stereoisomers and mixtures thereof, but preferably the E-isomer is preferred.

又、他方の有効成分である他の殺ダニ化合物としては、
特に限定されるものではないが、化合物Aと混合した場
合に相乗効果を示す化合物であれば良く、例えば以下に
示す公知の化合物から選択される1種又は2種以上の殺
ダニ化合物を使用することができる。
In addition, other acaricidal compounds that are the other active ingredients include:
Although not particularly limited, any compound that exhibits a synergistic effect when mixed with Compound A may be used; for example, one or more acaricidal compounds selected from the following known compounds may be used. be able to.

(1)、、2.2−トリクロロ−1.1−ビス(4−ク
ロロフェニル)エタノール(以下、化合物1という) (2)、エチル 4,4゛ −ジクロロヘンジレートC
以下、化合物2という) ■、イソプロピル 4.4゛−ジクロロヘンジレート(
以下、化合物3という) ■、ビス〔トリス(2−メチル−2−フェニルプロピル
)チン]オキサイド(以下、化合物4という) (5)、2−(4−ターシャリ−ブチルフェノキシ)シ
クロヘキシル 2−プロピニル サルファイド(以下、
化合物5という) ■、  trans−5(4−クロロフェニル)−N−
シクロヘキシル−4−メチル−2−オキソチアゾリジン
−3−カルボキサミド(以下、化合物6という)。
(1), 2,2-trichloro-1,1-bis(4-chlorophenyl)ethanol (hereinafter referred to as compound 1) (2), ethyl 4,4゛-dichlorohendylate C
(hereinafter referred to as compound 2) ■, isopropyl 4.4゛-dichlorohendylate (
(hereinafter referred to as compound 3) ■, bis[tris(2-methyl-2-phenylpropyl)tin] oxide (hereinafter referred to as compound 4) (5), 2-(4-tert-butylphenoxy)cyclohexyl 2-propynyl sulfide (below,
(referred to as compound 5) ■, trans-5(4-chlorophenyl)-N-
Cyclohexyl-4-methyl-2-oxothiazolidine-3-carboxamide (hereinafter referred to as compound 6).

(7)、3,6−ビス(4−クロロフェニル)−1゜2
.4.5−テトラジン(以下、化合物7という) ■、3−クロローα−エトキシイミノ−2,6−シメト
キシベンジル ベンゾエート(以下、化合物8という) ■、N−メチルビス(2,4−キシリルイミノメチル)
アミン(以下、化合物9という)[相]、  (R3)
−α−シアノ−3−フェノキシベンジル N−(2−ク
ロロ−α、α、α−トリフルオローp−)リルーD−バ
リネート(以下、化合物IOという) ■、5−4−フェノキシブチル N、N−ジメチルチオ
カーバメート(以下、化合物IIという) @、  (R3)−α−シンアノ−3−フェノキシヘン
シル2.2,3.3−テトラメチルシクロプロパンカル
ボキシレート(以下、化合物12という) 以上の殺ダニ化合物を例示することができるが、本発明
はこれらの殺ダニ化合物に限定されるものではない。
(7), 3,6-bis(4-chlorophenyl)-1゜2
.. 4.5-tetrazine (hereinafter referred to as compound 7) ■, 3-chloro α-ethoxyimino-2,6-simethoxybenzyl benzoate (hereinafter referred to as compound 8) ■, N-methylbis(2,4-xylylimino methyl)
Amine (hereinafter referred to as compound 9) [phase], (R3)
-α-cyano-3-phenoxybenzyl N-(2-chloro-α,α,α-trifluoro-p-)lylu-D-valinate (hereinafter referred to as compound IO) ■,5-4-phenoxybutyl N,N- Dimethylthiocarbamate (hereinafter referred to as Compound II) @, (R3)-α-synano-3-phenoxyhensyl 2.2,3.3-tetramethylcyclopropanecarboxylate (hereinafter referred to as Compound 12) The above miticides Although these compounds can be exemplified, the present invention is not limited to these acaricidal compounds.

本発明の化合物Aと組み合わせて使用する上記殺ダニ化
合物のうちで特に好ましい化合物としては、化合物1乃
至7から選択される化合物である。
Among the above acaricidal compounds used in combination with Compound A of the present invention, particularly preferred compounds are compounds selected from Compounds 1 to 7.

本発明の殺ダニ組成物はソ菜、果樹、園芸作物を加害す
る各種ダニ類、例えばナミハダニ、ミカンハダニ、カン
ザワハダニ、リンゴハダニ等のハダニ類に対して、単独
の使用からは想到し得ない相乗効果を奏するものである
The acaricidal composition of the present invention has a synergistic effect against various mites that attack vegetables, fruit trees, and horticultural crops, such as red spider mite, citrus spider mite, Kanzawa spider mite, apple spider mite, etc., which cannot be expected from its use alone. It is something to play.

本発明は、化合物A及び他の殺ダニ活性を有する化合物
から選択される1種又は2種以上の化合物を適当な割合
に配合して、農薬製剤上の常法に従い、使用に都合の良
い剤形に調製して使用すれば良く、例えば乳剤、水和剤
、粉剤、フロアブル剤等に調製して使用すれば良い。
The present invention provides a formulation that is convenient for use by blending one or more compounds selected from Compound A and other compounds with acaricidal activity in appropriate proportions and using the conventional method for agricultural chemical formulations. It may be used by preparing it into a form, for example, an emulsion, a wettable powder, a powder, a flowable agent, etc.

本発明の殺ダニ組成物の有効成分の配合割合は、化合物
A1重量部に対して、他の殺ダニ化合物を0.1〜10
0重量部の範囲の割合で配合すれば良く、好ましくは0
.1〜50重量部の範囲の割合で配合するのが良い。
The blending ratio of the active ingredients in the acaricidal composition of the present invention is 0.1 to 10 parts by weight of other acaricidal compounds to 1 part by weight of compound A.
It may be blended in a proportion within the range of 0 parts by weight, preferably 0 parts by weight.
.. It is preferable to mix it in a proportion ranging from 1 to 50 parts by weight.

本発明の殺ダニ組成物は上記方法により使用に都合の良
い剤形に調製し、使用に際してはそのまま又は水等で所
望の濃度に希釈して使用すれば良い。
The acaricidal composition of the present invention may be prepared into a dosage form convenient for use by the above-mentioned method, and may be used as it is or after being diluted with water or the like to a desired concentration.

以下に本発明の代表的な実施例及び試験例を例示するが
、本発明はこれらに限定されるものではない。
Typical examples and test examples of the present invention are illustrated below, but the present invention is not limited thereto.

尚、実施例中、部とあるのは重量部を示す。In the examples, parts indicate parts by weight.

実施例1゜ 化合物A            3部化合物5   
       30部 含水珪酸           30部ハイテノールN
−08 (第一工業製薬■製)     3部 リグニンスルホン酸カルシウム  2部永和剤用クレー
        32部化合物5を含水珪酸に含浸させ
た後、他の成分と均一に混合して水和剤とする。
Example 1゜Compound A 3 parts Compound 5
30 parts hydrated silicic acid 30 parts Hitenol N
-08 (manufactured by Daiichi Kogyo Seiyaku ■) 3 parts calcium lignin sulfonate 2 parts clay for permanent adhesive 32 parts Compound 5 is impregnated with hydrous silicic acid, and then mixed uniformly with other components to form a wettable powder.

実施例2゜ 化合物A            3部化合物1   
        30部5P−3005X (東邦化学■製)     10部 キシレン           57部以上を均一に混
合溶解し乳剤とする。
Example 2゜Compound A 3 parts Compound 1
30 parts 5P-3005X (manufactured by Toho Kagaku ■) 10 parts xylene 57 parts or more are uniformly mixed and dissolved to form an emulsion.

実施例3゜ 化合物A            3部化合物7   
       30部 NPE−1003部 (第一工業製薬■製) プロピレングリコール      5部ロドポール23
        0.5部(ロース・ブーラン−製) 水                      58
、5部以上を均一に混合し、水に分散させてフロアブル
剤とする。
Example 3゜Compound A 3 parts Compound 7
30 parts NPE-1003 parts (manufactured by Daiichi Kogyo Seiyaku ■) Propylene glycol 5 parts Rhodopol 23
0.5 parts (manufactured by Lois Boulin) Water 58
, 5 parts or more are uniformly mixed and dispersed in water to prepare a flowable agent.

実施例4゜ 化合物A            5部化合物2   
        5部 NPE−1003部 (第−工業製薬味製) プロピレングリコール      5部ロドポール23 (ロース・ブーラン−製)  0.5部水      
                84.5部以上を均
一に混合し、水に分散させてフロアブル剤とする。
Example 4 Compound A 5 parts Compound 2
5 parts NPE-100 3 parts (manufactured by Dai-Kogyo Seiyaku Aji) Propylene glycol 5 parts Rhodopol 23 (manufactured by Loos-Boulin) 0.5 parts water
Mix 84.5 parts or more uniformly and disperse in water to make a flowable agent.

試験例1.カンザワハダニ成虫に対する試験寒天シャー
レに浮かべたインゲン葉のディスクにカンザワハダニの
雌成虫を接種し、所定濃度に希釈した本発明の殺ダニ組
成物の薬液をスプレーガンで50m1散布した。
Test example 1. Test against adult Kanzawa spider mites Female adult Kanzawa spider mites were inoculated onto a disk of green bean leaves floating on an agar petri dish, and 50 ml of the acaricidal composition of the present invention diluted to a predetermined concentration was sprayed with a spray gun.

散布後、25°Cの恒温室に設置し、2日後に生存虫数
を調査し、下記の式に基づいて補正死生率を算出した。
After spraying, the plants were placed in a constant temperature room at 25°C, and two days later, the number of surviving insects was investigated, and the corrected mortality rate was calculated based on the following formula.

1デイスクに10頭接種し、1区当たり30頭供試した
Ten animals were inoculated per disk, and 30 animals per area were tested.

但し、A:無処理区の生存率。However, A: survival rate of untreated area.

B:処理区の生存率。B: Survival rate of treated plot.

結果を第1表に示す。The results are shown in Table 1.

亀−」−一表 結果を第2表に示す。Turtle-”-1 table The results are shown in Table 2.

特許出願人  日本農薬株式会社Patent applicant: Nihon Nohyaku Co., Ltd.

Claims (1)

【特許請求の範囲】 [1]、ターシャリ−ブチル4−〔(1,3−ジメチル
−5−フェノキシピラゾール−4−イル)メチレンイミ
ノオキシメチル〕ベンゾエートと他の殺ダニ化合物から
選択される1種又は2種以上の化合物を含有することを
特徴とする殺ダニ組成物。 [2]、他の殺ダニ化合物が以下の化合物から選択され
る1種又は2種以上である請求項第1項記載の殺ダニ組
成物。 (1)、2,2,2−トリクロロ−1,1−ビス(4−
クロロフェニル)エタノール (2)、エチル4,4’−ジクロロベンジレート(3)
、イソプロピル4,4’−ジクロロベンジレート (4)、ビス〔トリス(2−メチル−2−フェニルプロ
ピル)チン〕オキサイド (5)、2−(4−ターシャリ−ブチルフェノキシ)シ
クロヘキシル2−プロピニルサルファイド (6)、trans−5−(4−クロロフェニル)−N
−シクロヘキシル−4−メチル−2−オキソチアゾリジ
ン−3−カルボキサミド (7)、3,6−ビス(4−クロロフェニル)1,2,
4,5−テトラジン
[Scope of Claims] [1] One species selected from tertiary-butyl 4-[(1,3-dimethyl-5-phenoxypyrazol-4-yl)methyleneiminooxymethyl]benzoate and other acaricidal compounds Or an acaricidal composition characterized by containing two or more kinds of compounds. [2] The acaricidal composition according to claim 1, wherein the other acaricidal compound is one or more selected from the following compounds. (1), 2,2,2-trichloro-1,1-bis(4-
chlorophenyl) ethanol (2), ethyl 4,4'-dichlorobenzilate (3)
, isopropyl 4,4'-dichlorobenzilate (4), bis[tris(2-methyl-2-phenylpropyl)tin]oxide (5), 2-(4-tert-butylphenoxy)cyclohexyl 2-propynyl sulfide ( 6), trans-5-(4-chlorophenyl)-N
-cyclohexyl-4-methyl-2-oxothiazolidine-3-carboxamide (7), 3,6-bis(4-chlorophenyl) 1,2,
4,5-tetrazine
JP2192261A 1990-07-20 1990-07-20 Acaricidal composition Expired - Fee Related JP2976234B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2192261A JP2976234B2 (en) 1990-07-20 1990-07-20 Acaricidal composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2192261A JP2976234B2 (en) 1990-07-20 1990-07-20 Acaricidal composition

Publications (2)

Publication Number Publication Date
JPH0477402A true JPH0477402A (en) 1992-03-11
JP2976234B2 JP2976234B2 (en) 1999-11-10

Family

ID=16288346

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2192261A Expired - Fee Related JP2976234B2 (en) 1990-07-20 1990-07-20 Acaricidal composition

Country Status (1)

Country Link
JP (1) JP2976234B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997039630A1 (en) * 1996-04-22 1997-10-30 Basf Aktiengesellschaft Process and agents for controlling harmful fungi

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997039630A1 (en) * 1996-04-22 1997-10-30 Basf Aktiengesellschaft Process and agents for controlling harmful fungi
US6143745A (en) * 1996-04-22 2000-11-07 Basf Aktiengesellschaft Process and agent for controlling harmful fungi

Also Published As

Publication number Publication date
JP2976234B2 (en) 1999-11-10

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