JPH0468292B2 - - Google Patents
Info
- Publication number
- JPH0468292B2 JPH0468292B2 JP61102471A JP10247186A JPH0468292B2 JP H0468292 B2 JPH0468292 B2 JP H0468292B2 JP 61102471 A JP61102471 A JP 61102471A JP 10247186 A JP10247186 A JP 10247186A JP H0468292 B2 JPH0468292 B2 JP H0468292B2
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- catalyst
- synthesis gas
- stream
- hour
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000015572 biosynthetic process Effects 0.000 claims description 42
- 238000003786 synthesis reaction Methods 0.000 claims description 42
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 40
- 239000003054 catalyst Substances 0.000 claims description 39
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 15
- 239000005977 Ethylene Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 11
- 239000002131 composite material Substances 0.000 claims description 5
- 239000010457 zeolite Substances 0.000 claims description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 239000010948 rhodium Substances 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 75
- 239000007789 gas Substances 0.000 description 29
- 229910052799 carbon Inorganic materials 0.000 description 21
- 235000019441 ethanol Nutrition 0.000 description 21
- 238000006297 dehydration reaction Methods 0.000 description 14
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 14
- 230000018044 dehydration Effects 0.000 description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
- 229910004298 SiO 2 Inorganic materials 0.000 description 10
- 238000001816 cooling Methods 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 230000002194 synthesizing effect Effects 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910011212 Ti—Fe Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 229910052675 erionite Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61102471A JPS62258328A (ja) | 1986-05-02 | 1986-05-02 | 合成ガスからのエチレンの選択的合成方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61102471A JPS62258328A (ja) | 1986-05-02 | 1986-05-02 | 合成ガスからのエチレンの選択的合成方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62258328A JPS62258328A (ja) | 1987-11-10 |
| JPH0468292B2 true JPH0468292B2 (es) | 1992-11-02 |
Family
ID=14328363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61102471A Granted JPS62258328A (ja) | 1986-05-02 | 1986-05-02 | 合成ガスからのエチレンの選択的合成方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62258328A (es) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008110302A (ja) * | 2006-10-30 | 2008-05-15 | National Institute Of Advanced Industrial & Technology | エチレン製造用触媒 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6333342A (ja) * | 1986-07-29 | 1988-02-13 | Agency Of Ind Science & Technol | 合成ガスからのエチレンの製造法 |
| JPH0665384B2 (ja) * | 1987-12-21 | 1994-08-24 | 日揮株式会社 | 触媒の再生方法 |
| JP2006116439A (ja) * | 2004-10-21 | 2006-05-11 | National Institute Of Advanced Industrial & Technology | エチレン製造用触媒およびこの触媒を用いるエチレンの製造方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5692825A (en) * | 1979-12-18 | 1981-07-27 | Haldor Topsoe As | Method and catalyst for manufacturing gas mixture containing high quantity of c22hydrocarbons |
| JPS57159723A (en) * | 1981-03-30 | 1982-10-01 | Idemitsu Kosan Co Ltd | Selective preparation of lower unsaturated hydrocarbons |
| JPS60246329A (ja) * | 1984-05-21 | 1985-12-06 | Toyota Central Res & Dev Lab Inc | 炭化水素の合成方法 |
| JPS6183134A (ja) * | 1984-09-28 | 1986-04-26 | Agency Of Ind Science & Technol | 不飽和炭化水素の製造法 |
-
1986
- 1986-05-02 JP JP61102471A patent/JPS62258328A/ja active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5692825A (en) * | 1979-12-18 | 1981-07-27 | Haldor Topsoe As | Method and catalyst for manufacturing gas mixture containing high quantity of c22hydrocarbons |
| JPS57159723A (en) * | 1981-03-30 | 1982-10-01 | Idemitsu Kosan Co Ltd | Selective preparation of lower unsaturated hydrocarbons |
| JPS60246329A (ja) * | 1984-05-21 | 1985-12-06 | Toyota Central Res & Dev Lab Inc | 炭化水素の合成方法 |
| JPS6183134A (ja) * | 1984-09-28 | 1986-04-26 | Agency Of Ind Science & Technol | 不飽和炭化水素の製造法 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008110302A (ja) * | 2006-10-30 | 2008-05-15 | National Institute Of Advanced Industrial & Technology | エチレン製造用触媒 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62258328A (ja) | 1987-11-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9957206B2 (en) | Hydrocarbon conversion | |
| KR100192527B1 (ko) | 수소가 풍부한 기체의 제조방법 | |
| Raja et al. | Direct conversion of methane to methanol | |
| US5233113A (en) | Process for converting lower alkanes to esters | |
| TW413674B (en) | Process for the preparation of acetic acid | |
| CA1061805A (en) | Conversion of synthesis gas to aromatic hydrocarbons | |
| US6376562B1 (en) | Hybrid catalyst for hydrocarbon synthesis via hydrogenation of carbon dioxide | |
| JP2000501735A (ja) | 酸素結合化合物の転化における遷移金属含有小孔分子篩触媒の使用 | |
| US5840969A (en) | Process for the preparation of acetic acid from a synthesis gas of hydrogen and carbon monoxide | |
| CN101410353B (zh) | 丙烯的制造方法 | |
| JPH01146837A (ja) | シクロヘキセノンの脱水素方法 | |
| Klier et al. | Catalytic synthesis of methanol, higher alcohols and ethers | |
| EP0009976A1 (en) | Process for the production of amorphous aluminosilicates and their use as catalysts | |
| SU1194267A3 (ru) | Способ получени олефинов @ - @ | |
| JPH0468292B2 (es) | ||
| Park et al. | Catalytic reduction of carbon dioxide. The effects of catalysts and reductants | |
| Hutchings et al. | Methanol Conversion to Hydrocarbons over Zeolite H-ZSM-5: Investigation of the Role of CO and Ketene in the Formation of the Initial C C Bond | |
| WO2000029364A1 (en) | Preparation of polyoxymethylene dimethyl ethers by reaction of dimethylether with formaldehyde over heterogeneous catalysts | |
| EP0256479A2 (en) | Process for the catalytic transhalogenation of a poly-iodo-benzene | |
| CN107814690B (zh) | 一种乙二醇单甲醚的转化方法 | |
| US4393144A (en) | Method for producing methanol | |
| US4982032A (en) | Process for converting a wet acetylene-containing stream to aromatics using a zinc-promoted, crystalline, borosilicate molecular sieve catalyst composition | |
| JPS58116425A (ja) | ベンゼン、トルエン及びキシレンに富んだ炭化水素混合物の製法 | |
| CN111514940A (zh) | 一种一步法制备丙酮的催化剂、其制备方法及其应用 | |
| KR20190053339A (ko) | 메탄올의 제조 방법 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |