KR920005587B1 - Pesticidal composition - Google Patents
Pesticidal composition Download PDFInfo
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- KR920005587B1 KR920005587B1 KR1019860001310A KR860001310A KR920005587B1 KR 920005587 B1 KR920005587 B1 KR 920005587B1 KR 1019860001310 A KR1019860001310 A KR 1019860001310A KR 860001310 A KR860001310 A KR 860001310A KR 920005587 B1 KR920005587 B1 KR 920005587B1
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- activated carbon
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- carbon powder
- insecticides
- powder
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
Abstract
내용 없음.No content.
Description
본 발명은 2-3급-부틸이미노-3-이소프로필-5-페닐-3,4,5,6-테트라하이드로-2H-1,3,5-티아디아진-4-온[이하, 부프로페진(Buprofezin)이라고 한다]에 활성탄 분말을 배합하여 수득됨을 특징으로 하는 농약 조성물에 관한 것이다.The present invention relates to 2-3-butylimino-3-isopropyl-5-phenyl-3,4,5,6-tetrahydro-2H-1,3,5-thiadiazin-4-one [hereinafter, It relates to a pesticide composition characterized in that it is obtained by combining activated carbon powder with Buprofezin.
부프로페진은 일본국 공개 특허 공보 제 (소) 55-53206호 및 일본국 공개 특허 공보 제 (소) 57-31603호 등에 기재되어 있는 바와 같이, 벼의 해충인 토비이로운카, 히메토비운카, 세지로운카 등의 운카류, 쓰마그로요꼬바이 등 ; 오이, 가지 및 토마토의 해충인 온시쓰꼬나지라미 등 ; 감귤류의 해충인 야노네카이가라무시 ; 및 차의 해충인 구와시로 카이가라무시, 치야노미도리요꼬바이 등, 광범위한 해충에 대하여 장기간에 걸쳐 우수한 살충효과를 나타내는 살충제이다.Buprofezin is described in Japanese Patent Application Laid-Open No. 55-53206 and Japanese Patent Application Laid-Open No. 57-31603 and the like. Unka Ryu, Semaguroka, etc .; Onshitsu Konji-rami, etc. which are pests of cucumber, eggplant, and tomato; Yanoneka Igaramushi which is a pest of citrus fruits; And insecticides that exhibit excellent insecticidal effects over a long period of time against a wide range of pests such as Kushiro Kaigaramushi and Chiyano Midoriyokobai, which are pests of tea.
그러나 약제 처리시의 기온이 고온으로 될수록 부프로페진이 휘산하여 원하는 목적인 잔효성이 수득되지 않는 것으로 판명되었다.However, it was found that the higher the temperature at the time of drug treatment, the more the bupropezin volatilized to obtain the desired residue.
본 발명자들은 상기 기상조건에 의한 부프로페진의 휘산을 억제하여 안정한 장기간에 걸친 효과를 유지하는 약제를 수득하기 위해서 연구를 거듭한 결과, 분말 활성탄을 첨가함으로써 휘산이 억제되어 잔효성이 유지되는 것을 발견하여 본 발명을 완성시킨 것이다.The present inventors have conducted studies to obtain a drug that suppresses the volatilization of buprofezin under the above-mentioned gas phase conditions and maintains a stable long-term effect. It has found and completed the present invention.
일본국 공개 특허 공보 제 (소) 55-38326호에는 활성탄 분말에 피레스로이드계 살충제를 흡착시켜 수득되는 살충 조성물이 기재되어 있다. 이것은 피레스로이드계 살충제를 활성탄 분말에 직접 흡착시킴으로써 속효성과 잔효성을 얻는 것을 목적으로 한다. 또한 일본국 공개 특허 공보 제 (소) 56-169601호에는 25℃에서 수용 용해도가 5ppm인 농약 활성성분을 활성탄 및 1종 또는 2종 이상의 식물성 기름에 배합하여 수득되는 서방성 농약 입상 조성물이 기재되어 있다. 이것도 유효성분을 활성탄에 흡착시켜 유효성분을 서서히 방출시키는 기술이지만, 식물성 기름의 첨가량을 조정함으로써 방출량도 조절하여 잔효성을 유지하는 것이다.Japanese Laid-Open Patent Publication No. 55-38326 describes a pesticidal composition obtained by adsorbing a pyrethroid insecticide to activated carbon powder. This aims to obtain fast-acting and residual properties by directly adsorbing a pyrethroid insecticide to activated carbon powder. In addition, Japanese Laid-Open Patent Publication No. 56-169601 discloses a sustained-release pesticide granular composition obtained by blending an agricultural chemical active ingredient having an aqueous solubility of 5 ppm at 25 ° C. with activated carbon and one or two or more vegetable oils. have. This is also a technique of adsorbing an active ingredient to activated carbon to gradually release the active ingredient, but by adjusting the amount of vegetable oil added, the release amount is also adjusted to maintain residual activity.
그러나 본 발명에서는 상기한 선행기술과는 달리, 활성탄 분말을 무기 중량제의 일부 또는 무기 중량제에 가하여 사용함으로써, 약제 산포시의 온도가 비교적 낮은 경우, 즉 식물체에 부착된 부프로페진의 휘산이 일어나기 어려운 조건하에서는, 활성탄 분말은 무기 중량제로서 작용하고, 온도가 높은 경우, 즉 부프로페진의 휘산이 일어나기 쉽다고 여겨지는 조건하에서는, 활성탄 식물체에 부착된 부프로페진으로부터 휘산한 부프로페진을 모아 서서히 방산시켜, 그 결과 유효성분의 휘산에 의한 손실을 방지하는 동시에 소기의 잔효성도 유지할 수 있다.However, in the present invention, unlike the prior art described above, by using activated carbon powder in part of an inorganic weight agent or an inorganic weight agent, when the temperature at the time of drug dispersion is relatively low, that is, the volatilization of buprofezin attached to a plant is reduced. Under conditions that are unlikely to occur, the activated carbon powder acts as an inorganic weighting agent, and when the temperature is high, i.e., under conditions that are likely to result in volatilization of buprofezin, bupropazine volatilized from buprofezin attached to the activated carbon plant is collected. By gradually dissipating, as a result, the loss due to volatilization of the active ingredient can be prevented and the desired residual activity can be maintained.
본 발명에 따라서 부프로페진을 분제, 수화제, 과립수화제, 현탁제 또는 유동산제(flow dust)등의 제제 형태로서 사용하는 경우, 약제 처리후의 온도조건에 의한 부프로페진의 휘산을 억제하기 위해서 증량제의 일부 또는 증량제에 가하여 활성탄 분말을 배합하면 좋다.In the case of using buprofezin in the form of a powder, a hydrating agent, a granulating agent, a suspending agent or a flow dust according to the present invention, an extender for suppressing volatilization of buprofezin due to temperature conditions after treatment with a drug It is good to mix | blend activated carbon powder with a part or extender of this.
활성탄 분말은 부프로페진 1중량부에 대하여 0.2 내지 10중량부의 비율로 배합하는 것이 바람직하다.Activated carbon powder is preferably blended at a ratio of 0.2 to 10 parts by weight with respect to 1 part by weight of buprofezin.
본 발명에서 사용가능한 활성탄 분말은, 수증기로 활성화시키거나 염화아연으로 활성화시킨 야자수껍질활성탄, 목탄, 톱밥탄, 골탄 등의 어느 것도 좋고, 활성탄의 입도도 필요에 따라 적절히 선택하면 좋다.The activated carbon powder usable in the present invention may be any one of palm-bark activated carbon, charcoal, sawdust charcoal, bone charcoal and the like activated by water vapor or zinc chloride, and the particle size of the activated carbon may be appropriately selected as necessary.
활성탄 분말은 단독으로 또는 기타 무기 증량제와 조합하여 사용할 수도 있고, 사용가능한 무기 증량제로서는 점토, 활석, 탄산칼슘, 규조토, 석고, 벤토나이트, 산성벡토, 함수규산, 규산칼슘 등의 무기 증량제를 열거할 수 있고, 이들로 한정되는 것은 아니다.Activated carbon powder may be used alone or in combination with other inorganic extenders, and usable inorganic extenders may include inorganic extenders such as clay, talc, calcium carbonate, diatomaceous earth, gypsum, bentonite, acidic becto, hydrous silicic acid and calcium silicate. It is not limited to these.
본 발명의 유효성분인 부프로페진은 단독 또는 기타 살충제 또는 살균제와 혼합하여 사용할 수 있다.Buprofezin, the active ingredient of the present invention, may be used alone or in admixture with other insecticides or fungicides.
사용되는 살충제로서는, MIPC, MTMC, BPMC, NAC, MPMC, XMC 등의 카바메이트계 살충제, 다이아지논, 아세페이트, DMTP, PAP, 클로로피리포스메틸, MEP, 아조드린, 피리다펜치온 등의 유기인계 살충제, 펜발레레이트, 델타메트린 등의 합성 피레스로이드계 살충제, 칼탑, 티오시그람 등을 열거할 수 있다.Examples of the pesticide to be used include organic compounds such as carbamate insecticides such as MIPC, MTMC, BPMC, NAC, MPMC, and XMC, diazinone, acetate, DMTP, PAP, chloropyriphosphmethyl, MEP, azodrin, and pyridaphenthione. Synthetic pyrethroid insecticides, such as a phosphorus insecticide, penvalerate, and deltamethrin, a caltop, a thioggram, etc. can be mentioned.
사용되는 살균제로서는 이소브로티오란, 푸사라이드, TPN, IBP, EDDP, 블라스트 사이진 S, 폴리옥신, 캅탄, 다이포르탄, 티오파네이트, 베노밀 등을 열거할 수 있다.Examples of the fungicides to be used include isobrothioranes, fusrides, TPNs, IBPs, EDDPs, blast cysine S, polyoxins, captans, dipotanes, thiophanates, and benomils.
본 발명의 농약 조성물은 농약 제제상의 통상적인 방법에 따라 분제, 수화제, 과립수화제, 현탁제, 유동산제(flow dust)등의 제형으로 조정할 수 있다.The pesticide composition of the present invention can be adjusted to formulations such as powders, hydrating agents, granulating agents, suspending agents, flow dusts and the like according to conventional methods on pesticide formulations.
이하에 실시예와 시험예를 열거하지만 본 발명은 이들로 한정되는 것은 아니다. 이하에서 부는 중량부를 나타낸다.Examples and test examples are listed below, but the present invention is not limited thereto. In the following, parts represent parts by weight.
[실시예 1]Example 1
부프로페진 25.0부Buprofezin 25.0
NPE 100 0.5부NPE 100 0.5part
나트륨 라우릴설페이트 2.0부Sodium lauryl sulfate 2.0part
리그닌 설폰산나트륨 3.0부Lignin Sodium Sulfonate 3.0parts
활성탄 분말 25.0부Activated carbon powder 25.0 parts
점토 44.5부Clay Part 44.5
이상의 성분들을 균일하게 혼합분쇄하여 수화제로 만든다.The above components are mixed and ground uniformly to obtain a hydrate.
[실시예 2]Example 2
부프로페진 5.0부Buprofezin 5.0
다이아지논 폴리옥시에틸레노닐페닐에테르 25.0부25.0 parts of diazinon polyoxyethylenonylphenyl ether
암모늄 설페이트 2.5부2.5 parts ammonium sulfate
리그닌설폰산칼슘 4.0부Ligninsulfonate calcium 4.0parts
함수규산(시오노 타다시 세이야꾸제 카플렉스 #1120) 25.0부Water silicate (Shioku Tadashi Seiyaku Co., Ltd. Carplex # 1120) Part 25.0
활성탄 분말 10.0부Activated carbon powder 10.0 parts
탄산칼슘 28.5부Calcium Carbonate 28.5 parts
다이아지논을 함수규산 #1120에 함침시킨 후, 기타 성분을 가하여 균일하게 혼합분쇄하여 수화제로 한다.Diazinone is impregnated in hydrous silicic acid # 1120, and then mixed with the other components to be uniformly ground to obtain a hydrate.
[실시예 3]Example 3
부프로페진 5.0부Buprofezin 5.0
BPMC 폴리옥시에틸렌 노닐페닐 25.0부BPMC polyoxyethylene nonylphenyl 25.0 parts
에테르 암모늄설페이트 2.5부2.5 parts ether ammonium sulfate
리그닌 설폰산칼슘 4.0부Lignin calcium sulfonate4.0part
함수규산(시오노 타다시 세이야꾸제 카플렉스 #80) 10.0부Moisture Silicate (Ciplex # 80 made by Seion Tadashi Seiyaku) Part 10.0
활성탄 분말 10.0부Activated carbon powder 10.0 parts
점토 43.5부Clay Part 43.5
이상의 성분들을 균일하게 혼합분쇄하여 수화제로 만든다.The above components are mixed and ground uniformly to obtain a hydrate.
[실시예 4 ]Example 4
부프로페진 1.5부Buprofezin 1.5 parts
이소프로필인산 0.15부Isopropyl phosphate 0.15part
활성탄 분말 3.0부Activated Carbon Powder 3.0 parts
탄산칼슘 30.0부Calcium Carbonate 30.0parts
점토 65.35부Clay Part 65.35
이상의 성분들을 균일하게 혼합분쇄하여 분제를 만든다.The above components are mixed and ground uniformly to form a powder.
[실시예 5]Example 5
부프로페진 50.0부Buprofezin 50.0 parts
폴리옥시에틸레노닐 페닐에테르 암모늄설페이트 2.0부2.0 parts of polyoxyethylenonyl phenylether ammonium sulfate
폴리옥시에틸렌 스티렌화 페닐에테르 암모늄 설페이트 2.0부2.0 parts of polyoxyethylene styrenated phenylether ammonium sulfate
리그닌설폰산칼슘 3.0부Lignin sulfonate calcium 3.0 parts
전분 10.0부10.0 parts of starch
활성탄 분말 20.0부Activated carbon powder 20.0 parts
라지오라이트 #200 13.0부Rajio Light # 200 Part 13.0
부프로페진, 전분, 라지오라이트 및 활성탄 분말을 균일하게 혼합분쇄하고, 물에 용해시킨 계면활성제를 가하여 습화혼합시킨 다음, 0.7mm 스크린의 압출조립기로 조립하고, 이어서 50℃에서 건조시켜 과립수화제로 만든다.Uniformly pulverize buprofezin, starch, ragiolite and activated charcoal powder, add water-dissolved surfactant to wet mix, assemble into an extrusion granulator of 0.7 mm screen, and then dry at 50 ° C. Make.
[실시예 6]Example 6
부프로페진 40.0부Buprofezin 40.0 parts
NPE 100 1.5부NPE 100 1.5
폴리옥시에틸렌 스티렌화페닐 에테르(40% 액) 2.0부2.0 parts of polyoxyethylene styrenated phenyl ether (40% liquid)
폴리옥시에틸렌 노닐페닐에테르 포르말린 축합물(40% 액) 3.0부3.0 parts of polyoxyethylene nonylphenyl ether formalin condensate (40% liquid)
실리콘 오일(신에쯔 실리콘제 KM-73 0.5부Silicone oil (0.5 parts of KM-73 made from Shin-Etsu Silicone
프로필렌 글리콜 5.0부Propylene glycol 5.0 parts
크산탄껌 1.5부Xanthan gum 1.5 parts
활성탄 분말 10.0부Activated carbon powder 10.0 parts
물 36.5부36.5 parts of water
계면활성제, 프로필렌 글리콜, 크산탄껌, 실리콘오일 및 물의 용액에 부프로페진과 활성탄 분말을 가하고, 습식 분쇄기(샌드글라이더-이가라 시키카이샤제)로 분쇄하여 현탁제로 만든다.Bupropezin and activated carbon powder are added to a solution of surfactant, propylene glycol, xanthan gum, silicone oil and water, and ground by a wet grinder (manufactured by Sandglider-Igara Shikishaisha) to make a suspension.
[실시예 7]Example 7
부프로페진 20부Buprofezin 20 parts
기계유 40부40 parts of machine oil
백등유 15부White kerosene 15
메틸 나프탈레 5부Methyl naphthale part 5
폴리옥시에틸렌 올레일 에테르 5부5 parts polyoxyethylene oleyl ether
활성탄 분말 15부Activated Carbon Powder, Part 15
계면활성제를 함유하는 용제에 부프로페진과 활성탄을 가하고, 습식 분쇄기로 분쇄하여 오일 기본 유동제(oil base flowable)를 수득한다.Bupropazine and activated carbon are added to a solvent containing a surfactant and pulverized with a wet mill to obtain an oil base flowable.
[비교예 1]Comparative Example 1
실시예 1의 활성탄 분말 대신에 점토 69.5부를 사용하여 수화제를 수득한다.69.5 parts of clay are used instead of the activated carbon powder of Example 1 to obtain a hydrating agent.
[비교예 2]Comparative Example 2
실시예 2의 활성탄 분말 대신에 탄산칼슘 38.5부를 사용하여 수화제를 수득한다.38.5 parts of calcium carbonate was used instead of the activated carbon powder of Example 2 to obtain a hydrating agent.
[비교예 3]Comparative Example 3
실시예 3의 활성탄 분말 대신에 점토 53.5부를 사용하여 수화제를 수득한다.53.5 parts of clay are used instead of the activated carbon powder of Example 3 to obtain a hydrating agent.
[비교예 4][Comparative Example 4]
실시예 4의 활성탄 분말 대신에 점토 68.35부를 사용하여 분제를 수득한다.68.35 parts of clay is used instead of the activated carbon powder of Example 4 to obtain a powder.
[비교예 5][Comparative Example 5]
실시예 5의 활성탄 분말 대신에 라지오라이트 #200을 33.0부를 사용하여 과립수화제를 수득한다.33.0 parts of Ratiolite # 200 was used instead of the activated carbon powder of Example 5 to obtain a granulating agent.
[비교예 6]Comparative Example 6
실시예 6의 활성탄 분말 대신에 함수규산(시오노 타다시 세이야꾸제 약제 카플렉스 #80) 3부 및 물 43.5부를 사용하여 현탁제를 수득한다.Instead of the activated carbon powder of Example 6, 3 parts of hydrous silicic acid (Shiono Tadashi Seiyaku Pharmaceutical Carplex # 80) and 43.5 parts of water were used to obtain a suspending agent.
[비교예 7]Comparative Example 7
실시예 7의 활성탄 분말 대신에 기계유 55부를 사용하여 오일 기본 유동제를 수득한다.55 parts of machine oil is used instead of the activated carbon powder of Example 7 to obtain an oil base flow agent.
[시험예 1][Test Example 1]
휘산성 시험 실시예 및 비교예의 수화제, 과립수화제, 현탁제 및 오일 기본 유동제는 부프로페진으로서 100ppm이 되도록 물로 희석하고, 이의 1ml를 직경이 9cm인 샤알레에 균일하게 산포하여 공기 건조시킨다. 분제는 부프로페진으로서 100㎍을 직접 직경이 9cm인 샤알레에 균일하게 산포한다. 40℃의 항온기에 샤알레를 보존하고, 시간이 경과함에 따라 꺼내어 잔존 부프로페진양을 기체 크로마토그라피로 산출한다. 결과는 표 1에 나타낸다.Volatile test Examples and comparative examples of the wetting agent, granulating agent, suspending agent and oil base fluid are diluted with water to 100 ppm as buprofezin, and 1 ml thereof is uniformly dispersed in 9 cm diameter chaile and air dried. The powder is evenly disperse 100 μg as buprofezin directly in a 9 cm diameter chalet. Shale is preserve | saved in the thermostat of 40 degreeC, and it takes out as time passes and the amount of remaining buprofezin is computed by gas chromatography. The results are shown in Table 1.
[제1 표][Table 1]
[시험예 2][Test Example 2]
잔효성 시험Residual Test
실시예 및 비교예의 수화제, 과립수화제, 현탁제 및 오일 기본 유동제는 유효성분이 200ppm으로 되도록 물로 조정하고, 50ml를 분무기로 직경이 180cm인 포트(pot)에 심은 논벼에 산포하여 온실에 둔다. 분제는 3kg/10a 상당량의 약제를 진공벨쟈(beljar)로 직경이 18cm인 포트에 심은 논벼에 산포하여 온실내에 둔다. 약제 산포 직후 및 일정 일수 경화후의 각 포트에 1포트당 40두의 토비이로운카 3일째 유층을 접종하고, 각 포트에 대하여 접종 7일후에 사충수를 조사한다. 보정 사충율은 하기식으로 산출한다.The hydrating agents, granulating hydrating agents, suspending agents and oil base fluids of the Examples and Comparative Examples were adjusted with water so that the active ingredient was 200 ppm, and 50 ml was sprayed on rice planted in a pot of 180 cm in diameter with a sprayer and placed in a greenhouse. The powder is sprayed on a rice planted in an 18 cm diameter pot with a vacuum beljar, equivalent to 3 kg / 10a, and placed in a greenhouse. Immediately after drug spreading and for a certain number of days, each pot was inoculated with 40 oil-bearing oils per port on day 3, and each port was examined 7 days after inoculation. The calibrated mortality rate is computed by the following formula.
결과는 제2표에 나타낸다.The results are shown in Table 2.
[제2 표][Table 2]
Claims (6)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP36115 | 1985-02-25 | ||
| JP60036115A JPS61197503A (en) | 1985-02-25 | 1985-02-25 | Agricultural chemical composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR860006207A KR860006207A (en) | 1986-09-09 |
| KR920005587B1 true KR920005587B1 (en) | 1992-07-09 |
Family
ID=12460778
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019860001310A KR920005587B1 (en) | 1985-02-25 | 1986-02-25 | Pesticidal composition |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS61197503A (en) |
| KR (1) | KR920005587B1 (en) |
| CN (1) | CN86101763B (en) |
| FR (1) | FR2577759B1 (en) |
| GB (1) | GB2172804B (en) |
| HK (1) | HK51192A (en) |
| MY (1) | MY101853A (en) |
| PH (1) | PH23575A (en) |
| SG (1) | SG8690G (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2522935B2 (en) * | 1987-03-13 | 1996-08-07 | 日本農薬株式会社 | Insecticidal composition with improved residual effect |
| FR2837066B1 (en) * | 2002-03-14 | 2004-07-16 | Michel Gentet | PHYTOSANITARY COMPOSITION COMPRISING AN ACTIVE INGREDIENT AND A POWDER COMPOUND AND APPLICATION TO FIGHTING IN PARTICULAR AGAINST METCALFA PRUINOSA |
| CN101189967B (en) * | 2007-05-18 | 2010-04-14 | 陆剑飞 | Insecticidal composition |
| DE102009022893A1 (en) * | 2009-05-27 | 2010-12-02 | Bayer Technology Services Gmbh | Powder formulations with adsorbent particles |
| CN102084863B (en) * | 2011-03-01 | 2012-03-28 | 宁波市鄞州浩斯瑞普生物科技有限公司 | Slow-release preparation of slow-release thiadiazine substances |
| CN102273472A (en) * | 2011-08-16 | 2011-12-14 | 江苏东宝农药化工有限公司 | Compounded pesticide composite containing methyl carbamate and buprofezin and preparation method thereof |
| CN102986697A (en) * | 2012-12-24 | 2013-03-27 | 海利尔药业集团股份有限公司 | Insecticide-acaricide composition containing buprofezin and bifenazate |
| CN103271073B (en) * | 2013-06-18 | 2014-07-30 | 陕西农心作物科技有限公司 | Insecticidal composition containing epoxy worm moiety and buprofezin |
| BR112015032025A8 (en) * | 2013-06-21 | 2018-03-06 | Basf Se | concentrated composition, composition preparation process, suspension and method of controlling unwanted insect or mite attack |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS543083A (en) * | 1977-06-09 | 1979-01-11 | Nippon Nohyaku Co Ltd | Tetrahydro-1,3,5-thiadiazin-4-ones and insecticide-miticide containing the same |
| GB1592043A (en) * | 1977-06-09 | 1981-07-01 | Nihon Nohyaku Co Ltd | Tetrahydro-1,3,5-thiadiazin-4-one derivatives |
| JPS5538326A (en) * | 1978-09-11 | 1980-03-17 | Lion Corp | Insecticidal composition |
-
1985
- 1985-02-25 JP JP60036115A patent/JPS61197503A/en active Granted
-
1986
- 1986-02-24 CN CN86101763A patent/CN86101763B/en not_active Expired
- 1986-02-24 GB GB08604517A patent/GB2172804B/en not_active Expired
- 1986-02-24 FR FR868602503A patent/FR2577759B1/en not_active Expired - Fee Related
- 1986-02-25 KR KR1019860001310A patent/KR920005587B1/en not_active IP Right Cessation
- 1986-02-26 PH PH33447A patent/PH23575A/en unknown
-
1987
- 1987-09-21 MY MYPI87001806A patent/MY101853A/en unknown
-
1990
- 1990-02-06 SG SG86/90A patent/SG8690G/en unknown
-
1992
- 1992-07-09 HK HK511/92A patent/HK51192A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| GB2172804A (en) | 1986-10-01 |
| GB2172804B (en) | 1988-06-15 |
| MY101853A (en) | 1992-01-31 |
| JPS61197503A (en) | 1986-09-01 |
| FR2577759B1 (en) | 1991-11-22 |
| SG8690G (en) | 1991-01-18 |
| PH23575A (en) | 1989-09-11 |
| CN86101763B (en) | 1988-10-19 |
| KR860006207A (en) | 1986-09-09 |
| HK51192A (en) | 1992-07-17 |
| CN86101763A (en) | 1986-09-24 |
| GB8604517D0 (en) | 1986-04-03 |
| FR2577759A1 (en) | 1986-08-29 |
| JPH0566362B2 (en) | 1993-09-21 |
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